LIVING IN THE ENVIRONMENT, 18e G. TYLER MILLER • SCOTT E. SPOOLMAN 15 Nonrenewable Energy ©©Cengage CengageLearning Learning2015 2015 Core Case Study: Is the United States Entering a New Oil and Natural Gas Era? • Oil and natural gas – Two most widely used natural resources in the U.S. • Oil consumption is increasing – New extractions from oil shale cause environmental harm – Burning oil and natural gas will continue adding greenhouse gases to the atmosphere © Cengage Learning 2015 Natural gas 28% Nuclear power 8% Coal 22% Hydropower 3% Oil 37% Geothermal, solar, wind biomass 2% Fig. 15-1a, p. 374 Fig. 15-1b, p. 374 15-1 What is Net Energy and Why Is It Important? • Energy resources vary greatly in their net energy yields © Cengage Learning 2015 Net Energy Is the Only Energy That Really Counts • Net energy yield – Total amount of useful, high-quality energy available from a resource minus the energy needed to make the energy available to consumers – Related to: • Energy return on investment (EROI) – Energy obtained per unit of energy used to obtain it © Cengage Learning 2015 Net Energy Is the Only Energy That Really Counts (cont’d.) • First law of thermodynamics (law of conservation of energy): – It takes high-quality energy to get high-quality energy • Pumping oil from ground, refining it, and transporting it • Second law of thermodynamics (High qualitylow quality) – Some high-quality energy is wasted at every step © Cengage Learning 2015 Some Energy Resources Need Help to Compete in the Marketplace • An energy resource with a low or negative net yield cannot compete in open markets with alternatives that have higher net energy yields – Need subsidies from taxpayers • For example: nuclear power – Has a low net energy yield because a great deal of high quality energy is needed – The uranium fuel cycle is costly – Heavily subsidized © Cengage Learning 2015 15-2 What Are the Advantages and Disadvantages of Oil? • Conventional crude oil is abundant and has a medium net energy yield, but using it causes air and water pollution and releases greenhouse gases to the atmosphere – Unconventional heavy oil from oil shale rock and tar sands exists in potentially large supplies but has a low net energy yield and a higher environmental impact than conventional oil © Cengage Learning 2015 We depend heavily on oil • Oil is the world’s most widely used energy resource. • Used to: – heat our homes – grow most of our food – transport people and goods – make other energy resources available for use – manufacture most of the things we use everyday from plastics to cosmetics to asphalt on roads. © Cengage Learning 2015 We Depend Heavily on Oil • Crude oil (petroleum) – Black, gooey liquid consisting mostly of a mix of different combustible hydrocarbons along with small amounts of sulfur, oxygen, and nitrogen impurities. – Formed from decayed remains of ancient organisms that were crushed beneath layers of rock for millions of years. – Oil companies use huge machines to drill holes and remove rock cores to extract oil. © Cengage Learning 2015 • Peak production – – After a decade or so, the pressure in the well drops and the oil production declines – Global peak production for all world oil occurs when conventional oil declines faster than new oil field are found • Crude oil cannot be used as it comes out of the ground – Must be refined into: – Petrochemicals © Cengage Learning 2015 Lowest Boiling Point Gases Gasoline Aviation fuel Heating oil Diesel oil Naphtha Grease and wax Heated crude oil Furnace Asphalt Highest Boiling Point Fig. 15-4a, p. 377 Fig. 15-4b, p. 377 Are We Running Out of Conventional Oil? • How much oil is there? • Availability determined by: – 1.Demand – 2.Technology – 3. Rate at which we remove the oil – 4. Cost of making oil available – 5. Market price • Proven oil reserves – – available deposits from which oil can be extracted © Cengage Learning 2015 profitably; not fixed. Are We Running Out of Conventional Oil? (cont’d.) • To avoid running out of oil: • 1. Use unconventional heavy oil – Higher environmental cost; production cost • 2. Rely on three major options: – 1. Live with much higher oil prices – 2. Extend oil supplies (for example, improve vehicle efficiency) – 3. Use other energy sources © Cengage Learning 2015 Barrels of oil per year (billions) © Cengage Learning 2015 Projected U. S. oil consumption Arctic refuge oil output over 50 years Year Fig. 15-5a, p. 379 © Cengage Learning 2015 Fig. 15-5b, p. 379 Use of Conventional Oil Has Environmental Costs • Land disruption, greenhouse gas emission, air pollution, water pollution, and loss of biodiversity • Burning oil accounts for 43% of global CO2 emissions © Cengage Learning 2015 Trade-Offs Conventional Oil Advantages Disadvantages Ample supply for several decades Water pollution from oil spills and leaks Net energy yield is medium but decreasing Environmental costs not included in market price Low land disruption Releases CO2 and other air pollutants when burned Efficient distribution system Vulnerable to international supply interruptions © Cengage Learning 2015 Fig. 15-6, p. 380 Case Study: Oil Production and Consumption in the United States • The U.S.: – Produces 9% of the world’s oil and uses 23% of world’s oil – Has about 2% of world’s proven oil reserves – Imports 52% of its oil • Should we look for more oil reserves? – Extremely difficult – Expensive and financially risky © Cengage Learning 2015 Heavy Oil From Oil Shale Rock • A potential supply of heavy oil is shale oil • Oil shale rock contains kerogen that can be distilled to produce shale oil • 72% of the world’s reserve is in arid areas of western United States – Locked up in rock; requires lots of energy, money, and water – Lots of pollution, in air and water – Low net energy yield © Cengage Learning 2015 © Cengage Learning 2015 Fig. 15-7, p. 381 Heavy Oil from Tar Sands • Another soil of heavy oil is tar sands, or oil sands, which are a mixture of clay, sand, water, and contains bitumen ( a thick, sticky, tarlike heavy oil) • Extensive deposits in Canada and Venezuela – Oil sands have more oil than in Saudi Arabia • Problems with extraction – Serious environmental impacts – Low net energy yield © Cengage Learning 2015 © Cengage Learning 2015 Fig. 15-8, p. 381 Trade-Offs Heavy Oils from Oil Shale and Tar Sand Advantages Disadvantages Large potential supplies Low net energy yield Easily transported within and between countries Releases CO2 and other air pollutants when produced and burned Efficient distribution system in place Severe land disruption and high water use Fig. 15-10, p. 382 15-3 What Are the Advantages and Disadvantages of Using Natural Gas? • Conventional natural gas: – Is more plentiful than oil – Has a medium net energy yield and a fairly low production cost – Is a clean-burning fuel • However, producing it has created environmental problems © Cengage Learning 2015 Natural Gas Is a Useful, Clean-Burning, but Not Problem-Free Fossil Fuel • Natural gas – – mixture of gases, 50-90% methane CH4 – Medium net energy yield – Widely used for cooking, heating space and water, industrialized purposes – Provides 28% of energy consumed in US – Burns cleaner than oil and much cleaner than coal. © Cengage Learning 2015 • Conventional natural gas – Often found in deposits above conventional oil, as well as in shale rock. – When a natural gas deposit is tapped, propane and butane gases can be liquefied under high pressure and removed as: – 1. Liquefied petroleum gas (LPG) • Stored in tanks © Cengage Learning 2015 – 2. Liquefied natural gas (LNG) • Way by which to transport across oceans • Low net energy yield © Cengage Learning 2015 Natural Gas Is a Useful, Clean-Burning, but Not Problem-Free Fossil Fuel (cont’d.) • The U.S. produces natural gas conventionally and from shale rock – US does not have to rely on natural gas imports – Increasing environmental problems with shale rock extraction © Cengage Learning 2015 Trade-Offs Conventional Natural Gas Advantages Disadvantages Ample supplies Low net energy yield for LNG Versatile fuel Production and delivery may emit more CO2 and CH4 per unit of energy produced than coal Medium net energy yield Emits less CO2 and other air pollutants than other fossil fuels when burned Fracking uses and pollutes large volumes of water Potential groundwater pollution from fracking Fig. 15-11, p. 383 Case Study: Natural Gas Production and Fracking in the U.S. • Fracking – Drilling wells; using huge amounts of water, sand, and chemicals; dealing with toxic wastewater; transporting the natural gas • Drinking water contaminated with natural gas can catch fire • Fracking has several harmful environmental effects © Cengage Learning 2015 © Cengage Learning 2015 Fig. 15-12, p. 384 © Cengage Learning 2015 Fig. 15-13, p. 385 Unconventional Natural Gas • 1.Coal bed methane gas – Found in coal beds near the earth’s surface; in shale beds – High environmental impacts of extraction • 2. Methane hydrate – Trapped in icy water; in permafrost environments; on ocean floor – Costs of extraction is currently too high © Cengage Learning 2015 15-4 What Are the Advantages and Disadvantages of Coal? • Conventional coal is plentiful and has a high net energy yield at low costs, but using it results in a very high environmental impact – We can produce gaseous and liquid fuels from coal, but they have lower net energy yields and using them would result in higher environmental impacts than those of conventional coal © Cengage Learning 2015 Coal Is a Plentiful but Dirty Fuel • Coal – Solid fossil fuel formed from the remains of land plants that were buried 300-400 million years ago and exposed to intense heat and pressure over millions of years • Burned in power plants – Generates 42% of the world’s electricity Abundant fossil fuel– world’s largest coal reserves United States, Russia, China © Cengage Learning 2015 Coal Is a Plentiful but Dirty Fuel (cont’d.) • Environmental costs of burning coal – Dirtiest of all fossil fuels – Severe air pollution • Sulfur released as SO2 • Large amount of soot • CO2 • Trace amounts of mercury and radioactive materials © Cengage Learning 2015 Increasing moisture content Peat Lignite (not a coal) (brown coal) Heat Pressure Partially decayed plant matter in swamps and bogs; low heat content Increasing heat and carbon content Bituminous (soft coal) Heat Heat Pressure Low heat content; low sulfur content; limited supplies in most areas Anthracite (hard coal) Extensively used as a fuel because of its high heat content and large supplies; normally has a high sulfur content Pressure Highly desirable fuel because of its high heat content and low sulfur content; supplies are limited in most areas © Cengage Learning 2015 Fig. 15-14, p. 386 Waste heat Coal bunker Cooling tower transfers waste heat to atmosphere Turbine Generator Cooling loop Stack Pulverizing mill Boiler Condenser Filter Ash disposal Fig. 15-15a, p. 387 Fig. 15-15b, p. 387 The Clean Coal Campaign • To keep their profits, coal companies and energy companies has fought: – Classifying carbon dioxide as a pollutant – Classifying coal ash as hazardous waste – Air pollution standards for emissions • The 2008 clean coal campaign – Note: there is no such thing as clean coal © Cengage Learning 2015 Coal-fired electricity 286% Synthetic oil and gas produced from coal 150% Coal 100% Tar sand 92% Oil 86% 58% Natural gas Nuclear power fuel cycle Geothermal 17% 10% © Cengage Learning 2015 Fig. 15-17, p. 388 Trade-Offs Coal Advantages Disadvantages Ample supplies in many countries Severe land disturbance and water pollution Medium to high net energy yield Fine particle and toxic mercury emissions threaten human health Low cost when environmental costs are not included Emits large amounts of CO2 and other air pollutants when produced and burned © Cengage Learning 2015 Fig. 15-20, p. 389 We Can Convert Coal into Gaseous and Liquid Fuels • Conversion of solid coal to: – Synthetic natural gas (SNG) by coal gasification to remove sulfur and impurities from coal – Methanol or synthetic gasoline by coal liquefaction, synfuels, cleaner version of coal • Are there benefits to using these synthetic fuels? – Eh…—requires mining of 50% more coal; produces and burning synfuels leads to more CO2 in atmosphere; lots of water; lots energy; © Cengage Learning 2015 high cost for low yield Trade-Offs Synthetic Fuels Advantages Disadvantages Large potential supply in many countries Low to medium net energy yield Vehicle fuel Lower air pollution than coal Requires mining 50% more coal with increased land disturbance, water pollution and water use Higher CO2 emissions than coal Fig. 15-21, p. 389 15-5 What Are the Advantages and Disadvantages of Using Nuclear Power? • Nuclear power has a low environmental impact and a very low accident risk, but its use has been limited by: – A low net energy yield, high costs, fear of accidents, and long-lived radioactive wastes – Its role in spreading nuclear weapons technology © Cengage Learning 2015 Nuclear Power Plant • Nuclear Power Plant – A highly complex and costly system designed to perform a relatively simple task: to boil water and produce steam that spins a turbine and generates electricity. © Cengage Learning 2015 How Does a Nuclear Fission Reactor Work? • Uses complex and costly controlled nuclear fission reaction • Takes place in a reactor – Light-water reactors; Very inefficient – Fueled by uranium ore and packed as pellets in fuel rods and fuel assemblies in the core of a reactor – Control rods absorb neutrons generated in fission, regulating the rate of fission and amount o power produced © Cengage Learning 2015 How Does a Nuclear Fission Reactor Work? (cont’d.) • Takes place in a reactor (continued) – Water is the usual coolant; keeps components from melting and releasing radioactivity into the environment. – Containment shell around the reactor core to ensure radioactive materials do not escape into the environment. – Water-filled pools or dry casks for storage of radioactive wastes and spent fuel rod assemblies © Cengage Learning 2015 Small amounts of radioactive gases Uranium fuel input (reactor core) Control rods Containment shell Heat exchanger Waste heat Steam Turbine Generator Hot coolant Hot water output Coolant Cool water input Moderator Shielding Pressure Coolant vessel passage Periodic removal and storage of radioactive wastes and spent fuel assemblies Periodic removal and storage of radioactive liquid wastes Water Useful electrical energy about 25% Waste heat Condenser Water source (river, lake, ocean) Fig. 15-22a, p. 390 Fig. 15-22b, p. 390 What Is the Nuclear Fuel Cycle? • 1. Mine the uranium • 2. Process and enrich the uranium to make the fuel • 3. Use it in the reactor • 4. Safely store the radioactive waste • 5. Decommission the reactor © Cengage Learning 2015 Decommissioning of reactor Fuel assemblies Enrichment of UF6 Reactor Fuel fabrication (conversion of enriched UF6 to UO2 and fabrication of fuel assemblies) Conversion of U3O8 to UF6 Uranium-235 as UF6 Plutonium-239 as PuO2 Temporary storage of spent fuel assemblies underwater or in dry casks Spent fuel reprocessing Low-level radiation with long half-life Mining uranium ore (U3O8) Open fuel cycle today Recycling of nuclear fuel Geologic disposal of moderate and high-level radioactive wastes Fig. 15-23, p. 392 Trade-Offs Conventional Nuclear Fuel Cycle Advantages Disadvantages Low environmental impact (without accidents) Low net energy yield Emits 1/6 as much CO2 as coal Produces long-lived, harmful radioactive wastes Low risk of accidents in modern plants High overall cost Promotes spread of nuclear weapons © Cengage Learning 2015 Fig. 15-24, p. 392 Storing Radioactive Spent-Fuel Rods Presents Risks • Uranium fuel in a nuclear reactor lasts for 34 years; reactors are shut down for refueling • Extremely hot spent-fuel rods must be replaced, and are stored and cooled in water-filled pools • Placed in dry casks made of heat-resistant metal alloys and concrete filled with Helium • Must be stored for thousands of years •© Cengage Vulnerable to terrorist attack Learning 2015 © Cengage Learning 2015 Fig. 15-25, p. 393 Dealing with Radioactive Nuclear Wastes Is a Difficult Problem • High-level radioactive wastes – Must be stored safely for 10,000–240,000 years; too expensive to reprocess • Where can it be stored? – Deep burial: safest and cheapest option – There is still no facility – Shooting it into space is too dangerous © Cengage Learning 2015 Dealing with Radioactive Nuclear Wastes Is a Difficult Problem (cont’d.) • Plans in the U.S. to build a repository for high-level radioactive wastes in the Yucca Mountain desert region (Nevada) • Many problems including: – Cost of $96 billion – Rock fractures – Earthquake zone – Decrease national security © Cengage Learning 2015 Dealing with Radioactive Nuclear Wastes Is a Difficult Problem (cont’d.) • Dealing with old nuclear power plants: – Nuclear power plants reach the end of useful life after 40-60 years and must close – Decommission or retire the power plant – Dismantle the plant and safely store the radioactive materials – Enclose the plant behind a physical barrier with full-time security until a storage facility has been built – Enclose the plant in a tomb • Monitor this for thousands of years © Cengage Learning 2015 Can Nuclear Power Help Reduce Climate Change? • Nuclear power plants – no CO2 emission • However, building plants as well as the nuclear fuel cycle – emits CO2 • Need high rate of building new plants, and a storage facility for radioactive wastes © Cengage Learning 2015 Experts Disagree about the Future of Nuclear Power • Proponents of nuclear power: – Fund more research and development on safer and lest costly type of reactions – Pilot-plant testing of potentially cheaper and safer reactors • Opponents of nuclear power: – Very expensive; does not save on oil – Questions of safety – Fund rapid development of energy efficient and renewable energy resources © Cengage Learning 2015 Experts Disagree about the Future of Nuclear Power (cont’d.) • New technologies – Advanced Light Water Reactors (ALWRs) • Safer – Thorium based reactors in place of uranium • Less costly and safer © Cengage Learning 2015 © Cengage Learning 2015 Fig. 15-26, p. 395 Case Study: The 2011 Nuclear Power Plant Accident in Japan • Triggered by a major offshore earthquake and resulting tsunami • Four key human-related factors: – No worst-case scenarios – Seawalls too short – Design flaws – Relationship between plant owners and government © Cengage Learning 2015 Fig. 15-27, p. 396 Is Nuclear Fusion the Answer? • Fusion – Two isotopes (hydrogen) fused together at extremely high temperatures to form a heavier nucleus; Releases energy in the process – Scientists think it could form a limitless source of energy – No risk of a meltdown or release of large amounts of radioactive material;little risk of nuclear weapons. – Could also destroy toxic wastes and supply electricity to desalinate water! © Cengage Learning 2015 Is Nuclear Fusion the Answer? • Technology is very difficult to develop; 50 years of research and we’re still in the laboratory stage. © Cengage Learning 2015 Three Big Ideas • A key factor to consider in evaluating the long-term usefulness of any energy resource is its net energy yield • Conventional oil, natural gas, and coal: – Plentiful and have moderate to high net energy yields – Use of these fossil fuels, especially coal, has a high environmental impact © Cengage Learning 2015 Three Big Ideas (cont’d.) • The nuclear power fuel cycle has a low environmental impact and a very low accident risk, but limited use because of: – High costs – A low net energy yield – Long-lived radioactive wastes – Its role in spreading nuclear weapons technology © Cengage Learning 2015 Tying It All Together: A New U.S. Oil and Natural Gas Era and Sustainability • Conventional fossil fuels have high net energy yields • We cannot recycle energy – Recycling materials can help reduce energy needs • Relying on a diversity of energy resources – Will reduce environmental impacts © Cengage Learning 2015