Holy Cross High School N5 Topic 11 Plastics Homework Unit 3 – Key Area 2 - Plastics Forename(s) Surname Adapted from materials copyright Scottish Qualifications Authority Used with permission 1 2 3 4 5 6 7 8 9 10 11 12 Level Year Section Question I2 I2 I2 I2 SG SG I2 I2 SG SG SG SG 2007 2008 2009 2010 2008 2007 2007 2008 2011 2010 2009 2007 A A A A Credit Credit B B Credit Credit Credit Credit 14 18 18 15 3 4 7 6 13 10 18 18 Holy Cross High School 1. National 5 Chemistry Plastics Part of the structure of a polymer is drawn below. The repeating unit of this polymer is 1 Answer _____ 2|Page Holy Cross High School 2. National 5 Chemistry Plastics The flow diagram shows the manufacture of polythene from hydrocarbons in crude oil. Which line in the table identifies process X, Y and Z? Process X Process Y Process Z A distillation cracking hydrolysis B cracking combustion polymerisation C polymerisation distillation hydrolysis D distillation cracking polymerisation 1 Answer _____ 3. Part of the structure of an addition polymer is shown below. It is made using two different monomers. Which pair of alkenes could be used as monomers for this polymer? A B C D Ethene and propene Ethene and butene Propene and butene Ethene and pentene 1 Answer _____ 3|Page Holy Cross High School 4. National 5 Chemistry Plastics The structure below shows a section of an addition polymer. Which molecule is used to make this polymer? Answer _____ 1 4|Page Holy Cross High School 5. National 5 Chemistry Plastics The grid shows the structural formulae of some hydrocarbons. Identify the two hydrocarbons which can polymerise. 1 Answers _____ _____ 6. The structural formulae for some hydrocarbons are shown below. Identify the hydrocarbon which could be used to make poly(butane). 1 Answer _____ 5|Page Holy Cross High School 7. National 5 Chemistry Plastics Polystyrene is made from the monomer, styrene. The systematic name for styrene is phenylethene. (a) The monomer used to form polystyrene is shown. Which part of the structure of styrene allows the polymer to form? 1 (b) Complete the diagram to show how three styrene molecules join to form part of the polymer chain. 1 8. Poly(ethenol) is one of the substances used to cover dishwasher tablets. A section of the poly(ethenol) polymer is shown. Draw the structure of the repeating unit for this polymer. 1 6|Page Holy Cross High School 9. National 5 Chemistry Plastics Polyvinyldichloride (PVDC) is a plastic used in food packaging. The structure of part of a PVDC molecule is shown. Draw the full structural formula for the monomer used to make PVDC. 1 10. Poly(methyl methacrylate) is a synthetic polymer used to manufacture perspex. The structure of the methyl methacrylate monomer is shown. (a) Draw a section of the poly(methyl methacrylate) polymer, showing three monomer units joined together. 1 (b) Name the type of polymerisation taking place. 1 7|Page Holy Cross High School 11. National 5 Chemistry Plastics When superglue sets, a polymer is formed. Part of the polymer structure is shown. (a) Draw the structure of the repeating unit in the superglue polymer. 1 (b) The polymer shown above contains methyl groups (CH3). Another type of superglue, used to close cuts, has the methyl groups replaced by either butyl groups (C4H9) or octyl groups. Complete the table to show the number of carbon and hydrogen atoms in an octyl group. Number of Atoms Group Carbon Hydrogen methyl 1 3 butyl 4 9 octyl 1 8|Page Holy Cross High School 12. National 5 Chemistry Plastics Nylon is a polymer made from two different monomers as shown. During the polymerisation reaction, water is also produced. Suggest a name for this type of polymerisation. 1 9|Page