Unit VI: Study Guide Chapters 10, 11.4-11.6, and 13 To Know: -Definitions of all vocabulary words in bold and all sentences in italics. -Common compounds (and characteristics) of gases in table 10.1 on page 394. -Conversion factors for various pressure units (bottom of page 396). -Boyle’s law (10.2 on page 399) -Charles’ law (10.3 on page 400) -Avogadro’s law (10.4 on page 401) -Combined gas law (10.8 on page 405) -The ideal-gas equation (10.5 on page 402) -Density equation (10.10 on page 407) -The molar volume of an ideal gas at STP -Dalton’s law (10.12 on page 410 or 10.15 on page 411) -Kinetic molecular theory (not verbatim but generally) on page 414 -Root-mean-square equation (10.22 on page 417) -Graham’s law (10.23 on page 418) -The trends for effusion and diffusion -Differences between real and ideal gases. -Phase changes and names (figure 11.17 on page 449) -Signs of enthalpies of various phase changes -Relationship of vapor pressure to boiling point -Energetics of solution formation (figure 13.4 on page 531) -The process in forming a supersaturated solution -Factors affecting solution formaton (solute-solvent interactions, pressure and temperature) -Units of concentration: Mass % (13.5 on page 542), ppm (13.6 on page 542), ppb, mole fraction (13.7 on page 543), Molarity (13.8 pn page 543), and molality (13.9 on page 543). -Raoult’s law (13.10 on page 547) -Bp elevation and FP depression (13.11 on page 549 and 13.12 on page 550) -Osmotic pressure equation (13.13 on page 553) To Do: -Convert between units of pressure (mm Hg, atm, torr, Pa or kPa). -Calculate the effect of changes in variables on gases using the appropriate gas law. -Use the ideal-gas equation to solve gas problems. -Calculate the density or molar mass of a gas using equation 10.10. -Perform stoichiometric calculations using gases. -Use Dalton’s law to calculate partial or total pressures of a gas. -Calculate mole fraction. -Calculate partial pressures of gases collected over water. -Calculate the rms speed of a molecule using equation 10.22. -Use Graham’s law to calculate the rates of effusion or molar masses of a given gas. -Predict the relative rates of effusion or diffusion for two gases. -Use van der Waals equation to perform gas law calculations for real gases. -Calculate enthalpies for changes in temperature or phase. -Interpret a heating curve or phase diagram. -Locate the triple point, critical point, normal melting/boiling point, regions of solid, liquid, and gas states, and melting/boiling point at different pressures on a phase diagram. -Predict the relative solubility of a solute in a given solvent. -Perform calculations with and convert between units of concentration. -Perform stoichiometric calculations using solutions. -Calculate the lowering of vapor pressure by the addition of a nonvolatile solute using Roault’s law. -Calculate boiling point elevation and freezing point depression. -Calculate the osmotic pressure of a solution using equation 13.13.