Science 14 Alchemy was a subject that consisted of religion, science, and philosophy practiced from ancient times until the eighteenth century. Many alchemists spent their time trying to find mixtures that would bring a greater understanding of eternal life. Other alchemists tried to find ways to change inexpensive raw materials into gold. Hennig Brand – discovered phosphorous Phosphorous is a substance that glows in the dark The early Greeks believed that all matter was made up of only four elements: earth, air, fire and water. This theory has since been replaced. By the mid-1860s, scientists had discovered 64 elements and had recorded many of their properties. Elements are substances that cannot be broken down into other substances and contain only one kind of atom. How can we organize this information? Science Background: The development of the periodic table was a milestone in the study of chemistry. It let scientists quickly determine which elements have similar physical and chemical properties, and predict an element’s properties based on its location in the table. Although elements can be grouped according to their physical and chemical properties, each element has its own unique set of characteristics (e.g., melting point, boiling point, and density) that are slightly different from those of all neighbouring elements. This fact helped disprove early theories that only four elements existed. Careful measurements and investigations allowed scientists to discover many elements, each with its own unique physical and chemical properties. John Dalton described elements based on their relative mass. Using his work, we now know that different elements with equal volumes have different masses when compared to each other. For example, if you took one litre of hydrogen and compared its mass to the same volume of oxygen, the oxygen would be eight times heavier. Dmitri Mendeleev wrote all the information for each element on a separate file card and then put elements with similar properties in columns. He organized the elements within each group from lightest to heaviest. Then he organized the groups so that the lightest elements were on the left side of the table and the heaviest were on the right side. Mendeleev noticed that some elements seemed to be missing. He predicted these elements existed but had not yet been discovered. He made cards for the missing elements and even predicted their properties Mendeleev’s work provided the basis for the periodic table! The periodic table is a chart on which scientists have organized all of the elements. Mendeleev worked with 64 elements. Since then, the number of elements has grown to 112. Many of Mendeleev’s predicted elements have been discovered. http://www.pbs.org/wgbh/nova/education/ physics/developing-periodic-table.html http://science.discovery.com/tv- shows/greatest-discoveries/videos/100greatest-discoveries-shorts-periodictable.htm Elements in Mendeleev’s chart are made of atoms. Atoms are the smallest units of matter. Periodic tables do not all look the same but they do have some things in common: They all look like a chart. Each square of the table includes information about one element. Periodic Table: Patterns and Trends The elements in the periodic table are arranged in columns and rows so that elements with similar properties appear together. Columns = groups Rows = periods The modern periodic table separates metals from non-metals using a staircase-like division on the right side. Elements around this staircase have properties of both metals and non-metals. They are called metalloids. For example, silicon is a dull, brittle solid that conducts electricity well. Metals and Non-Metals Metals Non-Metals -Bright metallic shine (lustre) -Easily shaped (malleable) -Solids (except mercury) -Good conductors of heat and electricity -Dull, various colours -Brittle -Solids or gas (except bromine which is liquid at room temperature) -Poor conductors of heat and electricity The elements that touch the bolded staircase are metalloids with the exception of aluminum, which is a metal. Metalloids are elements that share some of the properties of metals and some of the properties of non-metals. http://www.youtube.com/watch?v=zGM- wSKFBpo New Version http://www.youtube.com/watch?v=IsBZx0tv6d Q Did you know? WWI Gas Mask: Chlorine is a very toxic greenishyellow gas. During WWI, some armies used chlorine gas as a weapon. Many soldiers died from inhaling the gas. The gas mask was invented to prevent such deaths. Is Chlorine a metal or nonmetal? Other important elements: Hydrogen - in the atomic bomb Nitroglycerin - in dynamite Aluminum — most abundant metal; resists extensive rusting; used in manufacturing and cosmetics. Linked to Alzheimer’s disease. Iron — second most abundant metal; used in steel formation. Steel is a major component in structures from cars to buildings. Iron is also an important component of proper nutrition and health (transports oxygen through the circulatory system). Nitrogen — most abundant gas in the atmosphere; required by all living organisms; major component in fertilizers and explosives. Largest single use of nitrogen (30 percent) is in enhanced oil recovery where pressurized nitrogen gas forces oil from subterranean deposits. Because it is non-reactive, nitrogen is also used by metal, chemical, and computer manufacturers to displace air during processing. Carbon — the basic component of organic life; graphite and diamond are the most common forms found in the environment. Graphites include charcoal, which may be burned via combustion to release stored energy. Carbon is found in a variety of important compounds including organic compounds. Some of these compounds may be used as fuels (e.g., methanol and ethanol) and burned to release great quantities of energy. This energy is used to provide heat, power, and transportation. Bismuth – has a very low melting point (271°C) making it an excellent “plug” for fire sprinklers. As a fire starts, the air near the ceiling quickly reaches temperatures up to 500°C. This melts the bismuth plug, letting the water flow from the sprinkler heads. Using the periodic table found at the back of your textbook, complete the table on the next slide/page. Element Name Symbol Period Group 4 17 1 18 Metal or Non-metal chromium P bohrium 7 15 metal 14 non-metal tin Cl Nb 5 Complete the “check your understanding” questions (#s 1, 2, 4) from p. 30 Science Heating Background causes compounds to decompose because as the particles move faster, the energy of their movements eventually outweighs the attraction between the atoms. This breaks the compound into its component elements. Running electricity through a substance works in the same way. Decomposition reactions played a critical role in finding new elements. Scientists like Antoine Lavoisier used heat to cause a decomposition reaction to see if they could separate a variety of substances into different elements. This work gave Lavoisier the name of “father of modern chemistry.” Lavoisier was able to predict that water was made of hydrogen and oxygen before Sir Humphry Davy actually used electrolysis to separate water into hydrogen and oxygen. Lavoisier also developed the principle that a substance could be considered an element only if it could not be broken down into simpler substances. Elements and compounds in society: Can you think of elements and compounds that we see and use daily? Compounds The A periodic table lists elements. substance made up of two or more different elements chemically combined together is known as a compound. Example: Oxygen is a pure substance that consists of a single element. Distilled water is a pure substance that consists of more than one element (hydrogen and oxygen). Therefore, water is a compound. *Most substances in the world are compounds. matter Pure substance element mixture compound Testing for compounds: Recall that an element is an pure substance that cannot be broken down into simpler substances Compounds, however, are made up of two or more elements. Therefore, compounds can be broken apart into simpler substances. This process is known as a decomposition reaction. **Video** BBC Atoms, Molecules, Elements, Compounds Animation http://www.youtube.com/watch?v=AfXxZwNLv PA Complete Complete counting atoms worksheet! the “check your understanding” questions on p. 34 #1-3. Introduction: The International Union of Pure and Applied Chemistry (IUPAC) also established standard names for chemical compounds. Though the rules of nomenclature developed by IUPAC are beyond the scope of this course, students may wonder why they see several names for a single substance. For example, the labels on iron vitamins may say the pills contain “ferrous sulfate” even though the international standard name is iron(II) sulfate. Different names such as this appear because iron is the substance’s common name, ferrous sulfate is a scientific name that predates the IUPAC standards, and iron(II) sulfate is the internationally recognized name. Element symbols – either one or two letters (often the first letter of the element) i.e.) C = Carbon N = Nitrogen However, once scientists ran out of letters, they began using the first letter of the element name and a second letter from the name. i.e.) Ca = calcium Zn = Zinc Also, some elements were discovered in ancient times and have Latin or Greek names. These elements were given a symbol based on their historic name. i.e.) Pb = Lead (which was known in Latin as plumbum Chemical Formulas: Used to represent the compounds formed by elements = Water 𝑪𝑶𝟐 = Carbon Dioxide i.e.) 𝑯𝟐 𝑶 Compound Sodium bicarbonate (baking soda) Glucose (sugar) Chemical Formula Complete the “check your understanding” questions on p. 37 #1-3 Review questions on page 38-39