Integrated Science Week 8 Competency: Classify matter in the environment in terms of their properties. Lesson 8-1 Density of Matter Time Frame: three periods I. Objectives: At the end of the activities, the students should be able to: 1. 2. 3. 4. 5. 6. II. discuss why some objects sink while others float in water; compare the densities of various objects; compute for the densities of solids, liquids and gases; discuss the applications of density to daily life; manifest positive attitudes in solving daily problems; and demonstrate cooperation in group activities. Subject Matter A. Topic: Density of solid, liquids and gases Applications of density to daily life B. References: Rabago, Lilia M..(1997). Science and Technology I. Araneta Avenue, Quezon City. pp.66 – 67. C. Materials: Refer to Student Activity Sheet 8-1a and 8-1b III. SD Publications, Inc. Learning Tasks (Days 1 and 2) A. Motivation 1. Ask the students to recall the properties of matter learned the previous week. Tell them that in today’s activity, they will study another property of matter called density. You can demonstrate floating and sinking of objects to show that their observation can be explained by the concept of density. 2. Ask them to recall the concepts of mass and volume. What is the difference between these two properties? 3. Ask the students to describe the methods they have previously learned in determining the volume of a liquid, a regular and an irregular solid. B. Preliminary Activity 1. Prepare the materials and put in respective trays. You will use the “STATIONS METHOD” for this activity. 2. Give instructions on how the groups will take turns in going the activities in the “STATIONS”. BSE-Department of Education 119 3. Drill on laboratory safety and procedures, as follows: Use of the beam balance and graduated cylinder Techniques in handling materials and glassware/equipment C. Activity Proper 1. Ask students to perform activity on Density of Matter 8-1a. Refer to the Student Activity Sheet 8-1a. 2. Move around and check if the students are doing the activity properly and on the right track and every group member is busy. Check whether they are following the safety procedures drilled on earlier. 3. Ask questions to check if they understand what they are doing. 4. The activity is good for 2 days. Its up to you to determine where you can cut the activity. This will probably depend on the pace of your students. You can let the students work on the density of solids today and do a short postdiscussion, then continue with the densities of liquids and gas the following day. They will have problem-solving activity on the third day. D. Discussion 1. Process data from the activity. Point out the similarities and differences observed from the data. 2. Discuss the answers to the questions found in the Student Activity Sheet. 3. Discuss the densities of some solids, liquids, and gases. Provide a set of data for the students to compare. E. Generalization Density is the amount of matter in a given volume. Different substances have different densities. Density can be determined by finding the mass and the volume of the objects then using the formula D = M Where d = density, m = mass, v= volume. V Mass is expressed in grams, and volume in mL or cm 3 , therefore the unit of density is g/cm 3 or g/mL. The density of water is 1.0g /mL. Materials that are less dense than water float on it. On the other hand, materials that are denser than water sink in it. E. Valuing/Application Knowing the concept of density is very useful in other ways: a. It can determine the purity of substance. b. Farmers can apply density in their work, they can tell whether certain seeds are good or not for planting by soaking the seeds in water; those that float are bad seeds; those that sink are good for planting. 120 BSE-Department of Education Save life - this is the motto of a lifeguard in a beach. Floating or sinking in water to save a life is the greatest achievement of a lifeguard, his milestone…his HALO! You may stop at this point. Ask the students to prepare their report for Activity 8-1a and read the procedure for Activity 8-1b. F. Assessment 1. Using the data about the densities of common substance (Refer to Science and Technology I by Rabago pp. 77) determine whether the following are true or false. a. b. c. d. e. f. A block of aluminum will float in mercury. T Copper will sink in gasoline. T To float in air, a balloon should be filled with helium. T The mass of 10 cm of gold is 56.9 g. F Ice will float on gasoline. F 90g of vegetable oil will have a volume of 100 m L. F 2. Choose the letter of the best answer. a. Which of the following is ductile? a. copper b. marble c. sandstone d. paper b. 50 mL of water has a density of 1g/cm 3 . What is the density of 25 mL of this water (at the same temperature) ? a. 50 g/cm 3 b. 2 g/cm 3 c. Which of the following can be used to identify a substance ? a. mass b. volume IV. c. 1 g/cm 3 d. 25 g/cm 3 c. weight d. density Agreement/Assignment 1. 2. Explain why goldsmiths can make bracelets and necklace out of metals like gold and silver. Find the density of a piece of concrete whose mass is 8.76 g and whose volume is 3.07 cm 3 . BSE-Department of Education 121 Student Activity Sheet 8.1 Density of Matter Activity 8-1a Materials small block of wood piece of marble oil graduated cylinder beam balance ruler balloon basin water Procedure A. Density of Solid 1. 2. 3. 4. 5. 6. 7. Measure the length, width and height of a block of wood in cm. Calculate the volume of the block in cm 3 . Measure the mass of the wood in grams using the beam balance. Record your data in the data table below. Determine the ratio of the mass to the volume of the block of wood. The ratio is the density of wood. Based on the value you got in the previous step, predict whether the block of wood will float on water or not. Fill a basin with water. Carefully lower the block of wood along the side of the basin. What happened to the block of wood? Does your prediction match with your observation? Determine the density of a piece of limestone by water displacement. B. Density of Liquid 8. 9. C. Density of Gas 10. 11. 12. 13. 14. 122 Get some water. Measure a volume of it similar to the volume of the block of wood in part A. Measure the mass of the water sample. Calculate its density. Repeat step 8 using oil instead of water. Compare its density with that of water. Get the mass of an empty balloon. Inflate the balloon and measure its mass again. Compare the mass of the balloon with and without air. Estimate the volume of air in the balloon. Estimate the density of air. Compare the densities of different substances in Table 8-1a. BSE-Department of Education Table 8-1b. Densities of different substances Substance Cork Hydrogen Concrete Ice Iron Balsa Wood Lead Oxygen Gasoline Density, g/cm3 0.24 0.00009 2.3 0.92 7.8 0.13 11.3 0.0014 0.68 Data A) Material observed Mass (g) Volume (cc) Density (g/cc) Mass (g) Volume (cc) Density (g/cc) Block of wood Water Block of wood in water B) Material observed Water Oil Air Questions 1. 2. 3. 4. 5. 6. 7. 8. What is the density of the block of wood? Do solids have the same densities? Compare the density of wood density with the density of water. What happens to the block of wood when placed in water? Is your prediction correct? Compare the densities of water and oil. Why does oil float on water? Give other liquids that float on water Why does balloon float on water? Which of the substances in Table 8-1b would float in water? Name the solids, the liquids, and the gases in Table 8-1b. Compare the densities of the gases with those of water. BSE-Department of Education 123 Generalization about densities of solids, liquids and gases III. Learning Tasks (Day 3) A. Motivation: Recall density and the method of determining it. Discuss the students’ assignment. Demonstrate the following: Set on the table the following materials: 1 L graduated cylinder small strips of cartolina Soda water marking pen A pea-sized stone raisins Pour the soda water into the graduated cylinder Use the POE strategy as follows: Predict: What will happen if a raisin or a kernel of popcorn is dropped into the liquid? How about a piece of stone? (Students write down their answers in cartolina strips. Let them show their answers. ) Observe: Drop a few raisins and the stone into the graduated cylinder. (The stone sank while the raisins fell to the bottom. Some floated at the liquid’s surface while others floated under the surface. Explain: Students explain what they have observed. (Stone is heavier than water that’s why it sinks; Raisin is lighter than water that’s why it floats). B. Activity Proper Review the activity performed the previous day. Recall the data obtained and the definition formulated from the data. Ask the question: “In what way is density related to your earlier observations?” From the definition of density, show the formula for determining the density of a substance. Illustrate the application of the formula with a few problems. 124 BSE-Department of Education For example: a. If the density of gold is 19.3 g/ cm3, what would be its mass if it occupies a volume is 4 cm3? b. Calculate the density of 10 g of carbon dioxide occupying a volume of 5000 cm3. c. Find the density of an alcohol sample having a mass of 20g and a volume of 25 cm3 . d. A piece of aluminum having a mass of 96.5g was dropped into a graduated cylinder containing 50 mL of water. When aluminum was dropped into the graduated cylinder, the water level rose to 85.0 mL. What is the density of aluminum? Discussion a. Given: density = 19.3 g/cm3 gold, volume = 4 cm3 Req’d: mass Soln: m= D/v ; m = 19.3 g/cm3 / 4 cm3 = 77.2 g b. Given: mass = 10 g carbon dioxide, volume = 5 000 cm3 Req’d: density Soln: D = m/v ; D = 10 g/ 5 000 cm3 = 0.002 g/cm3 c. Given: mass = 20 g alcohol, volume = 25 cm3 Req’d: density Soln: D = m/v ; D = 20 g/ 25 cm3 = 0.8 g/cm3 d. Given: mass = 96.5 g aluminum, volume = 85 – 50 = 35 mL Req’d: density Soln: D = m/v ; D = 96.5 g/ 35 cm3 = 2.76 g/cm Additional Problem If the density of a certain plastic used to make a bracelet is 0.78 g/ cm3, what mass would a bracelet of 4 cm3 have? Would this bracelet float or sink in water? Why? C. Generalization Density is ratio of mass per unit volume. It is expressed in g/ cm3, g/mL, or kg/m3. Substances differ in densities. Generally, solids are densest while gases are least dense. Liquids are denser than gases but less dense than solids. BSE-Department of Education 125 D. Valuing/Application: A person who cannot float in a freshwater lake can float easily in the sea. What does this tell you about the density of the saltwater? “Oil and water don’t mix”, is an old saying. Relate this to what you have learned about density to explain the scientific reason for this saying. Assume that the density of crude oil is 0.93 g/ cm3. a. Why does the oil pose a great danger if it spills in a body of water? b. Is the danger greater to birds and marine animals than it is to fish and other organisms that live on the ocean bottom? c. How is the density of oil an advantage in the clean-up? E. Assessment 1. A block of wood has a volume of 10 cm3 and a mass of 17 g. What is the density of the block of wood? a. 0.59.g/cm3 b. 7 g/cm3 c. 117 g/cm3 d. 170 g/cm3 2. A, B, and C are three immiscible liquids. When placed in a beaker, they occupy the positions indicated below: A B C Which of the following can be concluded? a. b. c. d. A is the densest of the three liquids. C is the least dense of the three liquids. B is denser than C but less dense than A. B is denser than A but less dense than C. 3. If the volume of a boy’s body is 8 cubic meters, with a mass of 20 kg, would he float in water? Explain your answer. 4. Fish are able to remain at a specific depth in water without much trouble. Many fish have an organ called a swim bladder that they can fill with air and empty at will. How does a swim bladder help a fish stay at one level of water? IV. Agreement How can a ship as big as Titanic with a mass of 46,328 tons have a density less than 2 g/ cm3? 126 BSE-Department of Education Student Activity Sheet 8.1b Density of Matter Materials paper ballpen calculator Procedure A. Solve the following density problems: 1. If the density of gold is 19.3 g/ cm3, what would be its mass if it occupies a volume is 4 cm3? 2. Calculate the density of 10 g of carbon dioxide occupying a volume of 5000 cm3. 3. Find the density of an alcohol sample having a mass of 20g and a volume of 25 cm3 4. A piece of aluminum having a mass of 96.5g was dropped into a graduated cylinder containing 50 mL of water. When aluminum was dropped into the graduated cylinder, the water level rose to 85.0 mL. What is the density of aluminum? B. Discuss the solution to the following problems: 1. If the density of a certain plastic used to make a bracelet is 0.78 g/ cm 3, what mass would a bracelet of 4 cm3 have? Would this bracelet float or sink in water? Why? 2. A person who cannot float in a freshwater lake can float easily in the sea. What does this tell you about the density of the saltwater? 3. “Oil and water don’t mix”, is an old saying. Relate this to what you have learned about density to explain the scientific reason for this saying. 4. Assume that the density of crude oil is 0.93 g/ cm3. a. Why does the oil pose a great danger if it spills in a body of water? b. Is the danger greater to birds and marine animals than it is to fish and other organisms that live on the ocean bottom? c. How is the density of oil an advantage in the clean-up? BSE-Department of Education 127 Integrated Science Week 8-Cont’d Competency: Investigate physical and chemical changes taking place in the environment. Lesson 8-2 Acids and Bases in Matter Time Frame: two periods I. Objectives At the end of the activities, the students should be able to: 1. 2. 3. 4. 5. II. prepare acid-base indicators from plants; test the prepared indicators on different concentrations of acids and bases; state the operational definition of acids and bases; testing for acids and bases in commonly-used materials; discuss the significance of knowing the characteristics of acids and bases in relation to the environment. Subject Matter A. Topic: Acids and Bases in Matter B. References: Any Integrated Science or Physical Science Textbook C. Materials: refer to the Student Activity Sheet 8-2a and 8-2b III. Learning Tasks A. Motivation 1. Bring out slices of dalanghita, green mango, and unripe sampalok. Call out 3 volunteers to come near the teacher’s table. Give a piece of dalanghita to the first, a slice of green mango to the second, and a piece of unripe sampalok to the third. Ask them to chew their respective fruit then ask the rest of the class to describe their facial expressions. What seems to be the problem of the three? What could be the reason for their unusual expressions? Ask further questions until students relate acids to sour taste. 2. Ask the students, if acidic foods taste sour, how about basic foods? Tell them that there are materials, other than foods. that are either acidic or basic but they cannot be identified through tasting . Another way is through the use of acid-base indicator. In this activity they will further differentiate acids and bases using improvised indicator from plants. B. Preliminary Activity 1. Gather different leaves: some groups can experiment on mayana leaves while the other groups can use gumamela flowers. Just be sure that they use the red variety. 2. Prepare the acids and bases before hand. Likewise check the materials which students brought from their homes. 128 BSE-Department of Education 3. Discuss objectives of the activity. 4. Drill on laboratory safety and procedures. Handling corrosive chemicals (hydrochloric acid and sodium hydroxide) Heating objects with an alcohol burner Transferring of liquids and solids Decanting liquids Using glassware like beaker, graduated cylinder, droppers, stirring rod Observing materials C. Activity proper a. Depending on the number of groups, assign half of the groups to use mayana leaves, the other half, gumamela flowers. This will show that indicators can be prepared from colored plants. However, the darker the color of plants, the better the extract. If there are other colored flowers in your area, you can ask the students to conduct an investigation of these flowers. The procedure for preparing the indicators is the same for most of the plants. They can even revise the procedure to suit their materials. b. The indicator extract gets spoiled if it is left for more than 5 minutes. Thus, remind the students to add alum immediately to the extract after it is decanted from the solution. Alum stabilizes the extract, makes the extract lasts a little longer, particularly if it is kept in a cool place. The indicator paper can last for a few months if stored in a clean and tightly covered bottle. c. The lesson is good for 2 days. It may be extended to 3 if the students are unable to get the correct color changes. Let them do Activity 8-2a today then conduct a short post-discussion. d. Do Activity 8-4b the following day. You can reduce the materials to be tested if you think it will use much time. It is better that they test materials that they use everyday like shampoo, detergents, and fruit juices. They may be fond of drinking colas, but their fondness may be lessened if they find that colas contain strongly acidic substances. You can ask them to test different brands of shampoos, detergents, fruit juices, and colas to find out which are good or bad for their health. e. Move around and check if the students are doing the activity properly and on the right track. See to it that every group member is busy. Check whether they are following the safety procedures. Ask questions to check if they understand what they are doing. D. Discussion a. Process the results gathered by each group. A group member can report orally or write on manila paper so that other groups can compare their results. Point out similarities and differences in the results. b. Discuss the answers to the questions in the student activity sheet. Additional discussion may include the following: The word acid and alkaline (older term for base) are derived form direct sensory experience. Acid comes from the Latin word acere meaning “sour”. All acids taste sour. Vinegar, fruit extract and juices tastes sour. Aspirin BSE-Department of Education 129 tastes sour if you let it stay awhile in your mouth. Its chemical name is acetylsalicylic acid. The word base, unlike acid, is not related to taste. All bases taste bitter. Mustard and ampalaya taste bitter. Cough syrup and many medicines taste bitter. Manufacturers add sugar and other flavorings to medicines to hide the bitter taste of the active ingredients. Bases feel slippery, sometimes people say soapy. This because they dissolve the oils from your skin and this reduces friction between your thumb and another finger as you rub them together. In essence the base is making soap out of you. Acids and bases destroy each other ‘s properties to produce a new substance, generally called salt. This type of reaction is called neutralization. Chemists use the pH scale to express how acidic (like an acid) or basic (like a base) a substance is. A pH value below 7 means that a substance is acidic, and the smaller the number, the more acidic it is. A pH value above 7 means that a substance is basic, and the larger the number, the more basic it is. The closer the pH of a substance to zero, the more acidic it is. Conversely, the closer the pH of a substance to 14, the more basic it is. Indicators are used to identify acids and bases. They are large organic molecules that change color at various pH values. The most common acid/base indicator is litmus paper which changes color (blue or red) in the presence of any acid or base. Most indicators have complex formulas that are synthesized by reactions. Plant indicators like mayana and gumamela extracts have its own colors at different pH values. These colors and approximate pH values are: Color changes of plant Indicator pH 1 2 3 4 5 6 red light pink red increasing acidity 7 8 9 10 11 12 blue green n e u t r a l 13 14 yellow increasing basicity The coloring matter responsible for the color changes are groups of organic substances known as anthocyanins and flavonoids. A typical anthocyanin shows red in acid, purple in neutral, and blue in basic solution, as observed on blueand red litmus paper. Anthocyanins and flavonoids show red in acids but yellow in strong base as observed on mayana and gumamela extracts. The green color is a mixture of blue and yellow. Both anthocyanins and flavonoids are usually present in many plants. 130 BSE-Department of Education Importance of pH pH and the body. Different aqueous solutions in various parts of our body have different pH values. Stomach fluids are strongly basic due mainly to the presence of dilute hydrochloric acid. The pH of gastric juice is about 2. Acid conditions are needed for the digestion of proteins. Our small intestines need alkaline liquids for the digestion of carbohydrates. Blood is almost neutral. However, blood traveling from the heart to the lungs carries a lot of carbon dioxide. This makes the blood weakly acidic with a pH slightly less than 7. Our body fluids must be maintained at correct pH values in order to function properly. pH and the soil. The pH of soil plays an important role in the growth of plants. It determines the availability of nutrients to plants. If the soil is too acidic or too basic, plants usually do not grow. Most plants require a pH of 7 to 8 to grow well. Lime, a basic substance, is sometimes added to an acidic soil to raise its pH or even neutralize it. Common Materials Hydrochloric Acid (4%) Stomach Acid Lemon Juice Vinegar Soft Drinks Tomato Juice Beer Rainwater (Unpolluted) Milk Cheese Urine, human Cow’s milk Saliva, human Drinking water Egg Whites Blood, human Seawater Baking Soda Ammonia Milk of Magnesia Sodium Hydroxide (4%) E. pH 0 1.0 – 3.0 2.2 – 2.4 2.5 – 3.0 2.0 – 4.0 4.0 4.0 – 5.0 5.0 6.0 – 6.6 4.8 – 6.4 4.8 – 8.4 6.3 – 6.6 6.5 – 7.5 5.5 – 8.0 7.6 – 8.0 7.3 – 7.5 8.3 9.0 10.0 – 11.0 10.5 13.0 – 14.0 Generalization Indicators show the presence of an acid or base in a substance by changing colors at different values or pH ranges. The pH scale is used to measure the degree of acidity and basicity. Acids and bases are found everywhere: in the homes, in schools, in the streets. BSE-Department of Education 131 F. Acids and bases have wide applications in the arts, industry, and agriculture. Acids and bases affect the environment. Valuing/Application a. Applying what they have learned, ask the students to find within and outside the building various acid and base products. Let them work in groups. The group that can identify the highest number of acids and bases will get additional grade points. b. Why do we study acids and bases? 1. Acids and bases are studied because many substances that we use daily contain acids and bases. They are found in food (citrus fruits, vegetables) , in cleaning materials (soap, toothpastes, cleansers). 2. Acids have applications in arts (etching), in industry (fertilizers, explosives, dyes), transportation (batteries) and the home (baking, preserving, cooking). 3. Bases have applications in industry (leather tanning), and agriculture (liming soils and lakes). 4. Acids and bases affect the human body (ulcers, excess use of antacids, stomach upset) 5. Acids affect the environment (acid rain and corrosion, acid lakes and rivers) G. Assessment 1. The deep blue indicator used in the analysis of some soil samples gave the following color changes: Red Blue Green Yellow - below pH 3 between pH 5 and pH 7 above pH 8 between pH 12 and pH 14 What is the change in color of the indicator if the extract from the soil sample was found to contain a weak base? a. deep blue to red b. deep blue to yellow c. deep blue to deep blue d. deep blue to green 2. Why don’t flower pigments dissolve when they become wet with rain? IV. Agreement/Assignment 1. Research Project: Have students, research in groups and report on the importance of pH levels in a public swimming pool, in soils, and a landfill site. 2. List some acids and bases and state their uses. 132 BSE-Department of Education Student Activity Sheet 8-2 Acids and Bases Activity 8-2a Materials Any colored flowers or leaves (e.g.red mayana leaves red gumamela flowers) yellow bell) test tubes test tube holder stirring rod tweezers filter paper muriatic acid distilled water sodium hydroxide solution beam balance 10 mL graduated cylinder 4 sets petri dish 6 droppers 10 mL graduated cylinder 100 mL beakers alcohol burner vials with cover scissors calamansi extract soap solution labeling pen Procedure A. Preparing the Acid/Base Indicator 1. 2. 3. 4. 5. Cut the leaves into pieces. Weigh about 6g of the leaves and place in a 100 mL beaker. Add 50 mL of water to the beaker and boil the contents for 5 min. or until the liquid has turned reddish brown. Carefully decant the extract into another beaker while still hot. Caution: Use cloth to hold the hot beaker. Immediately add a little amount of alum powder. Observe the solution. If the solution does not turn blue, add a little more of the alum. What do you think is the purpose of adding alum? Transfer the indicator solution into clean vials and keep covered when not in use. B. Preparing the Acid/Base Indicator Paper 1. 2. C. Cut a piece of filter paper into small several strips (1cm x 4cm). Transfer some of the liquid indicator in a petri dish. Place some of the filter paper strips in the petri dish and keep it immersed in the indicator for about 10 minutes. Then carefully remove each paper strip with a tweezer and transfer into another petri dish to dry. Testing the Indicators with Acids and Bases 1. Label 5 test tubes A to E and line in a test tube rack. BSE-Department of Education 133 2. Fill each test tube with 5 mL of the liquids as shown in the figure below. A muriatic acid 3. B calamansi extract C distilled water D soap solution E sodium hydroxide solution Get 5 pieces of the dry paper indicator. Spread out in a petri dish as in the figure below. A B D C E 4. Place 1-2 drops of the corresponding solution onto the paper indicator. Note down the changes in color of the paper indicators. For better results, place a white bond paper under the petri dish. Tabulate your observations. Remember these colors because they will be your basis of comparison in identifying other materials. 5. Keep the remaining indicator paper in tightly covered vials. This can last for several months. Do the same to the liquid indicator. You will use these in the Activity 8-4b. Data Solution Muriatic acid Calamansi Distilled water Soap solution Sodium hydroxide 134 Table 8-2a Nature of Solution Strongly acidic Weakly acidic Neutral Weakly basic Strongly basic Color change on Indicator Paper BSE-Department of Education Questions A. Preparing indicator Plant used: 1. 2. B. What was the color of the plant extract? _________________________________ What was the color of the plant extract with alum? _________________________ Making indicator paper from the indicator solution 1. What was the color of the filter paper after a. its immersion in the indicator solution? ________________________________ b. it was dried completely? ___________________________________________ C. Finding color changes of the indicator paper 1. What were the color changes of the indicator paper on the Muriatic acid Calamansi Distilled water Soap solution Sodium hydroxide 2. 3. 4. 5. 6. Which of the materials is/are strongly acidic? Weakly acidic? Which of the materials is/are strongly basic? Weakly basic? Which of the materials is/are neutral? What will happen to the indicators if exposed to air for sometime? If calamansi extract is acidic, why can it be taken by humans? In what ways is it different Generalization BSE-Department of Education 135 Student Activity Sheet 8-2 Acids and Bases Activity 8-2b Materials Acid/base indicator solution 10 mL graduated cylinder 4 sets petri dish 6 droppers test tubes vials with cover shampoo (different brands) tap water soft drinks fruits ammonia test tubes test tube holder stirring rod tweezers 10 mL graduated cylinder vinegar toothpaste fruit juices Alka-seltzer tablet detergent Procedure A. Testing for acids and bases in common materials 1. 2. 3. Prepare as many test tubes as there are materials to be tested. The materials to be tested must all be in solution form. Do not add water anymore to the liquid materials. If the material is solid, dissolve in a small test tube about ¼ teaspoon of the material with 20 mL of water. Stir the mixture well to make sure that the solid dissolves completely in the water. Test each liquid material by placing 1 –2 drops of it on an indicator paper. Let the indicator to dry then paste it lightly on a paper as shown in Table 2. If you ran out of paper indicators, prepare a new set using the remaining liquid indicator. Data Refer to Table 8-2b. Questions 1. 2. 3. 4. 5. 6. 136 Which of the materials is/are strongly acidic? Weakly acidic? Which of the materials is/are strongly basic? Weakly basic? Which of the materials is/are neutral? Why do we study acids and bases? Explain In what way is pH related to soil characteristics? Research on the application of acids and bases in agriculture. BSE-Department of Education Generalization Table 8-2b A tap water B soft drink C vinegar D fruit juice E ammonia F shampoo Paper indicators G Toothpaste H detergent solution I Alka-Seltzer solution J fruit extract K vegetable extract L cola drink Paper indicators BSE-Department of Education 137 Integrated Science Week 9 Competency: Investigate physical and chemical changes taking place in the environment. Lesson 9-1 Physical Changes in Matter Time Frame: one period II. Objectives At the end of the activities, the students should be able to; 1. describe the changes that matter undergo during a physical change; and 2. give examples of physical changes occurring in your surroundings. II. Subject Matter A. B. C. Topic: Physical Changes in Matter References: Any Integrated Science or Physical Science Textbook Materials piece of different materials: paper, cloth, plastic transparent cup metallic spoon blunt knife III. ice cubes rubber band modeling clay matches candle Learning Tasks A. Motivation 1. Look around you. List down some of the things you see. 2. Are all the things in your list considered matter? Why? 3. Choose one material. (e.g. a piece of paper) 4. Describe the material. (e.g. color, shape, feel, texture) 5. Will the material appear as it is now one month after? One year after? Give reasons for your answer. B. Pre-laboratory Activity 1. Prepare 6 stations for observations of the following changes: a. changes on paper, cloth, plastic b. changes on ice cubes c. changes on candle wax 138 d. changes on rubber band e. changes on clay f. changes on iron filings BSE-Department of Education 2. 3. 4. 5. C. Arrange students in groups and assign each member a specific task. Discuss objectives of the activity. Drill on laboratory safety and procedures. Give instructions on how students will perform the activities using the “Stations method” (e.g. how long each group is expected to stay in one station, should all the groups do the activities in all the stations or do at least 4). This will depend on the size of the classroom or laboratory, the number of students, availability of materials, and level of the students. It is suggested that the students perform at least 4 of the activities to arrive at the expected generalization. Activity proper 1. Ask students to perform activity on Physical Changes. Refer to the Student Activity Sheet. 2. Move around and check if the students are doing the activity properly and on the right track and every group member is busy. Check whether they are following the safety procedures drilled on earlier. 3. Ask questions to check if they understand what they are doing. D. Discussion 1. Process data from the activity. 2. Discuss the answers to the following questions (also found in the student activity sheet). a. In what ways did the following materials in the activity changed? 1. 2. 3. 4. 5. paper cloth plastic ice cubes candle wax 6. 7. 8. 9. rubber band clay magnet iron filings b. Was there a new material formed after each change? c. When do we say that a change is only physical? d. Which of the materials underwent physical change? Give your reasons for your choices. e. What are some evidences of a physical change? f. State an operational definition of a physical change. BSE-Department of Education 139 E. Generalization A physical change is characterized by changes in size, shape, hardness, texture of a substance; change in state of a substance; no change in identity; no formation of new substance/s; absorption or release of energy. F. Valuing/Application 1. 2. 3. 4. 5. Draw the Water Cycle and label its parts. Identify the physical changes involved in each process? Why is the water cycle important to our lives? What will happen if one of the processes stopped (e.g. evaporation)? What should you do in your own small way to keep the cycle functioning continuously? G. Assessment The situations below involve physical changes. 1. 2. 3. 4. 5. sharpening of pencil making ice candy chopping wood stretching a coiled spring magnetizing a needle 6. 7. 8. 9. 10. melting of butter flattening milk can making soap bubbles peeling cassava grinding coffee beans Identify the specific change (e.g. size, shape, hardness, texture, state) on each of the materials. IV. Agreement/Assignment 1. List some activities you do everyday that involve physical changes. Cite the importance of these activities to you. 2. Paper Folding (Technology / Creative Arts) a. Collect different colored papers. Make different designs (e.g. flower base or pencil holder, fan, floor mat, book marker, etc..) through paper folding. 140 BSE-Department of Education Student Activity Sheet 9.1 Physical Changes in Matter Materials piece of different materials: paper, cloth, plastic transparent cup metallic spoon blunt knife ice cubes rubber band modeling clay matches candle Procedure 1. Describe a piece of paper then tear it into small pieces. Do the same for the pieces of cloth and plastic. How do the torn pieces look? Compare its characteristics with the original. 2. Describe some ice cubes. Leave it on the container for a few minutes. Describe what happened to the ice cubes. Was there a change in the ice cubes? Can the ice cubes recovered? If so, state how. 3. Scrape the side of a candle wax and collect some pieces on to a spoon. Describe the wax pieces. Heat the spoon over a candle flame. What happened to the candle wax. Are the characteristics of the candle wax the same before and after heating? 4. Describe the characteristics of a rubber band. Stretch it and keep it in place for a little while, then release it. What happened to the rubber band? Did its characteristics change? If so, which characteristics? Stretch the rubber band to the fullest until it snaps. In what ways did the rubber band change? Is this the same rubber band as before it was stretched? 5. Cut a small piece of modeling clay. Press it with your hands. In what ways did the clay changed? Mold the clay into another shape. Does the clay have the same characteristics as the original clay? Will changing the shape change the clay into another material? 6. Describe some iron filings. Place some of the iron fillings on a piece of paper and place a magnet near them. What happened to the iron filings and magnet? BSE-Department of Education 141 Separate the iron filings from the magnet. Was there any change on the iron filings? How about the magnet? Data Material observed Initial observations Final Observations Questions 1. In what ways did the following materials in the activity changed? a. b. c. d. e. 2. 3. 4. 5. 6. paper cloth plastic ice cubes candle wax f. g. h. i. rubber band clay magnet iron filings Was there a new material formed after each change? When do we say that a change is only physical? Which of the materials underwent physical change? Give your reasons for your choices. What are some evidences of a physical change? State an operational definition of a physical change. Generalization 142 BSE-Department of Education Integrated Science Week 9-Cont’d Lesson 9-2 Chemical Changes in Matter Time Frame: two periods I. Objectives At the end of the activities, the students should be able to; 1. describe the indicators of chemical change; 2. define chemical change operationally; and 3. discuss some of the useful / beneficial and harmful effects of chemical changes to humans and properties. II. Subject Matter A. B. C. III. Topic: Chemical Changes in Matter References: Any Physical Science or General Chemistry textbook Materials: Refer to the Student Activity Sheet Learning Tasks A. Motivation 1. Ask the questions “When do we say that matter has undergone a physical change?” 2. Give situations that illustrate matter undergoing physical change. 3. Give the difference between elements and compounds and the kinds of elements. 4. Ask the students “What did you have for breakfast this morning? List at least three. “ (Answers may vary: e.g. rice, fish, meat, bread, butter) 5. Describe how food was prepared. Cite some of the changes before and after the preparation of each food. Pre-laboratory Activity 1. Prepare 6 stations for observations of the following changes: a. changes on bread b. changes on egg shells and vinegar c. changes on milk and vinegar d. changes on sugar e. changes on eggplant f. changes on hydrogen peroxide and potato BSE-Department of Education 143 2. 3. 4. 5. 6. Arrange students in groups. Give each member a specific task. Distribute student activity sheet. Discuss objectives of the activity. Drill on laboratory safety and procedures, e.g., a. heating with an alcohol lamp b. mixing materials (e.g. solid with liquid) c. handling chemicals 7. Give instructions on how students will go about performing the activities using the “Stations method” (e.g. how long each group is expected to stay in one station, should all the groups do the activities in all the stations or go to at least 4). This will depend on the size of the classroom or laboratory, the number of students, availability of materials, and level of the students. It is suggested that the students perform at least 4 of the activities to arrive at the expected generalization. B. Activity proper 1. Ask students to perform activity on Chemical Changes. 2. Move around and check if the students are doing the activity properly and on the right track. and every group member is busy. Check whether they are following the safety procedures drilled on earlier. 3. Ask questions to check if they understand what they are doing. You may stop at this point. You can ask the students to prepare their reports at home and be ready for the post discussion the following day. C. Discussion 1. Ask each group to present their data to the class. 2. Process the data. Point out the similarities and differences among the data. 3. Discuss the answers to the following questions (also found in the student activity sheet). 144 In what ways did the following materials in the activity changed? a. bread b. egg shells and vinegar c. milk and vinegar d. sugar e. eggplant f. hydrogen peroxide and potato Was there a new material formed after each change? When do we say that a change is chemical? Which of the materials underwent chemical change? Give your reasons for your choices. What are some evidences of a chemical change that can be observed? State an operational definition of a chemical change. Name some useful chemical changes and those that can bring beneficial effects to humans. BSE-Department of Education D. Generalization The visible and readily observable indicators of chemical changes are: evolution of light and heat release of a gas formation of solid particles (called precipitate) that separate from the liquid solution. formation of new substances/s E. Valuing/Application There are many chemical changes which have useful and beneficial effects on humans. Name some of these changes and explain why you consider them useful or beneficial. However, there are some chemical changes can have harmful effects to humans and properties. Name some of these changes and explain why you consider them harmful. Sample answers could be: F. Useful process of digestion of food photosynthesis fireworks in the sky cooking of food (frying fish, boiling egg, burning of fuel Harmful pollution of waterways taking in highly acidic foods rusting of furniture, utensils, and other materials that are made of iron decolorizing of cloth upon long exposure to sunlight decaying of foods Assessment Firecrackers are often used in celebrations to make the occasion more enjoyable. When firecrackers explode, the occasion becomes festive. a. b. What kind of change is involved in the explosion of firecrackers? Give at least 4 evidences of that change. BSE-Department of Education 145 Discuss why the following changes are considered useful / beneficial. bleaching and dyeing of cloth taking in antacid producing methane gas from waste materials Discuss why the following changes are considered harmful. dynamite fishing burning of gasoline in old vehicles decaying garbage in open garbage cans frequent use of bleaching powders and liquids IV. Agreement/Assignment 1. List down at least 10 naturally occurring chemical changes in the environment. 2. Project For You . (Technology) “Magic with chemical change” Dissolve 1 tablespoon of sugar in 1 tbsp. of water. Dip the end of the matchstick on the solution. Write a word on a sheet of paper. Dry the paper. To make the word appear, place the paper over the flame. As the sugar in the solution used to write on the paper burns, the word will appear. Investigate: Look for other materials that can replace sugar. 3. Link with scientists and Social Studies: Have students identify some historically significant chemical changes, and the scientists recognized for the changes. Ask the students to report them in class. 146 BSE-Department of Education Student Activity Sheet 9.2 Chemical Changes Materials a piece of pan de sal or any kind of bread small pieces of egg shells evaporated milk a piece of potato vinegar white sugar matches measuring cup alcohol lamp with denatured alcohol test tube holder 5 small clear bottles (wide-mouthed) cutter or knife spoon a pc. of eggplant 3% hydrogen peroxide rags medicine dropper Procedure Station 1. Changes on bread Describe a piece of bread. Cut a small piece from it. With a test tube holder place it over a flame for a minute or two or until you see changes on the bread. Describe the changes. Does the bread look the same as the original? Do you think you can recover the original characteristics of the bread? Station 2. Changes on egg shells and vinegar Pour ¼ cup of vinegar into a clear bottle. Drop a few small pieces of eggshells into the bottle. Observe the mixture. What happens to both vinegar and eggshells? Is there a new substance formed? If so, what do you think is this new substance? Station 3. Changes on milk and vinegar Pour ¼ cup of vinegar into a clear bottle. Add about 20 drops of evaporated milk into the bottle. Observe the mixture. What happens to both vinegar and eggshells? Was there a new substance formed? If so, what do you think is this new substance? Do you think you can still recover the original materials? Station 4. Changes on sugar Place some sugar on to a spoon. Wrap the handle of the spoon with a rug to avoid burns. Place the spoon over a flame for about 5 minutes. Describe all the changes you observe on sugar. Continue heating until the color becomes almost black. Are the characteristics of sugar the same before and after heating. Is it possible to recover the original sugar? Is the black substance formed still sugar? BSE-Department of Education 147 Station 5. Changes on eggplant Cut a small piece from the eggplant and observe its characteristics particularly the cut section. Leave this cut section exposed to the air. Observe it again after about 5 minutes. Does the cut section have the same color as before? What do you think will happen if the eggplant is exposed for a longer time? Station 6. Changes on hydrogen peroxide and potato Pour ¼ cup of hydrogen peroxide into a clear bottle. Add a small slice of peeled potato to the bottle. Observe the slice of apple for a few minutes and note down any change. What happens to the slice of apple? Is there any indication that another substance is present? What do you think is this substance? Data Materials observed Initial observations Final Observations Questions 1. In what ways did the following materials in the activity change? a. b. c. d. e. f. 2. 3. 4. 5. 6. bread egg shells and vinegar milk and vinegar sugar eggplant hydrogen peroxide and potato Was there a new material formed after each change? When do we say that a change is chemical? Which of the materials underwent chemical change? Give your reasons for your choices. What are some evidences of a chemical change? State an operational definition of a chemical change. Generalization 148 BSE-Department of Education Integrated Science Week 9-Cont’d Lesson 9-3 Effect of Heat in Matter Time Frame: one period I. Objectives At the end of the activities, the students should be able to: 1. 2. 3. 4. investigate how energy is involved in the changes that matter undergo; describe what happens to the volume of a solid, a liquid or a gas when it is heated; cite situations where the heat effects on matter are useful; recognize each one’s responsibility as a member of a community. II. Subject Matter A. Topic: Effect of Heat on Matter B. References: Rabago, Lilia M..(1997). Science and Technology I. SD Publications, Inc. Araneta Avenue, Quezon City. pp.143-144. Rabago, Lilia M..(1997). Science and Technology I Teacher’s Manual. SD Publications, Inc. Araneta Avenue, Quezon City. pp. 82-84. C. Materials: (See activity card) III. Learning Tasks A. Motivation During town fiestas, peddlers take the opportunity to sell big, beautiful balloons. There are times, however, when peddlers stand in corners and wait for customers under the heat of the sun for a long time. The overheated balloons would suddenly burst. Can you tell why this happens? B. Pre-laboratory Activity a. Prepare the tray that will contain all the materials for the activity. test tubes glass tubing (or straw), colored water water marking pen rubber stopper large bottle with cold water medicine dropper b. Arrange students in groups. c. Give each member a specific task. d. Discuss objectives of the activity. BSE-Department of Education 149 e. Drill on laboratory safety and procedures. Inserting a glass tubing through a rubber stopper Using a test tube Care of glassware C. Activity proper a. Ask students to perform activity as per instructions in the accompanying Student Activity Sheet. b. Move around and check if the students are doing the activity properly and on the right track. See to it that every group member is busy. Check whether they are following the safety procedures drilled on earlier. c. Ask questions to check if they understand what they are doing. D. Discussion a. Process the results that each group gathered. A group member can report orally or place in manila paper so that other members can compare their results. b. Point out similarities and differences in the results. c. Discuss the answers to the following questions (also found in the student activity sheet). 1. What is the effect of holding the test tube tightly with your hand? Did it have any effect on the water droplet in the glass tubing? Explain your answer. 2. What happened to water droplet when the test tube is placed in cold water? How do you compare this result with that in (1)? 3. What represents the volume of air in this activity? 4. What happened to the volume of air when it was heated? 5. What happened to the volume of air when it was cooled? E. Generalization F. Heating or cooling matter affects its volume. When matter is heated, it expands. Its volume becomes bigger. When matter is cooled, it contracts. Its volume becomes smaller. Valuing/Application The clinical thermometer is an instrument which depends upon the expansion and contractions of body temperature. When heat is absorbed, the mercury expands so it rises inside the bulb. When heat is transferred the mercury contracts so it falls. Using a clinical thermometer, can you tell if you have a fever? Explain your answer. 150 BSE-Department of Education G. Assessment Refer to Fig. 9-4. in the Student Activity Sheet for the following questions: 1. If heated, which of the following would most likely happen to the water level in the glass tubing? The water level will a. remain the same. b. rise up the tube. c. move down the tube. 2. Which of the following would best explain your observation? a. Matter is not affected by heat. b. Matter expands when cooled. c. Matter contracts when cooled. 3. If the water inside the test tube is placed in cold water, which of the following would most likely happen to the water level in the glass tubing? a. remain the same. b. rise up the tube. c. move down the tube. 4. Which of the following would best explain the result? a. Matter is not affected by heat. b. Matter expands when cooled. c. Matter contracts when cooled. IV. Agreement/Assignment Making An improvised thermometer 1. With a soft drink bottle, a straw, a rubber stopper, and colored water, construct an improvised thermometer. 2. Using your improvised thermometer, observe hotness and coldness of the surroundings during the day. Do this for one week a. Which part of the day usually indicates the highest temperature? b. Which part of the day usually indicates the lowest temperature? BSE-Department of Education 151 Student Activity Sheet 9.3 Effect of Heat on Volume of Air Materials test tubes glass tubing (or straw), colored water water marking pen medicine vials, rubber stopper large bottle with cold water medicine dropper Procedure 1. Prepare the setup as in Fig. 9-3. 2. Put a drop of colored water in the glass tubing. Do this carefully to keep the drop of water in the tubing. Mark the position of the drop of water. Hold the test tube tightly in the palm of your hand for about 5 minutes. Heat from your hands will flow to the test tube and the air inside the tubing. Observe any changes in the level of the water droplet. What happens to the drop of water as the air in the test tube is heated? What do you think has caused this to happen? 3. Place the test tube in a large bottle with cold water. Was there a change in the level of the water droplet? If so, what caused this change? Questions Drop of water 1. What is the effect of holding the test tube tightly with your hand? Did it have any effect on the water droplet in the glass tubing? Explain your answer. 2. What happened to water droplet when the test tube is placed in cold water? How do you compare this result with that in (1)? 3. What represents the volume of air in this activity? 4. What happened to the volume of air when it was heated? 5. What happened to the volume of air when it was cooled? Glass tubing Rubber stopper Test tube Air Fig. 9-4 Generalization 152 BSE-Department of Education Integrated Science Week 9-Cont’d Lesson 9-4 Energy Involved in a Chemical Change Time Frame: two periods I. Objectives At the end of the activities, the students should be able to: 1. compare the heat conducting properties of water and paper by boiling water; and 2. estimate the heat produced by a burning candle. II. Subject Matter A. Topic: Heat Energy of a Chemical reaction B. References: Any Integrated Science or Physical Science Textbook D. Materials: pieces of bond paper 2 iron rings and clamps 2 candles 2 iron stands matches 2 test tube holders or tongs water III. Learning Tasks A. Motivation 1. Recall the meaning of heat. Ask the questions: “Can we see heat? Can we feel it? Can we measure it? How do scientists measure heat? What is the unit of heat?” What is the effect of heat on objects? On people? Give examples. 2. Demonstrate to the class the effect of heat on dry paper and a paper wet with water. Prepare 2 setups each composed of an iron ring attached to an iron stand. You can also use a tripod in place of an iron ring, if available. Draw a 4column table on the board. Improvise 2 paper cups. Place each over the iron ring. Place a candle under each cup. Before you light the candles, ask the students to make predictions as to what will happen when each candle is lighted. Record their predictions in column 1 on the board. BSE-Department of Education 153 Light the candle under the first cup. Ask the students to describe their observations. You need not let the flame consume all the paper if it will pose any danger. You can put off the flame when you think enough observations have been given. Write the observations in Column 2. Light the candle under the cup with water. Let it burn for a few minutes until you think the students have noted the differences. Let them write their observations in the third column. In Column 4, let them give their explanations on their observations particularly on why the second cup did not burn. Analyze the results. The conclusion of the students should be that “the second cup does not burn because the water removes heat from the paper before the paper becomes hot enough to burn.” 3. Tell the students that in the next activity, they will calculate the amount of heat produced by the candle. Ask the students what they know about calories. They probably have read this on food labels. They have heard this from people who are dieting or controlling their food intake. Emphasize that a candle burns its wax with oxygen from the air releasing calories of energy (heat and light). In a similar way, our body burns food, though without a flame, to release energy (heat). B. Preliminary Activity 1. 2. 3. 4. 5. Prepare the materials for the demonstration and students’ experiment before the class starts. Write on the board a large 4-column table for the students’ data. After the demonstration, distribute the trays containing the materials for the experiment to each group. Distribute the Student Activity Sheet and discuss the objectives of the activities. Drill on laboratory safety and procedures, e.g., a. b. c. d. C. heating with a candle and test tube use of the test tube holder handling chemicals measuring with calibrated glassware (graduated cylinder, thermometer) Activity proper 1. Ask students to perform Activity 9-4 Heat Energy of a Chemical Change. 2. Move around and check if the students are doing the activity properly and on the right track and every group member is busy. Check whether they are following the safety procedures drilled on earlier. 3. Ask questions to check if they understand what they are doing. 154 BSE-Department of Education E. Discussion 1. Calories and Joules are units of heat. 2. Calorimetry is the measurement of heat flow. 3. When heat is transferred to an object, the temperature of the object increases. When heat is removed from an object, the temperature of the object decreases. The relationship between the heat ( Q ) that is transferred and the change in temperature ( DT ) is Q = mC T = C ( Tf - Ti ) The proportionality constant in this equation is called the heat capacity ( C ). The heat capacity is the amount of heat required to raise the temperature of an object or substance one degree. The temperature change is the difference between the final temperature ( Tf ) and the initial temperature ( Ti ). Quantity Symbol Unit heat Q joule (J) Energy transfer that produces or results from a difference in temperature temperature T o Measure of the kinetic energy of molecular motion temperature change DT o Difference between the final and initial temperatures for a process heat capacity C C or K C or K Cal/oC or J/oC Meaning Heat required to change the temperature of a substance one degree A calorimeter is an experimental device in which a chemical reaction or physical process takes place. The calorimeter is well-insulated so that, ideally, no heat enters or leaves the calorimeter from the surroundings. For this reason, any heat liberated by the reaction or process being studied must be picked up by the calorimeter and other substances in the calorimeter. E. Generalization The heat given off by the burning candle is equal to the heat absorbed by water. An increase in temperature of water indicates the absorption of heat. The production of new substances from the burning candle, the decrease in its mass (in an open system), change in temperature, production of heat and light, all indicate that a chemical change has taken place. The new substances are black soot (carbon), gases (carbon dioxide, carbon monoxide, and water vapor). BSE-Department of Education 155 F. Valuing/Application 1. Different substances have different heat capacities because of the kinds of molecules and atoms they posses. This means that for the same mass, different substances need different amounts of heat to change their temperatures 10C. 2. Foods rich in carbohydrates are called energy-giving foods because they give off large amounts of heat when they are burned. 3. Water’s heat capacity plays a major role in keeping us warm. The large heat capacity allows water to hold heat for a long time. Waters heat capacity controls the weather surrounding large bodies, such as the ocean. With water gaining all the heat though the day it slowly releases it during the night. This regulates the temperture of the area. With waters large heat capacity it allows us to hold heat better than most subtances. All organisisams have a temperture range. Humans have a range through 32 degrees to 43 degrees celcius. Humans are 87% water, because they do not have a large temperture range. G. Assessment 1. Which of the following changes indicate the removal or release of heat? a. when rain becomes clouds b. when clouds become rain c. when rain stays in liquid form d. when water from the sea changes into clouds 2. When you apply a few drops of alcohol on your hands, the spot feels cool while the alcohol is evaporating. Which statement below accounts for this observation? a. b. c. d. IV. the heat from the skin was absorbed by alcohol. the alcohol has lower temperature so it feels cool on the skin. the heat from the skin was used to separate the alcohol molecules. The amount of heat possessed by the body is lower than the amount of heat possessed by alcohol. Agreement/Assignment 1. Plan an experiment to show the effect of color of a material on the amount of heat absorbed by the material. 2. Conduct an investigatory project to determine which alternative source of heat like dry bagasse, rice hulls, wood chips, or peanut sheels release the greatest amount of heat. You may vary the kind of material and keep all other variables constant.. 156 BSE-Department of Education Student Activity Sheet 9.4 Heat Energy of a Chemical Change Materials candle water test tubes test tube holder small beakers beam balance small plastic saucer 10 mL graduated cylinder thermometer Procedure 1. Get the combined mass of the candle and plastic saucer with a beam balance. Assign this as initial mass, m1. 2. Pour 10 mL water into a test tube. Take the temperature of the water. Assign this as initial temperature, ti. 3. Let the candle stand firmly on the saucer. Carefully light the candle, then hold the test tube with a test tube holder in the flame. Move the test tube gently in small circles while in the flame for even distribution of heat. 4. Continue heating for about three minutes. Take the temperature of water just before removing the test tube from the flame. Assign this as final temperature, tf. 5. Put off the candle. Get again the combined mass of the candle and the saucer. Assign this as final mass, m2. Calculate the mass of the candle after burning. 6. The heat produced by the burning candle is determined through the amount of heat absorbed by the water . Thus, the heat absorbed by water from the burning candle is equal to the product of the heat capacity of water (1 cal/oC) , the mass of water (Dwater = 1g/mL), and the change in temperature of water. Data Material observed Initial observations Final Observations Water Initial temperature = Volume = Mass of water = (D=m/v) Final temperature = Volume = Mass of water (D=m/v) Candle Mass of candle and saucer = Mass of candle and saucer = Mass of candle =burned BSE-Department of Education 157 Questions 1. Which has a higher temperature, water before heating or water after heating? To what is the change in temperature due? 2. Did water produce heat or absorb heat? 3. Did candle produce heat or absorb heat? Why is the mass of the two materials be equal? 6. Why was the mass of water used in the calculation and not the mass of the candle? 7. What happened to the mass of the candle after it was burned? What does this indicate, a physical change or a chemical change? 8. Name the chemical changes that took place in the activity. 9. How much heat is evolved in burning 1g of candle? Generalization 158 BSE-Department of Education Integrated Science Week 10 Competency: Describe the properties of matter in terms of its component atoms or molecules Lesson 10-1 Molecules of Matter Time Frame: one period I. Objectives: At the end of the activities, the students should be able to: 1. 2. 3. 4. 5. II. give examples of molecules; cite evidences that molecules of matter are in constant motion; infer that there are spaces between molecules; compare diffusion of molecules in different materials; and explain diffusion in terms of the molecular model of matter. Subject Matter: A. Topic: Molecular Theory of Matter ; Diffusion of Molecules B. References: Gutierrez, Marlene M. (1999). Science and Technology for the Modern World. Diwa Scholastic Press Inc. Makati City. pp. 116 - 119 Gutierrez, Marlene M. (1999). Science and Technology for the Modern World . Teacher’s Manual. Diwa Scholastic Press Inc. Makati City. pp. 106 - 109 Rabago, Lilia M. (1997). Science and Technology I. SD Publications. Araneta Avenue, Q.C. pp 84 - 86 Rabago, Lilia M. (1997). Science and Technology I Teacher’s Manual. SD Publications. Araneta Avenue, Q.C. pp. 47 - 49 C. Materials: For the students: Refer to the Student Activity Sheet For the teacher: Visual Aids; Manila Paper III. Learning Tasks A. Motivation: Have you experienced smelling the food your neighbors are cooking? Surely you could tell the difference between the smell of adobo and fried tuyo or tinapa. Similarly, if you put some kalamansi juice into a glass of water, the whole glass of water will taste sour almost immediately. What will happen to the taste of water if you add a pinch of salt or sugar? BSE-Department of Education 159 B. Preliminary Activity 1. 2. 3. 4. 5. C. Preparation of materials per group: Arrange students in groups. Give each member a specific task. Discuss objectives of the activity. Drill on laboratory safety and procedures. Proper use of chemicals Correct mixing and smelling techniques Activity Proper 1. Ask students to perform activity on Diffusion of Molecules. Refer to the Student Activity Sheet. 2. Move around and check if the students are doing the activity properly and on the right track and every group member is busy. Check whether they are following the safety procedures drilled on earlier. 3. Ask questions to check if they understand what they are doing. D. Discussion 1. Compare the data gathered by the different groups. Look for similarities and differences. 2. Ask the students to explain why there are differences in the data. 3. Discuss the answers to the Guide Questions. Refer to the Student Activity Sheet. 4. Discuss the Molecular theory. Use this theory to explain the diffusion of molecules. 160 Molecular theory states that: a. Matter is made up of very tiny particles called molecules. b. Attractive forces exist between molecules. c. Molecules are continually moving. d. There are spaces between molecules. Attractive forces exist between molecules. The forces of attraction are greatest in solids because molecules are very near each other. They are weakest in gases because the molecules of gases are far from one another. Molecules of gases can move freely, as far as the space will allow them. Thus the volumes of gases depend on their containers. Molecules of gases are continually moving in all directions. They bump with each other, with the walls of the container, and with other molecules that cross their path. BSE-Department of Education Diffusion happens because molecules of a substance are in constant motion. When placed in a medium, they continue to move, and as they move they bump each other. They also bump the molecules of the medium and are in turn bumped by other molecules. The spaces between molecules of the medium allow the molecules of the substance to spread throughout the medium. Table 10-1. Comparison between solids, liquids, and gases Basis of Comparison a. Intermolecular space b. Molecular attractions c. Molecular motion D. Solid Smallest distance between molecules Liquid Gas back and forth Small space between molecules slip and slide Large space between molecules moves freely slowest slow fastest Generalization Molecule is the smallest stable unit of matter and possesses all the properties that identifies that matter. Attractive forces exist between molecules. Spaces exist between molecules. Molecules of a substance spread throughout a medium. They spread fastest in gaseous medium and slowest in solid medium. Molecules of solids, liquids, and gases differ in terms of intermolecular space, molecular attraction, and molecular motion. E. Valuing/Application 1. Why do bottles of alcohol, acetone, soft drinks, wines, and other similar materials have the following labels:” Keep tightly closed when not in use.” 2. What should you do to your garbage can so that bad smell and probably airborne bacteria will not reach you? 3. Explain why some food additives like food colors are added to soft drinks, and juices. 4. Many Batik cloths are made through “Tie Dyeing”. BSE-Department of Education 161 F. Evaluation: Answer the following questions: a. Why can you smell the odor of the food your mother is cooking in the kitchen? b. Why does water flow? c. Draw the arrangement of molecules in solids, liquids and gases. IV. Agreement/Assignment Answer briefly: 1. 2. 3. 162 Why should you cover your nose when someone in the room is smoking? Why should you cover your mouth whenever you cough? Many people from far away provinces opposed the operation of the Bataan Nuclear Power Plant because an accident in this plant would affect them. Do you think it is true? Why or why not? BSE-Department of Education Student Activity Sheet 10.1 Diffusion of Molecules Materials 1 slice of cooked gulaman or gelatin ¼ tsp of blue dye watch with second hand teaspoon medicine dropper bottle of bagoong soy sauce clear bottles water Procedure A. B. C. Place a slice of cooked gulaman or gelatin on a plate. Sprinkle ¼ tsp of blue dye on the surface of the gelatin. Record the time when you did this. Set the gelatin aside and observe how long it will take the blue dye to penetrate the Describe the movement of the dye. Place a drop of soy sauce into a half bottle of water. Record the time you dropped the soy sauce into the water. Observe the water for a few minutes without moving the glass. Note down your observations. Place a small bottle of bagoong in a box. Cover the box. Ask a group mate to sit about 2 ft. away from you. Tell her to record the time the moment she smells the bagoong. Record the initial time then open the box. Data Name of materials Observations on the materials before and after diffusion a. Gulaman Blue dye b. Soy sauce Water c. Bagoong BSE-Department of Education 163 Guide Questions A. 1. 2. 3. 4. 5. B. 1. 2. 3. 4. What happened to the blue dye? Did you observe any change? Describe the change. Did you see any change in color of gulaman? If so, what caused this change? Did your observations show that the blue dye spread in the gelatin? How long did it take the potassium permanganate crystals to spread down this far? Infer a reason for the spread of the dye in gelatin. What happened to the soy sauce as it was dropped into the glass of water? What happened to the soy sauce and water after a few minutes? How long did it take the soy sauce to spread completely? Infer a reason for the spread of the dye in gelatin. C. 1. 2. 3. 4. 5. 6. What happened when the bottle of bagoong was was uncovered? How long did it take for the odor to reach you? What was the smell of bagoong in the bottle? How did the smell of bagoong reach your classmate? How did the odor reach you? How long did it take for the odor to reach you? Why did it still reach you when you are farther away from the source? 7. Give examples of diffusion particles in liquid and in gas. Generalization 164 BSE-Department of Education Integrated Science Week 10-Cont’d Lesson 10-2 Intermolecular Attraction Time Frame: one period I. Objectives At the end of the activities, the students should be able to: 1. 2. 3. 4. illustrate by examples capillarity and surface tension; show how the molecular theory explains surface tension and capillarity; differentiate adhesion from cohesion; and appreciate the value of sensitivity in solving problems. II. Subject Matter A. Topic: Surface Tension, Capillarity (Adhesion. Cohesion) B. References: Gutierrez, Marlene M. (1999). Science and Technology for the Modern World. Diwa Scholastic Press Inc. Makati City. pp. 120 - 122 Gutierrez, Marlene M. (1999). Science and Technology for the Modern World . Teacher’s Manual. Diwa Scholastic Press Inc. Makati City. pp. 111 - 112 Rabago, Lilia M. (1997). Science and Technology I. SD Publications. Araneta Avenue, Q.C. pp 86 – 88 Rabago, Lilia M. (1997). Science and Technology I Teacher’s Manual. SD Publications. Araneta Avenue, Q.C. pp. 48 - 49 C. Materials: For the students: Refer to the Student Activity Sheet For the teacher: Illustration: Attraction between molecules; Picture of any insect striding on the surface of the water Spring of a ball pen, basin, water III. Learning Tasks A. Motivation Gently lay on top of the basin of the water a spring from a ball pen. (If done properly spring floats.) Can you give some explanations why the spring floats on water? Remove the spring from water. Wipe it dry. Touch one end of the spring to the surface of the water, then pull it up. What happens? What is the force that allows the water to be pulled up against gravity? BSE-Department of Education 165 B. Preliminary Activity 1. 2. 3. 4. Prepare the materials per group. Arrange students in groups and give each member a specific task. Discuss objectives of the activity. Drill on laboratory safety and procedures. C. Activity Proper 1. Ask students to perform activity on Surface Tension and Capillarity. Refer to the Student Activity Sheet. 2. Move around and check if the students are doing the activity properly and on the right track and every group member is busy. Check whether they are following the safety procedures drilled on earlier. 3. Ask questions to check if they understand what they are doing. D. Discussion 1. Compare the data gathered by the different groups. Look for similarities and differences. 2. Ask the students to explain why there are differences in the data. 3. Discuss the answers to the Guide Questions. Refer to the Student Activity Sheet. 4. Recall the models used to represent the arrangement of molecules in solids, liquids, and gases. Ask the questions: Why is iron hard to break? Why can water flow while iron cannot? 5. Review the Molecular theory. Ask the question: why can we not keep a gas in our hand while we can do so with solids? Or we can do it on a limited scale with liquids? Use this theory to explain the observations on the needle and water, and the varying levels of water in the plastic straws. Molecular Theory of Matter: a. b. c. d. Matter is made up of very tiny particles called molecules. Attractive forces exist between molecules. Molecules are continually moving. There are spaces between molecules. 6. Relate capillarity with adhesion and cohesion. 166 BSE-Department of Education E. Generalization Intermolecular forces of attraction exist between molecules of solids, liquids, and gases. The difference in the strength of these attractions accounts for the difference in arrangement of the molecules. The attraction is strongest in solids and weakest in gases. The strong attraction of water molecules to one another on the surface of the water drop results in a seemingly thin, elastic film or membrane covering the liquid. This effect is called surface tension. It is strong enough to support objects that are more dense than water such as the needle or water striders The rise of a liquid in a tube of small diameter is called capillary action or capillarity. It is also a manifestation of the presence of strong attractive forces. A liquid rises in a straw because of the stronger attraction between the molecules of straw and water. Adhesion is the attraction between two different kinds of molecules. (attraction between the molecules of the straw and those of water). Cohesion is the attraction between the same kind of molecules (attraction between the molecules of water). F. Valuing/Application There should be solidarity or cohesion among the members of a family, especially in times of troubles or difficulties. Everyone should be sensitive to each other’s needs and problems. Togetherness or oneness help lighten the difficulties and finding solutions becomes much easier. Everyone in the family, from oldest to youngest, is expected to adhere to the principles inculcated by the parents in facing/solving life’s trials. If water striders and other insects can walk on the surface of water, can humans do the same? In the critically-acclaimed movie “Crouching Tiger Hidden Dragon,” there was a scene when actors run on the surface of water. Is it possible? Why do liquids rise in the straw as you drink your soda or softdrink? G. Evaluation Choose the letter of the best answer: 1. The rise of water from the roots to all parts of the plants is called a. b. capillarity. cohesion and adhesion. c. gravitational force. d. surface tension. 2. Iron filings do not sink when placed slowly on the surface of the water because of a. adhesion. b. BSE-Department of Education capillarity. c. cohesion. d. surface tension. 167 3. Intermolecular attraction is greatest in: a. gases. b. liquids c. plasma d. solids. 4. Which of the following is part of the molecular theory of matter? a. b. c. d. molecules of matter are static. molecules of gases are very close each other. strong attractive forces exist between molecules of a solid. energy of molecules can be converted ot other forms. Identify the following: 5. Attraction between the same kind of molecules. (cohesion) 6. Rising of liquid inside fine tubes. (capillarity) IV. Agreement 1. Give other examples of natural phenomena involving reactions of matter. 2. Research on the processes followed in waste recycling and cite waste recycling practices carried out in the country. 168 BSE-Department of Education Student Activity Sheet 10.2 Activity 10-2a Surface Tension Materials glass of water clean bowl clean cloth or tissue paper a needle detergent solution medicine dropper Procedure 1. Carefully pour water into a clean bowl. 2. Gently place a dry needle horizontally on the surface of the water. Observe what happens to the needle. 3. Remove the needle from the water and wipe dry with a clean cloth. 4. Gently place the needle, vertically this time, into the water. Compare your observation here with the one you made in step 2. 5. Remove the needle again and wipe dry. 6. Repeat steps a and b. This time add 2 – 3 drops of detergent solution along one side of the bowl. Observe what happens to the needle. Data Materials Observations Questions 1. In procedure 2, did the needle float or sink in water? Explain your answer in terms of the molecular theory. 2. In procedure 4, did the needle float or sink in water? Explain your answer in terms of the molecular theory. 3. In procedure 6, what happens to the needle after adding some detergent to water? What was the effect of the detergent solution? 4. Have you watched insects called water striders play on the surface of a pond? What have you observed? Generalization BSE-Department of Education 169 Activity 10-2b: Capillarity Materials 3 colorless plastic straws (different diameter with the same length) a glass of colored water Procedure 1. Label the plastic straws A, B, and C. Dip the straws at the same time into a glass of colored water. Note down the amount of water that enters in each straw. Data Materials Observations Questions 1. 2. 3. 4. 5. In which straw did the water rise the highest? the lowest? Why are the levels of water different in the three straws? Why does the colored water rise in the straw? Do straw and water have the same kind of molecules? In what other situations do you observe a liquid rising in a small tube? Generalization 170 BSE-Department of Education Integrated Science Week 10-Cont’d Lesson 10-3 Symbols of Atoms and Molecules Time Frame: one period I. Objectives At the end of the activities, the students should be able to: 1. 2. 3. 4. describe how chemical elements are arranged in the periodic table; write the symbols of some elements and state how they were derived; name the element, given its symbol; determine the elements, the number of atoms of each element that comprise a formula unit of a compound; 5. differentiate an atom and a molecule; and 6. state the importance of elements and compounds in our lives. II. Subject Matter A. Topic: Symbols of Atoms and Molecules B. References: Any Integrated Science or Physical Science Textbook C. Materials: refer to the Student Activity Sheet 10-3 III. Learning Tasks A. Motivation 1. Recall some of the symbols used to represent safety measures that must be observed in and out of the laboratory. 2. Modern scientists use letters to represent symbols of elements and formulas of compounds. Show the Periodic Table. Ask the following questions: what do you see in the Periodic Table? (letters in each box, some boxes have only one capital letter , others have 2 letters with only the first letter capitalized. Elements arranged in rows and columns). 3. Call one representative from each group and ask them to come to the front. Ask them to group themselves in at least 2 ways. (Students may group according to height, weight, age, color, sex, group number, surname, etc…) B. Lesson Proper 1. Show again the Periodic Table. Tell the students that just like people, elements are grouped according to some criteria. What criteria were obviously used in the Periodic Table? (increasing number from left to right and top to bottom, decreasing size from left to right and increasing size from top to bottom if provided in the Periodic Table). BSE-Department of Education 171 2. Based on the periodic Table, state that More than 100 elements have been discovered or artificially-made; Elements are represented by symbols (letter/s); They also represent atoms of the elements; Atoms of elements have different masses and increases from left to right and from top to bottom; Atoms of elements have atomic numbers, representing the number of protons and electrons, also increases from left to right and from top to bottom; No two different elements have the same symbols. 3. Symbols of elements are used for the names of elements. The present system was devised by Johann Jacob Berzelius. He used the first letter , or combining the first letter and another letter of the English, Latin, or Greek name of the element. Only the first letter is capitalized. Some names were derived from the places they came from. Here are some symbols of elements and their derivation: Element Symbol Derivation Hydrogen H Helium He Carbon C Calcium Ca Chlorine Cl Cobalt Co Nitrogen N Nickel Ni Neon Ne Sulfur S Silicon Si Iodine I Copper Cu Cuprum Iron Fe Ferrum Lead Pb Plumbum Mercury Hg Hydrargyrum Potassium K Kalium Silver Ag Argentum Sodium Na Natrium Tin Sn Stannum Gold Au Aurum 3. Elements may be classified into metals, nonmetals, and metalloids. Compound may be classified as acids, bases, and salts. 4. Give the difference between an atom and a molecule; monatomic and diatomic molecules. 5. Majority of gases are unstable. They often exist in nature as diatomic molecules. Ex. O2, N2, Cl2, I2. See the illustrations Fig. 7.1 and &.2 p.103 Rabago, Lilia M., et, al (1997). Science and Technology, General Science. 172 BSE-Department of Education 6. Compounds are represented by 2 or more different symbols, also called formulas. Ex. CO, CO2, H2O, NH3, HNO3, H2SO4. Describe what the letters and numbers represent. Explain how the Law of Definite Composition is applied in writing chemical formulas. Here are formulas of some chemical compounds: Compound Sucrose (sugar) Acetic acid (vinegar) Sodium chloride Calcium oxide (lime) Calcium hydroxide (limewater) Calcium carbonate (limestone) Hydrochloric acid (muriatic acid) Hydrogen peroxide (agua oxigenada) Methanol (denatured alcohol) Sodium bicarbonate (baking soda) Silicon dioxide (quartz/sand) Chemical Formula C12H22O11 CH3COOH NaCl CaO Ca(OH)2 CaCO3 HCl H2O2 CH3OH NaHCO3 SiO2 Give the names and number of the atoms of elements comprising each formula unit. C. Discussion An atom is the smallest particle of an element. Two or more atoms can bond together to form a molecule. A compound is formed from the combination of at least two different atoms, which has properties quite different from the atoms in it. For example, sodium (Na), an extremely reactive, nearly explosive metal, and chlorine (Cl), a toxic yellow gas combine to form sodium chloride (NaCl), which is common table salt, a white crystalline solid. Atoms are made up of even smaller things called subatomic particles. There are three main types: proton (which has a very small positive electrical charge), neutron (which is neutral), and electron (which has a very small, negative electrical charge). You may see these referred to as p+, e–, and no. The protons and neutrons form the nucleus of the atom (not to be confused with the nucleus of a cell), while the electrons are constantly moving outside the nucleus and traveling at about the speed of light. The number of protons and electrons is important: this determines the nature of the element. Each element has a different number of protons, and if the number of protons in an atom is different changes, then you get a different element. The number of protons in an atom is called its atomic number. Normally, the number of protons and electrons match so the charge is balanced out. BSE-Department of Education 173 Within limits, the number of neutrons and electrons in an atom can vary. Isotopes are atoms of the same element with different numbers of neutrons. Protons and neutrons have about the same mass, but electrons are so much smaller, their mass is negligible by comparison (like carrying a feather when you weigh yourself on the bathroom scale). The atomic mass of an element is the mass of an atom of that element compared to the mass of an atom of carbon-12 expressed in atomic mass unit (amu). A molecule is a combination of 2 or more atoms linked together by a network of chemical bonds. Elements are represented by symbols, compounds by formulas. The symbol can stand for a) the name of the element b) one atom of the element c) a quantity of the element equivalent to its atomic mass. A chemical formula stands for the name of the compound, or a formula unit of the compound. It follows the Law of Definite Composition. The subscripts give the number of atoms of each element in a formula unit. The Law of Definite Composition states that elements combine in a fixed mass ratio to form a compound. F. Valuing/Application Discuss where the compounds are found and their common uses. Characteristics and uses of some elements and their compounds Lead – Its Latin name Plumbum was made the basis for plumbing, a term associated with water pipes and lead was once its major component. Many of lead compounds are poisonous. They are used in paint pigments and explosives. Mercury – It is the only metal that is liquid at room temperature. It is a a dense substance whose properties are used for making thermometer (from the Greek for measure heat) and barometers (from the Greek for measure weight). It is a poisonous substance associated with an incident in the village of Minamata in Japan. During the 1960’s, industrial discharges of mercury into the sea ended up in the fish that the local population ate. The result was Minamata disease, which caused people to lose control of their nervous system. Iodine – It is poisonous in its pure form but its compounds are essential to life. Iodine dissolves in alcohol to give tincture of iodine, used as disinfectant. Tin – At ordinary temperatures, tin is a white lustrous metal. At temperatures below 13oC, the metal slowly changes to gray, which is brittle. This causes tin roofs to decay at very low temperatures. Tin is used to coat other metals to stop them from corroding. “Tin” can are made from tinned iron. 174 BSE-Department of Education Calcium – Its compounds are very common in the Earth’s crust. It is found in minerals like chalk, limestone and marble (CaCO3, calcium carbonate), gypsum (CaSO4, calcium sulfate) found in blackboard chalks, and fluorspar (CaF2, calcium fluoride) used in toothpastes, lime (CaO, calcium oxide) neutralizing acidic soil. Potassium – It is found in the mineral feldspar (KALSi3O8, potassium aluminum silicate). Its compounds like potassium nitrate is used in fertilizer, explosives, and photography. Chlorine – It is a poisonous gas with an irritating odor. It’s compound, sodium chloride is used in foods. Its other compounds like sodium hypochlorite and hydrochloric acid is used as cleaners, bleach, and pesticides in DDT. Sulfur – It is normally associated with volcanoes. The bad eggs smell near volcanoes come from compounds of sulfur like hydrogen sulfide (H2S) and sulfur dioxide (SO2). Sulfuric acid (H2SO4) is one of the gases responsible for acid rain. Silicon – One of its compounds is silica (SiO2) which is the pure form of sand. Silica is also used in making glass and in computer chips. Aluminum – It is a common component of most rocks. Sapphire and ruby are forms of aluminum oxide (Al2O3). G. Assessment 1. Give the name of the element represented by each symbol a. Na f. Ne b. K g. Ca c. Pb h. Cl d. Ag e. Cu e. Sn f. Si 2. Give the name of each element and the corresponding number of atoms in a formula unit of the following compounds: a. limestone, CaCO3 b. sulfuric acid, H2SO4 c. baking soda, NaHCO3 d. vinegar, CH3COOH e. limewater, Ca(OH)2 f. nitric acid, HNO3 3. Give at least 3 elements, one compound for each and their uses. IV. Agreement/Assignment 1. What is a chemical reaction? a chemical equation? 2. What are the rules in writing a chemical equation? 3. Name some chemical reactions taking place around you and try to represent them with chemical equations BSE-Department of Education 175 Integrated Science Week 10-Cont’d Lesson 10-4 Chemical Reactions in the Environment Time Frame: two periods I. Objectives At the end of the activities, the students should be able to: 1. 2. 3. 4. 5. 6. describe a chemical equation; analyze some chemical reactions based on given rules; write the chemical reactions involved acid rain production; determine the effect of acid rain on limestone rock; identify the substances used in the reactions and the products formed; and explain the effect of acid on limestone statues and buildings. II. Subject Matter A. Topic: Chemical Reactions in the Environment B. References: Rabago, Lilia M., et, al (1997). Science and Technology, General Science.SD Publications Inc., Araneta Ave., Q.C. Villamil, Aurora M. (1998). Science and Technology I. Integrated Science Teacher’s Manual. Abiva Publishing House, Inc. Quezon City. pp. 29-30 C. Materials: refer to the Student Activity Sheet 10-3 III. Learning Tasks A. Motivation 1. Recall some of the chemical changes taken up in Activities 72- and 9-2. (a. heating of iron and sulfur, b. heating of copper sulfate, c. heating of sugar, d. eggshells and vinegar). Why were they considered chemical changes and not just physical changes? (production of new substances). These changes involved chemical reactions where substances, elements and/or compounds, reacted to produce new compounds. Recall the products of the four reactions. (a. iron sulfide, b. anhydrous copper sulfate and water, c. carbon and water, d. calcium acetate, carbon dioxide and water). The reactions can be illustrated with chemical equations. What do chemical equations consist of? How are they written? 176 BSE-Department of Education 2. Recall some of the mathematical equations that you have used so far. D = M/V ; A = L x W ; V = L x W x H ; P = F/A ; A = r2 What are the parts of the equations? What does each part signify? 3. In Science, particularly in Chemistry, we also write chemical equations. Show the simple chemical equations below: a. b. c. d. e. Fe + S FeS CaO + H2O Ca(OH)2 Mg + HCl MgCl2 + H2 H2CO3 H2O + CO2 HCl + NaOH HOH + NaCl Describe the parts of each equation. (reactants, products, plus (+) sign, arrow to represent equal, and numbers before the formulas). You may either give the names of the formulas or you can ask the students to do so if they are already with them. You can tell that the equations are representatives of the 4 general types of chemical equations. Tell the students that they will learn detailed formula writing in Chemistry in the third year. At this point it is enough that they become familiar with the formulas of some compounds that they will encounter in later topics like Lithosphere, Hydrosphere, etc. 4. Tell the students that in today’s lesson they will study only the simple reactions. They will apply this knowledge in an experiment that simulates acid rain. They will find out what happens to rainwater, one of the reactants, in the presence of gases like sulfur dioxide and nitrogen dioxide and write the appropriate chemical reactions. B. Preliminary Activity 1. 2. 3. 4. Prepare the materials and put in respective trays. Arrange students in groups and give each member a specific task. Discuss objectives of the activity. Drill on laboratory safety and procedures. Observing reacting materials Mixing materials Use of glassware C. Lesson Proper 1. Discuss a. what chemical equations show; b. some principles to remember in writing chemical equation; c. the rules in writing equation. BSE-Department of Education 177 2. Analyze the equations below and see whether it conforms to the principles and rues in writing chemical equations. a. b. c. Combination Reaction Fe + S FeS one atom of iron reacts with one atom of sulfur to form a compound of iron sulfide consisting consisting of one atom of iron and one atom of sulfur. Combination Reaction CaO + H2O One molecule of one molecule of calcium oxide reacts water Single Replacement Mg + HCl magnesium hydrogen atom chloride compound MgCl2 magnesium chloride compound Decomposition d. H2CO3 H2O + hydrogen water carbonate molecule molecule Single Replacement e. HCl + NaOH hydrogen sodium chloride hydroxide molecule compound Ca(OH)2 a compound of to form calcium hydroxide + H2 hydrogen molecule CO2 carbon dioxide molecule HOH + NaCl water sodium chloride molecule compound 3. Write the word reactions for those mentioned earlier in the motivation part, then the balance chemical equations. Students might find this a little difficult. You can provide the equations and let them do the balancing. 4. You may tell the student the type each reaction belong to differentiate them from one another but do not give this too much emphasis. They will take this up in detail in their third year. 5. You may give the chemical equations of some reactions taken up in previous lesson. You may stop at this point. Ask the students to read the procedure for Activity 10-3 and bring at least one medium-sized rock and a bottle of vinegar for the group’s use. 178 BSE-Department of Education 6. Perform Activity 10-3. Acid rain is a major pollutant in the world today. This activity designed to show the effect of acid rain on limestone rock. If limestone is not available, you may use marble chips. You can get these from stores selling construction materials. 7. Conduct a post-discussion on the observations and relate it to the effect of acid rain in the environment particularly on statues and buildings. D. Discussion 1. Chemical equations show: a. b. c. d. the reactants which enter into a reaction; the products which are formed by the reaction; the amount of each reactant used and each product formed. that the sign, , means “yields” or “forms” and shows the direction of the reaction. 2. There are some important principles in writing chemical equations: a. every chemical compound has a formula which cannot be changed; b. every atom used as reactant must be accounted for in the product. This is an application of the Law of Conservation of Matter, which states that in a chemical reaction, atoms are neither created nor destroyed. 3. Some things to remember about writing equations: a. the diatomic elements when they stand alone are always written with the subscript 2, e.g. H2, N2, O2, F2, Cl2, Br2, I2. b. see to it that each formula in the equation is correct before attempting to balance the equation. c. balance the equation by placing coefficients in front of the formulas to insure the same number of atoms of each element on both sides of the arrow. 4. There are four types of chemical reactions: a. Combination – two or more elements or two or more compound combine to form a single product. b Decomposition – A single compound decomposes or breaks down into its constituent elements or compounds d. Single Replacement – A compound is broken down by an element, either a stronger metal or nonmetal which replaces the metal in the compound. e. Double Replacement – two pairs of different compounds combine and results in the exchange of partners in between pairs. BSE-Department of Education 179 5. Equations for the chemical changes observed in Activity 7-2 and 9-2. CuSO45H2O copper sulfate pentahydrate C12H22O11 sucrose (sugar) CuSO4 + anhydrous copper sulfate 12C + carbon CaCO3 + 2 CH3COOH calcium acetic carbonate acid (limestone) (vinegar) 5H2O water 11H2O water Ca(CH3COO)2 calcium acetate + H2CO3 hydrogen carbonate (carbonic acid) You may stop at this point. Ask the students to read the procedure for Activity 10-3 for next day’s activity. 6. Acid rain is a broad term used to describe several ways that acids fall out of the atmosphere. A more precise term is acid deposition, which has two parts: wet and dry. Wet deposition refers to acidic rain, fog, and snow. As this acidic water flows over and through the ground, it affects a variety of plants and animals. The extent of effect depends on many factors, including how acidic the water is, the nature of the soils involved, and the types of fish, trees, and other living things that rely on the water. Dry deposition refers to acidic gases and particles. About half of the acidity in the atmosphere falls back to earth through dry deposition. The wind blows these acidic particles and gases onto buildings, car, homes, and trees. Dry deposited gases and particles can also be washed from trees and other surfaces by rainstorms. When that happens, the runoff water adds those acids to the acid rain, making the combination more acidic than the falling rain alone. Scientists discovered, and have confirmed, that sulfur dioxide (SO2) and nitrogen oxides (NO and NO2) are the primary causes of acid rain. Its sources are burning of fossil fuels like coal ,gasoline, and natural gas. 180 BSE-Department of Education Acid rain occurs when these gases react in the atmosphere with water, oxygen, and other chemicals to form various acidic compounds like sulfuric acid and nitric acid. Sunlight increases the rate of most of these reactions. SO2 + H2O H2SO3 sulfurous acid 2SO2 + O2 2 SO3; SO3 + H2O H2SO4 sulfuric acid 2 NO + O2 2 NO2 2NO2 + H2O HNO2 + HNO3 nitrous acid nitric acid NO2 + [OH]- HNO3 Acid rain looks, feels, and tastes just like clean rain. The harm to people from acid rain is not direct. Walking in acid rain, or even swimming in an acid lake, is no more dangerous than walking or swimming in clean water. However, the pollutants that cause acid rain (sulfur dioxide (SO2) and nitrogen oxides (NOx) also damage human health. These gases interact in the atmosphere to form fine sulfate and nitrate particles that can be transported long distances by winds and inhaled deep into people's lungs. Many buildings and monuments are made of stone, and many buildings use stone for decorative trim. Granite is now the most widely used stone for buildings, monuments, and bridges. Limestone is the second most used building stone. It was widely used before Portland cement became available in the early 19th century because of its uniform color and texture and because it could be easily carved Because of their composition, some stones are more likely to be damaged by acidic deposition than others. Granite is primarily composed of silicate minerals, like feldspar and quartz, which are resistant to acid attack. Sandstone is also primarily composed of silica and is thus resistant. Limestone and marble are primarily composed of the mineral calcite (calcium carbonate), which dissolves readily in weak acid; in fact, this characteristic is often used to identify the mineral calcite. BSE-Department of Education 181 Acid precipitation affects stone primarily in two ways: dissolution and alteration. When sulfurous, sulfuric, and nitric acids in polluted air react with the calcite in marble and limestone, the calcite dissolves. In exposed areas of buildings and statues, we see roughened surfaces, removal of material, and loss of carved details. Stone surface material may be lost all over or only in spots that are more reactive. E. Evaluation 1. Give the number of atoms of elements in each formula given in the table below: Fomula Number of Atoms of C H O Cu Ca N S Si CH3COOH CuSO45H2O HNO3 Ca(OH)2 SiO2 NH4NO3 2. Examine the chemical equations below: a) Compare the number of atoms in the reactant side and in the product side. b) Write YES if the number of atoms of the elements are equal on both sides and NO if the number of atoms of the elements are not equal on both sides, c) If your answer is no, explain why. 2.1 2.2 2.3 2.4 Zn + CuSO4 ZnSO4 + Cu KClO3 KCl + O2 CO + O2 CO2 HNO3 + NaOH NaNO3 + HOH IV. Agreement/Assignment 182 1. What is Waste Recycling? What are some of the methods followed in waste recycling? 2. Name some of the contributions of Filipino and Foreign scientists in waste recycling. BSE-Department of Education Student Activity Sheet 10.4 Simulating Acid Rain Materials vinegar medicine droppers watch glass medium-sized limestone rock small piece of basalt rock hammer Procedure 1. Place small pieces limestone in a watch glass. Place a piece of colored paper under the watch glass for better observation. 2. With a medicine dropper, place a few drops of vinegar onto the limestone. Describe your observations. 3. Continue dropping vinegar in a constant stream to simulate rain. What happens to the rock? Compare your observations on this rock with that in step 2. Data Material observed Initial observations Final Observations Questions 1. 2. 3. 4. 5. What happens when vinegar is combined with limestone? What were the indications that a chemical change took place? Write the balanced equations for the reactions. Discuss how rain becomes acidic. Explain how acid rain destroys statues and buildings. Generalization BSE-Department of Education 183