LESSON PLAN School : State Senior High School The Lesson : Chemistry Subject : Carbon Atom and Hydrocarbon Grade/ semester : X/ 2 Time Allocation : 8×45 minutes Standard of Competence : Understanding the properties of organic compound based on its structure and macromolecules compound. Basic Competency : Classifying the hydrocarbon compound based of it structure and the relation with compound properties. Teaching Objectives : Students are able to classify the hydrocarbon compounds based on saturation binding Students are able to write the nomenclature of alkanes, alkenes and alkynes Students are able to write the chemical formula of some hydrocarbon compound that the nomenclature is known. Students are able to explain the relation of hydrocarbon compounds boiling point with a molecular weight (Mr) and structure. Students are able to explain the relation of hydrocarbon state and the amount of C atoms Students are able to explain the isomer in the carbon compound Students are able to determine the isomer structure (order, position) and geometric isomers (cis - trans) Students are able to explain the kinds of carbon compound reaction (addition reaction, substitution, and elimination) Students are able to write a simple reaction to the compound alkanes, alkenes and alkynes (addition reactions, substitution and elimination) Indicator : Students are able to classify the hydrocarbon compounds based on saturation binding Students are able to write the nomenclature of alkanes, alkenes and alkynes Students are able to write the chemical formula of some hydrocarbon compound that the nomenclature is known. Students are able to explain the relation of hydrocarbon compounds boiling point with a molecular weight (Mr) and structure. Students are able to explain the relation of hydrocarbon state and the amount of C atoms Students are able to explain the isomer in the carbon compound Students are able to determine the isomer structure (order, position) and geometric isomers (cis - trans) Students are able to explain the kinds of carbon compound reaction (addition reaction, substitution, and elimination) Students are able to write a simple reaction to the compound alkanes, alkenes and alkynes (addition reactions, substitution and elimination) Teaching Method : Lecturing Giving Worksheet Question Answer Methode Discussion Media components : Notebook, LCD, Whiteboard, Worksheet. Learning materials : Classify hydrocarbon compounds Based on the bond that happens there are several kinds of hydrocarbon compounds are: the single bonds alkanes, alkenes have one double bond and alkynes has one triple bond Alkanes General formula: C n H 2n + 2 Nomenclature : no. branch – the name of branch – the name of the main chain Alkene General formula: C n H 2n Nomenclature : no. branch – the name of branch – no. of double bond – the name of main chain ended by ena Alkyne General formula: C n H 2n – 2 Nomenclature: alkyne just same with the name of alkene, but the main chain is ended by una Physical properties of Hydrocarbon Compounds The boiling point of hydrocarbons is influenced by relative molecule mass The bigger Mr value, make the boiling point of alkane is bigger too. Example: The boiling point of CH4 (methane) is – 164 0C and the boiling point of C2H6 (ethane) is – 89 0C. The boiling point of hydrocarbon compounds is influenced by its structural from the less total amount of branched-chain make the boiling point of alkane is higher. Example: Boiling point of n-pentane (C5H12) is 36 0C and boiling point of 1-methylbutane (C5H12) is 28 0C The Amount of C atoms connect with the hydrocarbon compounds state Alkanes, alkenes, and alkynes compound with small molecular mass have gas state in room temperature, while other have liquid or solid state. Isomers Isomers are compounds - compounds that same molecular formula, structural formula is different Types of isomers: Frame Isomers Frame compound is groups of compounds with the same Mr, but with different carbon frame. Example: n-butane with 2-methyl propane CH3 – CH2 – CH2 – CH3 CH3 – CH – CH3 n-butane CH3 2-methylpropane Position isomer Position isomer is compounds of isomer that is triggered by the difference of double or triple bond position in carbon chain Example: 1-pentene with 2-pentene CH2 = CH – CH2 – CH2 – CH3 CH3 – CH = CH – CH2 – CH3 1-pentene 2-pentene Geometric isomers (cis - trans) Geometrical isomer is compounds of isomer that is triggered by the difference of geometric position of a cluster attached to double-chained C atom. Reaction of Carbon Compounds Reactions of carbon compounds there are several kinds of addition reactions, substitution and elimination Types of Reaction Explanation Substitution The reaction of changing one reaction atom with another Addition reaction The reaction of double bond breaking or Illustartion A + BC AB + C C=C+A–BC–C molecule A B combining Elimination The dissociation reaction of C–CC=C+A–B reaction compounds, or the forming A B reaction of double bond (the reverse of addition reaction) Teaching and Learning Steps 1st meeting Opening ( 5 minutes) No. Activities Teacher’s Language 1. Greeting Good morning, class. 2. Asking for student’s condition How are you today? 3. Leading a prayer Before we start our lesson today, let’s pray together. Prayer, do. … Thank you. 4. Checking attendance Who is absent today? 5. Apperception Do you know how typical of carbon atom? Main activities ( 83 minutes) No. Activities Teacher’s Language 1. To know more thing about it please form the Exploration Teacher ask student to form the group of ... students. Each group discuss group and each group discuss different topic: different topic 1. the nomenclature of alkane compound and its properties 2. the nomenclature of alkene compound and its properties 3. the nomenclature of alkyne compound and its properties 2. Teacher ask students to present Please one group present the result... the result to the class. 3. Elaboration Ok who will give the question to your friend... Teacher and student discuss about it, and some student can give the question to group that present. And clarification teacher about give it if necessary. 4. Teacher give a chance to other Next group, please... group and discuss the topic. 5. Confirmation Teacher gives There is something or matter that still make a short you confuse? explanation if necessary. Closing ( 5 minutes) No. Activities Teacher’s Language 1. That’s all the time we have for today. Please, Propose the next topic read the next matter. 2. Leave Taking See you later. 2nd meeting Opening ( 5 minutes) No. Activities Teacher’s Language 1. Greeting Good morning, class. 2. Asking for student’s condition How are you today? 3. Leading a prayer Before we start our lesson today, let’s pray together. Prayer, do. … Thank you. 4. Checking attendance Who is absent today? 5. Apperception Oke, lets review the last matter, what is the chemical formula of methane and butane? are those compounds have same physical properties? Main activities ( 83 minutes) No. Activities Teacher’s Language 1. To know more thing about it please form the Exploration Teacher ask student to form the group of ... students. Each group discuss group and each group discuss different topic: different topic 1. the influence of Mr to boiling point of carbon compounds 2. the influence of structural form to boiling point of carbon compounds 3. the connection of hydrocarbon compounds with the amount of C atoms Teacher ask students to present Please one group present the result... the result to the class. 2. Elaboration Ok who will give the question to your friend... Teacher and student discuss about it, and some student can give the question to group that present. And clarification teacher about give it if necessary. Teacher give a chance to other Next group, please... group and discuss the topic. 3. Confirmation Teacher gives There is something or matter that still make a short you confuse? explanation if necessary. Closing ( 5 minutes) No. Activities Teacher’s Language 1. That’s all the time we have for today. Please, Propose the next topic read the next matter. 2. Leave Taking See you later. 3rd meeting Opening ( 5 minutes) No. Activities Teacher’s Language 1. Greeting Good morning, class. 2. Asking for student’s condition How are you today? 3. Leading a prayer Before we start our lesson today, let’s pray together. Prayer, do. … Thank you. 4. Checking attendance Who is absent today? 5. Apperception Oke, lets review the last matter, Write the structure formula of n-butane and 2-methyl propane! Is there any similarity of those compounds? Main activities ( 83 minutes) No. Activities Teacher’s Language 1. Okke, we will study about the isomer in Exploration Teacher explains about the alkane.... isomer in alkane, alkene, and alkyne compounds. 2. Elaboration I have the exercise for you, please doit... Teacher ask student to do the exercise. 3. Confirmation Please, someone of you share the answer to the Teacher ask student to share class.. the answer to the class and give clarification. Closing ( 5 minutes) No. Activities Teacher’s Language 1. That’s all the time we have for today. Please, Propose the next topic read the next matter. 2. Leave Taking See you later. 4th meeting Opening ( 5 minutes) No. Activities Teacher’s Language 1. Good morning, class. Greeting 2. Asking for student’s condition How are you today? 3. Leading a prayer Before we start our lesson today, let’s pray together. Prayer, do. … Thank you. 4. Checking attendance Who is absent today? 5. Apperception Who can tell me what will be happened if a hydrocarbon compound burned? Yes you right it produce CO2 and H2O. Its not the only one of kinds the reaction in hydrocarbon compound. You will study it now. Core activities ( 83 minutes) No. Activities Teacher’s Language 1. Okke, we will study about this reaction... Exploration Teacher explains about substitution, elimination, and addition reaction and gives its example. 2. Elaboration I have the exercise for you, please form the Teacher ask student to do the group of ... students and do it. exercise in group. 3. Confirmation Please, someone of you share the answer to the Teacher ask student to share class.. the answer to the class and give clarification. Closing ( 5 minutes) No. Activities Teacher’s Language 1. That’s all the time we have for today. Please, Propose the next topic read the next matter. 2. Leave Taking See you later. Learning Source Justiana, Sandri and Muchtaridi. 2009. Chemistry for Senior High School 1 Year X. Jakarta: Yudhistira. Purba, Michael. 2007. Kimia untuk SMA Kelas X Semester 1. Jakarta: Penerbit Erlangga. Sunardi. 2007. Kimia Bilingual Untuk SMA/ MA Kelas X Semester 1 dan 2. Jakarta: Yrama Widya. Assessment Cognitive : : The result of exercise. Psycomotoric (enclosure) Affective : Attendance Evaluation Exercise 1st Meeting: 1. Define the name of this following alkanes: a. H H H H H H H–C–C–C–C–C–C–H H H b. H H H CH3 H H H H H H–C–C–C–C–C–H H H c C2H5 H H H H H CH3 H H H H–C–C–C–C–C–C–C–H H H H H H H H 2. Show the structure of this following hydrocarbon: a. n-pentane b. 3-ethylhexane c. 2-methylpropane d. 2,2,3-trimethyloctane e. 2-ethyl-4,7-dimethyldecane 3. Define the name of this following alkenes: a. CH3 – CH2 – CH = CH2 b. CH3 – CH = CH – CH3 c. C2H5 CH3 – CH – CH = CH – CH2 – CH– H C2H5 4. Show the structure of this following hydrocarbon: a. 3-methylpropene b. 2-butene c. 2-methyl-2-pentene d. 2,3,4-trimethyl-2-heptene e. 3-ethyl-2,5-dimethyl-4-decene 5. Define the name of these following alkynes: a. CH3 – C ≡ C – CH3 b. CH ≡ C – CH2 – C ≡ CH c. CH3 – CH2 – CH2 – CH2 – CH2 – C ≡ C – CH3 d. CH3 – C ≡ C – CH2 – C ≡ C – CH – CH3 CH3 6. Show the structure of this following hydrocarbon: a. 1-pentyne b. 2-methylbutyn c. 3-methylpentyne d. 1,3-pentadynes 2nd Meeting: Predict and put in order the boiling point of these hydrocarbons: a. n-hexane b. 2-methylhexane c. n-pentane d. 2,3-dimethylbutane Explain your answer! 3rd Meeting 1. Compound that belongs to n-butane isomer is … a. 3-methylpropane b. 2-methylpropane c. 2,2-dimethylbutane d. 2-methylbutane e. 3-methylbutane 2. Define the frame, position, and geometrical isomer of C8H16! 3. Define the frame and position isomer of C8H14! 4th Meeting Complete the following chemical reaction: 1. C2H6 + O2 2. C3H8 + Cl2 3. CH2 = CH2 + HCl 4. CH2 = CH2 + Br2 Psycomotoric Perception sheet of students in group No Name Discussion activity in class Cooperation in group Paticipation in group Average Perception sheet of students No Name Assessment scale: 1 : Very less 2 : Less 3 : Enough 4 : Good 5 : Very good Participation Having a notion Asking Correct reactions Average