Chemistry 222 Exam I Review PowerPoint Notes Midterm I Chemistry 222 Exam I Review Chapters 8, 9 and 10 Chapters 8, 9 and 10 • Bring: calculator, pencil, scantron (50 questions / side, 100 questions total), "Organic Chemistry" lab, Exam Prep I, safety glasses (for lab) • 25 multiple choice questions, four short answer questions, ~2 hours in length • Returned Friday with "summary sheet" Good luck with your studying! Let's start the review! Chemistry 222 Professor Michael Russell MAR MAR Which of the following is NOT a correct Lewis dot structure? A. 1. N N 3.C. H B. 2. N O 4.D. C C N O A. C. B. D. MAR MAR Determine the formal charges for the formate ion: A. 0 B. +1 C.+1 D. 0 MAR Which of the following is NOT a correct Lewis dot structure? 0 0 –1 –1 0 –1 0 –1 Using VSEPR, which of the following corresponds to the molecular shape of SCl2? A. linear B. bent C.“T-shaped" D.trigonal pyramid E. orthorhombic MAR Page I-E1-1 Chemistry 222 Exam I Review PowerPoint Notes Based on VSEPR, which of the following corresponds to the molecular shape of the IF2─ ion? What is the approximate C-C-H angle in the acetylene, C2H2, molecule? A. linear B. bent (bond angle 120˚) C.“T-shaped” D.bent (bond angle 109.5˚) E. trigonal pyramid A. 90˚ B. 120˚ C.109.5˚ D.180˚ E. -30˚ MAR MAR Which of the following groups of elements is arranged correctly in order of increasing electronegativity? What is the carbon-oxygen bond order in formaldehyde, CH2O? A. Mg < P < N < F B. Mg < N < P < F C.N < Mg < P < F D.F < P < Mg < N A. 1 B. 2 C.1 ½ D.2 ½ E. -1 MAR What is the average carbon-oxygen bond order in the formate ion, HCO2–? MAR Given the bond dissociation enthalpies below, calculate the standard molar enthalpy of formation of NF3: ½N2(g) + ³⁄2 F2(g) → NF3(g) A. 1 B. 2 C.1 ½ D.2 ½ E. -1 MAR Bond Dissociation Enthalpy (kJ/mol) N≡N 946 F—F 159 N—F 272 A. 833 kJ/mol B. -105 kJ/mol C. 440. kJ/mol D. -578 kJ/mol E. -220. kJ/mol MAR Page I-E1-2 Chemistry 222 Exam I Review PowerPoint Notes Which of the bonds below is least polar? A. B—O B. B—N C.B—F D.B—C E. AC-DC Which of the following molecules is polar? A. BCl3 B. CO2 C.N2 D.ClF MAR MAR Which of the following molecules is most likely to have a dipole moment? What hybrid orbital set is used by the boron atom in the BCl4- ion? A. CH4 A. sp B.sp3 C.sp2 D.d2sp3 E.dsp3 B. SF6 C.BeF2 D.NF3 MAR Cysteine is one of the natural amino acids. MAR Cysteine is one of the natural amino acids. The molecule has Estimate the values of the indicated angles: A. 13 sigma (σ) bonds and 1 pi (π) bond B. 14 sigma (σ) bonds and 1 pi (π) bond C.20 sigma (σ) bonds and 1 pi (π) bond D.12 sigma (σ) bonds and 1 pi (π) bond A. Angle 1 = 180˚ B. Angle 1 = 109˚ C. Angle 1 = 109˚ D. Angle 1 = 180˚ MAR MAR Page I-E1-3 Angle 2 = 120˚ Angle 3 = 109˚ Angle 2 = 120˚ Angle 3 = 109˚ Angle 2 = 109˚ Angle 3 = 109˚ Angle 2 = 90˚ Angle 3 = 90˚ Chemistry 222 Exam I Review PowerPoint Notes Nitrogen can lose an electron to form N2+. What is the bond order of N2+? Is N2+ diamagnetic or paramagnetic? A. diamagnetic B. paramagnetic C.42 A. 1 B. 1.5 C.2 D.2.5 E. 3 MAR MAR What is the systematic name for this alkane? What is the bond order of the superoxide ion, O2–? A. 1 B. 1.5 C. 2 D. 2.5 E. 3 A. nonane B. 2-ethyl-5-methylhexane C. 2,5-dimethylheptane D. 2,3-dimethyloctane MAR MAR This compound: Given the following compounds: 1. C2H4 2. C5H10 3. C14H30 4. C7H8 Which one(s) could be an alkane? A. The compound is an isomer of pentane and is named 2,3-dimethylbutane. B. The compound is an isomer of octane and is named 2,2-dimethylbutane. C. The compound is an isomer of hexane and is named 2,2-dimethylbutane. D. The compound is an isomer of hexane and is named 3,3-dimethylbutane. MAR A. only 1 B. only 2 C.only 3 D.3 and 4 E. none of the above MAR Page I-E1-4 Chemistry 222 Exam I Review PowerPoint Notes What is the name of the molecule? A. butanoic acid B. butanal C. butanol D. 2-butanol E. methyl ethyl ketone MAR What is the name of the molecule? A. butanoic acid B. pentanal C. pentanoic acid D. pentanone E. pentanol MAR What is the name of the molecule? A. butanoic acid B. butanal C.butanol D.2-butanol E. butanone MAR End of Review good luck with your studying! Need more practice? • Practice Problem Sets (online) • Concept Guides (Companion and online) • Chapter Guides (online) • End of Chapter Problems in Textbook (every other question has answer at end) Good luck with your studying! MAR Page I-E1-5