UV exposure on ski-field at an Alpine site A.M. Siani, G.R. Casale, Sapienza - University of Rome, Dept. of Physics, Rome, Italy H. Diémoz, G. Agnesod, ARPA Valle d'Aosta (Aosta Valley Regional Environmental Protection Agency), Saint-Christophe (Aosta), Italy M. Borra, A. Militello, ISPESL, (Italian National Institute of Occupational Safety and Prevention), Occupational Hygiene Dept., Monteporzio Catone (Rome) Italy M. G. Kimlin, C.A. Lang, Australian Sun and Health Research Laboratory, Queensland University of Technology, Institute of Health and Biomedical Innovation, Brisbane, Australia A. Colosimo Sapienza - University of Rome, Dept. of Human Physiology and Pharmacology ,Rome, Italy Abstract. The purpose of our study was to assess personal UV exposure of two groups of volunteers (ski instructors and skiers) at the Alpine site of La Thuile (Valle d’Aosta region, Italy) using polysulphone and electronic dosemeters. Introduction The amount of solar ultraviolet (UV) radiation at the Earth’s surface depends on the incoming solar energy and the transmission properties of the atmosphere as well as the features of the site (surface topography and albedo). Mountain sites experience enhanced ambient UV radiation levels due to the concurrent effects of shorter radiation path-length, low aerosol load and high reflectivity of the snow surface. Although several studies of UV radiation at high altitude sites were carried out (Blumthaler et al, 1997; Schmucki and Philipona, 2002; Pfeifer et al., 2006), little is known about UV exposure of human beings in mountainous areas where outdoor working or recreational activities (such as skiing) occur. The Alps are one of the places where the highest values of UV levels in Europe (Schmucki and Philipona, 2002) are experienced and tourism is leading more and more people into ski fields with the result that not-protected skin and eye can be damaged due to the overexposure to UV radiation. Thus, the aim of our work was to assess personal UV exposure of two groups of skiers (ski instructors and skiers) at the Alpine ski field of La Thuile-Les Suches (2100 m a.s.l.) in Valle d’Aosta region (Italy). Measurements Broad-band radiometers, having an erythemal response, yield measures of the ambient erythemal ultraviolet irradiance (dose rate) between 280 and 400 nm. Spectral irradiance undertaken with a spectroradiometer and then convolved with the C.I.E. erythema action spectrum (1987) can provide an alternative way to quantify the ambient UV dose rate. The quantification of human UV exposure is indeed a complex issue as it is directly linked to ambient UV dose as well as to behavioural and cultural factors. Polysulphone dosimetry is a reliable and widely used methodology (Kimlin, 2005) to assess UV exposure of differently oriented surfaces and can be used in remote and not easily accessible places. In this study a spring (March 30-April 4, 2006) and a winter (January 29-30, 2007) field campaigns were carried out at La Thuile-Les Suches ski field (45.7°N, 6.6°E, 2100m a.s.l) under almost clear sky conditions (Fig.1) from h: 10:00 LT to 16:00 LT. During the campaigns the maximum UV index was 6.0 and 2.0, respectively. Twenty skier volunteers and thirteen ski-instructors participated in the field experiments. Polysulphone dosemeters were attached on the hat to the forehead of volunteers in order to better represent their face exposure. Each volunteer was provided with a set of three PS dosemeters to be changed every two hours to avoid saturation, and a questionnaire asking for a description of the activity within each two-hours period, body posture and time intervals spent in the shade or indoor. Electronic dosemeters (Giga Hertz X-2000) were also worn by some volunteers as additional sensors to evaluate UV exposure. Ambient ultraviolet doses were measured using the well calibrated broad-band UV-S-AE-T radiometer (Kipp&Zonen). In addition UV doses were also recorded by a YES UVB-1 and by a Bentham spectroradiometer at Saint Christophe (Aosta) (45.8°N, 7.4°E, 569m) and at Les Granges (45.7°N, 6.6°E, 1640m) by a second UV-S-AE-T broad band radiometer. All UV instruments belong to the ARPA Valle d’Aosta. The three sites were chosen in order to study the albedo and altitude effect on polysulphone calibration curves (ambient doses versus the corresponding change in PS film absorbance (ΔA at 330nm), prior and post exposure (Kimlin 2005). In addition, measurements of skin reflectance using the Minolta Spectrophotometer CM26000d (Minolta, Osaka, Japan) were carried out before and after the exposure on a non exposed skin and on the cheek. as measured by the PS dosimeter and the corresponding ambient dose, was used. Thus, Exposure Ratio is the fraction (%) of the ambient UV radiation received by each volunteer during the exposure time intervals. It was found that during the spring field campaign the ambient UV dose (UVD) from h: 10:00 to 12:00 LT was 953 J/m2, from h: 12:00 to 14:00 UVD was 1192 J/m2 and then in the last 120min UVD was 879 J/m2. ER showed an average value of 100% with a minimum of 32% and a maximum of 175%. Exposure derived by electronic dosemeters will be further analyzed Conclusions Fig.1 La Thuile-Les Suches field ski Preliminary results A careful quantification of the calibration curve is required when polysulphone dosimetry is used to evaluate personal UV exposure. The dose-response relation is represented by the typical best fit to a third degree polynomial and it is parameterized by a coefficient (c) multiplying a cubic polynomial function. It was found by Casale et al., (2006) that c values can range from 0.78 to 1.85 kJm-2 depending on ozone amounts and solar zenith angle (SZA). In Fig.2 PS calibration curves for the spring campaign are shown. Measured c values are 1.69±0.02 at Les Suches, 1.47±0.01 at Les Granges and 1.24±0.01 at Saint Christophe. This study was conducted to assess UV exposure in terms of Exposure Ratio, in an environment of high ultraviolet light exposure such as a mountainous site in the Alps. The average personal UV exposure resulted in being the same as (and in some cases even more than) the ambient UV radiation while as reported by Gies in the WHO report (2006), UV exposure can vary from 5% to 15% of total ambient UV radiation and for outdoor workers exposures can reach 20-30%. Furthermore the preliminary results indicate that no difference among ER values of instructors and skiers were found as expected. Further multivariate analysis on colorimetric parameters used as biological indicators of individual response to UV dose will be carried out. Acknowledgements This work was supported by ARPA Valle d’Aosta. The authors would like to thank the instructors of the La Thuile ski school and Espace S.Bernardo Funivie which kindly hosted the UV instruments and all volunteers of ARPA. References Fig.2 Simultaneous calibration curves at La Thuile-Les Suches, Les Granges, Saint Christophe 31/03/2006. These values are higher than those obtained theoretically (Casale et al, 2006) when total ozone of 330 DU and SZA between 41° and 58° were taken into account. The percentage difference between measured and theoretical values are 44%, 35% and 25% respectively. This can be due to the contribution of the multiple reflections from snow which enhances UV exposure. The albedo effect will further be investigated analyzing the results of the winter field campaign and also in absence of snow. To quantify personal exposures, Exposure Ratio (ER), i.e. the ratio between the erythemally weighted absorbed dose Blumthaler, M., W. Ambach, and R. Ellinger, Increase in solar V radiation with altitude, J. Photochem. Photobiol, B: Biol., 39,130–134, 1997. Casale, G.R., M. Borra, A. Colosimo, M. Colucci, A. Militello, A.M. Siani, R. Sisto, Variabilità among polysulphone calibration curves, Phys. Med. Biol. 51, 4413-4427, 2006. C.I.E. (Commission Internationale d'Eclairage) 1987 Research Note. A reference action spectrum for ultraviolet induced erythema in human skin C.I.E. J. 6 17-22 Kimlin M.G. Exposure to UV radiation and human health Proc. SPIE, Ultraviolet Ground and Space based measurements, models and effects V, San Diego August 2005, 5886, N1-8, 2005. Pfeifer M. T., P. Koepke, and J. Reuder, Effects of altitude and aerosol on UV radiation, J. Geophys. Res., 111, D01203, doi:10.1029/2005JD006444, 2006. Schmucki, D.A., R. Philipona, Ultraviolet radiation in the Alps: the altitude effect, Opt.Eng. 41(12) 3090-3095, 2002. WHO (World Health Organization) Public Health and the Environment “Solar Ultraviolet Radiation. Global burden of disease from solar ultraviolet radiation” Environmental Burden of Disease Series, No. 13-R. Lucas, T. McMichael, W. Smith, B. Armstrong. Editors A. Prüss-Üstün, H. Zeeb, C. Mathers, M. Repacholi 2006.