Name: Date: IB Chemistry Summer Assignment Laboratory Experiment Guidelines: Experiment objective: To determine the concentration of vinegar via reaction with baking soda. You are welcome to discuss ideas with your classmates, but you each must complete your own experiment and your own report. You do not need to record data in SI units. You may use English units or find a conversion factor that allows you to use SI units. You may also invent your own unit. It does not matter what concentration unit you report for the vinegar. You only need to use things that are commonly found around your house. Your grade is not based on accuracy. Your grade is based on how you approach and solve this problem. You will need to generate some novel ideas to meet the submission requirements given above. Exercises: Exercise 1 will be graded for accuracy. Any errors you make are not carried forward. In other words, a wrong answer that is used correctly in a subsequent step will be given full credit. The purpose of this problem is to reacquaint you with the quantifiable properties that one comes across in chemistry, and the interpretation of some of those values. Exercise 2 is strictly a thought exercise. Be creative. Do not be afraid to be wrong! Throw your ideas and thoughts at me. This is a great chance for me to see what concepts with which you are competent or unfamiliar. This will help me identify areas of strength and weakness for our class for when I put lesson ideas together. For exercise 2, you may want to consider the type of reaction, the reactivity of the elements involved, bond types, and thermochemical properties in your response. You can assume the reactions in exercise 2 are supposed to take place at room temperature. Please write up the lab report in a way so that the following IB criteria are addressed: Criteria Description Define Formulates a focused problem/research question and identifies the relevant problem/select variables. variables Controlling variables Designs a method for the effective control of the variables. Developing a Develops a method that allows for the collection of sufficient relevant data. method for collection of data Records appropriate quantitative and associated qualitative raw data, including units Recording raw and uncertainties where relevant. This mark is essentially for the setup and data appropriateness of your data table(s). Processing raw Processes the quantitative raw data correctly. This mark is for your calculations. data Presenting processed data Presents processed data appropriately and, where relevant, includes errors and uncertainties. I will focus mostly on units, rounding, and any relevant error calculation. You may include an outlier test here as well. Concluding States a conclusion, with justification, based on a reasonable interpretation of the data. Tell me which factors did or did not affect the period of the pendulum. Evaluating procedure(s) Evaluates weaknesses and limitations. Be specific, and for this assignment, do not be afraid to “throw something out there.” Show me how you think and what you are considering. Improving the investigation Suggests realistic improvements in respect of identified weaknesses and limitations. Good luck and looking forward to seeing you in the fall. Mr. Everett I prefer that you handle the decisions on your own. However, if you really need help, just email me at teverett@mhrd.org. Exercise 1: Consider the following compound with the following percent composition and a molar mass of 44.05 g: 54.53% carbon 9.15% hydrogen 36.31% oxygen Use this information to answer the questions below. Determine the molecular and empirical formula for this compound. Is this compound organic or inorganic? Explain. Could this compound contain a carbon-carbon double bond? Explain. Could this compound be a carboxylic acid? Explain. The melting point for this compound is 149.78 K and its boiling point is 293.3 K. Determine the compound's state of matter at room temperature. Write the reaction equation for this compound's combustion. Balance it. Calculate the volume of the gas product that will be produced from 2.00 g of the original compound. Assume the reaction takes place at STP. What will be the effect on the volume of the gas if the temperature at which the reaction takes place is increased? What will be the effect on the volume of the gas if the pressure at which the reaction takes place is increased? Recalculate the volume of the gas that is produced if the reaction takes place at 35°C and 175 kPa. Using the volume from the previous step, calculate the density of the gas produced. The heat of combustion for this compound is -2332.96 kJ. What does this value tell you about the reaction? Explain. Rewrite the reaction equation to include the value for the heat of combustion ( comb – which is the same as Hrxn). Solve for the heat of formation ( Hf°) of this compound. Will this compound increase or decrease entropy? Explain. Perform the necessary calculation to verify your previous statement. Based on the given value for comb and your previous statement regarding entropy, this reaction will be spontaneous always/never/at low temperatures/at high temperatures. Sketch a graph of Grxn vs. Temperature. Temperature should be in kelvin. Although it is just a sketch, the y-intercept and slope of the line are important. One of the questions we will continually address next year is “What makes reactions work?” In other words, why are some combinations of reactants explosive, others are mildly interesting, and others don't do anything at all. Hopefully, this past year has taught you some basic quantities that can be used to estimate how well a reaction will work. Below is a list of reactions. I want you to attempt to rank them from most to least reactive. You will provide an explanation. The purpose of this exercise is for me to see how well to integrate a variety of topics from across chemistry into providing your explanation. This part will only be graded for completion, but I expect a thorough, thoughtful response, that should be several paragraphs in length. You may include calculations or values for chemical properties as you feel appropriate. Cu (s) + 2 H2O (ℓ)→ Cu(OH)2 (s) + H2 (g) (NH4)2Cr2O7 (s) → N2 (g) + Cr2O3 (s) + 4 H2O (g) CO (g) + 2 H2 (g) → CH3OH (ℓ) 12 CO (g) + 6 H2O (g) → 2 C6H6 (s) + 9 O2 (ℓ) PbCO3 (s) → Pb+2 (aq) + CO3-2 (aq) 3 HCl (aq) + Al(OH)3 → AlCl3 (aq) + 3 H2O (ℓ)