Tamkang Journal of Science and Engineering, Vol. 3, No. 3, pp. 157-164 (2000) 157 Cool Thermal Discharge from Ice Melting with Time-Velocity Variation of Flowing Air by Complete Removal of Melt C. D. Ho, H. M. Yeh and W. P. Wang Department of Chemical Engineering, Tamkang University Tamsui, Taipei, Taiwan 251, R.O.C. E-mail: cdho@mail.tku.edu.tw Abstract A device of cool-thermal discharge system with performance improved has been developed by complete removal of melt with time-velocity variation of flowing air during on-peak power consumption. The simulation of estimating the thickness of ice melted and the thermal penetration distance in ice layer region with convective transfer by controlling air velocity with specified discharging fluxes on free surface has been derived. Three examples of different fluxes of cool-thermal discharges with constant inlet temperature of flowing air have been illustrated. Key Words: cool thermal discharge, melt removal, time-velocity variation, moving boundary 1. Introduction Cool-thermal storage system is a well known process as a demand-side management technology for shift air-conditioning needs from peak daytime periods to off peak nighttime and weekend period, while cool-thermal discharge system is that of ice melting to supply on-peak daytime cooling demands. The process with both operating systems of using of water associated with lowering on-peak daytime energy demand and increasing off-peak night-time energy demand has enabled users to significantly reduced their electricity costs, and hence the enhancement in electric utility profitability could be achieved. The mathematical statements of the capacity for cool-thermal storage systems with a constant mass rate and a constant volume rate of sublimation were derived [14,15]. The theoretical formulation of specified heat fluxes on the boundary and with convective boundary in cool-thermal discharge processes has been derived [8,9,16]. The improvements of energy transfer efficiency for cool-thermal storage and cool-thermal discharge systems were presented by several researchers [2,3,6,7,11,12]. It is evident that the maximum temperature gradient between the free surface and the ambient air, and hence the higher transfer rate of energy will be an important factor to design the cool-thermal discharge systems. There are two purposes in this work: first, to propose a new design of cool-thermal discharge system with air flowing over melting ice by complete removal of melt; second, to present an analytical approach by the use of the integral boundary-layer analysis. The present device of cool-thermal discharge system is to modify the previous works [8,9,16] for reducing the thermal resistance during ice melting by removing the melt completely and immediately, and the maximum temperature gradient and hence the heat transfer from ambient to the free surface is achievable. The process of heat transfer with moving boundary is so complicated and only a few of literature exists [1,4,13]. 2. Mathematical Statement A semi-infinite domain ice layer in cool-thermal discharge systems with uniform temperature (T∞ ) initially, constant physical properties of ice and no density change on melting were assumed. Before the free surface starts melting, the thermal penetration distance in ice layer region is presented in Figure 1(a). After taking a differential energy balance within the thermal penetration region, the temperature distribution may be obtained as 158 C. D. Ho et al. ∂ T / ∂ t = α i (∂ 2T / ∂ 2 x), 0 ≤ x ≤ δ (t ). (1) where δ (t ) is the thermal penetration distance. If an excess temperature ψ = T − T ∞ is introduced, Eq. (1) becomes ∂ψ / ∂ t = α i (∂ 2ψ / ∂ x 2 ), Ψ (0,t)=Ψ 0 ≤ x ≤ δ (t ). (2) Solid p Ψ (x,t) V(t), hm, Ψ air δ( t) Ψ ∞ =0 ψ (x , t ) = x Figure 1(a). A semi-infinite ice layer before melting. Ψ (0,t)=Ψ p δ = Solid 6α i t . δ( t)-X(t) ψ (0 , t ) = Ψ ∞ =0 x Figure 1(b). A semi-infinite ice layer after melting. 2.1 Before Melting, 0 ≤ t ≤ t i The temperature of ice surface reaches its melting point at t = t i , i.e. ψ = ψ p = T p − T ∞ . Before the temperature of ice surface reaches its melting point, the initial and boundary conditions are at t = 0; for IC, (3) ∂ψ − ki = q at ∂x x = 0; for BC1, (4) ψ ( x , t ) = 0, x = δ (t ); for BC2, (5) x = δ (t ); for BC3, (6) ∂ψ = 0, ∂x (7) (8) δ (t) X(t) δ (t ) = 0 , qδ x x [1 − 2 ( ) + ( ) 2 ]. 2k i δ δ Equation (8) is the expression for estimating the thermal penetration distance in ice layer, and the surface temperature can be obtained from Eqs. (7) and (8) as Ψ (x,t) V(t), hm, Ψ air where q = hm (ψ air − ψ ( 0, t )) , denoting the flux of energy absorption or the flux of cool thermal discharge at the free surface which is constant during the discharging period, and ψ air = Tair − T∞ , Tair is the temperature of flowing air at the free surface. The solution of Eq. (2) coupled with the use of Eqs. (3)-(6), was obtained by the following approximation method of integral boundary-layer analysis [5]. By following the same mathematical treatment performed in our previous work [16], except the temperature distribution in the ice layer region, the temperature distribution as well as the thermal penetration distance with constant q were obtained by representing ψ ( x, t ) in the quadratic expression with the use of Eqs. (4)-(6) as follows: at at qδ q = 2ki k 3 α it . 2 (9) Accordingly, the time, t i , needed for the surface temperature to reach the melting point and the corresponding penetration distance, δ i , may be calculated, respectively, by ti = 2 k i2ψ 3α i q 2 p 2 (10) and δi = 6α t i = − 2 k iψ q p (11) The hourly cool-thermal discharge flux with time-velocity variation of flowing air before starting to melt may be calculated from Cool Thermal Discharge from Ice Melting with Time-Velocity Variation of Flowing Air Complete Removeal of Melt ∂ψ ∂x q = −k i x =0 = hm (ψ air − ψ (0, t )), (12) while the total amount of cool thermal discharge per unit area during the time interval 0 to t i is Q (t ) = ∫ ti 0 = qdt = [ h m (ψ air ∫ ti − ki 0 ∂ψ ∂x dt x=0 − ψ ( 0 , t ))] t i (13) 2.2 After Melting, t ≥ t i ∂ψ / ∂t = α i (∂ 2ψ / ∂x 2 ), X (t ) ≤ x ≤ δ (t ). (14) at t = t i , for IC, ψ ( x, t ) = ψ p , at x = X; (15) for BC1, (16) − k (∂ψ ∂x ) + ρ Q m dX dt = q , x = X ; for BC1’, at ψ = 0, ∂ψ = 0, ∂ x (17) for BC2, (18) at x = δ (t ); for BC3. (19) Integrating Eq. (14) with respect to x over the range, X to δ , gives d δ dδ dX ψ dx − ψ (δ , t ) +ψ ( X , t) ∫ X dt dt dt ⎡ ∂ψ ⎤ ∂ψ = αi ⎢ − ⎥⋅ ⎣ ∂x x =δ ∂x x= X ⎦ (20) δ Assume that the temperature distribution in the ice layer can be represented by the following quadratic expression which satisfies Eqs. (16), (18) and (19) ψ (x , t ) ⎛ x − δ ⎞ =⎜ ⎟ ψp ⎝ X −δ ⎠ 2 (23) dX ∫X ψ dx + ψ ( X , t ) dt ⎡ ∂ψ = α i ⎢− ⎣ ∂ x x= X ⎤ ⎥, ⎦ (21) or, further using Eqs. (16) and (17) results in d ⎡ψ p δ ⎛ 2 + ⎜⎜ ψ ⎢ dt ⎣ 3 ⎝3 p + ⎤ α q ⎟⎟ X ⎥ = i , ki ⎠ ⎦ αiρ Qm ⎞ ki (24) Integration from t i to t results in δ =− α q(t − t) ⎤ ψ pδ i 3 ⎡⎛ αi ρ Qm 2 ⎞ + ψ p ⎟⎟ X − i i ⎢⎜⎜ ⎥+ 3 ⎠ ki 3 ψ p ⎣⎝ ki ⎦ (25) dX 1 = dt ρQm 2ki ψ p ⎛ ⎜⎜ q + X −δ ⎝ ⎞ ⎟⎟ ⎠ (26) Substitution of Eq. (25) into Eq. (26) gives dX 1 = × dt ρ Qm ⎧ ⎫ ⎪ ⎪ 2 ki ψ p ⎪ ⎪ ⎨q + ⎬ 3 ⎡⎛αi ρ Qm 2 ⎞ αi q(ti − t)⎤ ψ pδi ⎪ ⎪ ⎟ ⎜ ⎪ X +ψ ⎢⎜ k + 3ψp ⎟X − k ⎥ − 3 ⎪ p ⎣⎢⎝ i ⎠ i ⎦⎥ ⎩ ⎭ (27) After applying the boundary conditions, Eqs. (18) and (19), Eq. (20) becomes d dt (22) Substitution of Eq. (23) into Eq. (17) gives x = δ (t ); at α ρ Q m ⎞ ⎤ αq d ⎡ δ ⎛ . ψ ( x , t ) dx + ⎜ψ p + i ⎟X ⎥ = ⎢ ∫ dt ⎣ X k k ⎝ ⎠ ⎦ Substitution of Eq. (23) into Eq. (22) yields Once the surface temperature reaches the melting point, the ice is starting to melt and the melted ice is removed immediately, as shown in Fig. 1(b). The governing equation and the initial boundary conditions now become X = 0, 159 Once X is calculated from Eq. (27), ψ ( x, t ) and δ can then be calculated from Eqs. (23) and (25), respectively. Similarly, the hourly cool-thermal discharge flux and the total amount of cool thermal discharge per unit area during the time interval t i to t can be expressed respectively as follows: 160 C. D. Ho et al. ∂ψ x = X = − k i ( ∂ψ / ∂x ) + ρ Q m dX / dt ∂x = h m (ψ air − ψ p ), q = −k i (28) and Q (t ) = = ∫ t ∫ t ti ti V ( t ) = 2 . 268 ( µ g / L ρ g )[ Nu m ( t ) / Pr 1 / 3 ] 2 for laminar flow V (t ) = 66.06( µ g / Lρ g )[ Nu m (t ) / Pr 1 / 3 + 836]5 / 4 for turbulent flow qdt air − ψ p )]( t − t i ), (29) As an illustration, we consider here the following three examples of discharging fluxes: q = 1000 kJ/m 2 − h , The value of hm may be calculated by Eq. (12) with the use of Eq. (8), the expression for estimating the thermal penetration distances of ice layer, and with the inlet air temperature Tair = 32 o C , that is 3. Numerical Examples 1500 kJ/m 2 − h and hm = q ψ ait The average convection heat transfer coefficient hm , in Eqs. (12) and (28), may be estimated by Eqs. (30) and (31), which derived by Incropera and DeWitt [10]. − ψ (0, t ) ψ hm L = 0.664 Re 1L/ 2 Pr 1 / 3 , 0.6 ≤ Pr ≤ 50, kg ( and Re L = 2 .268 Nu m Pr 1 3 ) 2 (30) For turbulent flow hm L kg = (0.035 Re and in 4/5 L ⎡ 0.6 < Pr < 60 ⎤ , − 836) Pr , ⎢ 5 8⎥ ⎣5 × 10 < Re L ≤ 10 ⎦ 1/ 3 [( Re L = 66.06 Nu m Pr which hm = q /(ψ air 1 )+ 836] 5 3 4 (31) hm = q /(ψ air − ψ ( 0, t ) and − ψ p ) are the convective transfer coefficients of the periods before melting and after melting, respectively, and hm is function of time. In order to meet the specified discharging flux q and the temperature of flowing air, the air velocity is determined as follows: air − q ki 3 α it 2 (34) in which the temperature-time history at free surface may be obtained from Eq. (9), and then the average Nusselt number is calculated by the following Nu m ( t ) ≡ For laminar flow q = 2000 kJ/m 2 − h , with the ambient temperature, Tair = 32 o C . N um ≡ (33) 3.1 Before Melting, 0 ≤ t ≤ t i [ − k i ( ∂ ψ / ∂ x ) + ρ Q m dX / dt ]dt = [ h m (ψ Nu m ≡ (32) hm L kg (35) substitution of Eq. (35) into Eq. (32) or (33) gives V (t ) = 2.268( µ g Lρ g ) × ⎤ ⎡ ⎥ ⎢ Lq ⎥ ⎢ ⎥ ⎢ ⎛ ⎞ ⎢ k g ⎜ψ air − q 3 α i t ⎟ Pr 1 / 3 ⎥ ⎟ ki 2 ⎥⎦ ⎢⎣ ⎜⎝ ⎠ 2 for laminar flow V ( t ) = 66 . 06 (µ g Lρ g (36) )× ⎡ ⎢ Lq ⎢ ⎢ ⎛ 3 q ⎢ k g ⎜ ψ air − α it ⎜ 2 ki ⎢⎣ ⎝ for turbulent flow 5 ⎞ ⎟ Pr ⎟ ⎠ 1 3 ⎤ 4 ⎥ + 836 ⎥ ⎥ ⎥ ⎥⎦ (37) 3.2 After Melting, t ≥ t i Once the surface temperature reaches the melting point, the ice is starting to melt and the Cool Thermal Discharge from Ice Melting with Time-Velocity Variation of Flowing Air Complete Removeal of Melt melted ice is removed immediately. By following the same mathematical treatment in the previous section, except the temperature on free surface is at melting point thereafter. hm = ψ ait q −ψ = constant (38) p and then the average Nusselt number is calculated by the following Nu m ( t ) = Nu m ≡ hm L kg (39) substitution of Eq. (39) into Eq. (32) or (33) gives V = 2 .268 (µ g ⎡ Lq Lρ g )⎢ ⎢ k (ψ − ψ ⎣ g air p )Pr 1 3 2 ⎤ ⎡ Lq ⎢ Lρ g ) + 836⎥ ⎥ ⎢ k (ψ − ψ ) Pr 13 p ⎦ ⎣ g air 5 4 (41) for turbulent flow Table 1. Physical properties of ice (Incropera, et al., 1990) T ρ c k ( C ) (kg / m ) (kJ / kg ⋅ K ) (W / m ⋅ K ) 3 o 0 -20 920 920 2.040 1.945 1.88 2.03 L = 10m , 20m and 30m . Some physical properties of ice are given in Table l [10]. Substituting these values into the appropriate equations with the physical properties of ice taken at its average temperature, the equations of X , δ and ψ were derived. The thermal penetration distances and the temperature distributions in the ice layer may be estimated, respectively, from Eqs. (7) and (8) before melting and Eqs. (23) and (25) after melting, while the air velocity is calculated from Eq. (36) or (37) before melting and Eq. (40) or (41) after melting. The most important assumption in this work is that the decreases in volume due to the ice melting is neglected. Figures 2 and 3 show the relations of air velocity with the traversed length of air and the specified heat flux as a parameter for T∞ = −20 o C , respectively. It is seen from Figs. 2 and 3 that V is increasing before ice melting and (40) for laminar flow V = 66.06(µ g ⎤ ⎥ ⎥ ⎦ 161 Qm (kJ / kg ) 334 --- As an illustration, we assign the following numerical values for the physical properties of air and total operating time per day: ρ g = 115 . kg / m3 , (0o − 4 0o C) ; µg = 0067 . kg/ m-h , (0o − 4 0oC) . The physical properties of ice at 1 atm are given in Table l [10]. The results are shown in o Figs. 2 and 3 with T∞ = −20 C . 4. Results and Discussion As an illustration, we assign the following o o numerical values: T ∞ = −20 C ; T air = 32 C ; kept constant due to constant free temperature after melting. Moreover, V increases with both of the specified heat flux and the traversed length of air. The mathematical statement of cool-thermal discharge systems from ice melting with complete removal of melt, has been studied and the approximation solution has been derived with integral boundary-layer analysis in energy balances. The expressions for dimensionless thickness of melting ice X , Eq. (27), dimensionless thermal penetration distance δ , Eqs. (8) and (25), and the temperature distribution ψ ( x, t ) , Eqs. (7) and (23), are obtained. The results of the analysis indicated that, the flowing air velocity increases with the amount of cool thermal discharge and the traversed length of air. The present paper is actually the extension of cool-thermal discharge systems in the previous work [9], in which there is a water layer with thermal resistance existing while energy transferring from the flowing air to the ice layer surface. The maximum temperature gradient on the free surface with complete removal of melt in cool-thermal discharge systems has a positive influence on energy transfer rate, and hence the application of this concept to design cool-thermal discharge systems is technically and economically feasible. 162 C. D. Ho et al. 10 q = 2 0 0 0 k J /m 2 -h 9 8 7 q = 1 5 0 0 k J /m 2 -h V , m/sec 6 5 q = 1 0 0 0 k J /m 2 -h 4 3 2 1 0 0 .0 0 .2 0 .4 0 .6 0 .8 1 .0 t/t 0 Figure 2. Time-velocity variation of air with the traversed length as a parameter, (L=20 m) 8 L =30m 7 L =20m L =10m 6 V , m/sec 5 4 3 2 1 0 0 .0 0 .2 0 .4 0 .6 0 .8 1 .0 t/t 0 2 Figure 3. Time-velocity variation of air with the specified heat flux as a parameter. ( q = 1500 kJ/m − h ) Cool Thermal Discharge from Ice Melting with Time-Velocity Variation of Flowing Air Complete Removeal of Melt Nomenclature cp specific heat of ice (kJ / kg − K ) hm convective transfer coefficient (kJ / h−m2 − K) k g thermal conductivity of air (kJ / kg − m − K ) ki L thermal conductivity of ice (kJ / kg − m − K ) traversed length of air (m) Nu m Nusselt number (-) p atmosphere pressure (kPa) q cool-thermal discharge flux (kJ / m 2 − h) Qm heat of melting (kJ / kg ) T ( x, t ) ice temperature (K ) Tp melting point of ice (K ) T∞ initial temperature of ice layer (K ) t time (h) t i time needed for the surface temperature to reach the melting point (h) V flowing air velocity (m / sec) X thickness of melting ice (m) x x axis (m) Greek letters α i thermal diffusivity of ice, k i / ρc p (m 2 / h) δ thermal penetration distance (m) δ i thermal penetration distance as the surface temperature reaching themelting point (m) ψ T − T∞ (K ) ψ p T p − T∞ (K ) ρ 3 ice density (kg / m ) References [1] Carslaw, H. 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Y., “Cool Thermal Storage by Vacuum Freezing of Water with Constant Volume Rate of Sublimation,” Energy Convers. Mgmt., 33, 51 (1992). [16] Yeh, H. M. and Ho, C. D., “Cool Thermal Discharges from Ice Melting with Specified Heat Fluxes on The Boundary,” Energy-The Int, J., 21, 455 (1996). Tamkang Journal of Science and Engineering, Vol. 3, No. 3, pp. 157-155 (2000)