A Look Back at Chemistry 11 KEY 1. Convert the following into Scientific Notation: (do not change sig figs) 727 7.27x102 172000 1.72x105 0.000984 9.84 x 10-4 200.0 x 102 2.000 x 104 0.014 x 102 1.4 x 100 2. Convert each into decimal form: 1.56x 104 15,600 3.6 x 10-2 0.036 736.9 x 105 73,690,000 0.0059 x 105 590 0.00059 x 10-1 0.000059 3. Calculate the following. a) 2.34 x 1065 + 9.2 x 1066 = 9.4 x 1066 b) 313.0 ¬ 1.2 x 103 = -9 x 102 c) 8.95 x 1076 = 7.16 x 1071 1.25 X 105 d) (4.5 x 1029) (2.45 x 10100) =1.1 x 10130 e) 17.34 4.900 + 23.1 = 45.3 f) 9.80 ¬ 4.762 = 5.04 g) 3.9 x 6.05 x 420 = 9.9 x 103 h) 14.1 = 3 4. Give The number of significant figures in each of the following: a) 1.05 g 3 b) 0.0003040 mm c) 29000 ft 2 d) 0.90 L 2 4 e) the number of eggs in a dozen INFINITE HCl C3H8 SO2 NH4Cl KOH H2SO4 Al(OH)3 P2O5 Ba(OH)2 CH3COOH H2O AgNO3 PbSO4 H3PO4 Ca(OH)2 1. Classify the above as ionic or covalent by making two lists. Describe the difference between an ionic and covalent compound. Ionic NH4Cl KOH Covalent C3H8 SO2 AgNO3 PbSO4 H2O Ca(OH)2 P2O5 H3PO4 Al(OH)3 Ba(OH)2 CH3COOH Ionic compounds – formed when metal atoms transfer electrons to non-metal atoms. Covalent compounds- formed when non-metal atoms share electrons H2SO4 2. Classify the above as acids, bases, salts and molecular (covalent compounds) by making four lists. Acids HCl H2SO4 CH3COOH Bases KOH Ca(OH)2 Ba(OH)2 Salts NH4Cl AgNO3 PbSO4 Molecular C3H8 SO2 H2 O 7. Write formulas or names of the following. 1. SnO2 tin (IV) oxide 2. silver phosphate Ag3PO4 3. mercury (II) carbonate HgCO3 4. HCl hydrochloric acid 5. FeF3 iron (III) flouride 6. chromium (IV) sulfate Cr(SO4)2 7. (NH4)2C2O4 ammonium oxalate 8. silver thiosulfate Ag2S2O3 14. hydrogen peroxide H2O2 15. HgCr2O7 mercury (II) dichromate 16. barium acetate Ba(CH3COO)2 17. MnSO3 manganese (II) sulfite 18. H2SO4 sulfuric acid 19. tungsten (II) phosphide W3P2 20. ammonium hypochlorite NH4ClO 9. aluminum hydrogen phosphate Al2(HPO4)3 21. LiCN lithium cyanide 10. KClO4 potassium perchlorate 22. NaH2PO4 sodium hydrogen biphosphate 11. Sn(ClO3)2 tin (II) chlorate 12. HNO3 nitric acid 13. zinc hydroxide Zn(OH)2 H3PO4 Al(OH)3 P2O5 7. Write a balanced chemical equation for the following reactions: sodium hydroxide iron + oxygen sodium oxide + water iron (III) oxide carbon dioxide + water glucose + oxygen iron (II) sulfide + hydrochloric acid iron (II) chloride + hydrogen sulfide 8. Given 100 grams of NH3: a) how many molecules of ammonia are in the sample? b) how many moles of ammonia are in the sample? c) how many hydrogen atoms are in the sample? d) what volume would the sample occupy at STP? 3. Describe how you can identify each of the four categories by the formula of the compound. Acids The formula starts with H or ends in COOH except H2O. Bases The formula starts with a metal or NH4 and ends in OH. Salts The formula starts with a metal or NH4 and does not end in OH. Molecular The formula starts with a nonmetal other than H. 4. Calculate the molar mass of FeSO4 • 5H2O and Co3(PO4)2 • 6H2O. 241.9 g/mol 474.7 g/mol 5. 0.300 moles of NaCl is dissolved in 250.0 ml of water, calculate the molarity. Molarity = 0.300 moles = 1.20 M .250 L 6. 500. g of FeSO4.6H2O is dissolved in 600. ml of water, calculate the molarity. Molarity = 500g x 1 mole 259.9g = 3.21 M .600 L 7. How many grams of NaCl are required to prepare 100.0 ml of a 0.200 M solution? .100L x 0.200 mole x 58.5 g 1L 1 mole = 1.17g 8. 20. g of MgCl2 are dissolved in 250. ml of water, calculate the concentration of each ion. 20g x 1 mole 95.3 g 2+ Mg + Molarity = --------> = 0.84 M 2Cl- MgCl2 ----- 0.250 L 1.7 M 0.84 M 0.84 M 9. How many liters of 0.300 M NaCl contains 10.0 g of NaCl? 10.0g x 1 mole 58.5g x 1L 0.300 mole = 0.570 L 10. For each double replacement reaction write the formula equation, the complete ionic equation and the net ionic equation. a) b) H2SO4(aq) + -------> Na2SO4(aq) 2HOH(l) SO42-(aq) + 2Na+(aq) + 2OH-(aq) ---------> 2Na+(aq) + SO42-(aq) + 2HOH(l) H+(aq) + OH-(aq) 2H3PO4(aq) 6H+(aq) + ---------> HOH(l) 3Sr(OH)2(aq) -------> Sr3(PO4)2(s) 2PO43-(aq) + 3Sr2+(aq) + 6OH-(aq) 2PO43-(aq) + 3Sr2+(aq) + + 3Ca(NO3)2(aq) + 2Na3PO4(aq) ---------> 6OH-(aq) -------> 3Ca2+(aq) + 6NO3-(aq) + 6Na+(aq) + Zn(s) + ---------> + 6HOH(l) Sr3(PO4)2(s) + 6HOH(l) Sr3(PO4)2(s) + 6HOH(l) Ca3(PO4)2(s) + 6NaNO3(aq) 2PO43-(aq) ----------> Ca3(PO4)2(aq) + 6Na+(aq) + 6NO3-(aq) 3Ca2+(aq) + 2PO43-(aq) ----------> Ca3(PO4)2(aq) d) + 2H+(aq) + 6H+(aq) + c) 2NaOH (aq) 2HCl(aq) ---------> H2(g) + ZnCl2(aq) Zn(s) + 2H+(aq) + 2Cl-(aq) ---------> H2(g) + Zn(s) + 2H+(aq) ---------> H2(g) + Zn2+(aq) + 2Cl-(aq) Zn2+(aq) 11. 25.0 g of sodium reacts with water, how many grams of hydrogen are produced? How many grams of sodium hydroxide are produced? 2Na(s) 25.0 g Na x 25.0 g Na x + 2HOH(l) ---------> H2(g) + 2NaOH(aq) 1 mole 23.0 g 1 mole 23.0 g x x 1mol H2 x 2mol Na 2mol NaOH 2 mol Na x 2.02 g 1 mole 40.0 g 1 mole = 1.10 g = 43.5 g 12. How many millilitres of 0.200M NaOH is required to neutralize 25.0 ml of 0.100 M H2SO4 ? + H2SO4 2HOH + 0.025 L 0.100 M 2NaOH ------------> Na2SO4 ?L 0.200 M 0.0250 L NaOH x 0.100 mole x 2 mole NaOH x 1 L x 1000mL 1L 1 mole H2SO4 0.200mole 1L = 25.0 mL 13. A beaker of mass = 25.36g contains 2.00 L of a solution of BaCl2 and is evaporated to dryness mass = 28.59 g. Calculate the molarity of the solution. 28.59g – 25.36 =3.23g Molarity = 3.23g x 1 mole 208.3g = 0.00775 M 2.00 L CHALLENGE!!! 14. A 0.960 g sample of impure Na2CO3 is dissolved in water and then completely reacted with 0.200 M HCl requiring 65.3 mL. Calculate the percentage by mass of Na2CO3 in the sample. Na2CO3 + 2HCl CO2 + 2NaCl + H2O 0.00653 L ?g 0.200 M 0.0653 L HCl = x 0.200 moles x 1L 1 mole Na2CO3 2 mol HCl x 106 g = 0.069218 g x 0.960 g 100 7.21 % 0.069218g % % =