Electrons and the Periodic Table—A Unit of Study for Freshman Science Monica Mynk Unit Standards at a Glance: ACADEMIC PROGRAM OF EXPECTATIONS STUDIES 2.1 Scientific Ways of Thinking 2.2 Patterns and Structure and Predictions Transformation of Matter 2.4 Scale and Models KY CORE CONTENT SC-HS-1.1.1 Periodic Table SC-HS-1.1.4 Flow of Electrons SC-HS-1.2.3 Electric Force OCCUPATIONAL STANDARDS AC-001 EA-005 Unit Focus: Electrons and the Periodic Table Estimated Time of Completion: 5-7 Days Integration: Math, Social Studies Connections to Previous Learning: Atomic Structure Unit Organizer: Why is the periodic table similar to a piano, and how does this help you predict which chemicals are safe and which ones are harmful? Critical Vocabulary: atomic radius, charge, conductor, electric force, electron, energy level, insulator, ion, metal, nonmetal Essential Questions: 1. How is the periodic table arranged and why is this related to electrons? 2. How can atoms in the periodic table be grouped according to similar properties? 3. What is an ion and how do they form? 4. How do electrons move? Kentucky Program of Studies Structure and Transformation of Matter Enduring Knowledge When elements are listed in order by their number of protons, the same sequence of properties appears over and over in the list. The structure of the periodic table repeats this sequence of properties, which is caused by the repeating patterns of outermost electrons. Kentucky Core Content for Assessment SC-HS-1.1.1 DOK 2 Students will classify or make generalizations about elements from data or observed patterns in atomic structure and/or position on the periodic table. The periodic table is a consequence of the repeating patterns of outermost electrons. SC-HS-1.1.4 Students will understand that in conducting materials, electrons flow easily; whereas in insulating materials, they hardly flow at all. SC-HS-1.2.3 Students will understand that the electric force is a universal force that exists between any two charged objects. Opposite charges attract while like charges repel. Connections to Literacy: Reading and research assignment on periodic table scientists; Writing assignment in culminating activity Student Misconceptions: Source: http://amasci.com/miscon/opphys.html 1. Electrons that are lost by an atom are really lost (no conservation of mass) 2. Positively charged objects have gained protons instead of losing electrons 3. The electron shell is like an egg yolk shell, there to protect the nucleus 4. The electron cloud is like a rain cloud with electron suspended like raindrops 5. Atoms “own” their electrons and electrons know which atom they come from Learning Targets: 1. Students can identify negatively and positively charged ions and explain how they form. 2. Students can use the periodic table to predict the properties of elements. 3. Students can explain the placement of elements on the periodic table with respect to the number of protons in the atom. Table of Contents Unit Outline ............................................................................................................... 4 Culminating Activity ................................................................................................. 5 Rubric ............................................................................................................ 7 Mendeleev Lab .......................................................................................................... 8 Rubric ............................................................................................................ 11 History of the Periodic Table Research Project ......................................................... 15 Rubric ............................................................................................................ 15 Charges and Ions Class Practice ................................................................................ 16 Key................................................................................................................. 17 Conductor and Insulator Lab ..................................................................................... 18 Rubric ............................................................................................................ 22 Color the Periodic Table Activity .............................................................................. 23 Periodic Trends Lab ................................................................................................... 25 Rubric ............................................................................................................ 28 Unit Assessment ........................................................................................................ 30 Key................................................................................................................. 32 Resources ................................................................................................................... 34 Unit Outline Day 1 2 3 4 5 Essential Question(s) How is the periodic table arranged and why is this related to electrons? How is the periodic table arranged and why is this related to electrons? How do electrons move in the atom? What is an ion and how do they form? How can atoms in the periodic table be grouped according to similar properties? How can atoms in the periodic table be grouped according to similar properties? 6 All Essential Questions 7 All Essential Questions Objective(s) Instructional Strategies Assignments SC-HS-1.1.1 Arrangement of the Periodic Table Mendeleev Lab SC-HS-1.1.1 History of the Periodic Table History of the Periodic Table Research Project SC-HS-1.1.4 SC-HS-1.2.3 Charges and Ions Class Discussion Class Practice SC-HS-1.1.1 Groups and Families Color Periodic Table Activity SC-HS-1.1.1 Groups and Families Groups and Families Lab Culminating Assessment The Martian Periodic Table Assessment Electrons and the Periodic Table Exam SC-HS-1.1.1 SC-HS-1.1.4 SC-HS-1.1.6 SC-HS-1.1.1 SC-HS-1.1.4 SC-HS-1.1.6 Culminating Activity—The Martian Periodic Table Task: Students are members of a research team that has just been given a set of data for 30 new elements that were discovered on the planet Mars. They have access to melting points, boiling points, electronegativities, valence electrons, bonding properties, and energy levels. Unlike the planet Earth, where eight valence electrons represents a full shell, students will have to deduce what a full shell will be. They will arrange these elements according to their properties, design a visual model that can effectively be used to predict the discovery of future elements, and make a presentation defending their design to a board of scientists, and make a list of at least five elements which have yet to be discovered, predicting what their properties will be. Groups: Students will be divided into groups of three to five students, divided into the following roles: Phase One: Research and Data Researchers: (need 2) Reads the “literature” documenting the discovery of the elements and searches for similar properties. Graphing Specialist: Plots the data from the elements and searches for graphical trends. Phase Two: Organization All students will make index cards for each element and then arrange them in a reasonable order by discussing evidence and comparing properties Phase Three: Visual Product and Presentation Design Power Point slideshow, poster, etc.—Student will put together a class presentation with visuals defending their periodic table design Design Periodic Table—Students will draw or build a model of their periodic table design to be displayed in a science exhibit at the next World’s Fair Self-Scoring Checklist: _____Conclusions are based on data and evidence, not opinion _____Demonstrates a relationship between the properties of elements and their placement _____Utilizes visual aids to present their periodic table design to a panel of “scientists” made up of their peers _____Develops a model representing the relationship between properties of the Martian elements Martian Data Al Ar Ba Be Br Ca Cl Cs F Ga H He I K Kr Li N Na Ne O P Rn Se Sr Martian Name Georgium Hanagen Roomium Textium Dramagen Artium Skittium Mynkium Romancium Bandium Frassium Chatogen Mirrogen Nubelium Parkium Hallium Drawnium Willisium Cappelagen Contrium Powellium Boardium Tudium Imagen Charge 3 0 2 2 -1 2 -1 1 -1 3 1 0 -1 1 0 1 -3 1 0 -2 -3 0 -2 2 MP 660 -189 714 1277 -7 838 -101 29 -220 30 -259 --114 64 -157 181 -210 98 -249 -219 44 -71 217 768 BP 2450 -183 1640 2970 58 1440 -35 690 -188 2237 -253 -260 183 760 -152 1330 -196 892 -246 -183 280 -62 685 1380 Electronegativity 1.5 --0.9 1.5 2.5 1 3 0.7 4 1.6 2.1 --2.5 0.8 --1 3 0.9 --3.5 2.1 --2.1 1 Energy Level 3 3 6 2 4 4 3 6 2 4 1 1 5 4 4 2 2 3 2 2 3 6 4 5 Valence Electrons 3 7 2 2 6 2 6 1 6 3 1 2 6 1 7 1 4 1 7 5 4 7 5 2 spdf p p s s p s p s p p s p p s p s p s p p p p p s Culminating Activity Rubric Process Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Has clear vision of final product Properly organized Managed time wisely Acquired needed knowledge base Communicated efforts with teacher Product Format Mechanics of speaking/writing Organization and Structure Creativity and Originality Demonstrates knowledge Complete project Presentation Logical sequence of information Demonstrates full knowledge and appropriate elaboration Use of visuals to reinforce presentation No graphical or spelling errors Clear voice, precise pronunciation Appropriate gestures, body language, and posture Mendeleev Game OVERVIEW: Each student is given a card with the properties of a unique element on it. Students must discuss and arrange themselves in order in a specific time period. Then, they have to write a rationale for their location, which will be compared to the periodic table. STUDENT ROLES: One student is given the role of project manager in order to help keep students on task and moving. They will question students about their properties and help students who are in the wrong place move on. Two students will be assigned the role of “missing” elements—they will know who they are, all their properties the entire game, but the other students will have to try to place them by asking questions. All other students are given individual elements and expected to question each other about their properties. They will form groups and then try to make an overall arrangement. GAME RULES: 1. Students will be given 10 minutes to create the overall arrangement for each segment—it is important that students remain on task and keep moving. 2. Each student must ask at least three other students questions about their properties before deciding where they belong in the arrangement. 3. If the project manager asks a student to move to another place in the arrangement, the student has to move unless they can justify their placement to the teacher using properties. 4. Every student is accountable to write a rationale explaining why he or she belongs in their placement in the arrangement. PROCEDURE: 1. Project manager will be given a list of all mystery elements and their properties, excluding valence electrons, atomic masses and atomic numbers. All other students will be given an envelope with properties written on it. 2. Students will have 10 minutes to walk around the room asking each other questions and deciding where they belong. 3. The “missing” element students will assist the project manager in this part of the activity. 4. When time is called, students have to “freeze” and write a rationale for their location to share with the class. The project manager will call on students to explain their rationale, and they will ask students to move if they think they are misplaced. 5. Students will be given 10 minutes, they will get a second envelope with valence electrons for their element, and the groups will be asked to arrange themselves in some kind of order within their group. 6. The project manager will arrange the groups and attempt to place the missing elements by asking them questions about their properties. 7. When time is called, students again “freeze” and write their rationale. The project manager calls on students to explain their rationale and moves any students that seem out of place. 8. Students are given a final envelope with the atomic number and mass number of their element, and they can see how successful they were in the task. Notes: If you have a class over 20, it is more effective to skip the transition metals and explain to students you are only using main-block elements. A follow up activity might be to ONLY use transition metals. Mendeleev Lab Fact Sheet Name: _____________________________ Date: _________ Period: ____ Mystery Element Number ______ Orbital ______ Melting Point ______ Boiling Point ______ Valence Electrons ______ Density (at room temperature) ______ Atomic Size ______ Electronegativity ______ Ionization Energy ______ State of Matter (at room temp) ______ Atomic Number ______ Metal, Nonmetal or Semimetal ______ Mass Number ______ 1. 2. 3. 4. Instructions: When you are given a clue, fill in the information on your fact sheet and return the clue envelope to your teacher. After recording the information, mingle with other students and ask them questions to find out if your mystery element has the same properties as theirs. If you find someone with similar properties, stay together and discuss how you may be arranged in the periodic table. Write your rationale in the space provided on the back of this paper. The project manager has the right to move you at any time. If you feel you are in the right place, you must justify it with properties. When the exercise is finished, write your prediction for the symbol of your mystery element in the correct location on the blank periodic table above. Mendeleev Lab Rationale After you have looked at the information given in each clue and decided where you belong (which elements you should be next to), write a rationale in the space provided below, explaining how you came to your decision. For example, “I belong next to mystery element number 4 because we have similar melting points.” Be advised that some properties are better to use than others! Rationale One: _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ Rationale Two: _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ Rationale Three: _______________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ Mendeleev Lab Data Sheet (see resources for references and additional info; see Culminating assessment for electronegativities, etc.) Mendeleev Lab Rubric Process Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Clearly understood and followed instructions Filled out fact sheet Managed time wisely Completed rationales Communicated with other students Determined identity of mystery element Determined placement of mystery element Total Grade: Teacher Comments: Use websites such as http://www.matpack.de/Info/Nuclear/Elements/properties.html to look up the properties of about 35 elements on the periodic table. I use the ones listed above, but leave some of them out on purpose and give those cards to gifted students for differentiation. The project manager should be given all of the information and an explanation of how the periodic table is arranged prior to the lab so they can help get the students in order. This activity is very effective to use BEFORE teaching students about the concepts of electronegativity, etc. and if you take it a step farther and plot the data, the lab itself can be used to teach those concepts. I also like to have students research the properties for homework and then have a class discussion the following day. Students will really get the picture of how the periodic trends are definite patterns in the table. Another modification I have tried is to have students kneel, stand on their tiptoes, stand on chairs, etc, based on their atomic size when they make the final arrangement of the periodic table. History of the Periodic Table Research Project Task: Students are given names of scientists related to the periodic table and discovery of elements to research and present to the class. Students must produce a visual for their presentation (power point, poster, brochure, etc.) Groups: Students will be divided into groups of either two or three. Roles: Researchers, Presenters, Presentation Designers Research Topics Robert Boyle Antoine Lavoisier Dmitri Mendeleev Henry Moseley Glenn Seaborg 1st Ten Elements Discovered: Copper, iron, lead, tin, gold, silver, carbon, sulfur, mercury, arsenic Research Requirements: 1. Presentation must be at least 3 minutes long, and no longer than 5 minutes 2. Students who research scientists must explain how their work relates to the arrangement of the elements on the periodic table. 3. Students who research elements must determine the date of discovery, who discovered the element, properties of the element, common uses of the element, and some examples of compounds containing the element 4. Students must include at least one visual aid, or a power point presentation with pictures 5. Research must be submitted in an appropriate written form—not just a list of handwritten notes History of the Periodic Table Research Rubric Process Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Has clear vision of final product Properly organized Managed time wisely Acquired needed knowledge base Communicated efforts with teacher Process Total Product Format Mechanics of speaking/writing Organization and Structure Creativity and Originality Demonstrates knowledge Complete project Product Total Presentation Logical sequence of information Demonstrates full knowledge and appropriate elaboration Use of visuals to reinforce presentation No graphical or spelling errors Clear voice, precise pronunciation Appropriate gestures, body language, and posture Presentation Total Overall Total Charges and Ions Practice Name: _____________________________________ Date: ________________ Period: ______ For the following elements: 1. Tell whether electrons are lost or gained to form the ion, and how many electrons are exchanged during ionization. 2. How many electrons would the atom have if it were neutral? 3. How many electrons does the atom have now that it is charged? Element Lost/Gained # Electrons Exchanged # Electrons in a Neutral Atom # Electrons in the Charged Atom (Ion) 1. Li+1 2. F-1 3. Al+3 4. O-2 5. Be+2 Write the symbol, charge, and name of the following: 1. An element with 26 protons has lost three electrons ________ __________________ 2. An element with 16 protons gained two electrons ________ __________________ 3. An element with 3 protons has lost one electron ________ __________________ 4. An element with 5 protons has lost three electrons ________ __________________ 5. An element with 9 protons has gained one electron ________ __________________ Of the following: 19 -1 F 11 +3 B 1. Which of the examples are cations? 2. Which of the examples are anions? 3. Which of the examples are metals? 4. Which of the examples are nonmetals? 5. Which of the examples are semimetals? 7 Li+1 16 O-2 9 Be+2 28 Si-4 Charges and Ions Practice Key Name: _____________________________________ Date: ________________ Period: ______ For the following elements: 1. Tell whether electrons are lost or gained to form the ion, and how many electrons are exchanged during ionization. 2. How many electrons would the atom have if it were neutral? 3. How many electrons does the atom have now that it is charged? Lost/Gained # Electrons Exchanged # Electrons in a Neutral Atom # Electrons in the Charged Atom (Ion) 1. Li+1 Lost 1 3 2 2. F-1 Gained 1 9 10 Lost 3 13 10 Gained 2 8 10 Lost 2 4 2 Element 3. Al+3 -2 4. O 5. Be+2 Write the symbol, charge, and name of the following: 2. An element with 26 protons has lost three electrons ___Fe+3_ __Iron ____ 2. An element with 16 protons gained two electrons ___S-2_ ___Sulfur 3. An element with 11 protons has lost one electron _Na+1_ ___Sodium_________ _____ 4. An element with 5 protons has lost three electrons __B+3__ __ Boron__________ 5. An element with 17 protons gained one electron 7 Li+1 1. Which of the examples are cations? 11B+3 7 Li+1 2. 16 Of the following: 19 -1 F 11 +3 B Which of the examples are anions? 19F-1 3. Which of the examples are metals? 7Li+1 4. Which of the examples are nonmetals? 19F-1 5. Which of the examples are semimetals? 11B+3 O-2 9 __Cl-1_ ___Chlorine_________ 16 9 Be+2 28 Si-4 Be+2 16 O-2 28 Si-4 O-2 9 Be+2 28 Si-4 Name_____________ Date______ Period____ From http://www.angelfire.com/scifi/dschlott/coninsulab.html Conductor and Insulator Lab Background Information: When electrons move from place to place, an electric current is created. Not all materials allow electrons to flow though them. Materials that allow electrons to flow freely are called conductors. Materials that do not allow electrons to flow freely are called insulators. In this investigation you will test some common materials and determine which are electrical conductors and which insulators. Problem: Which materials are conductors and which are insulators? Materials: 1.5V Dry Cell, 1.5V Lamp With Sockets, 3 Connecting Wires, Test Materials: Penny (Copper); Paper; Wax; Glass; Aluminum Foil; Plastic; Paper Clip; Wood; Rubber; Cloth; Pencil Lead (Carbon). Procedure: 1. Set up a dry cell, lamp and connecting wires as shown in figure 1. Have your teacher check you setup before proceeding. Figure 1 2. Keep the ends of the two test wirs about 2cm apart. Bring the ends of the wires into contact with each of the test materials to be tested. Record your observations in the data table. 3. After you have tested all of the materials, disconnect the wires from the dry cell. Observations: Material Copper Silver Paper Wax Glass Aluminum Foil Plastic Paper Clip Wood Rubber Cloth Carbon Bright Dim No Light Analyze Data: 1. Which of the materials you tested are good conductors of electricity? 2. Which of the materials you tested are insulators of electricity? 1. Are metals electrical conductors or insulators? 2. Are nonmetals electrical conductors or insulators? 3. What does this say about the particles of a conductor? 4. Why is most electrical wiring, such as the connecting wires used in the investigation made of copper? Going Further Strip about 8cm of wood away from one side of a pencil to expose the lead core inside the pencil. Hold the two ends of your test wires as far apart as possible and touch them to the lead core. Slowly move the wires closer together and observe what happens to the lamp. Use what you have learned in this investigation to explain your observations. Additional Conclusion Questions: 1. How does specific heat relate to conductors and insulators of electricity? 2. Using the chart on page 641 in your text, What elements would make the best conductors? Insulators? 3. Why don't we use your answers to question 2? Conductor and Insulator Rubric Lab Participation Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Managed time wisely Followed safety rules Followed instructions—both written and oral Stayed with lab group No horseplay or other discipline issues Lab Participation Total Lab Procedure Pre-lab Question 1 Pre-lab Question 2 Pre-lab Question 3 Pre-lab Question 4 Students read procedure Students listened to instructions Students cleaned up after themselves Students appropriately discarded waste Data Table 1 Data Table 2 Data Table 3 Data Table 4 Analysis Question 1 Analysis Question 2 Analysis Question 3 Analysis Question 4 Conclusion Question 1 Conclusion Question 2 Lab Procedure Total Total Lab Grade Color the Periodic Table Activity Name: ___________________________________ Date: ____________ Period: _____ Look up the following terms and use them to label a blank periodic table. Actinides-- Alkali Metals-- Alkaline Earth Metals-- Halogens-- Inner Transition Metals-- Lanthanides-- Main Block Elements-- Metals-- Noble Gases-- Nonmetals-- Semimetals-- Transactinides-- Transition Metals-- Valence Electrons-- Coloring the Periodic Table Name: __________________________________ Date: _______ Period: ________ Label the following on the periodic table, or color-code and make a key. Actinides, alkali metals, alkaline earth metals, groups, halogens, inner transition metals, lanthanides, main-block elements, metals, noble gases, nonmetals, periods, semimetals, transactinides, transition metals, valence electrons Trends in the Alkaline Earth Metals As you know, members of the same family in the Periodic Table have similar physical and chemical properties. In this lab, you will investigate some trends in physical properties of the alkaline earth metals. Specifically, you will look at reactivity (how well a substance reacts with another substance), pH (the concentration of hydrogen ions; pH 1-6.9 is acidic, more H+, and pH 7.1-14 is basic, less H+), solubility (how well does a substance dissolve in another substance), and formation of an insoluble carbonate (i.e. sodium carbonate plus barium chloride yields barium carbonate, which is a white solid or precipitate.) Note: Phenolphthalein is a base indicator—it turns pink in a basic solution. Materials Balance calcium turnings (Ca) saturated solutions of: Test tubes (13) magnesium ribbon (Mg) calcium hydroxide(Ca(OH)2) Test tube holder magnesium sulfate crystals magnesium hydroxide (Mg(OH)2) Test tube rack calcium sulfate crystals barium hydroxide (Ba(OH)2) Wood splints barium sulfate crystals 0.1 M aqueous solutions of pH paper water (H2O) sodium carbonate (Na2CO3) stirrer phenolphthalein solution magnesium chloride (MgCl2) Bunsen burner 10.0 mL graduated cylinder calcium chloride (CaCl2) barium chloride (BaCl2) Pre-lab 1. Read the introduction and procedure before you begin. 2. Be prepared to answer Pre-lab questions before starting the experiment. 3. Complete statement of purpose and hypothesis and design data table as required. Procedure 1. Put on your safety goggles. Part A: Reactivity 2. Pour 5.00 mL water into a clean, dry test tube and place the tube in the rack. Drop one piece of calcium in the water. (CAUTION: Use test tube holders! The test tube will get very hot.) To collect the gas being released, hold a clean dry test tube over the reactant tube so the two mouth of the two tubes are touching. 3. Test for hydrogen gas with a burning wood splint. Revisit this procedure in your lab safety notes if necessary. 4. Add 2 –3 drops of phenolphthalein to the contents of the test tube. Record your observations. Clean and dry the test tube before proceeding to step five. 5. Repeat step 2 using a piece of magnesium ribbon. If you observe no change, heat the water to boiling, using a test tube holder. 6. When the water starts boiling, turn off the burner and stand the tube in a test tube rack. Use a burning wood splint to test for the presence of hydrogen gas. 7. Add 2 – 3 drops of phenolphthalein to the test tube. Record your observations. Clean and dry the test tube before moving on to part B. Part B: Solubility 8. Measure 1.00 g samples of each of the following and place into separate, labeled test tubes: magnesium sulfate crystals, calcium sulfate crystals and barium sulfate crystals. 9. Add 5.00 mL of water to each test tube. Using a stirring rod, mix the contents of each until you get as much of the solid as possible to dissolve. Rinse the rod before stirring each solution to avoid contamination. Record your observations. Part C: pH 10. Obtain 5.00 mL samples of solutions of calcium hydroxide, magnesium hydroxide, and barium hydroxide. Test each solution with pH paper. Record the pH of each solution. Part D: Formation of an Insoluble Carbonate 11. Stand three clean, dry test tubes on the rack. Add 5.00 mL of magnesium chloride solution to the first tube, 5.00 mL of calcium chloride to the second tube, and 5.00 mL of barium chloride solution to the third tube. 12. Add 1.00 mL of sodium carbonate to each test tube and record your results. 13. Follow teacher procedures to discard waste and clean all lab materials. Prelab Questions 1. Briefly state the purpose of this laboratory experiment. _____________________________________________________________________________ _____________________________________________________________________________ 2. State three safety rules that apply to this lab. _____________________________________________________________________________ _____________________________________________________________________________ 3. What trends do you expect to find within the Alkaline Earth Metals? To what specifically can you attribute these trends? _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ 4. Define the following terms: reactivity, pH, solubility, precipitate. _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ ____________________________________________________________________________ Data and Observations Part A: Reactivity Element (solid) Observations with water Observations with phenolphthalein Magnesium Calcium Part B: Solubility Substance Observations MgSO4 CaSO4 BaSO4 Part C: pH Solution pH Mg(OH)2 Ca(OH)2 Ba(OH)2 Part D: Formation of Carbonate Substance + Sodium Carbonate MgCl2 CaCl2 BaCl2 Observations Analysis 1. Describe the reactivity of the metals in the alkaline earth family in terms of their location in the group. _____________________________________________________________________________ _____________________________________________________________________________ 2. Describe the trend in the relative solubility of the alkaline earth compounds with sulfate. _____________________________________________________________________________ _____________________________________________________________________________ 3. Describe the trend in pH in the alkaline earth metals. _____________________________________________________________________________ _____________________________________________________________________________ _____________________________________________________________________________ 4. Describe the trend in the relative solubility of the alkaline earth compounds formed with carbonate. _____________________________________________________________________________ _____________________________________________________________________________ Conclusion 1. Predict where strontium, Sr, would appear in the four trends studied. _____________________________________________________________________________ _____________________________________________________________________________ 2. Explain the trend in reactivity within the family. Consider valence number, size of atom and shielding effects. _____________________________________________________________________________ _____________________________________________________________________________ Trends in the Alkaline Earth Metal Group Rubric Lab Participation Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Below Avg (1-5) Satisfactory (6-8) Excellent (9-10) Managed time wisely Followed safety rules Followed instructions—both written and oral Stayed with lab group No horseplay or other discipline issues Lab Participation Total Lab Procedure Pre-lab Question 1 Pre-lab Question 2 Pre-lab Question 3 Pre-lab Question 4 Students read procedure Students listened to instructions Students cleaned up after themselves Students appropriately discarded waste Data Table 1 Data Table 2 Data Table 3 Data Table 4 Analysis Question 1 Analysis Question 2 Analysis Question 3 Analysis Question 4 Conclusion Question 1 Conclusion Question 2 Lab Procedure Total Total Lab Grade Teacher Reflection: Trends in the Alkaline Earth Metals Lab This lab has been with me for about 8 years and is an adapted hodge podge of different labs I have found in textbooks and on the Internet. It is a pretty standard group 2 lab that is found in many textbook lab resources. Not too long ago I reworked it from an Internet site, It is very similar to a lab found at http://www2.asd.k12.ak.us/hauser/curriculum/html/Chemistry/Unit%201%20matter%20and%20 change/labs/Alkaline_Earth_Metals_Lab_1.htm , and there may be other Internet sources that are more like it than this one. Have students be cautious with the calcium because it will get hot. You may want to review appropriate procedures for heating a test tube, hydrogen wood splint test, and use of a Bunsen burner. Assessment Questions made with Exam View Test Generator from Glencoe Physical Science w/Earth Science, KY Edition **Note answers have correlation with core content strands; ** Modified True/False Indicate whether the statement is true or false. If false, change the identified word or phrase to make the statement true. ____ 1. The chart showing the classifications of elements according to their properties and increasing atomic numbers is called the periodic table. ____ 2. Elements arranged in vertical columns in the periodic table are called periods. ____ 3. The region around the nucleus occupied by the electrons is called the negative zone. ____ 4. The maximum number of electrons in the second energy level of an atom is 4. ____ 5. Metals are good conductors of heat and electricity. _________________________ ____ 6. The symbol for fluorine is Fe. _________________________ ____ 7. A very stable electron arrangement in the outer energy level is characteristic of noble gases. ____ 8. One proton and one electron are added to each element as you go across the periodic table. ____ 9. Electron cloud models are used to show how electrons in the outer energy level are bonded when elements combine to form compounds. ____ 10. According to present atomic theory, the location of an electron in an atom cannot be pinpointed exactly. Multiple Choice Identify the choice that best completes the statement or answers the question. ____ 1. Each inner energy level of an atom has a maximum number of ____ it can hold. a. electrons c. quarks b. neutrons d. protons ____ 2. A chemical symbol represents the ____ of an element. a. name c. group b. reaction d. structure ____ 3. Horizontal rows of the periodic table are called ____. a. clusters c. groups b. families d. periods ____ 4. Elements that are gases, are brittle, and are poor conductors at room temperature are ____. a. metals c. metalloids b. nonmetals d. isotopes Short Answer 1. Explain why the noble gases are stable. 2. Explain why the periodic table is such a useful tool. 3. Describe where the electrons are in the atom, where they have the least energy, and where they have the most energy. 4. Give the period and group for each of the following elements: F, O, P, S. 5. What is the name of each of the following elements, and classify it as a metal, a nonmetal, or a metalloid: Na, Ba, Ca, La, Ti, Al, As, At, Ar. 6. How many groups and how many periods make up the periodic table? 7. Why was the periodic table so named? 8. Who developed the first periodic table? Figure 17-1 9. Do the elements shown in Figure 17-1 belong to the same period or the same group? 10. Are the elements in Figure 17-1 metals or nonmetals? 11. Are the properties of the two elements in Figure 17-1 similar or quite different? 12. At room temperature, will the elements in Figure 17-1 be solids, liquids, or gases? Electrons and the Periodic Table Answers MODIFIED TRUE/FALSE 1. ANS: T PTS:1 DIF: B OBJ: 3/1 STA: SC-HS-1.1.1 2. ANS: F, groups PTS:1 DIF: B OBJ: 2/1 STA: SC-HS-1.1.1 3. ANS: F, electron cloud PTS:1 DIF: B OBJ: 1/4 STA: SC-HS-1.1.2 4. ANS: F, 8 PTS:1 DIF: B OBJ: 3/2 STA: SC-HS-1.1.1 5. ANS: T PTS:1 DIF: B OBJ: 3/3 STA: SC-HS-1.1.4 6. ANS: F, iron PTS:1 DIF: B OBJ: 1/1 STA: SC-HS-1.1.1 7. ANS: T PTS:1 DIF: B OBJ: 3/2 STA: SC-HS-1.1.1 8. ANS: T PTS:1 DIF: B OBJ: 3/1 STA: SC-HS-1.1.1 9. ANS: F, dot diagrams PTS:1 DIF: B OBJ: 3/2 STA: SC-HS-1.1.1 PTS:1 DIF: B OBJ: 1/4 STA: SC-HS-1.1.1 1. ANS: A PTS:1 DIF: B OBJ: 1/4 STA: SC-HS-1.1.2 2. ANS: A PTS:1 DIF: B OBJ: 1/1 STA: SC-HS-1.1.1 3. ANS: D PTS:1 DIF: B OBJ: 3/1 STA: SC-HS-1.1.1 4. ANS: B PTS:1 DIF: B OBJ: 3/3 STA: SC-HS-1.1.2 DIF:A OBJ: 1/4 10. ANS: T MULTIPLE CHOICE SHORT ANSWER 1. ANS: Their outer energy levels are full. PTS:1 2. ANS: It shows the relationship among the elements, and it can be used to predict similarities and differences among the elements. PTS:1 DIF:A OBJ: 3/2 STA: SC-HS-1.1.1 3. ANS: Electrons go around the nucleus in a cloud. Energy is lowest close to the nucleus, and highest away from the nucleus. PTS:1 DIF:A OBJ: 1/4 STA: SC-HS-1.1.1 4. ANS: F, period 2, Group 17; O, period 2, Group 16; P, period 3, Group 15; S, period 3, Group 16 PTS: 1 DIF: A OBJ: 3/2 STA: SC-HS-1.1.1 5. ANS: Na, sodium, metal; Ba, barium, metal; Ca, calcium, metal; La, lanthanum, metal; Ti, titanium, metal; Al, aluminum, metal; As, arsenic, metalloid; At, astatine, metalloid; Ar, argon, nonmetal PTS: 1 DIF: A OBJ: 3/3 STA: SC-HS-1.1.1 6. ANS: 18 groups, 7 periods PTS: 1 DIF: A 7. ANS: Because it shows a repeating pattern. PTS: 1 DIF: B 8. ANS: Dimitri Mendeleev PTS: 1 DIF: B 9. ANS: same group PTS: 1 DIF: B 10. ANS: metals PTS: 1 DIF: B 11. ANS: similar PTS: 1 DIF: B 12. ANS: solids PTS: 1 DIF: B OBJ: 3/1 STA: SC-HS-1.1.1 OBJ: 3/1 STA: SC-HS-1.1.1 OBJ: 3/1 STA: SC-HS-1.1.1 OBJ: 3/2 STA: SC-HS-1.1.1 OBJ: 3/2 STA: SC-HS-1.1.1 OBJ: 3/2 STA: SC-HS-1.1.1 OBJ: 3/2 STA: SC-HS-1.1.1 Resources Glencoe Physical Science w/Earth Science, KY Edition Examview Test Generator Websites for element data for Mendeleev Lab http://dl.clackamas.edu/ch104-07/electron.htm for electronegativities http://dl.clackamas.cc.or.us/ch104-07/atomic_size.htm for atomic size http://dl.clackamas.cc.or.us/ch104-07/ionization_energy.htm for ionization energies http://www.chemguide.co.uk/atoms/properties/atomorbs.html for atomic orbitals http://www.chemicalelements.com/show/meltingpoint.html for melting points http://www.chemicalelements.com/show/boilingpoint.html for boiling points Research sites for History of the Periodic Table http://chemistry.about.com/library/weekly/aa030303a.htm Discovery dates of elements http://www.chemicalelements.com/ Facts about elements