MTAu / Form 4 / 2nd term Exam 99-00 / Chemistry / Paper II / Page.1 Hoi Ping Chamber of Commerce Secondary School Final Term Examination 99/00 Chemistry Paper II 11.00 am – 12.00 am (1 hour) 1. 2. 3. ANSWER ALL QUESTIONS. All the answers should be marked on the Answer Sheet. Note that you may only mark ONE answer to each question. Two or more answers will score NO MARKS. All questions carry equal marks. No marks will be deducted for wrong answers. There are 50 questions in this paper. 1. Which of the following diagrams can represent a mixture of two elements ? 4. In the above experiment, a gas is evolved and burns at the jet. Metal X is probably 2. Element X has an isotope 31 15 X . Which of the following statements is/are correct ? (1) X belongs to Group V of the Periodic Table. (2) X can react with oxygen to form an ionic compound. (3) 3. 31 15 5. A. zinc. B. aluminium. C. magnesium. D. copper. X and Y are elements. The melting points of their chlorides are given below : Melting point (C) X has 16 neutrons. A. (1) only B. C. D. (2) only (1) and (3) only (2) and (3) only Chloride of X 586 Chloride of Y 0 Which of the following statements is correct ? Which of the following molecules has the greatest number of lone pairs of electrons ? A. chlorine B. hydrogen C. nitrogen D. oxygen Page.1 A. Both X and Y are metals. B. The chloride of Y is a solid at room temperature. C. The chloride of X conducts electricity in the solid state. D. The chloride of Y is a covalent compound. MTAu / Form 4 / 2nd term Exam 99-00 / Chemistry / Paper II / 6. Which of the following elements can 9. Aluminium is used to make window react together to form a covalent frames because compound ? (1) it is strong. (1) neon (2) it can resist corrosion. (2) hydrogen (3) it is the most abundant metallic (3) sulphur 7. element in the earth crust. (4) potassium Which of the above statements are A. (1) and (2) only correct ? B. (1) and (4) only A. (1) and (2) only C. (2) and (3) only B. (1) and (3) only D. (3) and (4) only C. (2) and (3) only D. (1), (2) and (3) Consider the following information : Substance Melting point /C Electrical Solubility conductivity at in water 10. Which of the following metals are present in 14 carat gold ? (1) Chromium room temperature W Page.2 - 53.5 Poor Slightly (2) Copper soluble (3) Silver X 61 Poor Insoluble A. (1) and (2) only Y 232 Good Insoluble B. (1) and (3) only Z 782 Poor Very C. (2) and (3) only soluble D. (1), (2) and (3) Which of the above substances exists as a simple molecular solid at room 11. In each of the four solutions shown below, a strip of zinc is added. temperature ? 8. A. W B. X C. Y D. Z Which of the following statements concerning helium is/are correct ? (1) The outermost electron shell of a Which of the following combinations is helium atom has an octet structure. correct ? (2) Helium is used to fill weather Tube Observation A. I No change molecules. B. II Brown coating on zinc A. (1) only C. III No change B. (2) only D. IV Grey coating on zinc C. (1) and (3) only D. (2) and (3) only balloons. (3) Helium exists as monatomic Page.2 MTAu / Form 4 / 2nd term Exam 99-00 / Chemistry / Paper II / 12. Consider the following chemical Page.3 15. equation : O2(g)+ 4Fe(OH)2(x) 2Fe2O3(y) + 4H2O(z) Which of the following combinations is correct ? x y z A. s s l B. s aq aq C. aq s aq D. aq aq l Which of the following metals would produce the largest voltage in the above set-up ? A. iron B. aluminium C. copper D. magnesium 13. In which of the following processes will lead be produced ? (1) the electrolysis of molten lead(II) bromide (2) heating lead(II) oxide strongly (3) adding magnesium to lead(II) 16. In which of the following reactions is the underlined reactant reduced ? A. Pb2+ + 2OH- Pb(OH)2 B. CO2 + 2Mg 2MgO + C C. 2NH3 + 3CuO 3Cu + N2 + 3H2O nitrate solution A. (1) only B. (2) only C. (1) and (3) only D. (2) and (3) only D. 14. Brass is commonly used for making ornaments because (1) it has an attractive appearance. (2) It can resist corrosion. (3) It is softer than copper. Which of the following combination is correct ? Mg + 2AgNO3 Mg(NO3)2 + 2Ag 17. Which of the following statements concerning iodine and chlorine is INCORRECT ? A. They exist as diatomic molecules. B. Their atoms have the same number of outermost shell electrons. C. They form ions with a single negative charge. D. Iodine is a stronger oxidizing agent than chlorine. A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) 18. A student mix equal volumes of acidified potassium permanganate solution and iron(II) sulphate solution together. Which of the following statements about the reaction is INCORRECT ? A. The colour of acidified potassium permanganate solution fades. B. Permanganate ion is reduced. C. Hydrogen ion is oxidized. D. Iron(II) ion is oxidized. Page.3 MTAu / Form 4 / 2nd term Exam 99-00 / Chemistry / Paper II / 19. Consider the equation : following chemical Page.4 24. Which of the following statements concerning citric acid is/are correct ? (1) It is a strong acid. (2) It is present in oranges. (3) It exists as a solid at room temperature. 20. Consider the following table : Element W X Y Z Atomic number 6 11 17 18 Which of the following elements is likely to be an oxidizing agent ? A. W B. X C. Y D. Z 21. Using 1 mole of reactant, which of the CrO4 (aq) Cr (aq) B. Cr2O72-(aq) Cr3+(aq) C. MnO4-(aq) Mn2+(aq) D. MnO4 (aq) MnO2(s) (2) only C. (1) and (3) only D. (2) and (3) only hydrochloric acid to give a gas. The solid is probably A. calcium oxide. B. calcium carbonate. C. sodium hydroxide. D. sodium carbonate. 26. Potassium permanganate solution acidified with dilute sulphuric acid is a commonly-used oxidizing agent. Dilute 3+ nitric acid is not used to acidify potassium permanganate solution because 2- A. 22. Consider the following flow diagram : CuO(s) B. an alkaline solution reacts with dilute highest number of electrons ? A. (1) only 25. A white solid dissolves in water to give following chemical changes involves the 2- A. Reactant X Cu(s) Reactant Y nitric acid is more expensive than sulphuric acid. B. Cu2+(aq) dilute nitric acid is an oxidizing agent and would react with the reducing agent. Which of the following combinations is C. correct ? nitric acid decomposes more readily than sulphuric acid. Reactant X Reactant Y A. H2(g) dilute H2SO4 B. CO(g) dilute HNO3 C. Mg(s) dilute HCl D. C(s) concentrated HCl D. dilute nitric acid would react with potassium permanganate solution. 27. Which of the following substances are commonly found in the waste water produced by electroplating factories ? (1) acids 23. Which of the following substances has a pH less than 7 ? (2) alkalis (3) cyanides A. lemon juice A. (1) and (2) only B. soap solution B. (1) and (3) only C. glass cleaner C. (2) and (3) only D. milk of magnesia D. (1), (2) and (3) Page.4 MTAu / Form 4 / 2nd term Exam 99-00 / Chemistry / Paper II / Directions : Q.28 and Q.29 refer to the Page.5 31. A sample of concentrated sulphuric acid has a density of 1.83 g cm-3 and contains following experiment. 94.0 % of sulphuric acid by mass. What is the concentration (correct to one decimal place) of sulphuric acid in the sample ? (Relative atomic masses : H=1.0 , O=16.0 , S=32.1) 28. Which of the following combinations is A. 17.5 M B. 18.3 M C. 18.7 M D. 19.8 M correct ? Gas X Gas Y A. chlorine hydrogen B. chlorine oxygen C. hydrogen chlorine (1) sodium hydroxide solution D. oxygen hydrogen (2) concentrated nitric acid 32. Which of the following reagents can be used to distinguish between Fe2+(aq) and Fe3+(aq) ions ? (3) ammonia solution 29. Which of the following statements A. (1) and (2) only concerning the above experiment is/are B. (1) and (3) only correct ? C. (2) and (3) only D. (1), (2) and (3) (1) Platinum electrodes should be used. (2) The concentration of Na+(aq) ions 33. Metal X reacts with dilute nitric acid to around the cathode increases. (3) The solution changes give a colourless solution. When sodium from hydroxide solution is added to the colourless to pink. solution, a white precipitate which A. (1) only dissolves in excess sodium hydroxide B. (2) only solution is formed. X is probably C. (1) and (3) only A. copper. D. (2) and (3) only B. iron. C. zinc. D. magnesium. 30. Which of the following can be used to distinguish between dilute hydrochloric acid and dilute nitric acid ? (1) copper (2) silver nitrate solution (3) Copper(II) carbonate solution A. (2) only B. (1) and (2) only C. (1) and (3) only D. (2) and (3) only Page.5 MTAu / Form 4 / 2nd term Exam 99-00 / Chemistry / Paper II / 34. The following experimental results were performed a titration experiment in which she added an acid react with 2 M NaOH and 4 M HCl was from a burette to an alkali contained in a reacted with 4M NaOH respectively : conical flask. The following diagrams No. show the initial and final readings of the Volume of Rise in alkali temperature acid 100 cm3 of 100 cm3 of 2 M HCl 2 student obtained when 2 M HCl was allowed to Expt. Volume of 1 37. A Page.6 burette. T1C 2 M NaOH 100 cm3 of 100 cm3 of 4 M HCl T2C 4 M NaOH Which of the following is correct ? A. T1 = T2 B. T1 = 2T2 What was the volume of the acid added C. 2T1 = T2 from the burette to the conical flask ? D. 4T1 = T2 A. 28.5 cm3 B. 28.6 cm3 Directions : Q.35 and Q.36 refer to the C. 28.7 cm3 following experiment : D. 28.9 cm3 A silver coin, with a mass of 12.00 g, was 38. One mole of calcium chloride contains dissolved completely in concentrated nitric A. 3 moles of atoms. acid. chloride B. 1 mole of cations. solution was added to the resulting solution, C. 1 mole of molecules. 14.35 g of a white precipitate [AgCl(s)] were D. 2 moles of ions. When excess potassium obtained. 39. 35. Which of the following equations correctly represents the reaction between silver and concentrated nitric acid ? A. Ag + 2H+ + NO3- Ag+ + NO2 + H2O B. Ag + 4H+ + 4NO3- Ag+ + 4NO2 + O2 + 2H2O C. 3Ag + 4HNO3 3AgNO3 + NO + 2H2 D. Ag + 4HNO3 AgNO3 + 3NO2 + 2H2O 36. What is the percentage by mass of silver Which of the following solutions gives the brightest bulb light in the set-up in the coin ? (Relative atomic masses : Cl=35.5, Ag=108) shown above ? A. 45% A. 1 M HNO3 B. 60% B. 1 M HCl C. 75% C. 1 M H2SO4 D. 90% D. 1 M CH3COOH Page.6 MTAu / Form 4 / 2nd term Exam 99-00 / Chemistry / Paper II / 40. The following diagrams show the steps Page.7 43. A 2.0 M sodium chloride solution is in the preparation of the acid solution. prepared by dissolving 11.7 g of sodium chloride in distilled water. What is the volume of the solution formed ? (Relative atomic masses: Na= 23.0, Cl= 35.5) A. 50.0 cm3 B. 100.0 cm3 C. 250.0 cm3 D. 500.0 cm3 44. The formula of a metal carbonate is The correct sequence of the diagrams is X2CO3. 100 cm3 of a solution containing A. I, IV, III, II 0.69 g of the carbonate requires 50 cm3 B. III, I, IV, II of 0.20 M hydrochloric acid for C. III, IV, I, II complete reaction. What is the relative D. IV, III, II, I atomic mass of metal X ? (Relative atomic masses : C = 12.0, O = 16.0) 41. The concentration of an aqueous A. 19.0 solution of an acid is 1.0 M. 25.0 cm3 of B. 23.0 this acid solution requires 37.5 cm of C. 39.0 2.0 M sodium hydroxide solution for D. 78.0 3 complete neutralization. What is the 45. The formula for Azone is A4. If one basicity of the acid ? A. 1 mole of Azone contains x atoms, how B. 2 many atoms will one mole of Axygen C. 3 gas (A3) contain ? D. 4 A. 4x B. 3x C. 4 3 x D. 3 4 x 42. Iron can be produced from iron(III) oxide by the following reaction : Fe2O3(s) + 3CO(g) 2Fe(s) + 3CO2(g) What mass of iron(III) oxide is required to produce 2.1 g of iron ? (Relative atomic masses: O= 16.0, Fe = 56.0) A. 3.0 g B. 4.5 g C. 6.0 g D. 9.0 g Page.7 MTAu / Form 4 / 2nd term Exam 99-00 / Chemistry / Paper II / Directions : Page.8 Each question below (Question No.s 46 to 50) consists of two separate statements. Decide whether each of the two statements is true or false; if both are true, then decide whether or not the second statement is a correct explanation of the first statement. Then select one option from A to D according to the following table : A. Both statements are true and the 2nd statement is a correct explanation of the 1st statement. B. Both statements are true and but the 2nd statement is NOT a correct explanation of the 1st statement. C. The 1st statement is false but the 2nd statement is true. D. Both statements are false. 1st statement 2nd statement 46. Both dry ice and quartz exist in the form of discrete molecules. Carbon and silicon atoms have the same number of electrons in their outermost shells. 47. Metals have conductivity. thermal Metals are composed of giant lattices of positive ions surrounded by valence electrons which are free to move throughout the lattices. 48. A solution of hydrogen chloride in methylbenzene (a non-polar solvent) can turn blue litmus paper red. Hydrogen chloride dissolves in methylbenzene to form hydrogen ions. 49. If a student accidentally spills some hydrochloric acid on his hand, he should immediately wash his hand with sodium hydroxide solution. Sodium hydroxide solution neutralize hydrochloric acid. 50. Before transferring 25.0 cm3 of a solution from a pipette into a conical flask, the flask should be washed with the solution first. Water in the conical flask will dilute the solution from the pipette. good END OF PAPER Page.8 can