ATOC 5051 INTRODUCTION TO PHYSICAL OCEANOGRAPHY Lecture 3 Learning objective: know and understand the Properties of sea water: 1 Pressure; 2 Temperature, salinity, density & tracers; 3 Sound in the sea; 4 Light in the sea (reading assignment). Properties of seawater • Pure water: • One major difference between pure and sea water is: salt in seawater (salinity). • Pure water physical properties are functions of Pressure (P) and temperature (T), whereas those of the seawater are functions of P, T, and salinity (S). • Freezing point: pure water at 0C; seawater, -2C. 1 Pressure • Pressure is the force per unit area exerted by water (or air for the atmosphere). • Units: Pascal or N/M2, or dyn/cm2; (1 Pascal=1 N/M2 ; 1N=105dyn) • In the atmosphere, pressure is often measured by “bars” or “milibars”; (1bar=105 Pascal=106 dyn/cm; 1mb=100Pa) • Ocean pressure is often measured by decibars (dbar). 1dbar=0.1bar=104 Pascal. Pressure • Why is pressure important for ocean circulation? Pressure gradient force (PGF)- a major force govern fluid motion: arises from pressure difference from one point to another. • PGF direction: high to low; • Ocean: P(z) - depends on the mass of water above (hydrostatic equation ~ later classes). (Range: 0 at z=0 to ~10,000dbar near ocean bottom, if we ignore atmospheric pressure). 2 Temperature (T) • Sea Surface Temperature (SST): Important variable for air-sea interaction and driving atmospheric circulation. T is also important for biological activities. • Units: oC, Kelvin. 0oC=273.16K 2 Salinity (S) • Original definition: the number of grams of dissolved matter in one kilogram of sea water. Old method to measure salinity: evaporate sea water and weigh the residual. Significance: (1) S affects density (how?) => stratification => mixed layer formation & ML depth => water sinking and rising=> thermohaline circulation; (2) Stratification – affect heat content in the mixed layer – air/sea interaction; (3) S: an indicator of hydrological cycle (ocean gauge) Salinity (S) • The “law” of constant proportion (Dittmar, 1884): Composition of dissolved matter does not vary much from place to place. [Reason] • Given the constant proportion: measure one component and then estimate the total amount of dissolved material, which is S. [Until 1950s.] Salinity • Main constituent of sea salt: Chlorine ion (Cl 55% of total); sodium ion (Na 30.6%). • In reality, proportion varies slightly with geographical locations. Correction needs to be made according to the location. Salinity: Units • Original, g/kg; part per thousand (ppt). • Replaced by practical salinity unit (PSU). • Later suggestions by SCOR (scientific committee for oceanic research): Unitless; • Thermodynamic Equation of Seawater – 2010 (TEOS-10): g/kg • Salt conservation (except for long geological time scales ~≥100,000yrs) in oceans. However, salinity does change, depends on Precipitation-Evaporation, river run off, etc. New in 2010 (most recently) • IOC (Intergovernmental Oceanographic Commission), SCOR (scientific committee for oceanic research), and IAPSO (international association for the physical sciences of the ocean) 2010. • The international thermodynamic equaiton of seawater – 2010: calculation and use of thermodynamic properties. IOC, UNESCO, pp. 196pp. (salinity • http://www.teos-10.org/pubs/ TEOS-10_Primer.pdf Units: g/kg Density (ρ) Units: kg/m3 ; g/cm3 • Fresh water: ~1000kg/m3; • Sea water: 1020-1050 kg/m3. • At the sea surface: 1020-1029 kg/m3. Density • ρ(T,S,P). (T,S) => water mass. Density is important because: water parcels basically move along isopycnic surfaces. Sea water density: (T,S,P). Colder water is denser. Saltier water is denser. Generally high pressure increases density. The dependence is nonlinear. Equation of state, based on laboratory experiments: Equation of state: density as a function of T,S &P At one standard atmosphere (effectively p=0) is: Where is the density of pure water with S=0. (see Gill, appendix 3 for the equation at pressure p). Tracers • Dissolved oxygen, nutrients (nitrate, phosphate, silicate,etc) are often used as tracers for water masses. • Caution: non-conservative (consumed). • Salinity is often a good tracer. 3. Sound in the sea • Detection in the ocean. • Frequency: 1Hz ~ thousands of kHz. Most instruments: 10-100 kHz, wavelength: 14 – 1.4 cm. • a) Echo sounding. Detect ocean depth. D=(C t)/2 (C: speed) • b) Sonar-echo sounder. SONAR (SOund Navigation And Ranging). C in water ~ 1500m/s. C~(P,T). P , C ; T ,C Sound in the sea Sonar echo sounder: Mapping ocean floor • High frequency (500khz-1MHz) SONAR=>better resolution (small objects and fine features) but propagates for a short distance. • Lower frequency (50-100KHz)=>lower resolution, but propagates for a longer distance. Sound in the Sea: SONAR • Detect submarine or school of fish. • Eco-sounder, emit sound beams and reflect back. Can turn 360 degrees, reach hundreds of meters in distance. SOFAR channel • SOund Fixing And Ranging (SOFAR). Sound speed minimum: ~1000m (600-1200m) in midand low latitudes. Near surface in subpolar and polar regions (board demo) • SOFAR channel acts as waveguide. Send out beams with moderate angle from the horizontal direction, refraction makes the sound waves channeled. Sound speed profile calculated ! Typical T & S profiles From the T&S profiles on the left in mid-low latitudes; SOFAR channel Physical oceanography application: SOFAR channel • Acoustic Thermometry of Ocean Climate (ATOC; http://atoc.ucsd.edu/: program ended a few years ago; http://aog.ucsd.edu/thermometry/index.htm) -measuring large-scale ocean circulation change (gyres, ENSO variability, global warming, etc). • Place sound sources & receivers in SOFAR channel. Based on the fact that C depends on T. Increased T will result in faster C and thus it takes a shorter time for the beam to arrive at the receiver. Heard Island Feasiblity Test (HIFT): Consistent With other in situ & satellite observations (small scale structures, such as Eddies, internal waves, etc. did not have much impacts in scattering the sound signals) Marine Mammal Research Program (MMRP) Results: Downloaded from http://atoc.ucsd.edu/ No obvious short-term Changes; some subtle shift in distribution of humpback whales, etc. away from acoustic sources • US Navy Sound surveillance system -array of hydrophones (during cold war). Other applications • Tracking of vessels in distress (i.e., During World War II, dropping into the ocean a small metal sphere (SOFAR bomb) specifically designed to implode at the SOFAR channel – secret distress signal by drowned pilots) • Humpback whales use the SOFAR channel to communicate. 4. Light in the sea (assigned reading) • Absorption and penetration. • Visible light: 0.39-0.76 ,from violet to red, most absorbed within the upper a few meters. • Light attenuation law: - vertical attenuation coefficient. - Clear water, k-0.02/m; turbid water: 2/m. Light penetration: some through mixed layer. Attracts modeler’s attention. • Euphotic zone: 0~200m (sunlight zone) – contains the vast majority of commercial fisheries and is home to many protected marine mammals and sea turtles • Twilight zone: 200-1000m (dysphotic zone; not much light, rapidly dissipates) • Midnight zone: >1000m (aphotic zone; no lights) http://oceanservice.noaa.gov/facts/ light_travel.html Summary • Salt – distinguish seawater from pure water; Pure water physical properties – (T,P); seawater – (T,S,P); • Pressure: PGF – important for ocean circulation; • Temperature; salinity; density; salinity – good tracer; • Sounds in the sea – detecting objections • Light in the sea – strong absorption near the surface… Euphotic zone (<200m), dysphotic zone (200-1000m), aphotic zone (>1000m)