H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C H2C Chemical Formula CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C Like a word • Describes Compounds • Lists what elements are present in the compound • Expresses the ratio of each element present • Subscripts = how many atoms of element to left of #. H2C Chemical Formula cont.. CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C • Example: CaI2 • The small 2 is a subscript. It indicates that for each molecule of calcium iodide, 1 atom of calcium is present for each 2 atoms of iodine. H2C Chemical Formula Practice CH2 H2C CH2 H2C CH2 H2C H2C H2C How many atoms of nitrogen are present? 1 How many CH2 present? How many CH2 present? CH2 H2C Consider the formula for potassium nitrate (KNO3): atoms of potassium are 1 atoms of oxygen are 3 H2C Your Turn….. CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C How many atoms of each element are in each of the formulas below? CaCl2 Pb2(CrO4)3 KCl NH4NO2 MgBr2 Mg(NO3)2 Na2S (NH4)2S Sr3N2 Ca(NO3)2 H2C Remember…….Ionic CH Compounds 2 H2C CH2 H2C H2C H2C • Composed of (+) cation and (-) CH2 anion for a net charge of zero • These charges are also called CH2 “oxidation numbers” CH2 H2C CH2 H2C H2C CH2 Charges? Cations: H2C H2C H2C H2C •CH Group 1 A = +1 2 • Group 2A = +2 2 •CH Group 3A (metals (below the zig-zag line)) = +3 • Group 4A (metals (below the zig-zag line)) = +4 CH2 • Group 5A (metals (below the zig-zag line))= +5 •CH Group 6A (metal (below the zig-zag line)) = +6 2 H2C CH2 H2C Charges? Cont… H2C CH2 Anions: H2C H2C H2C H2C •CHGroup 8A = 0 (noble gases) 2 • Group 7A = -1 2 •CHGroup 6A = -2 • Group 5A (non metals (above the zig-zag line)) = -3 CH2 • Group 4A (non metals (below the zig-zag line)) = -4 •CHGroup 3A (non metals (below the zig-zag line)) = -5 2 H2C CH2 H2C H2C IONIC Bonds in IONIC compounds! • Remember our example…NaCl. • What does ION mean? CH2 Charged particles CH2 • How do atoms become charged? CH2 H2C H2C H2C CH2 H2C CH2 H2C CH2 H2C +++--+++--- gain or give away ELECTRONS ZERO • The whole compound has to equal H2C CH2 H2C CH2 H2C H2C 1. Write each element’s symbol with its charge = ion formula CH2 2. Place the Cation (+) ion first and then place the anion (-) second. CH2 3. Move the superscript (charge of H2C CH2 H2C CH2 H2C How do I write Ionic Compound Formulas ? the first ion) to the bottom (subscript) of the second ion. H2C CH2 H2C How do I write Ionic Compound Formulas ? 4. Make the subscripts positive (+). CH2 Note: If the subscript is 1 then no H2C subscript is needed. CH2 H2C H2C Double check: The charges X the # of ions on each ion should add up to a net CH2 charge of zero. CH2 H2C CH2 H2C H2C Lets Practice… CH2 H2C H2C Cation CH2 Na+ CH2 H2C CH2 H2C CH2 H2C CH2 H2C Write the formula for Sodium Oxide Anion O-2 = Formula Na2O Na2O = 2 atoms of Na+ & 1 atom of O-2 Na+ + Na+ + O-2 = 0 (+1) + (+1) + (-2) = 0 H2C This is called the “criss-cross” CH method 2 H2C H2C Cation CH2 Ca+2 Anion Cl-1 CH2 Al+3 Cl-1 CH2 Li+1 N-3 CH2 Mg+2 N-3 H2C H2C H2C CH2 H2C = Formula Calcium CaCl2 chloride AlCl3 Aluminum chloride = Li3N Lithium nitride = Mg3N = Magnesium 2 nitride H2C Your Turn…..Write the CH Formula for aluminum sulfide Cation Anion Formula CH Al2S3 Al+3 S-2 = 2 H2C 2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C Al2S3 = 2 atoms of Al+3 & 3 atom of S-2 Al+3 + Al+3 + S-2 + S-2 + S-2 = 0 +3 + +3 + -2 + -2 + -2 = 0 H2C What about transitional elements? CH2 1. H2C H2C If given the name, the charge is provided with a Roman numeral CH2 2. If given the formula, write the charge in Roman numerals in parenthesis CH2 H2C H2C CH2 copper (I) oxide = Cu+1 and O-2 = Cu O 2 +4 and O-2 = lead (IV) oxide Pb O = Pb 2 4 CH2 H2C CH2 H2C iron (II) oxide = Fe+2 and O-2 = FeO H2C Transitional elements are easy… CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C cobalt (III) chloride gold (I) sulfide lead (II) iodide iron (III) oxide chromium (II) sulfide copper (II) chloride lead (IV) iodide CoCl3 Au2S PbI2 Fe2O3 CrS CuCl2 PbI4 H2C Name these transitional elements CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C Mn2O4 Cr2O3 PbCl2 FeI3 Cr2S3 CuCl PtI4 manganese (IV) oxide chromium (III) oxide lead (II) chloride iron (III) iodide chromium (III) sulfide copper (I) chloride platinum (IV) iodide H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C Polyatomic Ions • Group of bonded atoms w/a charge Place polyatomic ion in ( ) and treat as one unit and place the subscript on the outside of the (). • If the polyatomic is taken only once then () are not needed. • Ex: (PO4)3Phosphate ion with 3- charge Common Polyatomic ions H2C CH2 H2C + 1 charge + CH NH 2 4 -1 -2 -3 OHCO3-2 PO4-3 H2C Ammonium Hydroxide Carbonate Phosphate CH2 NO3SO4-2 H2C Nitrate Sulfate CH2 NO2SO3-2 H2C Nitrite Sulfite CH2 H2C CH2 H2C H2C Lets Practice… Formula for potassium carbonate CH 2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C Cation Anion + -2 K (CO3) + K + K (CO3 remove parentheses Formula = K2(CO3) -2 =0 ) K2CO3 H2C Formula for zinc nitrate CH2 Cation Anion Formula CH2 Zn+2 (NO3)-1 = Zn(NO3)2 H2C H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C Zn+2 (NO3)-1 (NO3)-1 = 0 What about Ionic Formulas with Polyatomics? H2C CH2 NH4 & Cl CH2 Al & NO3 H2C H2C CH2 Ca & CO3 CH2 K & PO4 H2C H2C CH2 H2C CH2 H2C (NH4)2Cl ammonium chloride Al(NO3)3 aluminum nitrate CaCO3 calcium carbonate K2PO4 potassium phosphate Let’s put it all together… H2C CH2 sodium hydroxide H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C NaOH HgSO4 mercury (II) sulfate Pb3(PO4)4 lead (IV) phosphate (NH4)2S ammonium sulfide Al(ClO3)3 aluminum chlorate Cu2CO3 copper (I) carbonate manganese (IV) oxide Mn2O4 Al2(NO3)3 aluminum nitrate FePO4 iron (II) phosphate Na2CrO4 sodium chromate ammonium chromate (NH4)2CrO4 How about the other way? H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C CH2 H2C Ca(OH)2 PbSO4 Cu3(PO4)2 (NH4)2O Al(BrO3)3 CuCO3 Mn2S4 Al2(SO4)3 Fe2(PO4)3 Li2CrO4 (NH4)2CO3 calcium hydroxide lead (II) sulfate copper (II) phosphate ammonium oxide aluminum bromate copper (II) carbonate manganese (IV) sulfide aluminum sulfate iron (III) phosphate lithium chromate ammonium carbonate