Chemistry 103, General Chemistry Lecture Section D0D (Call # 1023) Laboratory Sections D01 (Call # 1024) AND D02 (Call # 1025) Lecture: Laboratory: Instructor: Office and office hours: 2:00-2:50 pm MWF 8:00-11:50 am M (D01); 8:00-11:50 am W (D02) David E. Lewis After class MW 3-5, and F mornings from 9-11 in 458 Phillips. My Schedule: 8-9 9-10 10-11 11-12 12-1 1-2 2-3 3-4 4-5 Phone: Email: Monday Chem 103 D01 Chem 103 D01 Chem 103 D01 Chem 103 D01 Chemistry DPC mtg. Class prep Chem 103 D0D Office Hours Office Hours Tuesday Chemistry 103 Faculty Mtg Wednesday Chem 103 D02 Chem 103 D02 Chem 103 D02 Chem 103 D02 Chemistry Faculty Mtg Class prep Chem 103 D0D Office Hours Office Hours Thursday Friday Office Hours Office Hours Chemistry 274 Class prep Chem 103 D0D Out of office 836-4744 lewisd@uwec.edu Required materials: The textbook for the course is “Chemistry and Chemical Reactivity” by Kotz, Treichel and Weaver. An inexpensive scientific calculator capable of handling scientific notation and simple mathematical functions is required. You do not need a graphing calculator or a programmable calculator for this course. The lab manual will be provided to you during your first lab period. Safety goggles that cover the whole eye are required and you will not be allowed in lab without safety goggles. Course objectives: The faculty of UW-Eau Claire has stated eleven academic goals for the baccalaureate degree. This course should provide students an opportunity to develop (a) an ability to inquire, think, analyze; (b) an understanding of numerical data; (c) an understanding of science and scientific methods. The specific topics of the course include the structure of atoms, the structure and bonding of ionic compounds and of molecules, stoichiometry, types of chemical reactions and the physical and chemical properties of matter. Attendance policy: Attendance at lecture meetings will be monitored and students with excessive absences will be referred to the Dean of Students. Students will not be evaluated based on attendance. Students are solely responsible for material and announcements made in lecture. Make-up quizzes and exams will not be given. Students missing quizzes or exams because of an excused absence (proper documentation required) will be given a prorated grade for the missed quiz or exam. Attendance is mandatory at laboratory periods. Students missing labs because of an excused absence must make arrangements to attend another lab section to complete the laboratory work. Homework: A list of suggested homework problems for each chapter is included in the tentative course schedule on page 3. This list is a starting point; most students should identify and work similar problems for extra practice. These homework problems will not be collected or graded, but they are still important. Quizzes and Homework: Short (approximately 15 minute) quizzes will be given on every other Friday during lecture as outlined in the course schedule, and somework sets assigned on the alternate weeks will be graded by you in class on the other Fridays. The quizzes and homework sets will be based on material presented in lecture and the suggested homework problems, and may include problems based on the previous week's laboratory experiment. Exams: Three in-class 50-minute exams will be administered throughout the course of the semester as outlined in the course schedule (see below.) the final examination is cumulative, and is scheduled for May 12th at 3:00 p.m. All students must take the final examination to earn a grade above "F" in this course. Exam questions will be based on material covered in the assigned readings, lecture and in laboratory. Laboratory: The laboratory is an important part of the course and students must complete all laboratory assignments to pass the course. Points will be awarded in lab for completion of required activities, post-lab assignments based on the lab activities and in-lab practical exercises. Although most experiments will be completed in pairs or groups, some in-lab practical exercises will be performed individually. Furthermore, some quiz and/or exam questions will relate directly to lab experiences. Therefore, all students are strongly advised to become active participants in the laboratory sessions. The final laboratory experiment is a challenge problem that will be done individually, with only eight students in the laboratory working different problems at the same time. The Challenge Problem is attached to the end of this course outline. Students with disabilities: Any student who has a disability and is in need of classroom accommodations, please contact the instructor and the Services for Students with Disabilities Office in Old Library 2136 at the beginning of the semester. Academic Integrity: I consider any academic misconduct in this course as a serious offense, and I will pursue the strongest possible academic penalties for such behavior. The disciplinary procedures and penalties for academic misconduct are described in the UW-Eau Claire Student Services and Standards Handbook in the section titled, “Chapter UWS 14—Student Academic Disciplinary Procedures.” Course grades: Points can be earned as follows: Quizzes 25 pts each Homework sets 7 pts each + 1 free point for the semester with no absences Lab Midterms 100 pts each Final Total points possible 150 50 200 300 200 900 The following approximate point totals (assuming 900 total points) will be used to determine final grades. 792-900 (88-100%) 675-791 (75-87%) 549-674 (62-74%) 450-549 (50-61%) 0-449 (0-49%) A’s B’s C’s D’s F’s Tentative course schedule: # Week 1 1 2 Week 2 Date Lab: Jan 23 Jan 25 Lab: 3 Jan 28 4 5 Jan 30 Feb 1 Reading Check-In, Safety (M) Chapter 2 Chapter 2 Check-In, Safety (W) Using Vernier (MW) Chapter 2 Homework Set #1 Chapter 7 Chapter 7 *Quiz 1* Problems Data Handling, Significant Digits (M) Atomic structure; periodic table; Avogadro's number Ch 2: 1, 9, 11, 13, 17, 19, 21, 23, 45, 46, 47, 51 Data Handling, Significant Digits (W) Introductory Practical (MW) Electrons in atoms: shells, subshells, orbitals Ch 7: 1,3, 9, 11, 17, 19, 25, 27, 29, 31, 33, 37, 45, 60, 66 Week 3 Lab: 6 Feb 4 7 8 Feb 6 Feb 8 Week 4 9 Lab: Feb 11 10 11 Feb 13 Feb 15 Week 5 12 Lab: Feb 18 13 14 Feb 20 Feb 22 Week 6 15 16 Lab: Feb 25 Feb 27 Feb 29 Lab: Week 7 17 Mar 3 18 19 Mar 5 Mar 7 Week 8 Lab: 20 Mar 10 21 22 Mar 12 Mar 14 23 24 Mar 17Mar 23 Lab: Mar 24 Mar 26 Mar 28 Week 10 25 26 27 Lab: Mar 31 Apr 2 Apr 4 Week 11 Lab: Apr 7 Week 9 Gases 1: Atomic Microscope Chapter 7 Chapter 7 Chapter 8 *Homework Set 2* Gases 2: Vernier Chapter 8 Chapter 8 Chapter 8 *Quiz 2* Periodic Trends §9.1 - 9.3 §9.1 - 9.3 §3.1-3.3, 13.7 *Homework Set 3* Ionic Compounds #1 (W) Chap. 5 (except 5.10) Chap. 5 (except 5.10) *Exam 1* Ionic Compounds #2-3 (M) Ionic Compounds #2 (W) Chap. 5 (except 5.10) Chap. 5 (except 5.10) §3.5-3.6 *Quiz 3* Ionic Compounds #3-4 (M) Ionic Compounds #3 (W) Chapter 4 Chapter 4 Chapter 4 *Homework Set 4* Electronic structure of atoms Electron configurations; periodicity Ch 8: 1, 3, 11, 13, 17, 23, 25, 31, 33, 33, 34, 47, 49, 57, 59, 61, 65 Electron configuration; periodicity Ionic compounds - bonding & lattices; ion names & charges Ch 9: 1, 3, 9, 61; Ch 13: 23, 24, 28; Ch 3: 5, 7, 11, 13, 17, 21, 63, 68 Reactions in aqueous solution Covers lectures 1-14 and experiments in weeks 1-5 Ch 5: 1, 3, 7, 9, 11, 13, 19, 21, 23, 25, 27, 29, 35, 37, 39, 41, 43, 45, 47, 49, 53, 55, 59, 77, 79, 87 Compound formulas (empirical, molecular); mole Equations and stoichiometry Ch 3: 31, 39, 41, 49, 51, 57, 61, 99; Ch 4: 3, 7, 9, 15, 19, 21, 23, 27, 29, 37, 41, 52, 65, 79, 80, 83 Equations and stoichiometry **Spring Break** Ionic Compounds #4 (W) *Holiday* §5.10 §12.3 *Quiz 4* Stoichiometry #1 §9.4 §9.4 §9.5-9.6, 9.8, 9.10 *Homework Set 5* Stoichiometry #2 *Exam 2* stoichiometry in aqueous solution; titrations ideal gas law; covalent bonding & Lewis structurs Ch 5: 61, 63, 65, 69; Ch 12: 31, 33, 93 Ch 3: 27, 29 Ch 9: 11, 13, 15, 17, 21, 25, 29, 33, 37, 39, 41, 43, 45, 47, 51, 77, 98, 99 Dr. Mirzaei will run this week's labs Covers lectures 15-27 and experiments in weeks 57 28 29 Apr 9 Apr 11 Week 12 30 31 32 Lab: Apr 14 Apr 16 Apr 18 Week 13 33 34 Lab: Apr 21 Apr 23 35 Apr 25 Week 14 Lab: 36 37 Apr 28 Apr 30 May 2 Lab: May 5 May 7 May 9 Week 15 38 39 40 May 12 §9.5-9.6, 9.8, 9.10 §9.7 *Quiz 5* Stoichiometry #3 §9.7 §9.9 §9.9 *Homework Set 6* Molecules: Spartan §10.1-10.2 §10.1-10.2 §13.1-13.4 *Homework Set 7* Molecules: Liquid Properties §13.1-13.4 §13.1-13.4 *Examination 3* Challenge Problem §13.5-13.6 §13.5-13.6 §13.5-13.6 *Quiz 6* FINAL EXAMINATION Dr. Haag will deliver today's lecture Resonance; VSEPR; molecular shape; bond order & length bond polarity; electronegativity molecular polarity Valence bond theory; hybrid orbitals Ch 10: 1, 3, 5, 9, 23, 25, 51 Valence bond theory; hybrid orbitals; intermolecular forces Chapter 13: 1, 3, 5, 7, 9, 17, 20, 39, 53, 65, 67, 69 Intermolecular forces Lectures 28-35 and experiments in weeks 8-13 Laboratory Practical Final Intermolecular forces EVERYTHING Revised 1/08, AJG Chemistry 103 Lab Practical Exam The scenario: The end of the semester has arrived and the general chemistry lab requires cleaning before next semester. Unfortunately, you find three unlabelled samples and, in order to dispose these chemicals properly, you must identify them. All you know is that the chemicals (shown in the groups below) were used during the course of the semester. Your assignment: You will establish the identity of the three unknown samples. Your task is divided into the following parts: 1. Identify the group for each unknown. Your unknowns will be from three different groups. (Example: A K+ salt, a halogen, and an acid.) 2. Identify the specific compound from each group. (Example: KCl, Br2 and HCl) 3. Explain the reasoning that enabled you to come to these conclusions. K+ salts KCl KBr KI halogens Cl2 Br2 I2 Ca2+ salts carbonates hydrocarbons alcohols CaCl2 Na2CO3 hexane methanol CaBr2 K2CO3 heptane propanol CaI2 (Each unknown will be provided to you in the form of either a 1.0 M aqueous solution, a pure solid or a pure liquid.) acids HCl H2SO4 6M HCl(aq), 6M NaOH(aq), 6M H2SO4(aq), 6M HNO3(aq), I2(aq), Br2(aq), Cl2(aq), NaI(aq), NaBr(aq), NaCl(aq), water, cyclohexane, methanol, ethanol, propanol, pentane, hexane, heptane, acetone, all the solids in the solubility grid, sodium hydrogen carbonate, citric acid monohydrate, malic acid, lithium carbonate and potassium carbonate will be available for chemical tests. You will have your own laptop computer and set of Vernier probes available for measurements. For this assignment, identification of an unknown or group by the process of elimination is permitted. For example, if you know the unknown must be a “halogen” and prove that it is not Cl2 or I2, you may conclude that it is Br2. Prior to your lab period: This exercise is based entirely on experiments in the 103 lab manual. You will have the rest of the semester to prepare for this assignment. You may work with other Chemistry 103 students (in your lecture section) and consult your instructor while developing your problem-solving strategy. You MAY NOT seek help from other faculty or anyone not enrolled in your lecture section of this course. During your lab period: You will be given 75 minutes (including clean-up time) to identify your unknowns. A copy of this sheet will be provided to you. You will not be allowed to bring any notes, your lab manual, or your textbook into the lab. You will work alone and may not talk to the other students in the lab. While you may ask the instructor questions, he/she may not be willing to help, as in any exam situation. Report Sheet Final Lab Practical Exam NAME: Section: Partial credit will be awarded for incomplete (for example, you identify the group but not the specific chemical) identifications. You must describe your experiments and reasoning for full credit. Identification: Unknown # ___________ is in group _________________ and is ________________. Unknown # ___________ is in group _________________ and is ________________. Unknown # ___________ is in group _________________ and is ________________. Reasoning: In the space below, describe in detail for each sample how you reached your conclusions.