Alka Seltzer® Poppers Alka Seltzer is sometimes taken for acid indigestion. This over-the-counter medication is taken differently than most others since it is added to water before ingesting, rather than being “washed down” with the water. Let’s investigate this addition of Alka Seltzer to water. Materials 5 (or more) Alka Seltzer® tablets 1 35-mm film canister with lid ice-cold water (optional) 1/4-cup measure clear container such as a plastic cup or glass teaspoon measure very hot tap water room-temperature water tablespoon measure safety goggles Safety Goggles are recommended to protect your eyes from possible flying debris in this activity. Do not use water hot enough to scald. Exploration 1. Determine and record the active ingredients of Alka Seltzer tablets. 2. Add about 1/4 cup of room-temperature water into a clear container. Add an Alka Seltzer tablet to the water and observe. Keep the solution for use in Step 3. Describe what happens. What role does water play in this system? What is the identity of the most obvious product of this chemical change? Write the chemical equation which describes the reaction that has occurred. 3. Place 1 tablespoon of the solution from Step 2 in the film canister. Add half an Alka Seltzer tablet to the canister and immediately put on the lid. Hold the canister upright and away from your face. What happens? Explain your observations. 4. Design and perform an investigation to determine if the observations in Step 3 are reproducible. What did you do? What did you find out? 5. Repeat Step 3 with room-temperature water which has not had an Alka Seltzer tablet dissolved in it already. How do the results compare with those in Step 3? 6. Rinse out the canister and place 1 teaspoon of room-temperature water in it. Add half an Alka Seltzer tablet to it and immediately put on the lid as before. Compare your observations with those in Step 5 and explain any similarities and differences 7. What do you think would happen if you added 2 tablespoons of water to the canister before adding the Alka Seltzer? Try this variation using the same technique and explain your observations. 8. Design an experiment to determine the impact of changes in the temperature of the water on the system. Do not use water hotter than hot tap water or colder than ice water. Describe what you did and your observations. Explain what you observed. 9. Which trial is the control, the one to which the other trials are compared? Why is the number of variables changed important? What other variables might be studied in this system? Think About It What are the effects of changing the volume of water and the temperature of the water used in the investigation? © 2013 Terrific Science Burp Bottle Have you ever burped before? Burping is caused when there is an accumulation of gas in the digestive system. The “burp” occurs when the gas is released through the mouth. You can construct a “burp bottle” to imitate this action. Try this activity to find out how. Materials 2 plastic soft drink bottles of the same size (optional) narrow-necked glass (or other rigid) bottle water (optional) food color shallow tray or sink 1 of the following 2 sets of materials: Set 1 potato tape 8-inch piece of wire 3-inch piece of rigid plastic tubing (aquarium tubing), or barrel of a Bic® pen (can try another brand that has a removable tapered end) Set 2 2 one-hole #3 stoppers 3-inch piece of rigid plastic tubing that fits tightly into the one-hole #3 stoppers, or barrel of a Bic pen (can try another brand that has a removable tapered end) and tape Getting Ready 1. Cut one of the soft drink bottles to make a funnel as shown in Figure 1. 2. Half-fill the uncut bottle with water. 3. Use one of the two connectors described below to create an airtight seal between the funnel and the uncut soft drink bottle. Potato connector: If you are using a pen barrel that has a hole in the side, wrap tape around the barrel to cover up the hole. Carefully push the rigid plastic tubing or pen barrel all the way through the potato. If any potato (that would restrict air or water flow) becomes lodged inside the tubing, use a wire to push it out. Slide one end of the tubing into the mouth of the funnel all the way up to the potato and gently screw the potato onto the threads of the funnel. Lower the other end of the tubing into the mouth of the uncut bottle. Screw the potato onto the threads of the uncut bottle as you did with the funnel. (See Figure 2.) Stopper connector: Exploration 1. Place the apparatus in a shallow tray or sink. Fill the funnel 3/4 full with water (colored water is easier to see). Give the half-filled bottle a slight squeeze. Watch for several minutes. What do you observe? Explain your observations. 2. Gently unscrew the potato connector from the bottle (if using the stopper connector, twist to remove). Pour water out of the bottle until it is again only 1/2 full. Screw the potato connector back onto the bottle (if using stopper connector, twist to insert) and fill the funnel with water. Do not squeeze the bottle to start the burp. Does it to burp on its own? (Don’t wait more than 3–4 minutes.) 3. Experiment to determine the minimum amount of water in the funnel and the minimum amount of water in the uncut soft drink bottle that is needed for the burp phenomenon to begin without squeezing the bottle. What is the importance of water in these two locations? Why is it important that all seals be airtight? 4. Try to make a burp bottle using a glass (or other rigid) bottle instead of the uncut soft drink bottle. Why were you able (or not able) to get it to burp? Think About It What factors are responsible for the behavior of a burp bottle? © 2013 Terrific Science Chemistry of Solutions Do you know how to make a solution? Can you determine the concentration of the solution that you made? How does your solution behave? Try the following activity and find out. Materials table salt (NaCl) water cup measure tablespoon measure wooden spoon or wooden stir stick several Styrofoam cups thermometer (as used in making candy) sauce pan Exploration 1. Place 1 level tablespoon of table salt in a Styrofoam cup. Add 1/2 cup water to the cup. Mix thoroughly. Is this a saturated solution? One tablespoon of table salt weighs approximately 12 grams. There are approximately 240 mL in a cup. 2. Heat 1 cup water in the sauce pan until it is boiling. Suspend a thermometer in the water and record the temperature. Add 1 tablespoon salt to the water. Do not remove the water from the heat. Mix the solution with the wooden spoon or stir stick, never the thermometer. Record the temperature after it levels off. Explain your results. 3. Fill a Styrofoam cup with crushed ice. What do you think the temperature of ice is? Hold the thermometer in the ice and record the temperature after it levels off. Place 3 tablespoons salt in the cup. Stir with the spoon or stir stick. Observe the thermometer. What happens? Why? Think About It Why is it important that we understand solution chemistry? What are the applications of what you have seen in this activity? Chromatography on Paper We like to make colors an important part of our lives. That’s why manufacturers make products in a variety of colors. Have you ever wondered how these colors are created? We see a myriad of colors all around us, and many of them result from a mixing or blending of other colors. Colored markers are something we commonly use. A single color of marker may contain many different pigments. You can probably make some guesses as to what colors of pigments are contained in marker colors such as green, orange, and purple. How about black and brown? In this activity you will see for yourself. You may be surprised by your colorful results. Materials several brands and colors of water-soluble markers (Vis-à-Vis® work very well; try to include black, brown, and green) coffee filters scissors 2 glass containers (plastic can be substituted if acetone is not used) 2 adhesive labels (or paper and tape to make your own) plastic wrap or sandwich bags water one of the following: rubbing alcohol (70% isopropyl alcohol) acetone-based nail polish remover or hardware product Safety If you are using acetone, wear eye protection and avoid extensive or prolonged skin contact or inhalation. In addition, avoid spilling acetone on your clothing or other fabrics. Getting Ready 1. Squares : Cut two 2-1/2-inch x 2-1/2-inch squares out of the coffee filters. Using an accordion-style fold (so the square will be free standing), fold each square into four or five sections (depending on the number of colors/brands you are testing). 2. Ink dots : Place a different color of ink dot (about 1/2 cm in diameter) on each folded section of one square, about 1 cm from the bottom. Mark the other square in exactly the same sequence. You want to be able to readily compare the squares when you are done. (See Figure 1.) 3. Solvents : Label one container “water” and the other either “isopropyl alcohol” or “acetone,” depending on which one you are using. (Review the safety section about the use of acetone.) Pour about 1/2 cm of each solvent into the appropriately-labeled cup. Exploration 1. Carefully place a marked paper square (so it is free-standing) in each container. (If the solvent level touches the dots, pour out some of the solvent and prepare another square with ink dots.) Cover the containers loosely with plastic wrap or part of a sandwich bag. What is the purpose of doing this? 2. Observe the squares. Describe what the solvents are doing. What does this indicate about the solvents? What is happening to the ink dots? Explain in terms of attraction. © 2013 Terrific Science 3. Allow the chromatograms to develop until the solvents are about 1 cm from the tops of the squares. Remove the squares. Use a pencil to write the solvent used on the dry part of each square. Now compare the chromatograms and describe how they are alike or different. Think About It What are some of the factors that affect the usefulness of chromatography as a separation method? If a paper chromatogram of a red dye shows a smear of pink, is this conclusive evidence that the dye is a mixture? Explain. Diet versus Regular Soft Drinks Cans of soft drinks are so common that many people have done much of this exploration without realizing it. You, too, have probably cooled soft drink cans in ice water for a picnic. Here is your opportunity to see if you can make some generalizations about their behavior in water. Materials 1 12-fl oz (355 mL) aluminum can of diet soft drink, unopened 1 12-fl oz (355 mL) aluminum can of regular (non-diet) soft drink, unopened (use same brand as the diet soft drink if possible) container of water large enough to totally submerge both beverage cans in an upright position measuring cup calibrated in mL (if available) plastic, glass, or steel containers of diet and regular soft drinks of equal volumes, unopened (Use containers made of the same material.) Safety Do not use water hotter than that from the tap since very hot water can cause the containers of soft drinks to explode, as well as cause severe burns. Exploration 1. Holding the unopened cans in an upright position, submerge both cans in the container of water. Let go and record their orientations and whether they sink or float. 2. Repeat Step 1, but release the cans in a horizontal position. Record your observations. Explain any changes in orientation of the cans. 3. What property of matter accounts for the cans floating or sinking? How does this property differ for each soft drink can? If each container is made of aluminum and occupies the same volume, what do your observations say about the mass of the contents? Read the content information on the cans. What, if any, are the differences in ingredients? 4. With the measuring cup, measure the volume of the liquid in each can. How do these volumes compare to the volume of the can? How do you think the densities of the liquids compare? What would have to be done to determine the densities of the liquids? 5. Completely fill the cans with water. Submerge them in water and record whether they sink or float. Look up the densities of water and aluminum in your textbook. How do these values contribute to the behavior of the cans of beverages? 6. If materials are available, repeat Step 1 using plastic, glass, or steel containers of diet and regular soft drinks of equal volumes. Does the composition of the container make a difference in its floating/sinking behavior? Compare and contrast the results with those obtained for the aluminum cans. Think About It What factors account for the differences in density observed? © 2013 Terrific Science Hold the (Broken) Mayo! Although you were probably not aware of it, emulsions are very common around a household, as evidenced by several familiar foods and many cosmetics. Gourmet cooks and connoisseurs of fine sauces have long recognized the egg yolk as the mark of a classy sauce; one that is smooth and rich, with lots of oil or butter “held” into the water-based mixture. The secret of egg yolk is that it contains lecithin, a naturally-occurring emulsifying agent. Even so, the oil-holding capacity of a sauce is limited, and when too much oil is added (such as in mayonnaise), it “breaks” into two layers. Some substances behave similarly to emulsifying agents, but their effect is temporary. For example, solid paprika and dry mustard help stabilize French dressing by collecting on the surfaces of the oil droplets. Honey and sugar syrup are used to thicken some salad dressings; shaking suspends the oil droplets and their coalescing again is retarded by the viscosity of the liquid. Materials Vaseline® Intensive Care® (preferred) or other hand cream water 1/3 cup vegetable or mineral oil several small cups or plastic glasses teaspoon measure cup measure liquid dishwashing detergent clean towel or tissues (optional) beaten egg yolk or liquid soap (optional) additional vegetable or mineral oil (optional) 1 of the following emulsions: second brand of hand cream hair conditioner mayonnaise French dressing hollandaise sauce Safety You may dispose of each mixture down the drain. Exploration 1. Pour a little Vaseline Intensive Care (or other hand cream) into your palm and examine its appearance and feel. Wipe your hands with a clean towel or tissues. Does the hand cream label provide any clues as to whether it would be soluble in water and/or in oil? 2. Pour about 1 teaspoon Vaseline Intensive Care (or other hand cream) into a small cup or plastic glass. Add about 1/3 cup water and stir for several minutes. Use a dry finger to lightly touch the top of the liquid mixture. Record your observation(s) of sight and touch, including a comparison to those of Step 1. Explain what has happened to the components of the hand cream. What does this tell you about the ability of hand cream to hold water? 3. Pour about 2 teaspoons of liquid dishwashing detergent into a clean cup. Stir in about 1/2 teaspoon of the mixture from Step 2. Continue adding a little at a time until all the mixture has been stirred in. Compare your observations to those of Step 2 (neglect any suds). What can you say has happened to the components of the hand cream? What chemical term describes this functioning of a liquid detergent? 4. Pour about 1 teaspoon Vaseline Intensive Care (or other hand cream) into a small cup or plastic glass. Add about 1/3 cup vegetable or mineral oil and stir for several minutes. Use a dry finger to lightly touch the top of the liquid mixture. Record your observation(s) of sight and touch, including a comparison to those of Step 1. Explain what has happened to the components of the hand cream. What does this tell you about the ability of hand cream to hold oil? 5. Pour about 2 teaspoons liquid dishwashing detergent into a clean cup. Stir in about 1/2 teaspoon of the mixture from Step 4. Continue adding a little at a time until all the mixture has been stirred in. Compare your observations to those of Step 4 (neglect any suds). What can you say has happened to the components of the hand cream? What chemical term describes this functioning of a liquid detergent? 6. Does the sequence of adding a broken emulsion and the dishwashing detergent make a difference? Prepare a broken emulsion as in Step 2, then add small portions of liquid dishwashing detergent until two teaspoons have been added. 7. (optional) Repeat Steps 4 and 5, replacing the liquid dishwashing detergent with beaten egg yolk or liquid soap. Think About It Why is mayonnaise classified as an emulsion? What is the cure for a “broken” emulsion and how does it work? © 2013 Terrific Science Italian Dressing: Can Oil and Water Mix? You’ve probably shaken a bottle of oil-and-vinegar–type Italian salad dressing to mix it, only to have it separate again before you pour it on your salad. Isn’t this annoying? You can investigate this system to understand why it happens as well as to learn something about some other everyday liquids. Materials tape that can be written on pen ruler small, clear, colorless bottle (or jar) with lid 1 of the following to half-fill the bottle: equal amounts vegetable oil and water or vinegar oil-and-vinegar–type Italian salad dressing (not creamy style) liquid soap or detergent at least 3 of the following additives: tincture of iodine food coloring mineral oil rubbing alcohol nail polish remover soft drink baby oil Safety Since some of the additives are flammable, do not perform these activities near a heat source. You may dispose of the final mixture down the drain and recycle the empty bottle. Exploration 1. Place a strip of tape lengthwise on the bottle or jar, as shown in Figure 1. Half-fill the bottle or jar with either oiland-vinegar–type salad dressing or equal amounts of vegetable oil and water or vinegar. Use a pen to mark a line on the tape at the top of each layer. Measure and record the height of each layer (the distance between the layer’s bottom and its top). What observation(s) allows you to determine which substance constitutes the top layer and which one the bottom? What general property of substances is responsible for this positioning? Explain. 2. Add a little more water to the bottle, then remeasure the height of each layer. How can you tell if any of the added water dissolved in the oil? Explain your observations in terms of polarity. 3. Add just enough of one of the additives to your oil and water mixture to enable you to determine and record its position in the bottle. Also record the height of each layer and any other significant observations about the mixture. Gently shake the bottle and note any changes once the layers have again separated. 4. Repeat Step 3 with at least two more of the additives (added one at a time). 5. Add 20–30 drops of liquid soap or detergent to your mixture from Step 4. Shake the bottle well and allow it to stand for several minutes. Record the height of each layer and any other significant observations about the mixture. Explain your observations in terms of the nature of soap and detergent molecules. Think About It What can an oil-and-vinegar–type Italian salad dressing tell us about the polarity of some everyday liquids? Can oil and water mix? Layering Liquids You probably already know that a cork floats in water because it is less dense than water. You can use this principle to make a density column and to determine the relative densities of different objects. Materials clear glass bud vase or other slender glass container tablespoon measure liquids: vegetable oil dark Karo® syrup rubbing alcohol Dawn® or other dishwashing liquid ° water (addition of 1 or 2 drops of food coloring is optional) solids (as many as possible; must be small enough to fit in bud vase or other slender glass container): ball bearing or BB plastic bead rubber stopper cork super ball pine chip (part of a craft stick works) any other solids you wish to test Exploration 1. Place two tablespoons of one of the liquids listed above in the glass bud vase. Then add two tablespoons of one of the other liquids. What happens? How can you tell which one has the greater density? 2. Repeat this experiment several times using different liquids from the list. The densities of the liquids are: 0.87 g/mL, 0.91 g/mL, 1.00 g/mL, 1.26 g/mL, and 1.37 g/mL. Try to match up each density with its respective liquid based upon your results. 3. Now that you know the densities of each of the liquids, slowly pour two tablespoons of each of the liquids into the glass bud vase in order of decreasing density (the highest density liquid on the bottom) to create a density column. How does your density column look? 4. Drop each of the solids into the density column that you created in Step 3. What happens to each of the objects? Explain what the position of each object in the density column means. Can you tell what the density of each object is? Try other objects if you wish. Think About It What are the relative densities of various common liquids and solids? © 2013 Terrific Science Penny Sandwiches From 1864 until 1983, the usual composition of a penny (its actual name is “cent”) was 95% copper and 5% zinc and tin. Because of the increasing costs of copper, pennies are now composed of a zinc interior with a thin copper coating comprising only 2.4% of the penny. This activity allows you to remove the inside of the penny, leaving only the thin copper coating. Materials 2 pennies (dated 1983 or later) file or coarse sandpaper 2 cups lemon juice 2 cups vinegar 2 clear wide-mouthed containers (greater than 2-cup capacity) cup measure Safety Do not seal the bottles. The pressure of the hydrogen gas may be sufficient to shatter the bottles. Exploration 1. Using the file or coarse sandpaper, completely remove the copper coating from the edge of both pennies. Pour the lemon juice into one container. Position one penny in the container so that it is standing on its edge against the side of the container. Pour the vinegar into the second container and similarly position the second penny. Observe the pennies for 4 or 5 minutes. What do you see? What is occurring? What is the identity of the observed substance? 2. Observe the pennies over the course of 1 week and describe any difference(s) in their behavior. What accounts for the difference(s)? What specific process is occurring in each container? How do you know when the processes are complete? Write an appropriate equation representing the processes. Use your observations to rank the three elements hydrogen, copper, and zinc from most to least reactive. Think About It What is the chemistry-based reason for this peculiar construction of a penny? A Salty Separation It can be difficult to separate a solid from a liquid. Sometimes other chemicals can be added to aid in separation. You can imagine how difficult it would be to separate soap and water once they have been mixed. How well can you do it? Try the following activity and see. Materials bar of soap (do not use detergent) cheese or carrot grater water 1 of the following heat sources: stove hot plate microwave heat-safe container (appropriate for use with chosen heat source) 8 clear plastic cups or glasses 2 clear plastic cups or glasses for each additional optional solid used masking tape marker or pen coffee filters (fluted, basket-style filters are recommended, but any will do) 8 rubber bands teaspoon measure cup measure 5–7 stir sticks table salt sugar optional solids (use at least one): Epsom salt alum (aluminum potassium sulfate—used in canning and as an astringent) MSG (monosodium glutamate—used as a seasoning) crushed chalk (composed of CaCO3) Getting Ready Grate 1/2 cup of soap using a cheese or carrot grater. Place the grated soap in the heat-safe container, add 2 cups of water, and stir for several minutes. Heat the mixture using the stove, hot plate, or microwave, stirring occasionally until all of the soap shavings are dissolved. It is not necessary to boil the solution. Remove the solution from the heat and allow it to cool to room temperature. Exploration 1. Use the masking tape and pen to label two of the empty cups “control,” two others as “table salt,” and two as “sugar.” Pour 1/4 cup of the prepared soap-water solution into one cup of each labeled pair. Place a coffee filter in the other cup of each labeled pair. Fold the edge of the filter over the rim of the cup and secure it with a rubber band. 2. Add 2 teaspoons table salt to the cup of soap-water solution labeled “table salt.” Add 2 teaspoons sugar to the cup of soap-water solution labeled “sugar.” Stir each solution for several minutes. Compare them to the control cup with nothing added. 3. Pour each mixture into the corresponding cup with filter. Record the appearance of the filtrate that passed through the filter. How does the material in each of the filters look and feel? What is the purpose of the control cup? 4. Predict which of the optional solids on the materials list will do a good job of separating the soap from water. Repeat Steps 1 through 3 with at least one of the optional solids. Think About It What type of common compounds will separate soap from water? © 2013 Terrific Science Swirling and Churning Milk Although you might think food color and soap would spread throughout milk as they do in water, they don’t. Milk’s nonpolar fat globules have an effect on the dispersion, as the following activity will show. You might be surprised by your results! Materials 2 small, clear, plastic cups or glasses water 1/4 cup whole or 2% milk several different food colors in dropper bottles cotton swab dishwashing liquid 1/4 cup measure Safety Do not drink the milk used in this activity. Exploration 1. Pour about 1/4 cup water into one of the cups or glasses. Add one drop each of several different food colors to the surface of the water. What happens during the first minute? Why? 2. Pour about 1/4 cup of milk into the second cup or glass. Add one drop each of several different food colors to the surface of the milk. What happens to the food color? Explain why the food color behaves differently in milk than it does in water. 3. Wet one tip of the cotton swab with water and touch it to one of the food color drops in the milk. What happens to the food color? 4. Wet the other tip of the cotton swab with dishwashing liquid. Touch it to one of the food color drops in the milk. What happens to the food color? Think About It Look up the term “micelle.” Describe a micelle, and include an illustration. Then describe the nature of milk as containing fat micelles. Explain the observation in Step 4 based on the chemical nature of soap and milk. Tissue in a Cup: How Soggy? Have you washed any cups or glasses recently? Have you ever tried to submerge an inverted glass, jar, or cup into water only to have it bob back to the surface without the inside getting wet? What does this have to do with chemistry? You will find out as you investigate several aspects of this phenomenon through this activity. Materials clear plastic cup or clear glass paper cup several tissues or paper towels push pin or nail 2 containers large enough to completely submerge the cups (preferably with clear sides or a very large mouth to allow observation of the sides of the cup when submerged) ice-cold water very hot tap water Safety Be cautious of the sharp point on the push pin or nail. Use appropriate procedures to avoid burning yourself with hot tap water. Exploration 1. Fill one container with ice-cold water. Fill the second container with very hot tap water. Submerge an inverted clear cup or glass in the cold water for several minutes and observe from the side. Remove the cup from the cold water and, taking care not to burn yourself, submerge the inverted cup in the hot water for several minutes and observe as before. Repeat the submersion in cold and then hot water. Record your observations in a tabular format. Explain any differences in your observations of the cup in cold and hot water. 2. Using any of the materials listed above, devise a way to submerge a tissue or paper towel under water without getting it wet. Briefly outline your procedure and draw a labeled picture to illustrate what you observed. What kept your tissue from becoming wet? 3. Make a hole in the bottom of the paper cup with the push pin or nail. Repeat Step 2 with the paper cup. Record your observations of the water and tissues. Briefly explain your observations and draw a labeled picture to illustrate what occurred. Think About It What are some properties of air in an upside-down cup submerged in water? © 2013 Terrific Science What’s in a Potato? Have you ever used a 3% hydrogen peroxide solution to disinfect an open cut? If so, you probably noticed the formation of bubbles. Although hydrogen peroxide decomposes into water and oxygen gas very slowly at room temperature, the rate increases significantly in the presence of the enzyme catalase. Common substances containing catalase include blood, saliva, and potatoes. Does temperature affect the functioning of catalase? Materials 3–4 slices of fresh, raw potato or turnip 2 tablespoons 3% hydrogen peroxide solution 2–3 toothpicks or an eyedropper sauce pan or microwave-safe container stove, hot plate, or microwave tablespoon measure Getting Ready 1. Cool 1 tablespoon of 3% hydrogen peroxide in the refrigerator for several hours. 2. Boil a slice of potato or turnip until it is just slightly soft (several minutes); allow it to cool to the temperature of the other slices. Exploration 1. Use a toothpick or eyedropper to place several drops of room temperature 3% hydrogen peroxide solution onto a slice of fresh, raw potato or turnip. Observe for several minutes and record your observations. Does the behavior change with time? Write the balanced equation for the reaction. 2. Place several drops (same amount as in Step 1) of cooled 3% hydrogen peroxide onto a slice of fresh, raw potato or turnip. Compare your observations with those from Step 1. How can any differences be explained? 3. Place several drops (same amount as in Step 1) of room temperature 3% hydrogen peroxide onto a slice of previously-boiled potato or turnip. Compare your observations with those from Step 1. How can any differences be explained? 4. Spit into a sink. Put several drops of hydrogen peroxide onto the saliva. What do you observe? Explain. Challenge How does temperature affect the ability of catalase to quicken the decomposition of hydrogen peroxide? How is the reaction affected by a change in hydrogen peroxide temperature?