Atomic Structure Click to start Question 1 Which statement is correct about the isotopes of an element? They have the same mass number. They have the same number of protons and neutrons in the nucleus. They have more protons than neutrons. They have the same electron arrangement or configuration. Wrong Answer! Isotopes are 2 or more atoms of the same element with different number of neutrons (and therefore different relative isotope masses). They have the same numbers of protons and hence the same number of electrons. Question 2 A chemical element with the symbol X has the electron arrangement 2,8,6. Which chemical species is this chemical element most likely to form? the ion X3+ the ion X6+ the compound H2X [2H+X2-] the compound XF8[X8+ 8F-] Wrong Answer! H2S : [2H+X2-] Question 3 Which of the following particles contains more electrons than neutrons? 1 35 39 I. 1 H II. 17 Cl III. 19 K I only II only I and II only II and III only Wrong Answer! i. 1p 1e 0n ii. 17p 18e 18n iii. 19p 18e 20n Question 4 What information about the structure of a helium atom can be gained from its emission spectrum? Most of the mass of the atom is in its nucleus. The electrons may exist in any of several energy levels. The electrons in the helium atom are held near the nucleus. A helium atom contains two electrons and two protons. Wrong Answer! Emission spectra provide evidence that electrons exist in fixed energy levels within an atom. Question 5 What is the correct number of each particle in a fluoride ion, 19F- ? Note : p represents protons; n represents neutrons ; e represents electrons 9p , 10n , 8e 9p , 10n , 9e 9p , 10n , 10e 9p , 19n , 10e Wrong Answer! 9 protons (from periodic table) ; 10 electrons in the atom ( due to the single negative charge) and 10 neutrons (199) Question 6 How many valence electrons are present in the element of atomic number 14? 4 3 2 1 Wrong Answer! The element is Silicon with the element arrangement 2,8,4 Question 7 Which statement is correct about a line emission spectrum? Electrons neither absorb nor release energy as they move from low to high energy levels. Electrons absorb energy as they move from high to low energy levels. Electrons release energy as they move from low to high energy levels. Electrons release energy as they move from high to low energy levels. Wrong Answer! Electrons release energy as they move from high to low energy levels. Light is released. Question 8 What fraction of a radioisotope will remain after three half-lives? 1/16 1/3 1/8 3/4 Wrong Answer! 1 ½ ¼ 1/8 Question 9 A particular element consists of two isotopes: 72% of mass number 85 and 28% of mass number 87. What is the expected range of the relative atomic mass? Less than 85 Between 85 and 86 Between 86 and 87 More than 88 Wrong Answer! Relative atomic mass is a weighted average. The more abundant isotope has a mass number of 85. 72% x 85 + 28% x 87 Question 10 Which is the correct sequence for some of the various stages that typically occur in the analysis of an element during mass spectrometry? Electron bombardment, vaporization, acceleration, deflection, detection. Vaporization, electron bombardment, deflection, acceleration, detection. Vaporization, electron bombardment, acceleration, deflection, detection. Deflection, acceleration, electron bombardment, vaporization, detection. Wrong Answer! The sample is first vaporized by lowering the surrounding pressure. A mass spectrometer can only accept gaseous atoms or molecules. The molecules or atoms are then subjected to bombardment by high energy electrons which remove the valence electron to form unipositive ions. The ions are then accelerated by an electric field before entering a powerful magnetic field where they experience deflection according to their mass-to-charge ratio. Question 11 The atomic numbers and mass numbers for four different nuclei are given in the table below. Which two are isotopes? Atomic number Mass number I II III IV 101 102 102 103 258 258 260 259 I and II II and III III and IV I and IV Wrong Answer! I. 157 neutrons II. 156 neutrons III. 158 neutrons IV. 156 neutrons Question 12 Which electronic transition within a hydrogen atom requires the greatest energy? n=1n=2 n=2n=3 n=3n=5 n=5n=∞ Wrong Answer! Energy levels rapidly converge with an increase in n. Congratulations! • You have completed the quiz!