2011-10-21 Page 1 / 3 GPS Safety Summary Formaldehyde GPS Safety Summary SUBSTANCE NAME Formaldehyde GENERAL STATEMENT The environmental effects, ecotoxicology and toxicology information available for this chemical is provided based on studies and/or a reliable evaluation of its hazardous properties. See Health and Environmental Effects. This chemical should not enter surface water, groundwater water and soil. See Risk Management Recommendations. CHEMICAL IDENTITY Name Product names Chemical name (IUPAC) CAS number EC number Synonyms Formaldehyde Formaldehyde Methanal; Methyl Aldehyde 50-00-0 200-001-8 Methylene Oxide; Formalin; Methaldehyde USES AND APPLICATION Formaldehyde is used in the production of fertilizer, paper, plywood, and urea-formaldehyde resins. It is also used as a preservative in some foods and in many products used around the house, such as antiseptics, medicines, and cosmetics. PHYSICAL / CHEMICAL PROPERTIES Formaldehyde is a colorless gas at standard temperature and pressure. It has a characteristic, unpleasant odor. It is extremely flammable. Property Value Density 10 kg/cm3 Melting / Boiling point -1170°C/ -19.3°C Explosive Properties May form explosive gas-air mixtures Explosive Limits, Volume % in Air LEL: 7 % vol; UEL: 73% vol Auto-ignition temperature 430°C Relative vapour density 1.08 Molecular weight 30.03 Flashpoint Not applicable. Flammable Gas. HEALTH EFFECTS Low levels of formaldehyde can cause irritation of the eyes, nose, throat, and skin. Higher levels may cause tearing, blurred vision or burning sensations. Formaldehyde is highly toxic by inhalation. It is possible that people with asthma may be more sensitive to the effects of inhaled formaldehyde. Inhalation may cause lung oedema, an effect which may not be immediately apparent. Formaldehyde is toxic if ingested or absorbed through the skin. Drinking large amounts of formaldehyde can cause severe pain, vomiting, coma, and possible death. Chronic exposure to formaldehyde may cause cancer. Effect Assessment Result Acute toxicity (oral, dermal and inhalation) Toxic by inhalation, ingestion by skin absorption. Eye / Skin irritation Severely irritating – may cause irreversible damage to eyes /Irritating to skin Sensitization May cause sensitization Toxicity after repeated exposure Repeated exposure consistent with acute oral, dermal and inhalation toxicity Genotoxicity / mutagenicity No data available 2011-10-21 Page 2 / 3 GPS Safety Summary Formaldehyde Carcinogenicity Toxicity for reproduction Suspected human carcinogen No data available ENVIRONMENTAL EFFECTS Formaldehyde dissolves easily but does not last a long time in water. Most formaldehyde in the air breaks down during the day. The breakdown products of formaldehyde are formic acid and carbon monoxide. Formaldehyde does not build up in plants and animals. Effect Assessment Result Aquatic toxicity No data available. Fate and Behaviour Biodegradation Bioaccumulation potential PBT / vPvB conclusion Result No data available. No data available. No data available. EXPOSURE Human health Smog is a major source of formaldehyde exposure. Cigarettes and other tobacco products, gas cookers, and open fireplaces are sources of formaldehyde exposure. It is used in many industries and in hospitals and laboratories. Formaldehyde is given off as a gas from the manufactured wood products used in new mobile homes. The amount of formaldehyde in foods is very small. Household sources, such as fiberglass, carpets, permanent press fabrics, paper products, and some househould cleaners. Normal industrial practices assure limited workplace exposures. These practices include handling with good ventilation. All workers are trained in the properties and safe practices of using chemicals including using personal protective clothing. Environment Care should be taken to ensure that formaldehyde is not released to the environment. RISK MANAGEMENT RECOMMENDATIONS When using chemicals make sure that there is adequate ventilation. Always use appropriate chemical resistant gloves to protect your hands and skin and always wear eye protection such as chemical goggles. Do not eat, drink, or smoke where chemicals are handled, processed or stored. All releases that may include the substance must be directed to a wastewater treatment plant that removes the substance from the final releases to the receiving water. Releases to air are not expected and therefore no specific recommendations are required. STATE AGENCY REVIEW • EU-GHS Regulation (EU) No. 1272/2008 • EU-Risk Assessment (Regulation 793/93) • IPCS International Chemical Safety Card REGULATORY INFORMATION / CLASSIFICATION AND LABELING GHS-Labeling Statutory basis EU-GHS as per Regulation (EU) No. 1272/2008 Symbol(s) Signal word Danger H301: Toxic if swallowed. H311: Toxic in contact with skin. 2011-10-21 Page 3 / 3 GPS Safety Summary Formaldehyde H314: Causes severe skin burns and eye damage. H317: May cause an allergic skin reaction. H331: Toxic if inhaled. H351: Suspected of causing cancer. CONTACT INFORMATION WITHIN COMPANY Email address USA product.regulatory.services@evonik.com GLOSSARY Acute toxicity Biodegradable Bioaccumulation Carcinogenicity Chronic toxicity GHS Mutagenicity Reprotoxicity Sensitizing Teratogenic harmful effects after a single exposure breakdown of materials by a physiological environment accumulation of substances in the environment effects causing cancer harmful effects after repeated exposures Global Harmonized System on Classification and Labelling effects that change genes combining teratogenicity, embryo toxicity and harmful effects on fertility allergenic effects on fetal morphology DATE OF ISSUE 2011-10-21 New Disclaimer: This GPS Safety Summary is based on Evonik´s present knowledge and experience as of the date of issue. However, it implies no liability or other legal responsibility on the part of Evonik, including with regards to existing third party intellectual property rights, especially patent rights. In no event shall Evonik be responsible for damages of any nature whatsoever resulting from the use of or reliance upon the information herein or the chemical to which that information refers. In particular, no warranty, whether express or implied, or guarantee in the legal sense is intended or implied by Evonik. This GPS Safety Summary is only intended to provide general information about the chemical referred to herein but not any in-depth health and safety information. The information in this GPS Safety Summary is supplied on the condition that the persons receiving the same will make their own determination as to its suitability for their purposes prior to use. This GPS Safety Summary does not supersede or replace required regulatory and/or legal communication documents. Performance of the chemical described herein should be verified by testing which should be carried out only by qualified experts. Evonik reserves the right to make any changes to this GPS Safety Summary in accordance with technological progress or further developments. Reference to trade names used by other companies is neither a recommendation, nor does it imply, that similar products could not be used.