Chapter 10: The Mole Mole: Unit used in chemistry to quantify atoms because atoms are so tiny. Mole = 602, 213, 670, 000, 000, 000, 000, 000 or 6. 02 X 1023 This is Avogadro’s number. How many eggs are in 12 dozen? 12 πππ§ππ π₯ 12 ππππ = 144 ππππ 1 πππ§ππ How many eggs are in 12 moles? 6.02 π₯ 1023 ππππ 12 πππππ π₯ = 7.224 π₯ 10 24 ππππ 1 ππππ I have 246 eggs, how many dozen do I have? 246 ππππ π₯ 1 πππ§ππ = 20.5 πππ§ππ ππ ππππ 12 ππππ If I have 5.60 X 1023 eggs, how many moles of eggs do I have? 5.60 π₯ 1023 ππππ π₯ 1 ππππ = 0.93 πππππ 6. 02 π₯ 1023 How many representative particles are in 3.50 moles of sucrose? (Representative particle = ANYTHING!!! Usually: Atoms, Molecules, formula units) Now: Work Page 323: 1-4 & Page 324: 5 & 6 1. Determine the number of atoms in 2.50 moles of Zn. 6.02 π₯ 1023 2.50 πππππ ππ ππ π₯ = 1.51 π₯ 1024 ππ‘πππ 1 ππππ 2. Calculate the number of molecules in 11.5 mol of water. 3. How many formula units of AgNO3 are in 3.25 mol of AgNO3? 4. Calculate the number of oxygen atoms in 5 mol of oxygen molecules. Remember oxygen is diatomic. 5. How many moles contain each of the following? a. 5.75 x 1024 atoms Al b. 2.50 x 1020 atoms Fe 6. Identify the representative particles of each formula and convert the given number of rep. particles to moles. a. 3.75 x 1024 CO2 b. 3.58 x 1023 ZnCl2 10.2: Mass and the Mole A mole always contains the same number of particles; however, moles of different substances have different masses. Molar mass: the mass in grams of one mole of any pure substance. Molar mass of an element = atomic mass of that element. Molar mass of a compound? What is it equal to? Molar mass of a compound is equal to the mass of each of the elements in the compound. Ex. NaCl Na: 1 x 23= 23 Cl: 1 x 35= 35 23 + 35 = 58 grams Ex. H2SO4 H: 2 x 1 = 2 S: 1 x 32 = 32 O: 4 x 16 = 64 2 + 32 + 64 = 98 grams Practice: Find the molar mass: H2O2 H: 2 X 1 = 2 O: 2 x 16 = 32 2 + 32 = 34 grams CH3COOH C: 2 x 12= 24 H: 4 x 1= 4 O: 2 x 16 = 32 24 + 4 + 32 = 60 grams Ca3(PO4)2 Ca: 3 x 40 = 120 P: 2 x 31 = 62 O: 8 x 16 = 128 120 + 62 + 128 = 310 grams AgNO3 Ag: 1 x 108 = 108 N: 1 x 14 = 14 O: 3 x 16 = 48 108 + 14 + 48 = 170 grams C2H6O C: 2 X 12 = 24 H: 6 x 1 = 6 O: 1 x 16 = 16 24 + 6 + 16 = 46 grams 1 dozen jelly beans = 35 grams. How much does 5 dozen weigh? 5 πππ§ππ π₯ 35 πππππ 1 πππ§ππ = 175 πππππ How much does 3 moles of copper weigh? 3 πππππ ππ πΆπ’ π₯ 64 πππππ πΆπ’ 1 ππππ πΆπ’ = 192 πππππ ππ πΆπ’ Calculate the mass in grams of 0.0450 mole Cr. 0.0450 ππππ πΆπ π₯ 52 πππππ = 2.34 πππππ ππ πΆπ 1 ππππ πΆπ Determine the mass in grams of each of the following: a. 3.57 mole Al 27 πππππ π΄π 3.57 πππππ ππ π΄π π₯ = 96.39 πππππ π΄π 1 ππππ π΄π b. 42.6 mole Si 42.6 πππππ ππ π₯ 28 πππππ ππ = 1192.8 πππππ ππ 1 ππππ ππ 525 grams of Ca = ? moles 1 ππππ πΆπ 525 πππππ πΆπ π₯ = 13.125 πππππ ππ πΆπ 40 πππππ ππ πΆπ 25.5 grams of Ag = ? Moles 1 ππππ π΄π 25.5 grams of Ag x 108 πππππ π΄π = 0.236 πππππ ππ π΄π 300 grams of S = ? Moles 1 ππππ π 300 πππππ ππ π π₯ = 9.37 πππππ π 32 πππππ ππ π If 1 dozen jelly beans weigh 35 grams, how many jelly beans are in 280 grams of jelly beans? 280 πππππ πππππ¦ πππππ π₯ 1 πππ§ππ ππ 35 πππππ ππ π₯ 12 ππ 1 ππ§ ππ = 96 πππππ¦ πππππ How many atoms of gold are in 31.1 grams of Au? 1 ππππ π΄π’ 6.02 π₯ 1023 ππ‘πππ 31.1 πππππ π΄π’ π₯ π₯ = 9.50 π₯ 1022 197 πππππ π΄π’ 1 ππππ π΄π’ How many atoms are in the following: a. b. c. 55.2 grams of Li 1 ππππ πΏπ 6. 02 π₯ 1023 ππ‘πππ 55.2 πππππ πΏπ π₯ π₯ 7 πππππ πΏπ 1 ππππ πΏπ = 4.75 π₯ 1024 ππ‘πππ πππΏπ 0.230 grams of Pb 1 ππππ ππ 6.02 π₯ 1023 ππ‘πππ 0.230 πππππ ππ ππ π₯ π₯ 207 πππππ ππ 1 ππππ ππ = 6.69 π₯ 1020 ππ‘πππ 11.5 grams of Hg What is the mass of 6.02 π₯ 1024 ππ‘πππ ππ π΅π? 1 πππππ 209 πππππ π΅π 6.02 π₯ 10 ππ‘πππ ππ π΅π π₯ π₯ 6.02 π₯ 1023 ππ‘πππ 1 πππππ = 2090 πππππ ππ π΅π 24 What is the mass of 1.00 x 1024 atoms of Mn? 1 ππππ ππ ππ 55 πππππ ππ π₯ 6.02 π₯ 1023 ππ‘πππ ππ ππ 1 ππππ ππ ππ = 91.36 πππππ ππ ππ 1.00π₯1024 ππ‘πππ ππ ππ π₯ On separate sheet of paper: Classwork/Homework: Page 358-359: Problem #’s 84, 86, 88, 90, 91, 92, 93, 94, 95, 99, 102, 103, 104, 108, 109, 110, 112, 113, 116, 119. Chapter 10.3: Moles of Compounds Representative Particles: Elements = atoms Ionic bonds = Compounds (metal and nonmetal) = formula units Covalent bonds (nonmetal and nonmetal) = molecules We find moles of compounds just like we did before, except we use molar mass. Answer: How many moles of Cl- are in 2.5 moles ZnCl2? 2 πππππ πΆπ − 2.5 πππππ πππΆπ2 π₯ =5 1 ππππ πππΆπ2 How many moles of oxygen atoms are present in 5 moles of P2O5? 5 πππππ π2 π5 π₯ 5 πππππ π 1 πππππ2 π5 = 25 moles O What is the molar mass of the following? NaOH Na: 1 x 23 = 23 O: 1 x 16 = 16 H: 1 x 1 = 1 HCN H: 1 x 1 = 1 C: 1 x 12 = 12 23 + 16 + 1 = 40 grams N: 1 x 14 = 14 1 + 12+ 14 = 27 grams CaCl2 CCl4 What is the mass of 2.50 moles of (C3H5)2S? C: 6 x 12 = 72 H: 10 x 1 = 10 S: 1 x 32 = 32 72+10+32 = 114 grams 2.5 πππππ x 114 πππππ = 285 πππππ 1 ππππ How many moles are in 325 grams of Calcium Hydroxide, Ca(OH)2? 1 ππππ πΆπ(ππ» )2 325 πππππ ππ πΆπ(ππ»)2 x 74 πππππ πΆπ(ππ» )2 = 4.39 πππππ ππ πΆπ(ππ»)2