Objectives 1-2 A chemical reaction is the process of atoms rearranging ___________ to create new compounds by breaking and forming chemical _________. During chemical bonds energy reactions __________ is either stored or released. A chemical equation uses symbols to show what occurs during a ________________. It can be thought of chemical reaction as the “recipe” for a compound. Example: 2H2 + O2 2H2O Reactants – substances used in the reaction; located on the left side of the equation. Products – substances produced in the reaction; located on the right side of the equation. What are the reactants in this equation? H2 O2 What are the products in this reaction? H2 O If we wanted to make 4 molecules of H2O, how many O2 would we need?__________ 2 If we used 8 molecules of O2, how many 16 molecules of H2O would we make?_______ What are the products in this equation? FeCl2 Cu What are the reactants in this equation? Fe CuCl2 The reaction must start and end with the Same # of atoms and type of atoms All chemical equations must obey the law of conservation of mass. When an equation obeys the law of conservation of mass we say the equation is BALANCED (these represent reactions that can happen). When an equation does NOT obey the law of conservation of mass we say it is UNBALANCED (an unbalanced equation represents something that will never happen). How many atoms of hydrogen are in the reactants? Product? Reactants: H = 4 Product: H = 4 How many atoms of oxygen are in the reactants? Products? Reactants: O = 2 Product: O = 2 Yes Is this equation balanced? ___________ Why or why not? The number of atoms on both side are equal How many atoms of hydrogen are in the reactants? Product? Reactants: H = 2 Product: H = 2 How many atoms of oxygen are in the reactants? Products? Reactants: O = 2 Product: O = 1 No Is this equation balanced? ___________ Why or why not? The number of atoms on both side are NOT equal Objectives 3-5 The ability to do work; measured in joules or calories Move Make proteins Digest Transport molecules Pump Food Store A food source might not be available when energy is needed. Energy cannot be created or destroyed; it can change forms Living things must be able to covert energy from one form to another. 1. Macromolecules – energy is stored in the chemical ________ bonds of macromolecules. _________ Carbohydrates (Sugars) Lipids (Fats) Proteins Carbohydrates (Sugars)– C, H, O – primary energy source – 4 cal/g Lipids (Fats) –C, H, O – stored form of energy – 9 cal/g Proteins – C, H, O, N – 4 cal/g Bond between C & H have a lot of energy. It can be released by breaking bonds 2. Light – a ________ wave that has energy in the photons form of _________; this form is energy is plants used by __________ during _________________. photosynthesis (energy from light is stored in sugars) 3. ATP – Adenosine Triphosphate – the primary source of energy used by cells. 3 PHOSPHATES ADENOSINE When the last phosphate is removed, energy ___________ is released. + ℗ + Energy ATP ADP + Phosphate Energy from Food/light __________ is stored in chemical bonds in ATP. ADP + ℗ + Energy ATP 4. Electrons – Electrons (and their energy can be moved from one Compound _________ to another. Electron Carriers – special compounds that easily gain and lose electrons and can transfer energy from one place to another. Examples: NADP+ + ē (empty) NADPH (full) H=++ē Objectives 6-8 A protein that acts as a catalyst (speeds up chemical reactions) Why are enzymes needed? So reactions happen fast enough to sustain life functions How do enzymes work? Enzymes lower the activation energy of a chemical reaction. Activation Energy is the energy needed to start ______ a chemical reaction. No enzyme With enzyme Finish Each enzyme has a specificshape ________ based on how the ________ protein is folded. Substrate – Substance that the enzyme acts on Each enzyme binds only to certain substrates. In order for the substrate to bind shape to the enzyme it must be the right ________. The place where the substrate binds to the active site enzyme is called the _______ ______ Once the enzyme and substrate bind, a reaction occurs. Active site -substrate products ENZYME Example: The reaction shown below helps convert CO2 into a form that is more easily carried through the bloodstream. Without enzymes this reaction wouldn’t happen fast enough and dangerous levels of CO2 would build up in the bloodstream. The enzyme carbonic anhydrase allows this reaction to happen 10 million times faster. CO2 + H2O H2CO3 ENZYME Video Controlling Enzymes Enzymes don’t always need to be “ON.” There are 2 ways to turn an enzyme “OFF.” Competitive Inhibition – A substance other than the substrate blocks the Inhibitor active site Substrate Non- Competitive Inhibition –A molecule binds to a location other than the active site and changes the shape Substrate of the enzyme Inhibitor V ideo Objective 9, 10, 12, 13 sunlight water carbon dioxide Sugars (glucose) oxygen Equation: 6CO2 +12H2O C6H12O6 + 602 + 6H2O CO2 – carbon dioxide C6H12O6 – glucose (carb)H2O – Water (soil) O2 – Oxygen H2O - Water Waste products Purpose: To store energy from light in glucose A side note: structure of carbohydrates – carbohydrates are molecules made of carbon _______, _________, ________. hydrogen andoxygen Monosaccharide –Simple sugar (Glucose) quick energy Polysaccharide -Complex sugar made of many simple sugar (ex. Starch) Chloroplasts Grana –Stack of thylakoids Stroma – Background material of chloroplasts Thylakoid –Disk Containing chlorophyll Chlorophyll –Green, light absorbing pigments Pigment- light absorbing molecules Structures of Photosynthesis =Nucleus =Cell Wall Plant Cell Plant Cell Grana Thylakoid Grana Chlorophyll Thylakoid Objectives 14, 16 Purpose:To store energy from sunlight in glucose light Light Dependent Reactions use _________ H2O and ________. Energy is temporarily stored ATP and _________. NADPH O in _______ ________ is 2 given off as a waste product. Light Independent Reactions (Calvin Cycle) CO2 to convert the energy from uses _______ ATP _______ and _________ into ________. NADPH Glucose H2O ________is given off as a waste product. *add equation and thylakoid and stroma H2O CO2 Light NADP+ ADP +P Thylakoid ATP Calvin Cycle Stroma NADPH Chloroplast O2 6CO2 +12H2O C6H12O6 + 6O2 + 6H2O SUGARS Location: Thylakoid of Chloroplast Materials Needed: Light, H2O, ADP, NADP+ Final Products: O2, H+, ATP, NADPH 1. Energy from light strikes a chlorophyll molecule in the membrane of the thylakoid. This light energy excites an _electron_ and it passes through a chain of molecule called the electron transport chain. As it moves it loses energy. 2. Water in the plant is broken into, H+,_O and _electrons_. 3. The electrons replace the one lost from chlorophyll The O combine to form O2 and leave as a waste product. 4. The movement of electrons causes more H+ to move into the thylakoid. 5. Light strikes a 2nd chlorophyll molecule and the Electron is reenergized . This high-energy electron is picked up by NADP+ (an electron carrier) to form NADPH. 6. As this happens over and over again protons (H+) build up in the thylakoid. They can only get across the membrane by going through a protein_ The energy from the H+ moving through the channel converts ADP to ATP. Location:Stroma of chloroplasts Materials needed: ATP, NADPH, H+, CO2 Final products:Glucose, H2O ATP and NADPH Main Idea: Energy stored in ____ _____ from the light reaction is used in the Calvin Dioxide into cycle to convert ________ Carbon ________ high-energy sugars (Glucose). Objectives 9, 12-15 Food Molecules are burned The process by which _______________ in the cell in order to produce __________. Energy ATP so Purpose: to storeEnergy ________ from food in _____ cells can carry out life processes Remember: for cells to function they need energy; the main form of energy used by cells is ____. ATP The equation : C6H12O6 + 6O2 6CO2 + 6H2O + 36 ATP Glucose – Made by plants in photosynthesis; has LOTS of ______, Energy but it is not in a usable form. Plants during Oxygen – produced by _______ photosynthesis Energy used by ATP – the main source of ________ all Living things Water – released into the air as waste Location: Cytoplasm Mitochondria Photosynthesis Cellular Respiration Function To make Glucose Burn glucose for energy Location Chloroplasts Mitochondria/Cytoplasm Used by Reactants Products Equations Plants, Bacteria, Protists (Autotrophs) All living things CO2 + H2O C6H12O6 + O2 C6H12O6 + O2 + H2O CO2 + H2O + ATP 6CO2 + 6H2O Light C6H12O6 + 6O2+ H2O C6H12O6 + 6O2 6CO2 + 6H2O + 36ATP ATP is used up it must be replaced. As _____ ATP comes from The energy to build more ____ food It takes some energy to break down _____. food molecules, BUT cells get more energy from the food that they use to ____________ break it down. What is the major source of energy for organisms? Where does it come from? Food (Glucose) Plants (photosynthesis) Objective 14, 18 Equation: C6H12O6 + 6O2 6CO2 + 6H2O + 36 ATP Purpose:To get energy from glucose and store it in ATP Summary of Energy Flow: Energy from _______ is transferred to electron carriers Glucose and then to ATP ____. Glucose – one of the most basic carbohydrates; starting material for respiration ATP – main energy source used by the cell NAD+/NADPH+H - an electron carrier FAD/FADH2 – another electron carrier The first step of all forms of respiration is Glycolysis ________. After that if no oxygen is present the cell goes through fermentation. If oxygen is present the cell proceeds to cellular respiration. Electrons carried in NADH 1 Glucose 3 2 Glycolysis Pyruvic Acid Cytoplasm 2ATP 6O2 Electrons carried in NADH and FADH2 Krebs Cycle Electron Transport Chain Mitochondrion 2ATP 32 ATP + 6CO2 +6H2O Location:Cytoplasm Materials Needed:Glucose, NAD+, ADP Final Products:2 ATP, small sugars, NADH Main Idea: Glucose is broken down into 2 ATP are used and ____ 4 smaller sugars. ____ ATP are produced for a net gain of ____ 2 ATP. Some energy is Stored in _________. NADH Location:Mitochondria Materials Needed: Small sugars, NAD+ FAD Final Products: CO2, NADH, FADH2 Main Idea: The smaller sugars are broken down even further. The carbon atoms from CO2 the sugars combine with O2 to form______ which is given off as a waste product. The energy from the sugars is stored in FADH2 and _________. _________ NADH Location: Mitochondria Materials Needed:NADH, FADH2, O2 Final Products:ATP, H2O, (NAD+, FAD) Main Idea: Energy that has stored in NADH and FADH _________ ________ is converted to 2 _______ as electrons are passed along the ATP electron transport chain. At the end of the chain electrons combine with H+ and H2O Oxygen to form ___________ 36 ATP can be produced from one ______ CO2 molecule of glucose. Six molecules of _____ H2O are given off as and 6 molecules of _____ waste products. Objective 17 Oxygen - Aerobic Respiration. 1. With _________ When respiration happens in the presence of oxygen a _______________ Large Amount of ATP is produced. Oxygen 2. Without ____________Anaerobic Respiration. When respiration happens with NO oxygen, a _____________ Small amount of ATP is produced. Step 1: Glycolysis – first used by Ancient Bacteria _______ ________ to make ATP, it is now used by ALL living things. glucose Glycolysis breaks down _______ into smaller molecules and produces 2 ATP molecules. ___ Where does glycolysis happen? Cytoplasm Step 2: Fermentation (Anaerobic Respiration) – happens in the Cytoplasm ___________ ATP Does not make any new ________, but recycles the materials needed Glycolysis for _____________ to continue. (If this didn’t happen the cell would be stuck and couldn’t make any more ATP ____) 1. Alcoholic Fermentation – happens inYeast _____. The products of Glycolysis _________ break down into _______ ________ Dioxide and ethyl Carbon alcohol. How is this used in industry? To make alcoholic beverages 2. Lactic Acid Fermentation – muscles when happens in your ________ you exercise because they are not supplied with enoughoxygen ______. The products from _________ glycolysis are broken down into lactic acid and CO2 This can build up in your ____. muscles and it causes them to _____. When _______ oxygen is present burn they will switch back to oxidative respiration and break it down. 2 ATP Glycolysis Fermentation Anaerobic Respiration Aerobic Respiration Lactic Acid Alcohol