Presents OSHA Hazard Communication Standard 2012 (HCS) Global Harmonized System (GHS) OSHA Hazard Communication Standard (HCS) and GHS The United States officially adopted the Global Harmonized System of Classification and Labeling of Chemicals (GHS) on March 26, 2012. OSHA Hazard Communication Standard (HCS) is actually a revision of the original Hazard Communication Standard to align with the GHS. OSHA HCS Training Compliance • Adopting GHS brings major changes to OSHA HCS in 2 major areas. SAFETY DATA SHEET 1. Identification Product identifier EARTH SENSE® HD WASHROOM CLEANER Other means of identification 4047 Recommended use General purpose cleaner. Recommended restrictions None known. Manufacturer / Importer / Supplier / Distributor information 1. Label Elements 2. Safety Data Sheets Company name Address Telephone E-mail Contact person Emergency phone number National Chemical Laboratories, Inc. 401 N. 10th St. Philadelphia, PA 19123 (215) 922-1200 technicalsupport@nclonline.com CHEM-TEL (800) 255-3924 2. Hazard(s) identification Physical hazards Not classified. Health hazards Not classified. OSHA hazard(s) Not classified. Label elements Hazard symbol No symbol. Signal word None. Hazard statement Not available. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) Not classified. 3. Composition/information on ingredients Mixture The components are not hazardous or are below required disclosure limits. 4. First-aid measures Inhalation Move to fresh air. Get medical attention if symptoms occur. Skin contact Remove contaminated clothing and shoes. Wash skin with soap and water. Get medical attention if irritation develops or persists. Eye contact Flush eyes thoroughly with water for at least 15 minutes. Get medical attention if irritation develops and persists. Ingestion Rinse mouth thoroughly with water. Call a physician or poison control center immediately. Most important symptoms/effects, acute and delayed Mild eye irritation. Indication of immediate medical attention and special treatment needed Treat symptomatically. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media This material will not burn. Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media Not available. 04047 911785 SDS SDSUS US Version #: 01 Revision date: - Issue date: 12-13-2012 1/5 OSHA HCS Training Compliance • Label Elements • Product Identifier • Supplier Identifier • Signal Word • Hazard Pictograms • Hazard Statement • Precautionary Statements OSHA HCS Training Compliance • Label Elements • Product Identifier OSHA HCS Training Compliance • Label Elements • Product Identifier • Supplier Identifier OSHA HCS Training Compliance • Label Elements • Product Identifier • Supplier Identifier • Signal Word OSHA HCS Training Compliance • Label Elements • Product Identifier • Supplier Identifier • Signal Word • Hazard Pictograms OSHA HCS Training Compliance • Hazard Pictograms 1. 2. 3. 4. 5. 6. 7. 8. Exploding Bomb Gas Cylinder Health Hazard Flame Skull and Crossbones Exclamation Mark Flame Over Circle Corrosion OSHA HCS Training Compliance • Hazard Pictograms 1. Exploding Bomb Explosives Self-Reactives Organic Peroxides OSHA HCS Training Compliance • Hazard Pictograms 1. Exploding Bomb 2. Gas Cylinder Gases under pressure Compressed gases Liquefied Gases Refrigerated liquefied gases Dissolved gases OSHA HCS Training Compliance • Hazard Pictograms 1. Exploding Bomb 2. Gas Cylinder 3. Health Hazard Carcinogenicity 1A,1B,2 Respiratory Sensitizer 1 Reproductive Toxicity 1A,1B,2 Target Organ Toxicity 1,2 Mutagenicity 1A,2B,2 Aspiration Hazard 1 OSHA HCS Training Compliance • Hazard Pictograms 1. 2. 3. 4. Exploding Bomb Gas Cylinder Health Hazard Flame Flammable gases 1 Flammable aerosols 1,2 Flammable liquids 1,2,3 Pyrophoric Liquids and Solids Self-Heating substances and mixtures 1,2 Emits Flammable Gas 1,2,3 Organic Peroxides B,C,D,E,F OSHA HCS Training Compliance • Hazard Pictograms 1. 2. 3. 4. 5. Exploding Bomb Gas Cylinder Health Hazard Flame Skull and Crossbones Acute Toxicity (Fatal or Toxic) Categories 1,2,3 Oral Dermal Inhalation OSHA HCS Training Compliance • Hazard Pictograms 1. 2. 3. 4. 5. 6. Exploding Bomb Gas Cylinder Health Hazard Flame Skull and Crossbones Exclamation Mark Skin & Eye Irritant 2 Skin Sensitizer 1 Acute Toxicity (harmful) cat4 oral, dermal, inhalation Respiratory Tract Irritation Narcotic Effects Harmful to Ozone Layer (Not mandatory) OSHA HCS Training Compliance • Hazard Pictograms 1. 2. 3. 4. 5. 6. 7. Exploding Bomb Gas Cylinder Health Hazard Flame Skull and Crossbones Exclamation Mark Flame Over Circle Oxidizing Gases 1 Oxidizing Liquids 1,2,3 Oxidizing Solids 1,2,3 OSHA HCS Training Compliance • Hazard Pictograms 1. 2. 3. 4. 5. 6. 7. 8. Exploding Bomb Gas Cylinder Health Hazard Flame Skull and Crossbones Exclamation Mark Flame Over Circle Corrosion Skin Corrosion / Burns 1A,1B,1C Corrosive to Metals 1 Serious Damage to Eye OSHA HCS Training Compliance • Label Elements • Product Identifier • Supplier Identifier • Signal Word • Hazard Pictograms • Hazard Statement OSHA HCS Training Compliance • Label Elements • Product Identifier • Supplier Identifier • Signal Word • Hazard Pictograms • Hazard Statement • Precautionary Statements OSHA HCS Training Compliance • Using Labels in the workplace • Ensure proper storage of hazardous chemicals • Quickly locate first aid information when needed by employees or emergency personnel • Chemicals with multiple hazards, multiple pictograms are used to identify various hazards. • When there are similar precautionary statements, the one providing the most protective information will be included on the label. SAFETY DATA SHEET OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection Physical & Chemical Properties Stability & Reactivity Toxicological Information Ecological Information Disposal Considerations Transport Information Regulatory Information Other Information 1. Identification Product identifier EARTH SENSE® HD WASHROOM CLEANER Other means of identification 4047 Recommended use General purpose cleaner. Recommended restrictions None known. Manufacturer / Importer / Supplier / Distributor information Company name Address Telephone E-mail Contact person Emergency phone number National Chemical Laboratories, Inc. 401 N. 10th St. Philadelphia, PA 19123 (215) 922-1200 technicalsupport@nclonline.com CHEM-TEL (800) 255-3924 2. Hazard(s) identification Physical hazards Not classified. Health hazards Not classified. OSHA hazard(s) Not classified. Label elements Hazard symbol No symbol. Signal word None. Hazard statement Not available. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) Not classified. 3. Composition/information on ingredients Mixture The components are not hazardous or are below required disclosure limits. 4. First-aid measures Inhalation Move to fresh air. Get medical attention if symptoms occur. Skin contact Remove contaminated clothing and shoes. Wash skin with soap and water. Get medical attention if irritation develops or persists. Eye contact Flush eyes thoroughly with water for at least 15 minutes. Get medical attention if irritation develops and persists. Ingestion Rinse mouth thoroughly with water. Call a physician or poison control center immediately. Most important symptoms/effects, acute and delayed Mild eye irritation. Indication of immediate medical attention and special treatment needed Treat symptomatically. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media This material will not burn. Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media Not available. 04047 911785 SDS SDSUS US Version #: 01 Revision date: - Issue date: 12-13-2012 1/5 OSHA HCS Training Compliance • Safety Data Sheets 1. Identification OSHA HCS Training Compliance • Safety Data Sheets 1. Identification 2. Hazard(s) Identification OSHA HCS Training Compliance • Safety Data Sheets 1. Identification 2. Hazard(s) Identification 3. Composition/Ingredient Information OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. 9. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection Physical & Chemical Properties OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection Physical & Chemical Properties Stability & Reactivity OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection Physical & Chemical Properties Stability & Reactivity Toxicological Information OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection Physical & Chemical Properties Stability & Reactivity Toxicological Information Ecological Information OSHA HCS Training Compliance • Safety Data Sheets 1. Identification 2. Hazard(s) Identification 3. Composition/Ingredient Information 4. First Aid Measures 5. Fire-Fighting Measures 6. Accidental Release Measures 7. Handling and Storage 8. Exposure Control/Personal Protection 9. Physical & Chemical Properties 10. Stability & Reactivity 11. Toxicological Information 12. Ecological Information 13. Disposal Considerations OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection Physical & Chemical Properties Stability & Reactivity Toxicological Information Ecological Information Disposal Considerations Transport Information OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection Physical & Chemical Properties Stability & Reactivity Toxicological Information Ecological Information Disposal Considerations Transport Information Regulatory Information OSHA HCS Training Compliance • Safety Data Sheets 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. Identification Hazard(s) Identification Composition/Ingredient Information First Aid Measures Fire-Fighting Measures Accidental Release Measures Handling and Storage Exposure Control/Personal Protection Physical & Chemical Properties Stability & Reactivity Toxicological Information Ecological Information Disposal Considerations Transport Information Regulatory Information Other Information TIMELINE OF ACTIVITIES GHS / HazCom2012 ADOPTION Final Sell Through Period Dec. 1 , 2013 2013 June 1 , 2015 2014 All employees must be trained on new GHS Label Elements and how to read a new GHS 16 point Safety Data Sheet December 1, 2013 All employers must train employees on the new label elements and safety data sheet (SDS formerly called the MSDS – Material Safety Data Sheet) June 1, 2015 Chemical manufacturers, importers, distributors must comply with the GHS system. Hazard Classification: Classify both the health and physical hazards of a product. Labels: Labels must include a harmonized signal word, pictogram and hazard statement for each hazard class and category. Safety Data Sheets: SDS must be available in a specified 16 section format. The only exception is that distributors may ship inventory they have on hand that is not GHS compliant, until December 1, 2015. After December 1, 2015 distributors will no longer be able to ship material unless it is compliant with GHS. June 1, 2015 All materials shipped in commerce must comply with the GHS System. Dec. 1 , 2015 2015 Distributors Manufacturers must be must be shipping shipping products with products with proper GHS proper GHS labeling and labeling and new GHS 16 new GHS 16 point SDS must point SDS must be available. be available.