1. In a Lewis structure, what do the dots represent? 2. Draw the Lewis structure of the bromine atom. 3. How many dots are shown in the Lewis structure for the sulfur atom? 4. What are the two principal types of bonding called? 5. Name the two classes of element which are most likely to form an ionic compound if they are allowed to react with each other. 6. Draw the Lewis structure of the Pb2+ ion. 7. What constitutes a covalent bond between two atoms? 8. In what way is a polar covalent bond similar to a nonpolar covalent bond? In what way are they different? 9. What does it mean if an atom is said to have a high electronegativity? 10. The elements with the lowest electronegativities are found in the _______ _______ region of the periodic table. 11. Who first assigned electronegativity values to many of the elements? 12. What do we call the three-dimensional arrangement of positive and negative ions in an ionic solid? 13. Predict the formula of the compound formed when ions of sodium and sulfur combine. 14. Predict the formula of the compound formed when ions of barium and nitrogen combine. 15. What is the name of Fe2+ in the Stock system? 16. What does the suffix "-ous" on the common names of ions mean? 17. What is the term used for ions that are composed of two or more atoms bonded together? 18. What is the formula of the sulfate ion? 19. What is the name of the ion HCO3-? 20. What is the name of the ion NH4+? 21. Provide the name of Na3PO4. 22. What is the name of Cu2O in the Stock system? 23. Write the formula of sodium carbonate. 24. What kind of compound results when two or more different nonmetals share electrons? 25. What kind of bonding exists in substances which consist of discrete molecules? Page 1 26. Provide the formula of sulfur trioxide. 27. Write the formula of ammonia. 28. Provide the name of CCl4. 29. Provide the name of the compound whose formula is N2O5. 30. At what temperature is a liquid converted into a gas? 31. What is the term that describes a solid with no regular structure? 32. What is the term that describes a compound that, when dissolved in water conducts an electric current? 33. What is the term that describes a compound that, when dissolved in water does not conduct an electric current? 34. What kind of bonding is present in substances which are nonelectrolytes? 35. How many bonding electrons are shown in the Lewis structure for the bicarbonate ion, HCO3-? 36. Draw the Lewis structure of methylamine, CH3NH2. 37. Draw the Lewis structure of hydrogen sulfide, H2S. 38. What is wrong with the Lewis structure shown below for sulfur trioxide, SO3? O O S O 39. Ozone, O3, has two resonance forms. Draw them, given the skeletal arrangement O-O-O 40. What is defined as the amount of energy needed to break a bond holding two atoms together? 41. What is defined as the distance of separation of two nuclei in a covalent bond? 42. What do the letters VSEPR stand for? 43. If the shape of a molecule is trigonal planar, what are the values of the bond angles? 44. In the molecule AX2, the central atom A has two lone pairs of electrons in addition to the two bond pairs in the A-X bonds. What is the shape of this molecule? 45. The ammonia molecule, NH3, is polar. Why does this fact suggest that its shape is trigonal pyramidal, rather than trigonal planar? Page 2 46. Which of the following Lewis structures of neutral atoms is correct? A. 47. K Ba Al Sn O A B C D E + A A. 2+ Sn B A 2+ N C B. B - 3- I D C. E D. C D E. E H B. Cl C. D. O F E. Na Si B. P C. D. Cl Ar E. Br B. D. intermolecular nonpolar covalent ionic polar covalent The atoms lose electrons in forming ions. The elements are metals. They are located to the left of the periodic table. They have low ionization energies. They have high electron affinities. Assuming reactions between the following pairs of elements, which pair is most likely to form an ionic compound? A. B. C. D. E. 53. Ca Which one of the following is NOT true about elements that form cations? A. B. C. D. E. 52. E In the compound CH3Cl the bond between carbon and chlorine is A. C. 51. E. D Which of the following has the greatest electronegativity? A. 50. D. C Which of the following has the greatest electronegativity? A. 49. C. B Which of the following Lewis structures of ions is incorrect? Na 48. B. A copper and tin chlorine and oxygen cesium and iodine carbon and chlorine fluorine and iodine What kind of bond results when electron transfer occurs between atoms of two different elements? A. B. C. D. E. ionic covalent nonpolar single double Page 3 54. What is the old name of Cu+? A. B. C. D. E. 55. Give the name of FeSO4 in the Stock system. A. B. C. D. E. 56. C. D. E. PCl B. PCl3 C. PCl5 D. P2Cl5 E. P5Cl What term describes the temperature at which a solid is converted into a liquid? A. B. C. D. E. 60. is longer than a single bond between the same two atoms has a lower bond energy than a single bond between the same two atoms arises when two electrons are transferred from A to B consists of two electrons shared between A and B consists of four electrons shared between A and B What is the correct formula of phosphorus pentachloride? A. 59. lithium and iodine sodium and oxygen calcium and chlorine copper and tin carbon and oxygen A double bond between two atoms, A and B A. B. 58. iron monosulfuric acid iron(II) sulfate iron(III) sulfate ferrous sulfate ferric sulfate Assuming reactions between the following pairs of elements, which pair is most likely to form a covalent compound? A. B. C. D. E. 57. cupric ion cuprous ion copper(I) ion copper(II) ion ferrous ion critical point flash point sublimation point melting point boiling point What term describes a solution of a compound in water that conducts an electric current? A. B. C. D. E. amorphous solution an electrolyte solution a nonelectrolyte solution superconducting solution isoelectric solution Page 4 61. How many bonding electrons are in CO2? A. 62. 2 C. 3 D. 4 E. 8 0 B. 1 C. 2 D. 3 E. 8 D. 12 E. 16 How many valence electrons are in SO42-? A. 64. B. How many nonbonding electrons are in CH4? A. 63. 1 2 B. 64 C. 32 According to VSEPR theory, if the valence electrons on a central atom are 3 bond pairs and one nonbonding (lone) pair, the geometry (shape) at this atom will be A. B. C. D. E. linear bent (angular) trigonal planar trigonal pyramidal tetrahedral 65. T F In Lewis structures, the chemical symbol of an element represents both the nucleus and the lower energy (nonvalence) electrons. 66. T F The name of SnO2 is tin(I) oxide. 67. T F The old name of iron(III) chloride is ferrous chloride. 68. T F The are three atoms of iodine represented in the formula NaIO3. 69. T F In solid NaCl, no molecules of NaCl exist. 70. T F Ionic solids are amorphous. 71. T F Molecular compounds usually involve ionic bonding. 72. T F As a rule, ionic compounds tend to have lower melting and boiling points than covalent compounds consisting of small molecules. 73. T F In the water molecule, the oxygen atom is an exception to the octet rule. 74. T F The NO2 molecule can never satisfy the octet rule. 75. T F Six electrons shared between two atoms corresponds to a bond order of three. 76. T F Resonance occurs when two or more different, valid Lewis structures can be drawn for a molecule+. 77. T F The existence of resonance makes a molecule less stable than would otherwise be the case. 78. T F Because the C-H bond in methane is polar, the CH4 molecule will also be polar. 79. T F Chemical bonds are intramolecular forces. Page 5 80. T F In determining properties such as solubility, melting point and boiling point, intramolecular forces are more important than intermolecular forces. 81. T F As a rule, a polar substance will be a good solvent for nonpolar solutes, and vice versa. Page 6 Answer Key for Test "chapter4.tst", 8/17/04 No. in No. on Q-Bank Test Correct Answer 4 1 1 valence electrons 4 2 2 Br 4 4 4 4 3 4 5 6 4 4 7 8 4 9 4 4 4 4 4 4 4 4 4 10 11 12 13 14 15 16 17 18 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 3 4 5 6 six ionic bonding and covalent bonding metal, nonmetal Pb 2 a shared pair of electrons 7 8 In each case, the bond consists of an electron pair shared between the bonded atoms. The difference is that the sharing is unequal in the case of the polar covalent bond, equal in a nonpolar covalent bond. The atom has a strong attraction for shared electron pairs 9 (electrons in covalent bonds). bottom left 10 Pauling 11 crystal lattice 12 Na2S 13 14 Ba3N2 15 iron(II) ion 16 lower positive charge 17 polyatomic 18 SO42hydrogen carbonate 19 ammonium 20 sodium phosphate 21 copper(I) oxide 22 Na2CO3 23 covalent 24 Covalent 25 SO3 26 NH3 27 carbon tetrachloride 28 dinitrogen pentoxide 29 boiling point 30 amorphous 31 electrolyte 32 nonelectrolyte 33 covalent 34 ten 35 H H 36 H 4 37 37 4 38 38 H C N H H S H Page 1 Answer Key for Test "chapter4.tst", 8/17/04 No. in No. on Q-Bank Test Correct Answer The structure shows 26 valence electrons, but there should only be 24. 4 39 39 O 4 4 4 4 4 4 40 41 42 43 44 45 40 41 42 43 44 45 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 O O O O O bond energy bond length Valence Shell Electron Pair Repulsion 120° bent or angular If the molecule were trigonal planar, the symmetry would result in a nonpolar molecule. The centers of positive and negative charge would coincide. C C D C D E C A B B E E C D B E A C D T F F F T F F F F T T T F F T F F Page 2