1. Wastewater Characteristic 1.1 Definition Wastewater refers to the water that is contaminated by human activity. The water may be discharged from household, agricultural activities, office and industrial wastes that are no longer safe for human consumption. The flow of storm water and groundwater also contributes to wastewater. By weight, wastewater is only about 0.06% solids - dissolved or suspended materials carried in the 99.94% water flow. The water to solids ratio is essential to transport solids through the collection system (Drinan, Spellman 2013). Wastewater can be classified into two types which are gray water and black water. Greywater is water from bathroom sinks, showers, tubs, and washing machines whereas blackwater is the waste that we flushed off from a toilet or urinal. 1 1.2 Wastewater sources and general constituents The different specific substances that comprise wastewater vary in amount or concentration, dependent on the source. Table 1.1 Typical Composition of Untreated Domestic Wastewater Constituent Abbreviation Concentration (mg/L) Biochemical oxygen demand BOD5 100-300 Chemical oxygen demand COD 250-1,000 Total dissolved solids TDS 200-1,000 SS 100-350 TKN 20-80 TP 5-20 Suspended solids Total Kjeldahl nitrogen Total phosphorus (as P) Source: (Drinan, Spellman 2013) Human and animal wastes Domestic wastewater contains solids and liquids discharges of humans and animals and runoff to the environment, for example, excreta such as faecal and urine. These contribute millions of bacteria, viruses and other organisms (some pathogenic) to the wastewater and they can endanger public health (Drinan, Spellman 2013). Household wastes Residential wastewater flows may contain tissue paper, detergent, garbage, kitchen wastes and other possible substances that may pour of flush into the sewer system (Drinan, Spellman 2013). Industrial Wastes Manufacturing plants in the factories usually discharge materials or fluid that is highly in toxic into the collection system. Those materials include chemicals, acids, alkali detergents and some other materials. Industrial wastewater can be treated within public treatment facilities but often industries must provide some level of treatment prior to their waste stream entering a public treatment system. This may prevent compliance problems for the treatment facility. An industry may provide 2 pretreatment to the effluent because its on-site treatment is more economical than paying municipality fees for advanced treatment (Drinan, Spellman 2013). Storm water runoff During storm events, storm water runs off and takes the pollutant and contaminant on the earth surfaces. The run-off matters may contain sand, gravel, grit as well as floor levels of water. In the past, storm water system and sewage system were combined. However, new construction discharges wastewater into a dual storm water and sewage system which both of them flows into different collection systems. Groundwater filtration Old and improper sealed collection systems may allow groundwater to enter the system through cracks, breaks and unsealed joints (Drinan, Spellman 2013). This may contribute large amount of water to the wastewater flows that contain grit (Drinan, Spellman 2013). 1.3 Physical Characteristic The presence of solids in water, level of turbidity of wastewater, color, odor and temperature are the main concerns of the wastewater physical characteristic. Solids There are suspended and dissolved solids in the water we flushed off. They are in different sizes and classified by their chemical characteristics and size distribution (Drinan, Spellman 2013). The solids consist of organic, inorganic particles and immiscible fluids. Organic matters are mainly found in domestic water used. Whereas, Industrial wastewater contains either organic or inorganic suspended impurities. Turbidity Turbidity is a measure of water clarity. It indicates the amount of material suspended in water decreases that the passage of light through the water. As suspended materials absorb heat, water temperature rises. Warm water thus reduces the concentration of dissolved oxygen in the water. Some organisms can‟t survive in the warmer water. Besides that, higher turbidity reduces the amount of light penetrate through the water, which reduces photosynthesis and the production of the oxygen (EPA, 2012). 3 Sources of turbidity can be from urban run-off, soil erosion, waste discharge from household or factory and the excessive growth of algae. Color Initially, wastewater is a light brownish gray color. The flow becomes increasingly more septic when it continuously passes through the collection systems as more anaerobic conditions develop (Drinan, Spellman 2013). Fresh sewage color of gray will turns dark gray then to black. Odor As the wastewater contains various kinds of waste, it produces odor. In most urban area, treatment plants are physically covered to prevent odors from leaving the unit processes. However, toxic concentrations of gas will increase in these contained spaces after some time. To overcome this problem, such units should be positively vented to wet chemical scrubbers to prevent the buildup of toxic gas (Drinan, Spellman 2013). Temperature Temperature of wastewater affects how quickly and effectively chemicals dissolved and the time for chemical reaction to take place (Drinan, Spellman 2013). Biological wastewater treatment systems are more efficient at higher temperature as bacteria tend to break down at high temperature. The lower the influent temperature, the more chemical is needed for treatment (Drinan, Spellman 2013). However, summer heat increases chlorine demand, promotes algae and microbial growth (Drinan, Spellman 2013). 1.4 Chemical Characteristic Chemicals in the wastewater such as total dissolved solids (TDS), metals, organics, and nutrients may affect its composition and pH rating. Total dissolved solids Total dissolved solid (TDS) is also known as the residue that remains in the water after the filtration and evaporation process. TDS is also a measure of the amount of material dissolved in water. 4 High concentrations of TDS reduce water clarity, contribute to a decrease in photosynthesis, combine with toxic compounds and heavy metals in the water, and lead to an increase in water temperature (Murphy, 2007). Factors that affect the amount of total dissolved solids including: i. Geology and Soil in the Watershed ii. Urban Runoff iii. Fertilizer Runoff iv. Wastewater and Septic System Effluent vi. Soil Erosion vii. Decaying Plants and Animals Metals High concentrations of dissolved metals are mainly found in industrial wastewater as a result of their manufacturing processes. Heavy metals are harmful to human‟s body and the environment. It must be removed to achieve a high water quality level. High concentration of metals will kill microorganisms during the activated sludge process. Metals are removed by chemical treatment, though that doesn‟t end the metals toxicity problem for waste stream processing. Industrial wastes with high levels of toxic metals or organic substances can contaminate sewage biosolids, thereby limiting biosolids disposal options and raising disposal costs (Drinan, Spellman 2013). Organics The microorganisms that rely on microbial decomposition consume dissolved oxygen in water. This process is called biochemical oxygen demand (BOD). BOD is defined as the amount of oxygen required by aerobic microorganisms to decompose the organic matter in measured amount of water, keep at 68 °F (20 °C) over a 5-day incubation period. Without continuous oxygen replacement, dissolved oxygen levels decrease until the cycle fails as the microbes used up the oxygen available to consume and decompose the organics (Drinan, Spellman 2013). 5 The presence of organic matters in wastewater includes proteins, lipids, carbohydrates, and detergents. And about 30% of it is non-biodegradable (Drinan, Spellman 2013). Table 1.2 summary of various type of organic matter in wastewater Types of organic matters The content of organic in wastewater matters Proteins Amino Acids, Explanation Carbon, The greater mass Hydrogen, Oxygen, Sulphur, wastewater Phosphorous, Nitrogen of biosolids material is made up of solids, or coated with protein so that it reacts as protein would. Lipids Fats, Oils, Waxes Lipids are soluble in organic solvents (ether, ethanol, and acetone, but marginally water soluble. Food Wastes Lipids, Fats (compounds of Fats that alcohol and glycerol), Oils, wastes Greases found are in very food stable organic compounds, and do not easily decompose. Grease High amounts reduce the of grease efficiency of filters, nozzles, and sand beds. Grease adheres to the walls of sedimentation tank, where it decomposes and form scum. Carbohydrates Soluble: Sugars, Cellulose Insoluble: Starch, Fibers Lower organisms (bacteria) Wood use carbohydrates to synthesize fats and proteins, as well for energy. Detergents Detergents are slightly soluble in water and cause foaming 6 when outfall in effluent into surface waters. Detergents reduce the oxygen uptake in biological processes. Source: (Drinan, Spellman 2013) Inorganics Table 1.2 summary of various type of organic matter in wastewater Types of inorganics matters in Descriptions wastewater pH (hydrogen ion concentration) pH indicates the intensity of acidity or alkalinity in wastewater and affects biological and chemical reactions. Increased pH increases the contact time needed for chlorine disinfection. Chlorides Chloride is the major inorganic constituent in wastewater. It does not cause any harmful effects on public health. Nutrients (Nitrogen and Phosphorous) Nutrients are essential to the reproduction and growth of plants and animals. Excessive nitrate concentrations in drinking water will endanger both human‟s health and animal infants. Phosphorus released into drinking water supplies as little effect on human health but too much phosphorus in water supply will contribute to algae bloom and lake eutrophication. Others Sulphur, toxic inorganic compounds, heavy metals. Source: (Drinan, Spellman 2013) 7 1.5 Biological Characteristic Biological characteristic of wastewater is defined by the levels of bacteria, viruses, and microscopic animals present. Human wastes infected with disease can produce harmful pathogenic organisms in the water that enter the sewage (Drinan, Spellman 2013). Bacteria Bacteria are microorganisms that are too small to see with naked eyes. They are fundamental to several wastewater treatment unit processes, especially those responsible for degradation of organic matter (Drinan, Spellman 2013). However, these bacteria must be controlled as the excessive growth of some species ordinarily useful bacteria (such as Sphaerotilus natans-a filamentous organism) may reduce the treatment efficiency. Besides that, waterborne pathogenic bacteria transmit diseases that cause gastrointestinal disorder (Drinan, Spellman 2013). Viruses Viruses are parasitic microorganisms that are much smaller than bacteria. They are not easily trapped by standard filtration methods, as the varieties of viruses are extremely minute (Drinan, Spellman 2013). Generally, waterborne viral infections cause nervous system disorder. Viruses rely on a host to live and reproduce. As it remains dormant until an appropriate host ingests them, viruses that reenter the water supply from wastewater effluent can cause problems for downstream water use (Drinan, Spellman 2013). Algae Algae are aquatic plants that live in water. They only grow near the water surface in order to get sunlight for photosynthesis. Aquatic algae are found in freshwater, wastewater, marine waters as well as polluted water. In aerobic and facultative ponds, algae usually supply oxygen for microbial breakdown of wastes. During days, algae rely on sunlight to produce oxygen and use up carbon dioxide whereas on dark days or nights, they use up oxygen to produce carbon dioxide. However, heavy algae growths will raise the level of suspended solids concentration in the wastewater effluent (Drinan, Spellman 2013). 8 Protozoa Protozoa are the simplest animal species that are widely distributed and highly adaptable (Drinan, Spellman 2013). Some protozoa are parasitic, while others are free living. Protozoan populations are an essential part of activated sludge treatment processes and they are removed by sedimentation after the process (Drinan, Spellman 2013). Effluent must not contain too much protozoan levels. In order to remove them from wastewater, filtration method is usually used. Worms (helminthes) Worms are organisms with aerobic requirements that inhabit mud and slime (Drinan, Spellman 2013). Worms can metabolize solid organic matters that other microbes cannot degrade, and feed on sludge deposits. This helps to break down the organic matters in the water stream (Drinan, Spellman 2013). Indicator organisms Testing and identification of pathogens presents inherent problems. Some organisms are tough and persistent, and others from protective spores that allow them to resist treatment processes designed to kill off pathogens. The indicator organisms alert us to the possible presence of sewage contamination. For example, coliforms that present in the wastewater indicate sewage contamination, it as well mean that the water source could contain pathogenic microorganisms (Drinan, Spellman 2013). Coliforms Wastewater contains more coliform groups than polluted water. For example, fecal coliforms are present in the intestinal tracts of all mammals. Coliform group testing involves estimating the number of fecal coliform bacteria present in a measured water sample. This will provides a ratio of contamination to define the quantity of water (Drinan, Spellman 2013). 9 2. Conventional Wastewater Treatment 2.1 Introduction Conventional here carries the meaning of generally practiced or used in most places. A conventional wastewater treatment has a combination of physical, chemical and biological processes and functions to dispose solids and organic or inorganic matter in the wastewater. There are a few stages involved called preliminary, primary, secondary and tertiary wastewater treatment. Different treatment plants utilized different types of treatment and thus some may skip one of the treatment stages. Regardless of that, the main aim of all treatment plants to achieve a high quality effluent that is safe to the humans and environment. Figure 2.1 summary of a conventional wastewater treatment process Source: (Ohioline, n.d.) 2.2 Preliminary sewage system 2.2.1 Introduction Preliminary sewage system is mainly the removal of sewage constituents that ensures the treatment operations to go on smoothly as well as gain a satisfactory quality of final effluent ( Indah Water Konsortium, 2013). Moreover, a treated sludge could be produce that is suitable for recovering it for specified disposal objectives such as disposal for the purpose of agriculture (Epa Environmenta Protection Agency, 1995). 10 2.2.2 Types of Treatment Process The major processes in preliminary sewage system are screening and comminution (grinding), grit removal, pre-aeration, flow measurement and flow balancing ( Indah Water Konsortium, 2013). Figure 2.2 Screening Source: (Cooke, 2014) Screening Screening is the first operational process for the wastewater treatment process. It involves the removal of non-biodegradable and floating solid such as rags, plastics, tin, containers, papers, and wood that may cause blockage of the accumulation of unwanted material as well as protect the downstream plant from damage ( GAH Global, 2010). There are fine screening and coarse screening. Coarse screen is to remove and eliminate the large solid rags and debris from wastewater with the opening of 0.25 inch while fine screen with the opening of 0.1 inch to 0.6 inch is to reduce the amount of suspended solids before entering to the primary treatment process (United State Environment Protection Agency, 2003). The cleaning methods of the screen involve manually cleaning screen and mechanically cleaning the screen. Manually cleaning is important to avoid the accumulation of the solid inside the screen (R.Spellman, n.d.). The solids are removed manually and frequently by the operators as it may cause the emanation of the odors, insects and rodent problem (R.Spellman, n.d.). While mechanically cleaned screen uses the mechanized rake to discharge them out and keep in a storage hopper with maintenance work such as lubricating the equipment (R.Spellman, n.d.). 11 Moreover, the disposal ways of solids are by burial in an approved landfill or grinding the solids into small particle and later placed back to the wastewater flow for further processing in both manually and mechanically cleaned screen (R.Spellman, n.d.). Figure 2.3 Comminutor Source: (Cooke, 2014) Comminution Comminution is under the process called shredding which is an alternative to screening to reduce the sizes of the solids and able to pass through the plant without causing clogging to the machine (R.Spellman, n.d.). The solid that pass through are chopped between the cutters however floating or large objects are not able to be discharged. Aligning, sharpening and replacing the cutters are needed to maintain the good condition of the comminutors (R.Spellman, n.d.). 12 Figure 2.4 Grit Chamber Source: (Cooke, 2014) Grit removal Grit removal is physical unit operation through grit chamber or centrifugal separation of the sludge (about civil.org, 2014). The main function of the grit removal is to remove heavy inorganic solids which include sand, gravel, clay, egg shell, coffee grounds, metal filing and seeds to prevent the excessive mechanical wears (R.Spellman, n.d.). Pre-aeration Pre-aeration is a process of forcing and compressing the air into the wastewater by mechanical agitation to promote the absorption of the atmosphere air hence increases the reduction of Biochemical Oxygen Demand (BOD) in grit chamber (Cooke, 2014) . Flow measurement Flow measurement is used to ensure the efficiency of wastewater treatment process, collect information for hydraulic and organic loading, and preparation of the compliance report. Flow rates are gained from the quantity of liquid that passes through the specific point at a given time. (Darine, 2000) Flow balancing Flow balancing or flow equalization is to enhance the performance of the treatment plant by providing stable organic loading (Darine, 2000). The excessive flow is directed to the storage basin and hence maintains an adequate mixing and aeration during low flow period for the safety purpose (Darine, 13 2000). 2.3 Primary sewage system 2.3.1 Introduction In primary sewage system, the processes involved are sedimentation and floatation to separate the suspended sludge and high amount of organic matter from wastewater using primary clarifier ( Indah Water Konsortium, 2013). Total suspended solid and the Biochemical Oxygen Demand level could also be reduced in this stage (Evoqua Water Technologies, 2014). 2.3.2 Treatment Process Primary Clarifier Primary clarifier is the process when wastewater flows slowly into the large tank from the screening and grit removal process (Alberta Capital Region Wastewater Commision, 2014). Organic sludge will settle and later pumped to the gravity thickener according to the solid‟s weight. The surface of the wastewater will float with the grease and scum will appear on the surface of the wastewater (The City of Watertown, New York, n.d.). The scum is then skimmed off the tank by decanting and sent to the digesters for biological treatment. The remaining clarified liquid with dissolved material will flow to the secondary stage (Alberta Capital Region Wastewater Commision, 2014). Figure 2.5 Sedimentation and Floatation Source: (Alberta Capital Region Wastewater Commision, 2014) 14 2.4 Secondary Sewage Treatment 2.4.1 Introduction Secondary sewage treatment involves the process of activated sludge, bio- infiltration and sedimentation ( Indah Water Konsortium, 2013). The objective for the secondary treatment or biological treatment is to provide biochemical oxygen demand (BOD) by converting dissolved, suspended, and colloidal organic wastes to more stable solids so that it can be removed through settling and released to the environment without causing harm (R.Spellman, n.d.). 2.4.2 Types of Treatment Process Activated Sludge In activated sludge process, the aeration tank or the basin acts as the dispersed- growth reactor that mixes the suspended solid in the wastewater and microorganism for the purpose of supplying oxygen to the biological suspension by aeration devices. Next, the microorganisms are separated from the liquid through sedimentation and clarified liquid is produced as secondary effluent. Part of the biological sludge is recycled to the aeration basin to maintain the level of suspended solids. The remaining sludge are removed and sent for further sludge processes (Natural Resources Management and Environment Department, 2014). Bio-Filter A bio-filter consists of a basin support media such as stones, plastic shapes or wooden slats. A layer of biological and fixed film is formed when the microorganism is in contact with the media. Oxygen by natural flow and forced air by blowers are supplied to the film (Natural Resources Management and Environment Department, 2014). As the result, the thicknesses of bio-film increase as the new organisms grow (Natural Resources Management and Environment Department, 2014). A portion of the film is removed or sloughed off from the media by separating the liquid in a secondary clarifier and the clarifier liquid is a secondary effluent (Natural Resources Management and Environment Department, 2014). To enhance the performance of the hydraulic distribution filter, part of the film is being recycled to the bio-filter (Natural Resources Management and Environment Department, 2014). 15 Rotating Biological Contactors (RBCs) Rotating biological contactors (RBCs) carries the same function with bio-filter (Natural Resources Management and Environment Department, 2014). However, the media in RBCs is a rotating dics that sinks partially into the flowing wastewater in the reactor (Natural Resources Management and Environment Department, 2014). The attachment of the bio-film from the air could supply oxygen when the film is exposed on the air or submerged in the liquid (Natural Resources Management and Environment Department, 2014). The transfer of the oxygen to the wastewater by surface turbulence can create the dics rotation (Natural Resources Management and Environment Department, 2014). Fixed Film System In fixed film system, biological growth such as biomass or slime is used to adjoin to the media which may be stone, redwood, and other durable substances that could withstand against weather (R.Spellman, n.d.). When the wastewater in contact with the slime and the media, the organisms will remove and oxidize the organic solids (R.Spellman, n.d.). The media is used to provide large open space ventilation for slime growth. Trickling filters and rotating biological contractors are under the process of fixed film devices (R.Spellman, n.d.). Suspended Growth System Suspended growth system uses a biological growth mixed with wastewater. To improve water quality, wastewater reacts with the microorganism in the surface of the water to allow the breakdown of the organisms (IHS Global Spec, 2014). 2.5 Tertiary sewage system 2.5.1 Introduction Tertiary sewage system is a chemical and biological process treatment to discharge the nutrients, toxic substances including heavy metals, suspended solids and pathogen ( Indah Water Konsortium, 2013). The processes include filtration, disinfection and tertiary ponds. However, not all countries go through tertiary treatment system, some countries stop at secondary treatment. For example, in Malaysia, the wastewater treatment systems mainly focus on the basic standard of preliminary, primary and secondary treatment ( Indah Water Konsortium, 2013). 16 2.5.2 Treatment Process Disinfection The method of disinfection involves injecting chlorine solution at the head end of the chlorine contact basin. Moreover, ozone and ultra violet irradiation can be used for disinfection but is not common. Chlorine contact basins are designed in rectangular shape channels with baffles to prevent short circuiting as well as to provide a contact time of 30 minutes. PH, contact time, organic content and effluent temperature are the other factors when disinfection takes place (Natural Resources Management and Environment Department, 2014). Figure 2.6 maturation ponds in Korba, Tunisia 2.6 Benefits of Conventional Wastewater Treatment System In general, all wastewater treatment plants play a major role to the entire population in the world. There are a few benefits of conventional wastewater treatment system such as solving the problem of insufficient water supply and protecting the environment and living beings Insufficient Water Supply Although the Earth surface is covered over 70% of water, but the real issue that is concerning the human population is the quantity of clean and fresh water available. Referring to T. Dooley (2014), out of 70% of water on Earth surface, 97.5% of it is salt water, thus leaving 2.5% as 17 fresh water. In 2.5% of fresh water, approximately 70% of that fresh water is frozen in the icecaps of Greenland and Antarctica; thus leaving the remaining present as soil moisture, or present in deep the underground aquifers as groundwater which is not accessible for human to use. Hence, there is only less than 1% of the world's fresh water (approximately 0.007% of all water on earth) is accessible for direct human consumption. This is the water found in lakes, rivers, reservoirs and those underground sources that are shallow enough to be recovered at a reasonable cost. Hence it can be said that only this amount is frequently renewed by rain and snowfall, and is therefore available on a sustainable basis. According to Soli J Arceivala and Shyam R Asolekar (2006), there are two types of reusable wastewater after treatment, reuse of urban wastewater in agriculture and horticulture from sewered areas, and reuse in industrial and commercial establishments to meet chronic water shortages in public water supplies. The reuse of urban wastewater in agriculture and horticulture are collected from sewered areas and later treated to be clean and reused for a good cause. If the water is not treated, it may improve or deteriorate the soil condition, which affects the farming activity. Besides that, the reuse of urban wastewater in industry and commerce is able to meet water shortage with a simple step of water conservation and obeying the code which mentions that the greater the extent of reuse one wants, the higher the degree of treatment will be. Hence, by conserving, the recycle process of wastewater is reduced and maintaining sufficient of water supply. Protect Environment and All Living Beings Wastewater that is not treated or treated partially would affect the aquaculture or even leading to pollution and hazard disease. Microorganisms present in the wastewater will contaminate the water source, hence resulting in killing millions of aqua creatures, and producing a strong odor which may cause the livings near the area to suffer, or human suffering from water borne diseases that may be fatal. Thus, the wastewater produced must be treated with suitable treatment methods before discharging into any water course to avoid unwanted problems to occur. 2.7 Problems with Conventional Wastewater Treatments Systems All machines, systems or methods will always have its benefits and problems. Thus, the problems associated with conventional wastewater treatment system is cost involved throughout the whole operation 18 High cost Generally, all conventional wastewater treatment systems need a high cost for construction, operating and maintenance. The initial capital costs, land purchase, engineering design and supervision charges, civil construction, interest charged on loan during, if any, during construction period. After the start-up of plant which include direct operating costs and fixed costs, such as, staff salary, fuel and electricity, transport, maintenance and repairs, and insurance. Based on Soli J Arceivala and Shyam R Asolekar (2006), it mentioned that municipal and industrial effluent treatment plants operate at a high cost. Treatment costs essentially depend on the type of wastewater to be treated, its quantity and on the treatment process used to achieve the desired quality of effluent. Studies also indicate that industrial wastewater treatment is generally more expensive than municipal wastewater due to its high chemical content that requires advance treatment processes. 2.8 Application of bio-solids and bio-effluents in Malaysia 2.8.1 Introduction In Malaysia, the average annual rainfall is 2800mm and has an estimated total surface area of 566 cubic meters which is more than enough water to supply for agriculture, domestic and industry and power sectors (Rifici, n.d.). As sludge could be easily treated with suitable methods, it should reuse in an organized way to minimize the greenhouse effect that is currently harming the environment. 2.8.2 Application Methods On 24th April 2012, Port Dickson Local Council (PLDA) agreed to use the bio-solid and bioeffluent generated from the Indah Water‟s treatment plant for landscaping purpose. These may in return help in saving cost by replacing the usage of commercial fertilizers to the bio-solid and bio- effluent in landscaping (Engku Azman Tuan Mat, n.d.). A research conducted by Agriculture University of Malaysia (UPM) shown that rubber tree with the application bio-solid has a better growth rate compared to those rubber trees which used the conventional fertilizers (Indah Water Konsortium, 2012). From the interview of “The Most Prospect Group”, mentions that plants that uses sludge fertilizers grew very quickly as sludge is rich in various nutrients (Kadir, 2013). 19 The chairman of Indah Water Konsortium, Datuk Ir Abdul Kadir Mohd Din said, “The sludge is reusable and recyclable in the form of solid, liquid and waste. The effluent can be reused in cooling system in industrial area. In domestic area, the effluent can flush toilets as well as gardening and landscaping based on the concept of sustainability through zero waste management” (Rifici, n.d.). Moreover, Indah Water Company had proposed to produce bricks using bio-solid through latest advance technology – Nanotechnology (Rifici, n.d.). As the brick quality is indicated by the sludge proportional and the firing temperature, results shows that sludge contents can decrease the brick shrinkage when firing. Through compressive tests, the strength of the brick added with 10% of sludge is similar to the normal clay bricks (Chih-Huang Weng, 2002). Chairman of Indah water had proposed to invest in renewable energy resources with bio-solid during the interview of “The Most Prospect Group” (Kadir, 2013). Methane gas is the by product from the wastewater treatment can be used as renewable energy source while reducing greenhouse effect (Rifici, n.d.). In Indah Water‟s Research and Development, they are looking forward to change sludge into coal (Kadir, 2013). 20 3. Sustainable Wastewater Treatment 3.1 Introduction Statistics have shown that there are approximately two million tons of sewage waste coming from industries and agriculture sectors being discharged into waterways and there is a minimum of 1.8 million children at the age below five that suffers from water related disease and dies (United Nations Environment Programme, 2010). Throughout the years, the word „sustainable‟ has been defined in various ways by different individuals. According to the World Commission on Environment and Development, sustainability is the ability to meet the needs of the present without affecting the ability of the future generations to meet their own needs (Evans, 2014). On the other hand, World Wide Fund for Nature defined sustainable as” improving the quality of human life while living within the carrying capacity of the Earth‟s supporting ecosystem” (Evans, 2014). Thus, sustainable wastewater treatments is needed to produce a higher quality effluent that will cause a minimum amount of damage Mother Nature without the usage of additional chemicals that may pollute the environment neither a higher usage of energy as the earth‟s resources are depleting. 3.2 Factors Affecting the Design of the Wastewater Treatment System Health and Hygiene The concerns of the public on the risk of being expose to harmful pathogens and dangerous substances that could affect their health through the sanitation system such as toilets (Women in Europe for a Common Future, 2010). Environment and Natural Resources The energy, water and other resources that are needed for the construction, maintenance and operation of the treatment system and also the potential release of gases that could harm the environment is involved in this category. Other than that, it also includes the recycling and reuse of the wastewater, biogas and bio solids (Women in Europe for a Common Future, 2010). 21 Technology and Operation The entire system must be able to function in an easy manner which includes collection, transport, treatment and re-use of final products, as well as the operation of the systems by the local authority or technicians. Besides that, whether or not the area has a vulnerability of power failures, floods, and inadequate water source (Women in Europe for a Common Future, 2010). Financial and Economic This factor relates to the issue of the capacity of households and the communities to pay for the sanitation provided which includes, construction, operations, maintenance and other required areas (Women in Europe for a Common Future, 2010). 3.3 Types of sustainable wastewater treatments The types of sustainable wastewater treatments that will be discussed in this section are Microbial Fuel Cell (MFC), Constructed Wetland Treatment and Up-Flow Anaerobic Sludge Blanket (UASB) 3.3.1 Microbial Fuel Cell 3.3.1.1 Introduction Microbial Fuel Cell (MFC) is a new approach towards the production of electricity from wastewater treatment. There is a similarity to the Chemical Fuel Cell (CFC) which is both cells convert chemical energy into electricity. The main difference between these two cells is that CFC uses elemental catalyst to speed up the process whereas MFC uses bacteria to catalyze the fuel oxidation (Satira Hambali et al., 2014). Bacteria are microorganisms that are able to convert a variety of organic compounds into useful resources (Microbial Fuel Cell, 2008). MFC is also called a bioreactor that uses catalytic reactions of various microorganisms which is put in anaerobic conditions to convert chemical energy into electricity. Microbes or microorganisms have a natural presence in the waste and will generate electrons as the digest the organic material in the sludge (Saiful Bahri Kamaruddin, 2013). It is a sustainable wastewater treatment as it addresses to the issue of bioenergy and has a minimum amount of sludge production. The reason for the reduced amount of sludge produced is because only a small fraction of energy is used up by the microorganism for growth (sludge) while a large portion is being utilized for the conversion of bioenergy (Satira Hambali et al., 2014). 22 3.3.1.2 Working Principle MFC has an anode (anaerobic chamber) and cathode (aerobic chamber) compartment separated by a Proton Exchange Membrane (PEM). At the anode compartment, microorganisms oxidize the fuel and hence producing carbon dioxide (CO2), electrons and protons. Through an external circuit, electrons are transferred to the cathode while protons are being transferred through the PEM. At the cathode compartment, electrons and protons are used up combining with oxygen to produce water (Saiful Bahri Kamaruddin, 2013). The related equations are shown below: (CH2O)n + nH2O 4e- + 4H+ + O2 nnCO2 + 4ne- + 4nH+ (Oxidation reaction at the anode) 2H2O (Reduction reaction at the cathode) The overall reaction is the degradation of the organic matter and the generation of electricity (Satira Hambali et al., 2014). Figure 3.1 The sequence of the process in the Microbial Fuel Cell Source : (Mercer, 2012) Although this waste treatment is sustainable, however there are still a few challenges to overcome. Firstly, the electricity generated is still small and hence may still be unable to supply sufficient power to the waste water treatment plant. Besides that, materials used for the MFC is costly such as Platinum which is used at the cathode and PEM (Saiful Bahri Kamaruddin, 2013). However, further researches are being conducted to increase the production of electrical power 23 such as reduced anode-cathode spacing and new separator materials (Westenhaus, 2012). A possible substitution material for platinum that is being looked into is the biocathodes that uses bacteria as a catalyst (Satira Hambali et al., 2014). 3.3.2 Constructed Wetlands 3.3.2.1 Introduction Constructed wetlands are “wastewater treatment systems that are composed of one or more treatment cells in a built and partially controlled environment designed and constructed to provide wastewater treatment” (United States Environmental Protection Agency, 2000). Wetland is considered to be one of the most biologically diverse and productive natural ecosystems. Wetlands are being constructed to treat wastewater in less dense areas as it aids in the improvement of the water quality and help save wildlife habitat. Furthermore, constructed wetlands also have a lower operating and maintaining and are able to support fluctuating water levels. In addition, constructed wetlands is a favorable choice of treating wastewater because it gives aesthetical value to the land and eliminate odors coming from the wastewater (United States Environmental Protection Agency, 2004). 3.3.2.2 Guidelines for Construction of Wetlands Treatment Certain guidelines are needed in order to construct a successful wetland. Firstly, to avoid damage to the natural wetlands and aquatic life, construction can only be carried out on uplands and outside floodplains. Secondly, the role of the wetlands must also be looked into. For example impact on water quality or adjacent land uses. Other than that, soil suitability, vegetation and existence of endangered species must also be considered before deciding the location of construction. There must also be suitable control of water that will be easy to adapt if changes in quality, depth or flow is required. Lastly, a good management plan is needed to ensure its sustainability in a long-term (United States Environmental Protection Agency, 2004). Generally, constructed wetlands provide a pretreatment for the wastewater by filtration, settling and decomposition of bacteria. The treated effluent produced should have less than 30mg/ liter of Biochemical Oxygen Demand (BOD), less than 25mg/liter Total Suspended Solids (TSS) and less than 10000cfu/100mL fecal coliform bacteria in it (Gustafon et al., 2002). 24 3.3.2.3 Types of Constructed Wetlands There are two types of constructed wetlands, named Surface Flow (SF) and Subsurface Flow (SSF). Surface Flow Wetland SF wetlands is more similar to natural wetlands from appearance as they have aquatic plants that are planted in the soil on the bottom of the wetland where the water will flow through the leaves and stems of plants (United Environmental Protection Agency, 2000). A common SF system consists of a basin or channel that is surrounded by a barrier of ponded wastewater and soil to support the roots of the vegetation‟s. This type of constructed wetland is more suitable for large community systems in mild climates (Gustafson et al., 2002). Figure 3.2 A schematic diagram of the Surface Flow Wetland Source: (Water Online, 1999) Subsurface Flow Wetland SSF wetlands has a different appearance from natural wetlands as this system does not have standing water, instead it contains a bed of crushed rocks sand or soil that has aquatic plant on top. Wastewater flows beneath the soil or crushed rocks through the roots and rhizomes of the plant; hence the wastewater is not visible to others (United Environment Protection Agency, 2000). SSF wetland is normally used for small flows of wastewater such as individual homes or small cluster of resorts (Gustafson et al., 2002). 25 Figure 3.3 The Process of a Conventional Subsurface Wastewater Infiltration System Source : (Feeney, n.d.) Figure 3.4 A schematic diagram of a subsurface wetland system Source: (Gustafon et al., 2002) SSF wetlands is normally more favourable than SF wetlands as the issue on mosquito‟s are negligible, have less ordor issues, have better thermal protection as wastewater flows beneath the soil and the soil or rock gives a bigger surface area that supports the development of microorganisms (State of Ohio Environmental Protection Agency, 2007). 3.3.2.4 Treatment Process by Constructed Wetlands After going through the septic tanks, the wastewater enters into the constructed wetlands through the distribution box. As the wastewater flow through the plants, solids are being removed by filtration and settling within the root hair of the plants. Some organic matter will also be removed but eventually it will be removed through biodegradation where bacteria consume the waste materials and hence converting them into other forms for example methane or carbon dioxide. These products produced are then used up the plants or bacteria. The biological treatment involved here may be anaerobic (septic tanks) or aerobic as wetlands are exposed to 26 the atmosphere or by “leaking” of the oxygen coming from the roots of the various aquatic plants. Some septic tanks also have active aeration component in cooperated in it for aerobic process to take place and thus fully breaking down the BOD and nitrifying the ammonium (Gustafon et al., 2002). Constructed Wetlands consists of four components, which are liner, distribution box, plants and underdrain system. Liner functions as the separator to prevent groundwater from entering the system from below (Gustafon et al., 2002). Distribution box serves as the purpose to distribute the wastewater across the wetland, either by gravity or pressure (Gustafon et al., 2002). Plants in the system are used to filter and break down organic matter. The flower must grow and flourish in the system so that the system can operate at a maximum efficiency (Gustafon et al., 2002). The underdrain system which is located the end of the wetland carries the treated effluent out of the wetland and maintains the level of the effluent below the surface of the gravel or rocks to prevent the breeding of mosquitoes (Gustafon et al., 2002). However, there are also drawbacks of using a constructed wetland system to treat wastewater. Firstly, wastewater with a high concentration of certain pollutant may not be suitable as it may not be able to filter out the pollutant. Each wetland is required to be built differently depending on the usage and climate of the community (State of Ohio Environmental Protection Agency 2007). Moreover, this system requires a large area of land for construction and hence is not appropriate for high density areas (Feeney, n.d.). 3.3.3 Up-Flow Anaerobic Sludge Blanket (UASB) 3.3.3.1 Introduction UASB reactor is an anaerobic treatment system that functions based on the break-down of organic materials through anaerobic digestion (Spuhler, 2014). Through anaerobic digestion, the UASB reactor produces methane as a biogas and forms a blanket of granular sludge that is processed by the anaerobic microorganisms (Miller, 2013). Conversion rate in UASB is higher compared to the conventional anaerobic processes because of its high biomass concentration 27 (Uemura, Harada, 2010). UASB utilizes minimum amount of energy because it neither requires mechanical mixing within the reactor nor recirculation of sludge and effluent is needed (Uemura, Harada 2010). Other than that, the biogas (methane) produced can be recovered and used as a source of energy in the treatment plant (Uemura, Harada, 2010). 3.3.3.2 Treatment Process UASB treat waste starting from the bottom of the reactor. The substrate slows rise up through the sludge bed first and later passes through the sludge blanket that is made from a biologically form of granules and particles (Karthikeyan, Kandasamy, n.a.). The microorganisms that are present in the sludge blanket will digest the organic pollutants in the wastewater. Granular sludge is formed from the maturation of suspended sludge and is vital as the bacteria present in the granules have a better efficiency rate in producing biogas (Spuhler, n.d.). Figure 3.5 The cross section of a UASB Source: (Spuhler, n.d.) 28 Figure 3.6 A Up-Flow Anaerobic Sludge Blanket used in China Source: (Tian Yue, 2010) The UASB reactor also has a 3 phase (Gas-Liquid-Solid or also known as GLS) separator situated on top of the sludge blanket to separate solid particles (sludge) apart from the gas, liquid and solid formed (Miller, 2013). Biogas that is formed is prevented from going in the settling compartment but is instead being collected in the gas collector for later usage, suspended solids settles down in the compartment while the effluent is being released for further treatment (Lier, Anand Vashi, Lubbe, Heffernan, 2010) . One of the major disadvantages of using this type of treatment to treat wastewater is the posttreatment is required before the water can be discharged as the effluent may still contain bacteria or viruses. Furthermore, a constant temperature of 15 degrees Celsius to 35 degrees Celsius is needed for the anaerobic process hence it is not suitable for cold weather countries. Highly skilled people are needed for the operation and monitoring of this system (Beddow, 2010). 29 4. Sustainable Wastewater Management 4.1 Introduction Water pollution and water scarcity have been one of the major issues discussed in today‟s world (Dr. Seetharam Chittoor Jhansi, etc., 2013). As discussed in the previous sections, water scarcity has and always been an issue in today‟s world. With the fast pace of human population growth, the source of potable water will be threaten. A sustainable wastewater treatment management is a treatment system that is energy saving, easy to operate, low in investment, operation and maintenance cost, and environmental friendly (Dr. Seetharam Chittoor Jhansi, etc, 2013). Table 4.1 The Three Main Urban-Water and Resource-Management Sustainability Goals Economy Able to achieve a financially stable state with sufficient resources to sustain infrastructures Environment Able to have a locally sustainable water supply Energy-neutral system with a minimum amount of chemical consumption An efficient nutrients management that reduces the disposal and thus protecting the aquatic environment Society Able to have easy access to clean water and suitable sanitation for all Source : (Daigger, 2008) In order to face future environmental issues in a sustainable method, wastewater must be acknowledged as an alternative source of water, energy, nutrients and other materials (The International Water Association, 2014). 4.2 Reasons of Why Countries have Unsustainable WWM One of the reasons why certain countries have unsustainable WWM is because of the commonly used centralized treatment systems. Based on Centre for Science and Environment (2013), these systems have been said to be costly, difficult to operate and failed to cater the massive amount of wastewater produced. Partially treated of untreated effluent then flows to the water body can thus causes harm to the environment. 30 Other than that, the other reason is that some developing countries utilize technologies that are the same from Western treatment systems without considering the inappropriateness no matter in culture, land and climate. In addition, different countries produces different amount of sewage. For instance, domestic wastewater in arid areas such as the Middle East has a higher concentration of oxygen demand per volume sewage compared to countries such as US and Europe (Dr. Seetharam Chittoor Jhansi, etc., 2013). 4.3 Methods to have a Sustainable Wastewater Management There are various methods to produce a sustainable wastewater management system as such using a decentralized treatment system and having proper energy management 4.3.1 Utilizing a Decentralized Treatment System Up to now, there are still many countries that use centralized wastewater treatment system. Centralized treatment systems or known as “public sewer systems”, commonly provide service for established towns and large cities. It carries the wastewater to a central location for treatment. On the other hand, decentralized treatment systems are systems that are not linked to a public treatment system. The wastewater collected from houses can either be treated onsite or to a private treatment plant (Idaho Department of Environmental Quality, 2014). Table 4.2. Comparison of centralized and decentralized wastewater treatment system Centralized Treatment System Old and taught in Differences engineering Knowledge schools High in capital cost Decentralized Treatment System New and not taught in engineering schools Capital Cost Transfers water away from source Effluent Low in capital cost Keeps water close basin Highly trained operators Skills Basic operation skills Long, disruptive construction Construction Short, less-disruptive construction Source : (Kreissl, 2009) 4.3.1.1 Benefits of Decentralized Treatment System There are many benefits of using decentralized wastewater treatment system instead of centralized treatment system. The benefits are as below: 31 Increasing Water Quality and Availability Decentralized wastewater treatment system is able to treat domestic sewage effectively and efficiently thus protecting and supporting local water supplies. Besides that, wastewater from this system maintains in the local watershed. As the wastewater returns to the drain field, it disperses into the underlying soil and later recharges the groundwater or flow back to the local watershed. The treatment level for advanced decentralized treatment systems are comparable to the centralized wastewater treatment system and at the same time keeping the amount of phosphate and nitrogen that enter into the groundwater to a minimum. In addition, more contaminants can be removed when the wastewater is discharged to the soil (United States Environmental Protection Agency 2014). Furthermore, this system can also be design to suit the community needs. For example different communities have different soil conditions, water tables, locations of stream or rivers from the community and different ecosystem (Ministry for the Environment, 2014). Using the Natural Treatment Properties of the Soil Decentralized treatment system enables wastewater to be treated by using the natural environment. Pollutants and the money spent on solving pollution can be reduced by preventing them from entering the lakes and rivers. Soil plays a role in filtering and providing the natural treatment by filtering out those harmful bacteria, viruses and nutrients (United States Environmental Protection Agency, 2014). 4.3.2 Proper Energy Management In the past, the cost of fossil fuels and electricity was relatively low and stable and thus not much attention was paid on the design and operation of the wastewater treatment system. However, with the increasing cost of energy, depleting source of fossil fuels suppliers and impacts of greenhouse gas emissions, efficient energy management is needed (Metcalf, Eddy 2014). Proper energy management is vital to take the opportunity to recover and utilize energy from sources within the treatment facilities (Metcalf, Eddy, 2014). 4.3.2.1 Factors for Energy Management The factors of achieving a more efficient energy management are to save the cost of energy and to improve energy supply reliability 32 Energy Cost Savings To operate a wastewater treatment facility, a massive amount of energy resources is required to bring about various reactions. The cost spent on operating the system comes second after labour cost. Thus energy cost can be saved by using energy efficient equipment, controlling the process for optimized energy use and selecting the suitable energy sources (Metcalf, Eddy, 2014). Reliable Supply of Energy A reliable supply of energy for treatment systems are vital as unforeseeable events for instance a major blackout of power supply. Although most of the treatment plants have emergency generators, but the power from the generators are not sufficient to operate in full scale. In reality, wastewater actually contains more energy than that needed for treatment, hence it can also be said that if all the energy in the wastewater are recovered, the treatment plants could become the net exporters of energy (Metcalf, Eddy, 2014). 4.3.2.2 Types of Energy in Wastewater Wastewater contains chemical energy and thermal energy. Energy that is contained in organic molecules is chemical energy that can be released through chemical reactions. Thermal energy is the heat retained in the wastewater (Metcalf, Eddy, 2014). Chemical Energy Wastewater contains inorganic and organic molecules which will release the chemical energy retained in the molecules when it undergoes exothermic reactions. A certain portion of the chemical energy is taken from the liquid stream in the form of sludge in preliminary and primary stage of treatment. Besides that, another part of the chemical energy is transformed into biomass and reaction products such as carbon dioxide and methane during the biology treatment. During sludge processing, methane gas can be recovered and used at a source of energy (Metcalf, Eddy, 2014). 33 Figure 4.1 shows the distribution of chemical energy in conventional wastewater treatment plant through anaerobic treatment and activated sludge treatment Source: (Metcalf, Eddy, 2014) Chemical energy that has been recovered can be utilized after transforming the wastewater constituents that contains the chemical energy into fuel. The recovering of chemical energy has been used at treatment plants by generating biogas from sludge with anaerobic sludge digestion. These biogases have been used for boilers and other combustion systems to provide energy for others. Other than that, dried biosolids can also be used a source of energy. The principal technologies used to produce electricity from the burning of gaseous fuels taken from wastewater are reciprocating engines, gas turbines and microturbines (Metcalf, Eddy, 2014). Figure 4.2 Typical processes for recovering and utilizing biogas produced by anaerobic digestion of sludge Source: (Metcalf, Eddy, 2014) 34 Figure 4.3 Typical processes for recovering of chemical energy by the combustion of sludges and biosolids Source: (Metcalf, Eddy, 2014) In addition, boilers can also be used to recover gaseous fuels. Boilers are commonly used at treatment facilities to produce hot water or steam for steam turbines, space heating and hot water supply. Heat is required at treatment plants to heat up anaerobic digester and building, and sludge pretreatment and drying. The difference between using engines or turbines and boilers to recover gaseous fuels is that gas pretreatment is not need when biogas is used for boilers (Metcalf, Eddy, 2014). Thermal Energy In wastewater, thermal energy exists in the form of temperature. Wastewater effluents, heated air or exhaust from unit processes that involves combustion of fuels are sources where thermal energy can be recovered. These excess heats can be used for heating the digester, drying up the solids, supplying hot water and warming up the space. Restoring and usage of thermal energy involves the transferring of heat energy from a heat source to a heat demand (Metcalf, Eddy, 2014). Heat can be recovered from two sources, which are combustion systems and wastewater. Exhaust heat from engine generators generates a high temperature of waste heat to produce hot water or steam. Wastewater typically has a higher temperature compared to the ambient temperature and thus can act as a reliable source of thermal energy. During warmer seasons, it 35 can be utilized as a heat sink. Due to the low availability of heat in the wastewater, a heat pump is used to recover the heat from the wastewater (Metcalf, Eddy, 2014). 4.3.3 Methods of Proper Energy Management Method of proper energy management includes minimizing the usage of energy at treatments plants and increasing the energy production at the treatment plant itself. Minimizing Usage of Energy Energy usage at treatment plants can be reduced to a minimum by making some modification and optimization to the treatment processes. For example controlling dissolved oxygen in activated sludge. This method will not only reduce power consumption but at the same time increase process performance reliability (Metcalf, Eddy, 2014). Increasing Energy Production Onsite Energy production can be increased by having a more efficient method to remove organic materials from wastewater before introducing it to the biological secondary treatment for anaerobic digestion. Research has shown that it is possible to remove a total of 70% of the total suspended solids in the primary effluent. Other than that, improving the volatile solid destruction in the anaerobic digesters is also another method to increase energy production (Metcalf, Eddy, 2014). 36 5. Case Study 5.1 Introduction Each countries produces different amount of waste, which may contain different kinds of organic or inorganic materials, and thus have different treatment facilities to treat the waste. There are certain countries that have their wastewater to undergo primary process but some do not. Hence, case study is conducted to have a better understanding on different wastewater treatment plants that are operating in different countries. In this report, there will be two case studies discussed, the first one is an Up-flow Anaerobic Sludge Blanket Reactor-Ceramic Membrane Bioreactor Plant (UASB-Ceramic MBR Plant) situated in Jurong, Singapore and the other is Eco Machine at the heart of Omega Center for Sustainable Living, Rhinebeck, New York. 5.2 UASB-Ceramic MBR Plant, Jurong, Singapore 5.2.1 Introduction “With one of the most advanced water management systems in the world, Singapore is fast becoming a global hub for water management knowledge, technology and services” (International Enterprise Singapore 2014). Singapore has been recognized for its excellent field in health, economic and education system, however one of the major issues faced is that Singapore do not have sufficient water source to meet its needs. In the past years, Singapore has been importing millions of liters of potable water from neighboring country, Malaysia through pipelines (Duerr 2013). Although there is rain all year round in Singapore, however due to limited space, additional reservoirs can‟t be built (Duerr, 2013). Hence, PUB, Singapore‟s national water agency and MEIDEN Singapore collaborated to build Singapore‟s first UASB-Ceramic MBR Plant to not only treat wastewater but also to recycle industrial used water (Water World, 2014).This treatment plant has a treatment capacity of 4550m3 approximately 1 million gallons per day (Science Direct, 2014). 5.2.2 Treatment Process UASB-Ceramic MBR Plant is the first of its kind in Singapore that merges two types of technology, named the up-flow anaerobic sludge blanket (UASB) and the ceramic membrane bioreactor (MBR) (Woo, 2014). 37 5.2.2.1 Up-Flow Anaerobic Sludge Blanket (UASB) Up-Flow Anaerobic Sludge Blanket is an anaerobic treatment process that breaks down organic matter through digestion. Further information has been discussed in section 3 of sustainable wastewater treatment. Singapore decided to use UASB in this treatment system as it is able to remove organic contaminants more efficiently compare to other conventional pretreatment systems (Science Direct, 2014). 5.2.2.2 Ceramic Membrane Bioreactor (MBR) Figure 5.1 A Flat-Sheet Ceramic MBR by MEIDEN Source: (Meidensha Corporation, 2013) UASB reactor discussed above is a pretreatment for wastewater and thus post treatment is required. Membrane bioreactor (MBR) is a combination of a filtration process such as microfiltration or ultrafiltration along with an activated sludge treatment to produce a high quality effluent (Lesjean, Judd, 2006). There are many types of MBR available in the market, however in this case study, the flat-sheet ceramic membrane is used. The flat-sheet ceramic membrane from Meiden has a precise removal of suspended solids of 0.1 μm or larger and has a good resistance towards chemicals, oil and heat. Other than that, it also has a low deterioration rate on a long-term usage and saves more energy compared to other membrane. The efficiency of the membrane filtration can be recovered by cleaning the membrane with high pressure water or suitable chemical accordingly (Meiden Water Treatment Solutions, 2009). 38 Figure 5.2 Types and sizes of suspended solid removed by the flat type ceramic MBR Source: (Meiden Water Treatment Solution, 2009) Figure 5.3 Ceramic MBR units used at the Jurong, Singapore treatment plant Source: (Woo, 2014) 39 Figure 5.4 Equalization Tanks (EQ Tanks) at the Jurong reclamation plant Source: (Woo, 2014) Figure 5.5 Aeration tank for Ceramic MBR at Jurong Source: (Woo, 2014) 40 5.2.3 Recycled Potable Water (NEWater) 5.2.3.1 Introduction UASB-Ceramic MBR Plant situated at Jurong, Singapore is able to treat and recycle wastewater up to 1 million gallons per day for industrial usage only. However, in order to produce potable water, further advance treatment is needed. NEWater is of high quality recycled water produced from treated effluents that undergoes further treatment in order to enable the water to be safe to drink. It has passed approximately one hundred thousand tests and fulfilled the World Health Organization requirements (Singapore Public Utilities Board, 2013). NEWater now meets up to 30% of Singapore‟s water requirements (Singapore Economic Development Board, 2014). 5.2.3.2 Process Involved in NEWater Microfiltration (MF) The first stage of treating the treated wastewater is through MF. Treated effluents passes across the membrane to remove or filter out suspended solids, bacteria or viruses thus only remaining dissolved solids and organic molecules (Singapore Public Utilities Board, 2013). Reverse Osmosis (RO) In this stage of treatment, a semi permeable membrane is used to only permit very small molecules for example water molecules to pass through. Hence, it further filtrate unwanted contaminants. At this stage, the water produced is considered of high quality (Singapore Public Utilities Board, 2013). Ultraviolet or UV Disinfection UV disinfection is the last stage of treatment to ensure that all harmful organisms are inactivated and thus the purity of the produced water is guaranteed (Singapore Public Utilities Board, 2013). 41 5.3 Eco Machine, Omega Center for Sustainable Living, Rhinebeck, New York 5.3.1 Introduction Eco Machine, situated at the core of the Omega Center for Sustainable Living is water filtration system that does not have an appearance of a wastewater treatment plant. The naturalinfluenced technology used by the Eco Machine is designed by Dr. John Todd, who is a pioneer in ecological design (OMEGA, 2014). Eco Machine is a water reclamation system that uses plants, bacteria, algae and fungi to recycle the wastewater. In other words, Eco Machine is a constructed wetland. It is able to treat up till 5 million gallons of wastewater per year (BNIM, 2010). Treated water will be returned to the large aquifer deep below the campus (OMEGA, 2014). The whole building operates based on solar and geothermal power only and hence no additional energy is needed for operation. Other than that, Omega Center for Sustainable Living also serves as a learning place to educate people on the power of nature (Tackett, 2013). Figure 5.6 The Outside appearance of the Eco Machine. Source: (Tackett, 2013) 42 Figure 5.7 People visiting Omega Center for Sustainable Living Source: (Tackett, 2013) 5.3.2 Treatment Process Wastewater from the campus is collected and conveyed into two equalization tanks (EQ tanks) so that the system is able to consistently know the range of the water flow as it depends on the people in the campus. The wastewater from the EQ tanks is then put through the treatment processes (John Todd Ecological Design, 2012). There are a few stages involved which are septic tanks, equalization and anoxic tanks, constructed wetlands, treatment lagoons and recirculating sand filter. Stage one (Septic Tanks) Initially, all the wastewater from the EQ tanks is distributed into two huge septic tanks. Organic matters are being break down in the septic tanks through anaerobic process. The suspended solids in the tanks are digested and settle to the bottom of the tanks (John Todd Ecological Design, 2012). Stage two (Equalization and Anoxic Tanks) Effluent from the septic tanks flows into two equalization tanks where additional separation of water and solid takes place. Since the inflow wastewater is not balanced due to the number of occupants, the EQ tanks will evenly distribute the wastewater to the anoxic tanks over a 24-hour 43 cycle. In the anoxic tanks, nitrates and phosphate is removed and the partially treated wastewater flow to the splitter where it is further distributed to four constructed wetlands (John Todd Ecological Design, 2012). Stage three (Constructed Wetlands) A total of four wetlands are constructed by Omega. “Native loving plants” which are recognized for their ability to aid in treating wastewater are used at the wetlands. Oxygen is contributed by the roots of the plants to the water. The roots of the plants also serve a purpose of supplying a surface area for the bacterial processes to metabolize the nutrients present in the wastewater. Through this process, ammonia is converted into nitrates. These nitrates are then converted into nitrogen gas which is not harmful to the environment (John Todd Ecological Design, 2012). Stage 4 (Treatment Lagoons) Treatment lagoons contain plants, fungi, algae, snails, and bacteria to further clean the water. On the other hand, these living organisms use the nutrient coming from the water to grow and thrive (Solaripedia, 2009). Stage 5 (Sand Filtration) The water is then further cleaned though sand filtration. Microorganisms that are living or attached to the sand grain traps the solids or consumes the organic compound. At this stage, the water has achieved a high quality state that is able to be reused for non-potable usage (John Todd Ecological Design, 2012). Stage 6 (Dispersal Field) The treated effluent is then returned to the underground aquifer through the soil. The purified water is able to be used for usage such as toilet flushing in the campus (John Todd Ecological Design, 2012). 44 Septic tanks Subsurface Dispersal Constructed Wetlands Aerated Lagoons Sand Filter Figure 5.8 The plan view of the Omega Center for Sustainable Living and the location of the treatment processes Source: (The Omega Center for Sustainable Living, 2007) 45 6. Recommendations for Future Improvement of Wastewater Treatment Processes 6.1 Introduction In the recent years, many scientist and researchers have been developing innovative ways to provide the world with various alternatives to treat wastewater efficiently without harming the environment. The main objective is to recover excess energy that is stored in other sources and to minimize the energy usage by undergoing different biological processes (Metcalf, Eddy, 2014). 6.2 Methods of Improvements Recovering Excess Energy Contained in Various Sources Normal conventional primary clarification obtains approximately 50% of total suspended solids (TTS) and 30%-40% of chemical oxygen demand (COD). TTS and COD that have not been removed in the primary treatment process will undergo the secondary process for further treatment. If there is a method to remove all of the particulate COD before the biological treatment, more energy could be recovered. One of the methods that could be used is the Primary Effluent filtration (PEF). Thus, with a combination of PEF and primary sedimentation, approximately 90% of TTS and 60 % of COD could be removed (Metcalf, Eddy, 2014). Minimizing the Usage of Energy by Using Different Biological Processes Currently, there are various upcoming biological processes that are being looked further into for their potential in saving energy and chemical consumption, for example the removal of nitrogen. A new process called partial nitritation and deammonification can be utilized to reduce 60% of oxygen demand as well and reduces 90% of its demand for external carbon sources compared to the conventional nitrification and denitrification (Metcalf, Eddy, 2014). Anaerobic Baffled Reactor can be used to improve the treatment for wastewater. It is capable to remove heavy sediment solids; consequently carryover wastewater will have lower chemical oxygen demand level before going to next step of processes. A common construction of Anaerobic Baffled Reactor includes different compartments with various outlet levels and series of baffles plates so that heavy solids have no chance of escaping. Basically, it is an enhanced septic tank which aims to boost up the removal efficiency and dissolved solids. Furthermore, it uses a series of baffles to force the wastewater to flow under and over the baffles as it passes from the inlet to the outlet. In addition, anaerobic treatment processes consume less energy and 46 produce less sludge, consequently lead to lower operational costs compared to aerobic processes. Although Anaerobic Baffled Reactor treatment is beneficial, but both remaining sludge and effluents still need further treatment in order to be reused or discharged properly. Figure 6.1 The Cross Section of an ABR According to MOREL & DIENER (2006), anaerobic baffled reactors are based on a physical treatment and a biological treatment. One of the advantages of using this system is that it generally requires low level of maintenance because basically there are no mechanical moving parts and the baffles position is already fixed without needing further renovation. However, when the sludge accumulation starts to increase and eventually build up to spill over to another section. Therefore, it needs auto desludging system to prevent waste from carryover to the corresponding compartment. Another major advantage of using anaerobic baffled reactor is that energy usage and consumption will be at minimal level. The only requirement is to drive the pump to transfer wastewater to a higher level elevated tank which then feeds by gravitational force going to the reactor. Some of the anaerobic baffled reactor had hybrid systems which increase the treatment efficiency. The figure below show had a reactor contains two baffled up-flow and two anaerobic filter chambers after an initial settling tank. Anaerobic treatment in the pond enhances the 47 microbial quality of the effluent (SASSE, 1998) Figure 6.2 Cross section of a hybrid baffled septic tank with clarifier Other methods to reduce the energy usage are anaerobic treatment at ambient temperature and membrane-absorption process. Anaerobic processes utilized less energy compared to aerobic processes as they do not need aeration for the removal of biodegradable chemical oxygen demand and also produce biogas that can be used for energy production. On the other hand, membrane-absorption process is a process that will not need biological treatment to treat wastewater. Wastewater that has been filtered will further undergo a series of different membranes and residual organic matter that passes through the membrane will be absorbed (Metcalf, Eddy, 2014). 48 7. Conclusion In conclusion, the process of acquiring recycled and reusable water has to be well-developed and planned. In order to obtain the recycled water efficiently, a R&D (research and development) department is an essential. Wastewater treatment plants are changing and also different from a country to another as different countries have different needs as discussed in the previous section. Thus, the researchers must keep on developing new techniques or a better way to obtain a higher quality effluent that is able to be reused. In such ways, new processes may save more energy, time and resources, and prevent pollution, which then is available for others to use it immediately. 49 8. 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