Do Now On your Daily Organizer, describe each scenario as conduction, convection or radiation: A. B. C. D. E. A fire warming up someone’s body who is sitting near the fire A pot of water heating up on the stove Putting an ice pack on a burn Light from a lamp shines on you and warms you up. Holding a mug filled with coffee to warm up your hands Today’s Agenda 5 min • Do Now 5 min • Important Dates 25 min • First Law of Thermodynamics 20 min • Second Law of Thermodynamics 5 min • Exit Ticket Today’s Agenda 5 min • Do Now 5 min • Important Dates 25 min • First Law of Thermodynamics 20 min • Second Law of Thermodynamics 5 min • Exit Ticket Important Dates & Reminders Homework This Week Progress Reports Missing Last Unit Exam Next Thursday Study Guide Tomorrow February Monthly News Project Due Lab Notebooks Next Thursday Feb. 28th Congrats to both Girls’ and Boys’ Basketball! Today’s Agenda 5 min • Do Now 5 min • Important Dates 25 min • First Law of Thermodynamics 20 min • Second Law of Thermodynamics 5 min • Exit Ticket First Law of Thermodynamics The First Law of Thermodynamics basically states that in a closed system, energy can neither be created nor destroyed, only transformed or transferred. There is an energy balance in the universe. What does this sound a lot like??? Connection to Heat Whenever heat is added to a system, it transforms to an equal amount of some other form of energy. That form of usable energy is WORK. Conservation of Energy Some visual examples of this principle st 1 Law Equation Q = DE – W Q = (EF– EI) -W Q = heat added TO THE SYSTEM DE = D in internal energy W = Work done ON THE SYSTEM If the system does work, W is NEGATIVE Example A total of 135 J of work is done on a gaseous refrigerant as it undergoes compression. If the internal energy of the gas increases from 0 J to 156 J during the process, what is the total amount of energy removed from the gas by heat? Example Answer A total of 135 J of work is done on a gaseous refrigerant as it undergoes compression. If the internal energy of the gas increases from 0 J to 156 J during the process, what is the total amount of energy removed from the gas by heat? Q = ΔE – W Q = 156 J – 135 J Q = 21 J Guided Practice An object has an initial internal energy of 48 J. The internal energy increases to 73 J when 38 J of work is done. What is the amount of energy in the form of heat that was gained by the system during this? Guided Practice Answer An object has an initial internal energy of 48 J. The internal energy increases to 73 J when 38 J of work is done. What is the amount of energy in the form of heat that was gained by the system during this? Q = ΔE – W Q Q = (EF – EI) – W = (73 J – 48 J) – 38 J Q = -13 J Step Up The internal energy of a system is initially 27 J. After 33 J of heat is added to the system, the internal energy is measured to be 86 J. How much work was done on the system? Step Up Answer The internal energy of a system is initially 27 J. After 33 J of heat is added to the system, the internal energy is measured to be 86 J. How much work was done on the system? Q = ΔE – W Q 33 = (EF – EI) – W J = (86 J – 27 J) – W 33 J = 59 J – W W = 59 J – 33 J W = 26 J Step Further The internal energy of a system is initially 45 J. A total of 28 J of energy is added to the system by heat while the system does -31 J of work. What is the system’s final internal energy? Q = ΔE – W Q = (EF – EI) – W Step Further Answer The internal energy of a system is initially 45 J. A total of 28 J of energy is added to the system by heat while the system does -31 J of work. What is the system’s final internal energy? Q = ΔE – W Q 28 = (EF – EI) – W J = (EF – 45 J) – (-31) J 28 J = (EF – 45 J) + 31 J -3 J = EF – 45 J EF = 42 J Practice Problems Complete the practice problems on the Daily Organizer under First Law of Thermodynamics Today’s Agenda 5 min • Do Now 5 min • Important Dates 25 min • First Law of Thermodynamics 20 min • Second Law of Thermodynamics 5 min • Exit Ticket Second Law of Thermodynamics The entropy of the universe increases in all natural processes and reactions. Entropy is the measure of a system’s disorder. Second Law of Thermodynamics The entropy, or disorder, of the universe increases in all natural processes. After cleaning your room, it always has a tendency to become messy again. This is a result of the second law. To understand disorder more, think about gas in a jar that is suddenly released. What is going to happen? As the disorder in the universe increases, the energy is transformed into less usable forms Calculating Entropy When a body absorbs an amount of heat Q from a reservoir at temperature T, the body gains and the surroundings lose an amount of entropy Positive S: Entropy Increased Negative S: Entropy Decreased Example 1 A system has 91 J of heat transferred to it raising its temperature 15 °C. What was the increase in entropy? Example 1 Answer A system has 91 J of heat transferred to it raising its temperature 15 °C. What was the increase in entropy? ΔS = Q/ΔT ΔS = 91 J/15 °C ΔS = 6.1 J/°C Guided Practice A system starts out at 56 °C. It loses 117 J of heat causing its temperature to decrease to 11 °C. What was the decrease in entropy? Guided Practice Answer A system starts out at 56 °C. It loses 117 J of heat causing its temperature to decrease to 11 °C. What was the decrease in entropy? ΔS = Q/ΔT ΔS = 17 J/(11 °C – 56 °C) ΔS = -2.6 J/°C Step Up When a system increases its temperature from 14 °C to 29 °C, its entropy also increases by 9 J/°C. How much heat energy was transferred into the system? Step Up Answer When a system increases its temperature from 14 °C to 29 °C, its entropy also increases by 9 J/°C. How much heat energy was transferred into the system? ΔS = Q/ΔT 9 J/°C = Q/(29 °C – 14 °C) Q = 135 J Step Further When a system initially at 59 °C has 65 J of heat transferred into it, its entropy increases by 14 J/°C. What was the final temperature of the system? Step Further Answer When a system initially at 59 °C has 65 J of heat transferred into it, its entropy increases by 14 J/°C. What was the final temperature of the system? ΔS = Q/ΔT 14 J/°C = 65 J/(TF – 59 °C) TF – 59 °C = 65 J/(14 J/°C) TF – 59 °C = 4.3 °C TF Add 59 to both sides! = 63.3 °C Practice Problems Complete the practice problems on the Daily Organizer under Second Law of Thermodynamics Today’s Agenda 5 min • Do Now 5 min • Important Dates 25 min • First Law of Thermodynamics 20 min • Second Law of Thermodynamics 5 min • Exit Ticket