Periodic Table of Element Mrs. Clendenon The Periodic Table Name as many things as you can about what you remember about the periodic table of elements 1 1 IA 1 H Periodic Table 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA 1.00797 2 3 Li 4 5 Be B 6.939 9.0122 3 4 5 6 7 11 Na 12 Mg 22.9898 24.305 19 20 K Ca 3 IIIB 21 Sc 4 IVB 22 Ti 5 VB 23 V 6 VIB 24 Cr 7 VIIB 25 Mn Rb Sr Mo Tc 85.47 55 87.62 88.905 91.22 92.906 95.94 56 57 72 73 74 [99] 75 Ba 7 N 8 O 9 F He 4.0026 10 Ne 10.811 12.0112 14.0067 15.9994 18.9984 20.179 8 26 Fe 9 VIIIB 27 Co 10 28 Ni 39.102 40.08 44.956 47.90 50.942 51.996 54.9380 55.847 58.9332 58.71 37 38 39 40 41 42 43 44 45 46 Cs 6 C 18 VIIIA 2 Y La Zr Hf Nb Ta W Re 132.905 137.34 138.91 178.49 180.948 183.85 186.2 87 88 89 104 105 106 107 Fr Ra Ac Ku [223] [226] [227] [260] Ru Rh Pd 11 IB 29 12 IIB 30 Cu Zn 63.54 47 65.37 48 Ag Cd 13 Al 14 Si 15 P 16 S 17 Cl 18 Ar 26.9815 28.086 30.9738 32.064 35.453 39.948 31 32 33 34 35 36 Ga Ge 65.37 49 72.59 74.9216 78.96 79.909 83.80 50 51 52 53 54 In Sn As Sb Se Te Br I Kr Xe 101.07 102.905 106.4 107.870 112.40 114.82 118.69 121.75 127.60 126.904 131.30 76 77 78 79 80 81 82 83 84 85 86 Os 190.2 108 Ir Pt Au Hg Tl Pb Bi Po At Rn 192.2 195.09 196.967 200.59 204.37 207.19 208.980 [210] [210] [222] 109 http://www.chemsoc.org/viselements/pages/periodic_table.html Periodic Table: It is arranged by metals, nonmetals and metalloids 1 IA 1 18 VIIIA 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA 2 3 4 5 6 7 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB Metals 10 11 IB 12 IIB Nonmetals Metals How would you describe metals? Metals are lustrous (shiny), malleable, ductile, and are good conductors of heat and electricity. They are mostly solids at room temp. Nonmetals – How would you describe these? Nonmetals are the opposite. They are dull, brittle, nonconductors (insulators). Some are solid, but many are gases, and Bromine is a liquid. Metalloids – How would you describe these? Metalloids, aka semi-metals are just that. They have characteristics of both metals and nonmetals. They are shiny but brittle. And they are semiconductors. Across the Periodic Table Elements are arranged horizontally across the periodic table (rows 1-7), what is this arrangement called? Periods These elements have the same number of valence shells. How many shells are in period 2? 6? Period 2 would have two shells, while period 6 would have 6. 1 IA 1 18 VIIIA 2 IIA 13 IIIA 2nd Period 2 3 3 IIIB 4 IVB 5 VB 6 VIB 4 5 6 7 6th Period 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 14 IVA 15 VA 16 VIA 17 VIIA Down the Periodic Table Elements are arranged vertically down the periodic table (columns or group, 1- 18 or 1-8 A,B), what are they called? Family/Groups What do these elements have in common? Same number of valence electrons. 1 IA 1 18 VIIIA Alkali Family: 1 e- in the valence shell 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 2 3 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 4 5 6 7 Halogen Family: 7 e- in the valence shell 17 VIIA The roman numerals represent the number of valence electrons each family have. How many valence electrons are in the Alkali Earth Family? 1 valence electron 1 IA 1 18 VIIIA Alkali Family: 2 IIA 13 IIIA 14 IVA 2 3 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 4 Halogen Family: 5 6 7 15 VA 16 VIA 17 VIIA H Li 1s1 1 1s22s1 3 Na 11 K 19 Rb 37 Cs 55 Fr 87 Do you notice any similarity in these configurations of the alkali metals? They all have 1 valence electron 1s22s22p63s1 1s22s22p63s23p64s1 1s22s22p63s23p64s23d104p65s1 1s22s22p63s23p64s23d104p65s24d10 5p66s1 1s22s22p63s23p64s23d104p65s24d105p66s 24f145d106p67s1 Valence electrons for Elements Recall that the valence electrons for the elements can be determined based on the elements position on the periodic table. This is based on the family/group they are found in Infamous Families of the Periodic Table Name all 6 families. Halogen Noble Gas Halogens Alkali Alkaline (earth) 1 IA 1 18 VIIIA 2 IIA 13 IIIA Transition Metals 2 3 4 5 6 7 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 14 IVA 15 VA 16 VIA 17 VIIA Trend in Atomic Radius Atomic Radius: The size of at atomic radius decrease the closer the element are to the noble gases (to the right). The atomic radius increases as the elements increase in the number of periods (moving down). Which atom is larger in size? K or Kr? ___________ K In or Rb ? ________ Rb Periodic Table: electron behavior The periodic table can be classified by the behavior of their electrons METALS Alkali Alkaline Transition These elements tend to give up e and form CATIONS become + METALLOID These elements will give up e- or accept e- NON-METALS Noble gas Halogens Halogens These elements tend to accept e- and form ANIONS become negative 1 IA 1 18 VIIIA 2 IIA 13 IIIA 2 3 4 5 6 7 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 14 IVA 15 VA 16 VIA 17 VIIA Trends in Atomic and Ionic Size Metals Nonmetals Group 1 Group 13 Group 17 e e Li+ Li 152 F 64 60 e e Na+ Na 95 e e 136 e Al3+ Al 143 F1- 50 Cl Cl1- 99 186 181 e e K+ Br K 227 133 Cations are smaller than parent atoms 114 Br-1195 Anions are larger than parent atoms Trend in Electronegativity Electronegativity: •Electronegativity is a measure of an atom’s attraction for another atom’s electrons. •Elements with a high electronegatvity (EN) means it pulls the electron towards itself strongly! •Metals are electron givers and have low EN while nonmetals are electron takers and have high EN. •What about the noble gases? •They have no EN because they have a full outer electron orbital Electronegativity F Cs Which element has the highest EN? Fluorine Which element has the least EN? Cesium Electronegativity 1A 1 Period 2 3 4 5 6 7 8A H 2.1 2A 3A 4A 5A 6A 7A Li Be B C N O F 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Al Si P S Cl 1.5 1.8 2.1 2.5 3.0 Na Mg 1.2 3B 4B 5B 6B K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br 0.8 1.0 1.3 1.5 1.6 1.6 1.7 1.6 1.8 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te 0.8 1.2 1.4 1.6 1.8 1.9 2.2 2.2 2.2 1.7 1.7 1.8 Cs Ba La* Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At 0.7 1.1 1.3 1.5 1.7 1.9 2.2 2.2 1.8 1.8 2.0 1.0 0.9 y Fr Ra Ac 0.7 0.9 1.1 8B 7B 1.5 1.8 2.2 1.8 1B 2B 0.9 1.8 1.9 1.9 2.4 1.9 2.0 1.9 1.9 2.4 2.1 * Lanthanides: 1.1 - 1.3 yActinides: 1.3 - 1.5 Hill, Petrucci, General Chemistry An Integrated Approach 2nd Edition, page 373 Below 1.0 2.0 - 2.4 1.0 - 1.4 2.5 - 2.9 1.5 - 1.9 3.0 - 4.0 2.8 I 2.5 2.2 Trend in Ionization Energy Definition – amount energy needed to remove the outer most electron As you go down a group, the first IE decreases because...The electron is further away from the attraction of the nucleus, and The larger the atom is, the easier its electrons are to remove. Trend from left to right – increases Trend from top to bottom – decreases First Ionization energy He Helium is a noble gas, the energy to remove its outer valence electron will be extremely high Why does Lithium have a low IE? Lithium would have a lower IE because it has a larger atomic radius than H H Be B Li Why do atoms steal electrons or give them away? Atoms behave in ways to try and achieve a noble gas configuration. Would Beryllium have a higher first or second ionization energy level? Second Atomic number Ionization Energy F N o b l e G a s Cs Summary of Trend Ionization Energy: Largest toward Fluorine Electronegativity: Most favorable Fluorine Atomic Radius: Largest toward SW corner of PT Review Game Round 1 White board How many valence electrons does Krypton have? 8 What is the family name of the group 2A elements? Alkaline Earth Metals Name three characteristics of a metal. Metals are lustrous (shiny), malleable, ductile, and are good conductors of heat and electricity. They are mostly solids at room temp. What is the family name of the group 8A elements? Nobel Gases Draw the Lewis Dot structure for chlorine. How many valence electrons does this element have? Ca 1s22s22p63s23p64s2 2 Where are metalloids located? They are the elements touching the staircase. What is the family name of the group 7A elements? Halogens A vertical column ( ↓ ) of elements on the periodic table may also be referred to as a: Family or Groups What is the family name of the group 1A elements? Alkaline metals Describe three characteristics of a nonmetal. Nonmetals are the opposite. They are dull, brittle, nonconductors (insulators). Some are solid, but many are gases, and Bromine is a liquid Draw the lewis dot structure for Bromide. A horizontal row ( → ) of elements on the periodic table may also be referred to as a: Period Review Game Round 2 clickers Cations have a ______________ charge and are ______________ than the atoms from which they formed. A. negative/larger B. positive/smaller C. positive/larger D. negative/smaller B Given the representation of a chlorine atom, which circle might represent an atom of bromine? A. Circle C B. None of these C. Circle D D. Circle B c Of the following elements, which one would have the largest radius? A. Hydrogen (H) B. Potassium (K) C. Sodium (Na) D. Cesium (Cs) d The elements with the smallest atomic radii are found in the: A. lower left-hand corner of the periodic table B. lower right-hand corner of the periodic table C. upper left-hand corner of the periodic table D. upper right-hand corner of the periodic table d Anions have a ______________ charge and are ______________ than the atoms from which they formed. A. positive/smaller B. negative/smaller C. positive/larger D. negative/larger d Of the following elements, which one would have the largest ionization energy? A. Hydrogen (H) B. Potassium (K) C. Cesium (Cs) D. Sodium (Na) a The energy required to remove an electron from an atom is known as: A. electronegatvity B. radioactivity C. electron affinity D. ionization energy D Given the representation of a chlorine atom, which circle might represent an atom of fluorine? A. Circle C B. None of these C. Circle B D. Circle D b The most active metals are located in the: A. upper right hand corner of the periodic table B. lower left hand corner of the periodic table C. upper left hand corner of the periodic table D. lower right hand corner of the periodic table B Of the following elements, which one would have the smallest radius? A. Bromine (Br) B. Fluorine (F) C. Chlorine (Cl) D. Iodine (I) B As one moves down ( ↓ ) a group on the periodic table, the ionization energy of the elements encountered tends to: A. stay the same B. decrease C. increase B Of the following elements, which one would have the largest electronegativity energy? A. Chlorine (Cl) B. Fluorine (F) C. Iodine (I) D. Bromine (Br) B Of the following elements, which one would have the largest radius? A. Lithium (Li) B. Nitrogen (N) C. Boron (B) D. Neon (Ne) A Given the representation of a chlorine atom, which circle might a chloride ion, Cl-? A. Circle C B. Circle B C. Circle D D. None of these D As one moves from left to right ( → ) within a period across the periodic table, the atomic radius of the elements encountered tends to: A. increase B. stay the same C. decrease C Which of these elements would have the lowest first ionization energy? A. Element D B. Element C C. Element A D. Element B A The least electronegative elements are the: A. Transition metals B. Alkali metals C. Halogens D. Metalloids B As one moves from left to right ( → ) within a period across the periodic table, the ionization energy of the elements encountered tends to: A. decrease B. increase C. stay the same B The measure of the attraction that an atom has for electrons involved in chemical bonds is known as: A. electron affinity B. radioactivity C. electronegatvity D. ionization energy C