5 3. Methods 3.1 The EM technique and its applicability to measure soil moisture The EM instruments measure the bulk electric conductivity. The latter is a function of the soil structure, texture and mineralogy as well as its water content and the salt content of the water (Cook 1998). All these factors are important, because the electrical currents are transferred through soil on different paths. Electrons can move through the soil moisture, along the surfaces of particles that are in contact with one another or through alternating layers of particles and solution (McNeill 1980a). The general premise behind the use of GEM for soil moisture measurements is that given all other parameters remain unchanged, the variability of the GEM measurement of the electric conduction with time reflects the change of soil moisture with time. The temporal changes of the water content should therefore be an easy a parameter easy to capture. Combined with other soil moisture measurements in the same area or an accurate estimation of the amount of dissolved salt in the soil water and the clay content together with the conductivity of the solid soil even an absolute calibration of EM readings for the soil moisture content of a certain area should be possible. 3.1.1 The relationship between bulk electric conductivity and soil moisture content The measured conductivity is called the apparent or bulk conductivity and it is a function of the combination of the different conducting soil components mentioned above. Rhoades et al (1976) show that the bulk electric conductivity is a quadratic function of the volumetric water content: ECa a * ECw * v b * v ECw ECc 2 (1) where v is the volumetric water content, ECw is the electrical conductivity of the soil water, ECc is the surface electric conductivity it is dependent on the type and amount of clay in the soil and a and b are regression parameters related to soil texture. 6 Nadler and Frenkel (1980) and Shainberg (1980) suggest for conductivity above 400 mS/m equation (1) can be approximated with a linear equation: ECa ECw * v * T ECs (2) where ECw is the electrical conductivity of the soil solution, v is the volumetric water content, T is the tortuosity and ECs is the solid phase contribution to the apparent electrical conductivity. One goal of this experiment was to determine whether a linear or a quadratic relationship between measured soil moisture and EM readings existed at the same measurement locations. 3.1.2 Basics of frequency-domain EM methods The EM creates a primary electromagnetic field which induces eddy currents in the subsurface material. These in turn induce a secondary electromagnetic field, which modifies the total field. The difference between these two fields is a function of the subsurface conductivity (Cook 1998). The EM records the magnetic intensity of the secondary field that is given by the equation (Mares 1984): H (t ) H0 cos( t ) (3) where H0 is the primary magnetic field, is the angular frequency and the angle determines the phase delay. The phase delay is caused by the short amount of time the particles in the ground need to adjust to the imposed field (White 1994). The quantities which display a zero phase delay are referred to as in-phase quantities and the quantities which are displaced in phase with respect to the source current by 90 are referred to as in quadrature. The apparent conductivity is therefore related to the measured quadrature phase values (Won 1996). The relationship is linear. Cond = 360*PPM(Q)/ Freq Cond is the conductivity in units of mS/M PPM(Q) is the quadrature phase reading Freq is the frequency in Hz (4) 7 This relationship in equation 4 is valid only for surveys over poorly conductive ground with an induction number smaller than one. The induction number is defined as intercoil spacing (1.67m for the GEM-300) divided by the skin depth. The skin depth can be derived from a special nomogram (Won 1996). For all the measurements that we have been conducting the induction number was <1. 3.1.2.1 The depth response The penetration depth of the GEM ranges from zero up to several meters. The penetration depth of the electromagnetic field is dependent on the frequency. Lower frequencies reach greater depths than higher frequencies, due to the stronger attenuation of the high frequency waves (Won, 1996). The option of measuring different frequencies in the same cycle, potentially allows to create a 3D - image of the soil water distribution. To date the depth response of the one frequency EM had to be calculated theoretically. The conductivity measured with the EM is the integrated conductivity over a specific depth range. The influence of the conductivity of each depth each layer is given by a depth response function (z) (McNeill, 1980). ECa ( z) EC( z)dz 0 (5) where (z) is the depth response function and EC(z) is the electric conductivity of the layer z. At low soil conductivity, for example for non-saline soils, the response function is independent of the earth conductivity. McNeill (1980) calculated a (z) function for the EM31 which operates at a frequency of 14 k Hz (Fig. 4) . This function should approximately be valid for the frequency f4 = 14010 Hz used in the present study. Fig. 3: horizontal h and vertical v dipole response function ( McNeill, 1980) 8 If the (z) function for a certain frequency is known, the conductivity distribution with z can be calculated numerically. We assume that the total conductivity is a linear combination of the conductivities for distinct soil layers. It is then possible to determine the conductivity of a distinct layer by minimizing the magnitude of the (z) below and above this certain the depth interval. This is done by introducing a weighting factor a ( z) n a ( z) (6) i 1 i i (z) is the weighted depth response function, ai is the weighting factor for the ith layer and i(z) is the response function for the ith layer. With a good selection of a one can damp (z) below and above a certain depth enough to only receive a strong signal from this distinct z layer (Cook, 1992). Fig.4: Cummulative depth response functions for different frequencies (Cook, 1998) 3.1.2.2 The GEM-300 For all experiments we used the new GSSI GEM-300. It consists of transmitter coil with an alternating current running through it, inducing an electromagnetic field at different frequencies. Seven different frequencies can be registered within the same measuring cycle. The GEM can transmit frequencies within the range from 325 up to 19975 Hz. There is a receiver unit that records the in-phase and quadrature components of the returning signal. 9 The data for both phases is converted into a PPM unit as follows: (Won 1996 ) PPM 106 * Hs Hp (7) Where Hs is the secondary magnetic field at the receiver coil and Hp is the primary field at the receiver coil. A control processor unit runs the system software manages the power and stores temporarily the measured data. The measured values can easily be transferred onto a computer and then into a plotting program such as ‘Magmap’ or ‘Surfer’ to display the data as 2D contour maps for further analysis. The GEM-300 offers different survey modes. One can either perform a continuous survey or station wise measurements. Both modes are applicable to all user-defined grids. The continuous mode is a very fast way to do a survey with a flexible grid that needs only the grid end points to be laid out. The ‘station wise’ survey offers the option of very accurate positioning of the measurement points within a user-defined grid. A: GEM-300 B: Aqua Probe C: TDR Fig. 5: The different measuring instruments 3.2 How the true moisture content was measured Subsurface moisture was determined using vertical TDR and a depth integrated capacitance sensor to The TDR consists of 20cm long stainless rods inserted vertically in the ground. An electric impulse was then sent along these two rods and compared to the returned signal. The type of material surrounding the two rods influences the returning signal. If the dielectric constant of the material is high, the signal propagates slower. The dielectric constant of water is much higher than most other materials; therefore a signal within a wet or moist medium propagates slower than if the same medium 10 were dry. Moisture content can be determined by measuring the propagation time over a fixed length probe (Slik, 1993). From the time the dielectric constant can be derived as given in equation (8) ct Lp 2 (8) where Lp is length of the probe in the soil and t is the one way travel time of the wave along the rod, Topp (1980) linked the dielectric constant to the volumetric water content: 5.3 * 10 2 2.92 * 10 2 55 . * 10 4 2 4.3 * 10 6 3 (9) where is the dielectric constant of the porous medium. In our study TDR yielded a point value of the volumetric moisture content integrated over the upper 20cm of the soil. The Aqua Probe Moisture Probe used in this study is classified as a "Capacitance" sensor. The Moisture Probe transmits a very low powered "Radio Frequency" through the soil at user-defined depth (0-80cm) to measure moisture. There are two copper bands on the end of the sensor that function as radio antennas. One antenna transmits a low powered "RF" signal that is received by the other antenna. The proprietary microprocessor can determine the moisture content by the change in frequency of the signal it receives (link 3). The more moisture in the soil, the more the frequency of the signal is changed. The AP has a repeatable accuracy of +/- 2% (link 3). The AP has a resolution of 1% of the relative water content. The AP probe yields relative soil moisture of the upper 50-80 cm of the soil with a user defined resolution. A calibration with soil samples is needed to convert the relative soil water content into the volumetric moisture content. 11