Physics 827 Problem Set 9 Due Friday 12/04/2009 9.1 Shankar 10.1.3 (page 258) (Important) This is straightforward algebra. Just observe that à p21 + p22 = pI + pII √ 2 !2 à + pI − pII √ 2 !2 = p2I + p2II with a similar result for x21 + x22 . This is obvious since we are rotating by π/4 and the norm of the vector is preserved. Lazy that I am I would have said this and skipped the algebra. Promoting the classical coordinates and momenta to quantum operators the Hamiltonian becomes PI2 P2 1 2 ]. + II + mω 2 [XI2 + 3XII 2m 2m 2 The Schrödinger equation is h̄2 − 2m à ∂2 ∂2 + ∂x2I ∂x2II ! ψE (xI , xII ) + 1 mω 2 [x2I + 3x2II ] ψE (xI , xII ) = E ψE (xI , xII ) . 2 Since the Hamiltonian is separable (this was the point of finding the normal coordinates) the total energy is additive and we can write ψE (xI , xII ) = ψEI (xI ) ψEII (xII ) and E = EI + EII . We obtain two decoupled equations and we can write down the energies. (b) Elementary calculus yield ∂ ∂xI ∂ ∂xII ∂ 1 ∂ 1 ∂ = + = √ + √ . ∂x1 ∂x1 ∂xI ∂x1 ∂xII 2 ∂xI 2 ∂xII ∂ ∂xI ∂ ∂xII ∂ 1 ∂ 1 ∂ = + = √ − √ . ∂x2 ∂x2 ∂xI ∂x2 ∂xII 2 ∂xI 2 ∂xII Therefore, ∂2 ∂2 ∂2 ∂2 + = + . ∂x21 ∂x22 ∂x2I ∂x2II This yields the kinetic energy operator. The potential energy arises as before à x21 + x22 2 + (x1 − x2 ) = xI + xII √ 2 !2 à + 1 xI − xII √ 2 !2 + ³√ 2xII ´2 = x2I + 3x2II . 9.2 Shankar 11.4.2 Clearly, the infinitesimal generator of translations, PX does not commute with the Hamiltonian. [PX , H] 6= 0 since ∂/∂x does not commute with V (x) = V0 sin(2πx/a). The Hamiltonian is invariant under translation by integer multiples of the basic period √ a, i.e., [Ta , H] = 0. Given a plane wave eipx/h̄ / 2πh̄, the Hamiltonian H has nonzero matrix elements between this state and only the states with momentum given by p ± (2πh̄)/a. Thus, one can conclude that the momentum is conserved up to integer multiples of 2πh̄/a. 9.3 Read section 12.3 (p313-315) and do Shankar 12.3.3 and 12.3.4 (These are important) Consider the matrix element 1 Z 2π 2 2 hm|ψi = √ dφ e−imφ cos2 φ A e−ρ /(2∆ ) ; 2π 0 |hm|ψi|2 × ρdρ yields the probability for the particle to be found with an Lz value of mh̄ and the value of the radial co-ordinate between ρ and ρ + dρ. Note the factor ρdρ in two dimensions. Thus the probability to be in the state |mi is given by the integral over ρ since we do not care what the radial coordinate is. The wave function is separable and therfore, the constant arising from the ρ integral is independent of m and thus the ρ-dependence can be ignored. So we can focus on the angular dependence only: ³ ´2 ψ(φ) ∝ eiφ + e−iφ ∝ e2iφ + 2 + e−2iφ . Thus, the probabilities to obtain the values 2h̄, 0, and −2h̄ are in the ratio 1 : 4 : 1. Normalization yields the answer. The wave function in 12.3.4 can be written as ·µ ¶ µ ¶ ¸ ρ ρ −ρ2 /(2∆2 ) 1 iφ −iφ ψ(ρ, φ) = A e −i e + +i e . 2 ∆ ∆ Once more the probability of obtaining Lz value of +h̄ and the radial co-ordinate lying between ρ and ρ + dρ is given by 2 2 π 2 2 ρ + ∆ |A|2 e−ρ /∆ × ρdρ . 2 ∆2 The corresponding probability for −h̄ is the same: the key observation is that |(ρ/∆) − i| = |(ρ/∆) + i|. Thus the two probabilities are equal. 2