What You’ll Learn • You will be able to distinguish among electric conductors, semiconductors, and insulators. • You will examine how pure semiconductors are modified to produce desired electric properties. • You will compare diodes and transistors. Why It’s Important Semiconductors have electric properties that allow them to act as oneway conductors to amplify weak signals in many common electronic devices. Fast Math Computers and electronic devices use the controlled movement of electrons and holes in semiconductors to do quick calculations and logical operations. Think About This A silicon microchip might be small, but it may contain the equivalent of millions of resistors, diodes, and transistors. How can this level of complexity be produced in such a tiny structure? physicspp.com 774 How can you show conduction in a diode? Question Which way does a two-color light-emitting diode (LED) conduct? Procedure 1. Obtain a bi-color (red-green) LED and a 9- to 12-V AC power supply or transformer. 2. Wire a 100-Ω resistor and the LED in series with the AC source. 3. Be careful when plugging in the AC source so you are not shocked. Do not touch the resistor as it may become hot. Plug the AC source into a GFCI receptacle. 4. Record your observations of the LED. 5. Hold a stroboscopic disk in front of the LED and spin it. Record your observations of the LED as viewed through the disk. viewed through the stroboscopic disk? Critical Thinking Suggest a possible explanation for your observations. Analysis What color was the LED after you plugged in the power supply? What color was the LED as 29.1 Conduction in Solids E lectronic devices depend not only on natural conductors and insulators, but also on materials that have been designed and produced by scientists and engineers working together. This brief investigation into electronics begins with a study of how materials conduct electricity. All electronic devices owe their origins to the vacuum tubes of the early 1900s. In vacuum tubes, electron beams flow through space to amplify and control faint electric signals. Vacuum tubes are big, require lots of electric power, and generate considerable heat. They have heated filaments, which require the replacement of the tubes after one to five years. In the late 1940s, solid-state devices were invented that could do the jobs of vacuum tubes. These devices are made of materials, such as silicon and germanium, known as semiconductors. The devices amplify and control very weak electric signals through the movement of electrons within a tiny crystalline space. Because very few electrons flow in them and they have no filaments, devices made from semiconductors operate with a low power input. They are very small, don’t generate much heat, and are inexpensive to manufacture. The estimated useful life of these devices is 20 years or more. Objectives • Describe electron motion in conductors and semiconductors. • Compare and contrast n-type and p-type semiconductors. Vocabulary semiconductors band theory intrinsic semiconductors dopants extrinsic semiconductors Section 29.1 Conduction in Solids 775 Horizons Companies Band Theory of Solids You have learned about electric conductors and insulators. In conductors, electric charges can move easily, but not in insulators. When you examine these two types of materials at the atomic level, the difference in the way they are able to carry charges becomes apparent. You learned in Chapter 13 that crystalline solids consist of atoms bound together in regular arrangements. You also know from Chapters 27 and 28 that an atom consists of a dense, positively charged nucleus surrounded by a cloud of negatively charged electrons. These electrons can occupy only certain allowed energy levels. Under most conditions, the electrons in an atom occupy the lowest possible energy levels. This condition is referred to as the ground state. Because the electrons can have only certain energies, any energy changes that occur are quantized; that is, the energy changes occur in specific amounts. Carbon Silicon Energy ■ Figure 29-1 Energy levels of an atom are split apart when other atoms are brought closer, resulting in an energy gap between the valence and conduction bands. Energy bands Suppose you could construct a solid by assembling atoms together, one by one. You would start with an atom in the ground state. At large interatomic spacings ( 0.8 nm) with no very near neighbors, the graph in Figure 29-1 shows two discrete energy levels for the atom. As the solid crystal forms by moving atoms closer to the atom, the electric fields of these other neighboring atoms affect the energy levels of its electrons. In the solid crystal, the result is that the ground state energy levels in each atom are split into multiple levels by the electric fields of all of its neighbors. There are so many of these levels, and they are so close together, that they no longer appear as distinct levels, but as the energy bands shown in Figure 29-1. The lower energy or valence bands are occupied by bonding electrons in the crystal, and the higher energy or conduction bands are available for electrons to move from atom to atom. Notice in Figure 29-1 that the atomic separations for crystalline silicon and crystalline carbon (diamond) translate to valence bands and conduction bands that are separated by energy gaps. These gaps have no energy levels available for electrons. They are called forbidden energy regions. This description of valence and conduction bands, separated by forbidden energy gaps, is known as the band theory of solids and can be used to better understand electric conduction. For example, the band diagram in Conduction band C Si Conduction band E 5.5 eV E 1.1 eV Valence band Valence band 0.2 0.4 0.6 0.8 Atomic separation (nm) 776 Chapter 29 Solid-State Electronics ■ Figure 29-2 In a material that is a good conductor, the conduction band is partially filled. The blueshaded area shows energies occupied by electrons. Conductor Conduction band Energy Figure 29-1 suggests that a lot more energy will be required to move valence electrons from the valence band to the conduction band in the case of crystalline carbon (diamond structure) compared to silicon. Carbon in graphite form is a much better conductor because the structure of the atom arrangement in graphite gives it a smaller energy gap than that of diamond. Crystalline silicon has a smaller energy gap than diamond does. At absolute zero, the valence band of silicon would be completely full and the conduction band would be completely empty. At room temperature, some number of valence electrons have enough thermal energy to jump the 1.1-eV gap to the conduction band and serve as charge carriers. As the temperature increases and more electrons gain enough energy to jump the gap, the conductivity of silicon will increase. Germanium has an energy gap of 0.7 eV, which is smaller than that of silicon. This means that germanium is a better conductor than silicon at any given temperature. However, it also means that germanium is too sensitive to heat for many electronic applications. Relatively small changes in temperature cause large changes in the conductivity of germanium, making control and stability of circuits troublesome. Lead has an interatomic spacing of 0.27 nm. Figure 29-1 shows that this would translate to a band-gap diagram in which the conduction band overlaps the valence band. One would, therefore, expect lead to be a good conductor, and it is. Materials with overlapping, partially filled bands are conductors, as indicated in Figure 29-2. Valence band Conductors When a potential difference is placed across a material, the resulting electric field exerts a force on the electrons. The electrons accelerate and gain energy and the field does work on them. If there are bands within the material that are only partially filled, then there are energy levels available that are only slightly higher than the electrons’ ground state levels. As a result, the electrons that gain energy from the field can move from one atom to the next. Such movement of electrons from one atom to the next is an electric current, and the entire process is known as electric conduction. Materials with partially filled bands, such as the metals aluminum, lead, and copper, conduct electricity easily. Random motion The free electrons in conductors move about rapidly in a random way, changing directions when they collide with the cores of the atoms. However, if an electric field is put across a length of wire, there will be a net force pushing the electrons in one direction. Although their motion is not greatly affected, they have a slow overall movement dictated by the electric field, as shown in Figure 29-3. Electrons continue to move rapidly with speeds of 106 m/s in random directions, and they drift very slowly at speeds of 105 m/s or slower toward the positive end of the wire. This model of conductors is called the electron-gas model. If the temperature is increased, the speeds of the electrons increase, and, consequently, they collide more frequently with atomic cores. Thus, as the temperature rises, the conductivity of metals is reduced. Conductivity is the reciprocal of resistivity. As conductivity is reduced, a material’s resistance rises. V ■ Figure 29-3 The electrons move rapidly and randomly in a conductor. If a field is applied across the wire, the electrons drift toward one end. Electron flow is opposite in direction to conventional current. Section 29.1 Conduction in Solids 777 The Free-Electron Density of a Conductor How many free electrons exist in a cubic centimeter of copper? Each atom contributes one electron. The density, atomic mass, and number of atoms per mole of copper can be found in Appendix D. 1 Cu Cu e Analyze the Problem Cu e e • Identify the knowns using Appendix D. 2 Cu Known: Unknown: For copper: 1 free e per atom 8.96 g/cm3 M 63.54 g/mol NA 6.021023 atoms/mol free e/cm3 ? Cu e Cu e Cu e Solve for the Unknown Cu e Cu e e 1 free e (free e) (NA ) ( ) M cm3 atom ( ) e 8.96 g 1 mol 1 free 6.021023 atoms 3 ( 1 atom )( 1 mol )( 63.54 g 8.491022 free e/cm3 in copper 3 )( 1 cm ) Substitute free e/1 atom 1 free e/1 atom, NA 6.021023 atoms/mol, M 63.54 g/mol, 8.96 g/cm3 Evaluate the Answer • Are the units correct? Dimensional analysis on the units confirms the number of free electrons per cubic centimeter. • Is the magnitude realistic? One would expect a large number of electrons in a cubic centimeter. Math Handbook Dimensional Calculations pages 846—847 1. Zinc, with a density of 7.13 g/cm3 and an atomic mass of 65.37 g/mol, has two free electrons per atom. How many free electrons are there in each cubic centimeter of zinc? 2. Silver has 1 free electron per atom. Use Appendix D and determine the number of free electrons in 1 cm3 of silver. 3. Gold has 1 free electron per atom. Use Appendix D and determine the number of free electrons in 1 cm3 of gold. 4. Aluminum has 3 free electrons per atom. Use Appendix D and determine the number of free electrons in 1 cm3 of aluminum. 5. The tip of the Washington Monument was made of 2835 g of aluminum because it was a rare and costly metal in the 1800s. Use problem 4 and determine the number of free electrons in the tip of the Washington Monument. Insulators In an insulating material, the valence band is filled to capacity and the conduction band is empty. As shown in Figure 29-4, an electron must gain a large amount of energy to go to the next energy level. In an insulator, the lowest energy level in the conduction band is 5–10 eV above the highest energy level in the valence band, as shown in Figure 29-4a. There is at least a 5-eV gap of energies that no electrons can possess. 778 Chapter 29 Solid-State Electronics Although electrons have some kinetic energy as a result of their thermal energy, the average kinetic energy of electrons at room temperature is not sufficient for them to jump the forbidden gap. If a small electric field is placed across an insulator, almost no electrons gain enough energy to reach the conduction band, so there is no current. Electrons in an insulator must be given a large amount of energy to be pulled into the conduction band. As a result, the electrons in an insulator tend to remain in place, and the material does not conduct electricity. a Insulator Conduction band E 5 eV Forbidden gap Valence band Semiconductors Electrons can move more freely in semiconductors than in insulators, but not as easily as in conductors. As shown in Figure 29-4b, the energy gap between the valence band and the conduction band is approximately 1 eV. How does the structure of a semiconductor explain its electronic characteristics? Atoms of the most common semiconductors, silicon (Si) and germanium (Ge), each have four valence electrons. These four electrons are involved in binding the atoms together into the solid crystal. The valence electrons form a filled band, as in an insulator, but the forbidden gap between the valence and conduction bands is much smaller than in an insulator. Not much energy is needed to pull one of the electrons from a silicon atom and put it into the conduction band, as illustrated in Figure 29-5a. Indeed, the gap is so small that some electrons reach the conduction band as a result of their thermal kinetic energy alone. That is, the random motion of atoms and electrons gives some electrons enough energy to break free of their home atoms and wander around the silicon crystal. If an electric field is applied to a semiconductor, electrons in the conduction band move through the solid according to the direction of the applied electric field. In contrast to the effect in a metal, the higher the temperature of a semiconductor, the more able electrons are to reach the conduction band, and the higher the conductivity. An atom from which an electron has broken free is said to contain a hole. As shown in Figure 29-5b, a hole is an empty energy level in the valence band. The atom now has a net positive charge. An electron from the conduction band can jump into this hole and become bound to an atom once again. When a hole and a free electron recombine, their opposite charges neutralize each other. b Semiconductor Conduction band E 1 eV Forbidden gap Valence band ■ Figure 29-4 Compare the valence and conduction bands in an insulator (a) and in a semiconductor (b). Compare these diagrams with the one shown in Figure 29-2. ■ Figure 29-5 Some electrons in semiconductors have enough thermal kinetic energy to break free and wander through the crystal, as shown in the crystal structure (a) and in the bands (b). a b e Atom core Conduction band e Electron Hole e Free electron Hole Valence band Section 29.1 Conduction in Solids 779 The electron, however, has left behind a hole at its previous location. Thus, as in a game of musical chairs, the negatively charged, free electrons move in one direction and the positively charged holes move in the opposite direction. Pure semiconductors that conduct as a result of thermally freed electrons and holes are called intrinsic semiconductors. Because so few electrons or holes are available to carry charge, conduction in intrinsic semiconductors is very low, making their resistances very high. Fraction of Free Electrons in an Intrinsic Semiconductor Because of the thermal kinetic energy of solid silicon at room temperature, there are 1.451010 free electrons/cm3. What is the number of free electrons per atom of silicon at room temperature? 1 Si Si Si Atom core Electron e Analyze the Problem • Identify the knowns and unknowns. Known: 2.33 g/cm3 Si Si Si Si Si Si Unknown: Hole free e/atom of Si ? M 28.09 g/mol NA 6.021023 atoms/mol For Si: 1.451010 free e/cm3 2 Si e Free electron Solve for the Unknown 1 free e 1 (M ) (1.451010 free e/cm3 for Si) NA atom 28.09 g 1 cm3 1.451010 free e 1 mol 23 6.0210 atoms 2.33 g 1 mol cm3 ( ) () ( )( )( )( 2.901013 free e/atom of Si or, roughly 1 out of 3 trillion Si atoms has a free electron 3 ) Substitute NA 6.021023 atoms/mol, M 28.09 g/mol, 2.33 g/cm3, free e/cm3 Si 1.451010 free e/cm3 Evaluate the Answer • Are the units correct? Using dimensional analysis confirms the correct units. • Is the magnitude realistic? In an intrinsic semiconductor, such as silicon at room temperature, very few atoms have free electrons. Math Handbook Operations with Scientific Notation pages 842—843 6. In pure germanium, which has a density of 5.23 g/cm3 and an atomic mass of 72.6 g/mol, there are 2.251013 free electrons/cm3 at room temperature. How many free electrons are there per atom? 7. At 200.0 K, silicon has 1.89105 free electrons/cm3. How many free electrons are there per atom at this temperature? What does this temperature represent on the Celsius scale? 8. At 100.0 K, silicon has 9.231010 free electrons/cm3. How many free electrons are there per atom at this temperature? What does this temperature represent on the Celsius scale? 9. At 200.0 K, germanium has 1.161010 free electrons/cm3. How many free electrons are there per atom at this temperature? 10. At 100.0 K, germanium has 3.47 free electrons/cm3. How many free electrons are there per atom at this temperature? 780 Chapter 29 Solid-State Electronics Doped Semiconductors The conductivity of intrinsic semiconductors must be increased greatly to make practical devices. Dopants are electron donor or acceptor atoms that can be added in low concentrations to intrinsic semiconductors. Dopants increase conductivity by making extra electrons or holes available. The doped semiconductors are known as extrinsic semiconductors. n-type semiconductors If an electron donor with five valence electrons, such as arsenic (As), is used as a dopant for silicon, the product is called an n-type semiconductor. Figure 29-6a shows a location in a silicon crystal where a dopant atom has replaced one of the silicon atoms. Four of the five As valence electrons bind to neighboring silicon. The fifth electron is called the donor electron. The energy of this donor electron is so close to the conduction band that thermal energy can easily move the electron from the dopant atom into the conduction band, as shown in Figure 29-7a. Conduction in n-type semiconductors is increased by the availability of these extra donor electrons to the conduction band. p-type semiconductors If an electron acceptor with three valence electrons, such as gallium (Ga), is used as a dopant for silicon, the product is called a p-type semiconductor. When a gallium atom replaces a silicon atom, one binding electron is missing, creating a hole in the silicon crystal, as shown in Figure 29-6b. Electrons in the conduction band can easily drop into these holes, creating new holes. Conduction in p-type semiconductors is enhanced by the availability of the extra holes provided by the acceptor dopant atoms, as shown in Figure 29-7b. Both p-type and n-type semiconductors are electrically neutral. Adding dopant atoms of either type does not add any net charge to a semiconductor. Both types of semiconductor use electrons and holes in conduction. Only a few dopant atoms per million silicon atoms are needed to increase the conductivity of semiconductors by a factor of 1000 or more. Silicon is doped by putting a pure silicon crystal in a vacuum with a sample of the dopant material. The dopant is heated until it is vaporized, and the atoms condense on the cold silicon. The dopant diffuses into the silicon on warming, and a thin layer of aluminum or gold is evaporated onto the doped crystal. A wire is welded to this metal layer, allowing the user to apply a potential difference across the doped silicon. a Electron n-type b Donor levels a Arsenic Donor Si Si Si Si As Si Si Si Si Excess electron free to move b Gallium Acceptor Si Si Si Si Ga Si Si Si Si Excess hole free to move ■ Figure 29-6 A donor atom of arsenic with five valence electrons replaces a silicon atom and provides an unbound electron in the silicon crystal (a). An acceptor atom of gallium with three valence electrons creates a hole in the crystal (b). p-type Acceptor levels Conduction bands Forbidden gap Electron Hole Hole Valence bands ■ Figure 29-7 In an n-type semiconductor (a), donor energy levels place electrons in the conduction band. In a p-type semiconductor (b), acceptor energy levels result in holes in the valence band. Section 29.1 Conduction in Solids 781 Thermistors The electric conductivity of intrinsic and extrinsic semiconductors is sensitive to both temperature and light. Unlike metals in which conductivity is reduced when the temperature rises, an increase in temperature of a semiconductor allows more electrons to reach the conduction band, and conductivity increases and resistance decreases. One semiconductor device, the thermistor, is designed so that its resistance depends very strongly on temperature. The thermistor can be used as a sensitive thermometer and to compensate for temperature variations of other components in an electric circuit. Thermistors also can be used to detect radio waves, infrared radiation, and other forms of radiation. The Conductivity of Doped Silicon Silicon is doped with arsenic so that one in every million silicon atoms is replaced by an arsenic atom. Each arsenic atom donates one electron to the conduction band. Arsenic Donor a. What is the density of free electrons? b. By what ratio is this density greater than that of intrinsic silicon with 1.451010 free e/cm3? c. Is conduction mainly by the electrons of the silicon or Si Si Si the arsenic? 1 Analyze the Problem • Identify the knowns and unknowns. Known: Unknown: free e/cm3 donated by As ? ratio of As-donated free e to intrinsic free e ? 1 As atom/106 Si atoms 1 free e/As atom 4.991022 Si atoms/cm3 1.451010 free e/cm3 in intrinsic Si 2 Si As Si Si Si Si Excess electron free to move Solve for the Unknown a. free e As atoms Si atoms free e from As 3 As atom Si atoms cm cm3 ( ) ( )( )( 1 free e 1 As atom free e 3 1 As atom 1106 Si atoms cm ( ) ( )( )( ) 4.991022 Si atoms cm3 ) 4.991016 free e/cm3 from As donor in doped Si ( ( 3 free e /cm in doped Si b. Ratio 3 free e /cm in intrinsic Si Substitute free e/As atom 1 free e/1 As atom, As atoms/Si atoms 1 As atom/1106 Si atoms, Si atoms/cm3 4.991022 Si atoms/cm3 ) 4.991016 free e/cm3 in doped Si 1.451010 free e/cm3 in intrinsic Si ) Substitute 4.991016 free e/cm3 in doped Si, 1.451010 free e/cm3 in intrinsic Si 3.44106 As-donated electron per instrinsic Si electron c. Because there are over 3 million arsenic-donated electrons for every intrinsic electron, conduction is mainly by the arsenic-donated electrons. 3 Math Handbook Evaluate the Answer • Are the units correct? Using dimensional analysis confirms the correct units. • Is the magnitude realistic? The ratio is large enough so that intrinsic electrons make almost no contribution to conductivity. 782 Chapter 29 Solid-State Electronics Ratios page 838 11. If you wanted to have 1104 as many electrons from arsenic doping as thermally free electrons in silicon at room temperature, how many arsenic atoms should there be per silicon atom? 12. If you wanted to have 5103 as many electrons from arsenic doping as thermally free electrons in the germanium semiconductor described in problem 6, how many arsenic atoms should there be per germanium atom? 13. Germanium at 400.0 K, has 1.131015 thermally liberated carriers/cm3. If it is doped with 1 As atom per 1 million Ge atoms, what is the ratio of doped carriers to thermal carriers? 14. Silicon at 400.0 K, has 4.541012 thermally liberated carriers/cm3. If it is doped with 1 As atom per 1 million Si, what is the ratio of doped carriers to thermal carriers? ■ Figure 29-8 Photographers use light meters to measure the intensity of incident light on an object. 15. Based on problem 14, draw a conclusion about the behavior of germanium devices as compared to silicon devices at temperatures in excess of the boiling point of water. Light meters Other useful applications of semiconductors depend on their light sensitivity. When light falls on a semiconductor, the light can excite electrons from the valence band to the conduction band in the same way that other energy sources excite atoms. Thus, the resistance decreases as the light intensity increases. Extrinsic semiconductors can be tailored to respond to specific wavelengths of light. These include the infrared and visible regions of the spectrum. Materials such as silicon and cadmium sulfide serve as light-dependent resistors in light meters used by lighting engineers to design the illumination of stores, offices, and homes; and by photographers to adjust their cameras to capture the best images, as shown in Figure 29-8. 29.1 Section Review 16. Carrier Mobility In which type of material, a conductor, a semiconductor, or an insulator, are electrons most likely to remain with the same atom? 17. Semiconductors If the temperature increases, the number of free electrons in an intrinsic semiconductor increases. For example, raising the temperature by 8°C doubles the number of free electrons in silicon. Is it more likely that an intrinsic semiconductor or a doped semiconductor will have a conductivity that depends on temperature? Explain. 18. Insulator or Conductor? Silicon dioxide is widely used in the manufacture of solid-state devices. Its energy-band diagram shows a gap of 9 eV between the valence band and the conduction band. Is it more useful as an insulator or a conductor? physicspp.com/self_check_quiz 19. Conductor or Insulator? Magnesium oxide has a forbidden gap of 8 eV. Is this material a conductor, an insulator, or a semiconductor? 20. Intrinsic and Extrinsic Semiconductors You are designing an integrated circuit using a single crystal of silicon. You want to have a region with relatively good insulating properties. Should you dope this region or leave it as an intrinsic semiconductor? 21. Critical Thinking Silicon produces a doubling of thermally liberated carriers for every 8°C increase in temperature, and germanium produces a doubling of thermally liberated carriers for every 13°C increase. It would seem that germanium would be superior for high-temperature applications, but the opposite is true. Explain. Section 29.1 Conduction in Solids 783 29.2 Electronic Devices T oday’s electronic instruments, such as radios, televisions, CD players, and microcomputers, rely on semiconductor devices that are combined on chips of silicon a few millimeters wide. In these devices, current and voltage vary in more complex ways than are described by Ohm’s law. As a result, semiconductor devices can change current from AC to DC and amplify voltages. Objectives • Describe how diodes limit current to motion in only one direction. • Explain how a transistor can amplify or increase voltage changes. Vocabulary Diodes diode depletion layer transistor microchip The simplest semiconductor device is the diode. A diode consists of a sandwich of p-type and n-type semiconductors. Rather than two separate pieces of doped silicon being joined, a single sample of intrinsic silicon is treated first with a p-dopant, then with an n-dopant. Metal contacts are coated on each region so that wires can be attached, as shown in Figure 29-9a. The boundary between the p-type and the n-type regions is called the junction. The resulting device, therefore, is called a pn-junction diode. The free electrons on the n-side of the junction are attracted to the positive holes on the p-side. The electrons readily move into the p-side and recombine with the holes. Holes from the p-side similarly move into the n-side, where they recombine with electrons. As a result of this flow, the n-side has a net positive charge, and the p-side has a net negative charge. These charges produce forces in the opposite direction that stop further movement of charge carriers. The region around the junction is left with neither holes nor free electrons. This region, depleted of charge carriers, is called the depletion layer. Because it has no charge carriers, it is a poor conductor of electricity. Thus, a junction diode consists of relatively good conductors at the ends that surround a poor conductor. ■ Figure 29-9 A diagram of the pn-junction diode (a) shows the depletion layer, where there are no charge carriers. Compare the magnitude of current in a reverse-biased diode (b) and a forward-biased diode (c). a Junction Diode Metal p-type Holes b Reverse-Biased Diode n-type Depletion layer c Holes filled 784 R n-type I Chapter 29 Solid-State Electronics Junction p-type Electrons leave Electrons Forward-Biased Diode R p-type Metal New holes created Electrons and holes recombine at junction n-type I New electrons added When a diode is connected into a circuit in the way shown in Figure 29-9b, both the free electrons in the n-type semiconductor and the holes in the p-type semiconductor are attracted toward the battery. The width of the depletion layer is increased, and no charge carriers meet. Almost no current passes through the diode: it acts like a very large resistor, almost an insulator. A diode oriented in this manner is a reverse-biased diode. If the battery is connected in the opposite direction, as shown in Figure 29-9c, charge carriers are pushed toward the junction. If the voltage of the battery is large enough—0.6 V for a silicon diode—electrons reach the p-end and fill the holes. The depletion layer is eliminated, and a current passes through the diode. The battery continues to supply electrons for the n-end. It removes electrons from the p-end, which is the same as supplying holes. With further increases in voltage from the battery, the current increases. A diode in this kind of circuit is a forward-biased diode. The graph shown in Figure 29-10 shows the current through a silicon diode as a function of voltage across it. If the applied voltage is negative, the reverse-biased diode acts like a very high-value resistor and only a tiny current passes (about 1011 A for a silicon diode). If the voltage is positive, the diode is forward-biased and acts like a low-value resistor, but not, however, one that obeys Ohm’s law. One major use of a diode is to convert AC voltage to DC voltage with only one polarity. When a diode is used in a circuit that does this, it is called a rectifier. The arrow in the symbol for the diode, which you’ll see in Example Problem 4, shows the direction of conventional current. Diode Current v. Voltage Current (mA) 20 15 10 5 0 5 3 2 1 0 1 Voltage (V) ■ Figure 29-10 The graph indicates current-voltage characteristics for a silicon junction diode. A Diode in a Simple Circuit A silicon diode, with I/V characteristics like those shown in Figure 29-10, is connected to a power supply through a 470- resistor. The power supply forward-biases the diode, and its voltage is adjusted until the diode current is 12 mA. What is the power supply voltage? 1 R Analyze and Sketch the Problem • Draw a circuit diagram connecting a diode, a 470- resistor, and a power supply. Indicate the direction of current. 2 Known: Unknown: I 0.012 A Vd 0.70 V R 470 Vb ? I Diode Vb Vd Solve for the Unknown The voltage drop across the resistor is known from V IR, and the power supply voltage is the sum of the resistor and the diode voltage drops. Vb IR Vd (0.012 A)(470 ) 0.70 V Substitute I 0.012 A, R 470 , Vd 0.70 V 6.3 V 3 Evaluate the Answer • Are the units correct? The power supply’s potential difference is in volts. • Is the magnitude realistic? It is in accord with the current and the resistance. Math Handbook Order of Operations page 843 Section 29.2 Electronic Devices 785 22. What battery voltage would be needed to produce a current of 2.5 mA in the diode in Example Problem 4? 23. What battery voltage would be needed to produce a current of 2.5 mA if another identical diode were added in series with the diode in Example Problem 4? 24. Describe how the diodes in the previous problem should be connected. 25. Describe what would happen in problem 23 if the diodes were connected in series but with improper polarity. 26. A germanium diode has a voltage drop of 0.40 V when 12 mA passes through it. If a 470- resistor is used in series, what battery voltage is needed? ■ Figure 29-11 Diode lasers are used as both light emitters and detectors in bar-code scanners. Light-emitting diodes Diodes made from combinations of gallium and aluminum with arsenic and phosphorus emit light when they are forwardbiased. When electrons reach the holes in the junction, they recombine and release the excess energy at the wavelengths of light. These diodes are called light-emitting diodes, or LEDs. Some LEDs are configured to emit a narrow beam of coherent, monochromatic laser light. Such diode lasers are compact, powerful light sources. They are used in CD players, laser pointers, and supermarket bar-code scanners, as shown in Figure 29-11. Diodes can detect light as well as emit it. Light falling on the junction of a reverse-biased pn-junction diode creates electrons and holes, resulting in a current that depends on the light intensity. Use the diode circuit in Example Problem 4 with Vb 1.8 V, but with R 180 : 1. Determine the diode current using the first approximation. 2. Determine the diode current using the second approximation and assuming a 0.70-V diode drop. 3. Determine the diode current using the third approximation by Diode Current v. Voltage 14.0 12.0 Current (mA) Approximations often are used in diode circuits because diode resistance is not constant. For diode circuits, the first approximation ignores the forward voltage drop across the diode. The second approximation takes into account a typical value for the diode voltage drop. A third approximation uses additional information about the diode, often in the form of a graph, as shown in the illustration to the right. The curve is the characteristic current-volatage curve for the diode. The straight line shows current-voltage conditions for all possible diode voltage drops for a 180- resistor, a 1.8-V battery, and a diode, from a zero diode voltage drop and 10.0 mA at one end, to a 1.8-V drop, 0.0 mA at the other end. 10.0 8.0 Graphic solution 6.0 4.0 2.0 0.0 0.2 using the accompanying diode graph. 4. Estimate the error for all three approximations, ignoring the battery and resistor. Discuss the impact of greater battery voltages on the errors. 786 Getty Images Chapter 29 Solid-State Electronics 0.6 1.0 1.4 Voltage (V) 1.8 a pnp-transistor b C Circuit symbols B C B E E C C p Transistors ■ Figure 29-12 Compare the circuit symbols used to represent a pnp-transistor (a) and an npntransistor (b). npn-transistor n B n B p E E p B base n C collector E emitter Transistors and Integrated Circuits A transistor is a simple device made of doped semiconductor material. An npn-transistor consists of layers of n-type semiconductor on either side of a thin p-type layer. The central layer is called the base and the regions on either side are the emitter and the collector. The schematic symbols for the two transistor types are shown in Figure 29-12. The arrow on the emitter shows the direction of conventional current. The operation of an npn-transistor is illustrated in Figure 29-13. The two pn-junctions in the transistor can be thought of as initially forming two back-to-back diodes. The battery on the right, VC, keeps the collector more positive than the emitter. The base-collector diode is reverse-biased, with a wide depletion layer, so there is no current from the collector to the base. When the battery on the left, VB, is connected, the base is more positive than the emitter. That makes the base-emitter diode forward-biased, allowing current IB from the base to the emitter. The very thin base region is part of both diodes in the transistor. The charges injected by IB reduce the reverse bias of the base-collector diode, permitting charge to flow from the collector to the emitter. A small change in IB thus produces a large change in IC. The collector current causes a voltage drop across resistor RC. Small changes in the voltage, VB, applied to the base produce large changes in the collector current and thus changes in the voltage drop across RC. As a result, the transistor amplifies small voltage changes into much larger changes. If instead the center layer is an n-type region, then the device is called a pnp-transistor. A pnp-transistor works the same way, except that the potentials of both batteries are reversed. Current gain The current gain from the base circuit to the collector circuit is a useful indicator of the performance of a transistor. Although the base current is quite small, it is dependent on the base-emitter voltage that is controlling the collector current. For example, if VB in Figure 29-13 is removed, the collector current will drop to zero. If VB is increased, the base current, IB, increases. The collector current, IC, will also increase, but many times more (perhaps 100 times or so). The current gain from the base to the collector ranges from 50 to 300 for general-purpose transistors. Diode Laser A typical diode laser emits light at 800 nm, which is the near infrared. The beam is output from a small spot on a GaAlAs chip, and when powered by 80 mA, the diode has a forward voltage drop of about 2 V. Diode lasers commonly are used in optical fiber transmissions. ■ Figure 29-13 A circuit using an npn-transistor demonstrates how voltage can be amplified. IC RC RB B IB VB Section 29.2 Electronic Devices VC 787 Red Light Make a series circuit with a DC power supply, a 470- resistor, and a red LED. Connect the short lead of the LED to the negative side of the power supply which is plugged into a GFCI-protected receptacle. Attach the other lead to the resistor. Connect the remaining resistor lead to the positive side of the power supply. Slowly increase the voltage until the LED glows. Note the voltage setting on the power supply. 1. Hypothesize what will happen if you reverse the direction of current. 2. Experiment by reversing the connections to the battery. Analyze and Conclude 3. Explain your observations in terms of LED characteristics. ■ Figure 29-14 A technician prepares a large silicon crystal to be sliced into wafers for microchips. 788 In a tape player, the small voltage variations from the voltage induced in a coil by magnetized regions on the tape are amplified to move the speaker coil. In computers, small currents in the base-emitter circuits can turn on or turn off large currents in the collector-emitter circuits. In addition, several transistors can be connected together to perform logic operations or to add numbers together. In these cases, they act as fast switches rather than as amplifiers. Microchips An integrated circuit, called a microchip, consists of thousands of transistors, diodes, resistors, and conductors, each less than a micrometer across. All these components can be made by doping silicon with donor or acceptor atoms. A microchip begins as an extremely pure single crystal of silicon, 10–30 cm in diameter and 1–2 m long, as shown in Figure 29-14. The silicon is sliced by a diamond-coated saw into wafers less than 1-mm thick. The circuit is then built layer by layer on the surface of this wafer. By a photographic process, most of the wafer’s surface is covered by a protective layer, with a pattern of selected areas left uncovered so that they can be doped appropriately. The wafer is then placed in a vacuum chamber. Vapors of a dopant such as arsenic enter the machine, doping the wafer in the unprotected regions. By controlling the amount of exposure, the engineer can control the conductivity of the exposed regions of the chip. This process creates resistors, as well as one of the two layers of a diode or one of the three layers of a transistor. The protective layer is removed, and another one with a different pattern of exposed areas is applied. Then the wafer is exposed to another dopant, often gallium, producing pn-junctions. If a third layer is added, npn-transistors can be formed. The wafer also may be exposed to oxygen to produce areas of silicon dioxide insulation. A layer exposed to aluminum vapors can produce a pattern of thin conducting pathways among the resistors, diodes, and transistors. ■ Figure 29-15 Microchips form the heart of the central processing unit of computers. A penny is shown in the picture to represent scale. Thousands of identical circuits, usually called chips, are produced at one time on a single wafer. The chips are then tested, sliced apart, and mounted in a carrier; wires are attached to the contacts; and the final assembly is then sealed into a protective plastic body. The tiny size of microchips, shown in Figure 29-15, allows the placement of complicated circuits in a small space. Because electronic signals need only travel tiny distances, this miniaturization has increased the speed of computers. Chips now are used in appliances and automobiles as well as in computers. Semiconductor electronics requires that physicists, chemists, and engineers work together. Physicists contribute their understanding of the motion of electrons and holes in semiconductors. Physicists and chemists together add precisely controlled amounts of dopants to extremely pure silicon. Engineers develop the means of mass-producing chips containing thousands of miniaturized diodes and transistors. Together, their efforts have brought our world into this electronic age. 29.2 Section Review 27. Transistor Circuit The emitter current in a transistor circuit is always equal to the sum of the base current and the collector current: IE IB IC. If the current gain from the base to the collector is 95, what is the ratio of emitter current to base current? 28. Diode Voltage Drop If the diode characterized in Figure 29-10 is forward-biased by a battery and a series resistor so that there is more than 10 mA of current, the voltage drop is always about 0.70 V. Assume that the battery voltage is increased by 1 V. a. By how much does the voltage across the diode or the voltage across the resistor increase? b. By how much does the current through the resistor increase? physicspp.com/self_check_quiz 29. Diode Resistance Compare the resistance of a pn-junction diode when it is forward-biased and when it is reverse-biased. 30. Diode Polarity In a light-emitting diode, which terminal should be connected to the p-end to make the diode light? 31. Current Gain The base current in a transistor circuit measures 55 A and the collector current measures 6.6 mA. What is the current gain from base to collector? 32. Critical Thinking Could you replace an npntransistor with two separate diodes connected by their p-terminals? Explain. Section 29.2 Electronic Devices 789 Horizons Companies Diode Current and Voltage Alternate CBL instructions can be found on the Web site. physicspp.com Semiconductor devices, such as diodes and transistors, are fabricated using a semiconductor that is made of partly p-type material and partly n-type material. A semiconductor doped with donor atoms is called an n-type semiconductor, while a semiconductor doped with an element leaving a vacancy or a hole in the lattice structure is referred to as a p-type semiconductor. A diode is made by doping adjacent regions of a semiconductor with donor and acceptor atoms, forming a p-n junction. In this lab, you will investigate the voltage and current characteristics of a diode that is placed in a direct current circuit and compare the response with your knowledge of resistors. QUESTION How do the current-voltage characteristics of a diode, an LED, and a resistor compare? Objectives Materials ■ Collect and organize data of voltage drop and DC power supply, variable, 0–12 VDC 100-Ω resistor, 12- or 1-W 1N4002 diode LED, red ammeter, DC, 0–100 mA voltmeter, 0–5 VDC hook-up wire current for a diode and an LED. ■ Measure the current passing through a diode and an LED as a function of voltage drop. ■ Compare and contrast the current-voltage characteristics of a resistor with diodes. Safety Precautions Procedure ■ Use caution with electric connections. Avoid contact with the resistor, which may become hot. ■ Plug power supplies into only GFCI-protected receptacles to prevent shock hazard. 1. Prepare a data table similar to the one shown on page 791. 2. As indicated on the schematic diagram below, wire the negative terminal of the power supply to the negative side of the ammeter using the hook-up wire provided. 100 Diode 012 VDC a b V LED mA 3. Locate the end of the diode with the silver band around it. Attach this end to the positive side of the ammeter. 4. Attach one end of the 100-Ω resistor to the free end of the diode. 790 Data Table Voltage (V) Drop Across Diode Diode Current (mA) LED Current (mA) 0 0.1 9. Connect the shorter lead on the LED to the positive side of the ammeter (negative side of the voltmeter) where the silver banded end of the diode had been connected. Connect the longer lead of the LED to the resistor and to the positive side of the voltmeter. 10. Plug in the power supply. Slowly turn up the power supply to increase the voltage drop across the LED from 0 up to 2.0 V, in 0.1-V increments. Record the corresponding current at each voltage. Additionally, observe the LED and record your observations of it. 0.2 0.3 1.7 ———— Analyze 1.8 ———— 1.9 ———— 2.0 ———— 1. Make and Use Graphs On one chart, sketch and label graphs of current versus voltage drop for both the diode and the LED. Place current on the y-axis and voltage on the x-axis. What are the shapes of these curves? 5. Attach a wire from the free end of the 100-Ω resistor to the positive lead on the power supply. 6. As shown in the schematic, the voltmeter is in parallel with the diode. Attach a wire from the positive side of the voltmeter to the end of the diode attached to the resistor. Connect the negative side of the voltmeter to the end of the diode with the silver band, which is attached to the ammeter. 7. The diode circuit should look like part a of the schematic. Make sure the power supply is turned to zero and plug it in. Slowly turn up the power supply to increase the voltage drop across the diode from 0 up to 0.8 V, in 0.1-V increments. Record the corresponding current at each voltage. CAUTION: If your current goes higher than the capacity of your ammeter, do not increase the voltage any higher, and discontinue taking readings. Turn the power supply to zero and unplug it. 8. Observe the LED leads. One should be shorter than the other. Replace the 1N4002 diode with the LED so that it corresponds with part b of the schematic. 2. Formulate Models Using Ohm’s law, compute and plot on the same graph the voltage-current relationship for a 100-Ω resistor from 0 to 2 V. Label this line 100 Ω. What is the form of this plot? Conclude and Apply 1. Compare and Contrast How do the currentvoltage curves for a diode, an LED, and a resistor compare? 2. Which of these devices follow Ohm’s law? 3. Analyze and Conclude Diodes are described as having a turn-on voltage. What is the turnon voltage for a silicon diode? For the LED you used? 4. Explain Why would the specifications for an LED give a light output at a specific current, such as 20 mA? Going Further What could be done to get better measurements of current for the diode? Real-World Physics To find out more about solid-state electronics, visit the Web site: physicspp.com Small incandescent lightbulbs typically draw 75–150 mA of current at a particular voltage. Why might manufacturers prefer using LEDs in a battery-powered CD or MP3 player? 791 Artificial Intelligence The phrase artificial intelligence was first used in 1955. It is defined as “the scientific understanding of the mechanisms underlying thought and intelligent behavior and their embodiment in machines.” Sometimes, a task needs artificial intelligence to be very logical. At other times, it may need artificial intelligence to think and behave with human biases. The goals in the field of artificial intelligence are to develop systems that can do both. A prototype Mars rover decides how to navigate obstacles. Artificial intelligence also is used to create expert systems in computers that are programmed with knowledge about specific topics. Humans can tell the computer the details of a specific situation, and the computer calculates the most logical course of action. In a medical environment, an expert system can be used to accurately diagnose disorders. Artificial intelligence weighs the facts of the situation and then infers which actions are most appropriate. However, artificial intelligence can operate only with facts that have been taught to the computer. Users must constantly be aware of this limitation of expert systems. The robot, Kismet, displays human facial expressions. Applications Artificial intelligence already Careers Studying mathematics, mathematical is used in many areas, and it will do even more for us in the future. When a computer plays chess, it searches through hundreds of thousands of possible moves before selecting the best one. Research is being done to improve the efficiency of search algorithms. Artificial intelligence currently is used for speech recognition to allow hands-free dialing of cell phones and for some interactive telephone transactions. It is not yet fully capable of understanding natural language, but that is a goal. Three-dimensional computer vision is another future application. To mimic the sensory input and behaviors of humans, computers need to extract three-dimensional reality from two-dimensional images. Progress has been made, but humans are still much better than computers at this. With improved vision, artificial intelligence may control automobiles on Earth, or robots exploring another planet, with no human navigators needed. logic, and computer programming languages is important for developing systems that can make rational decisions. Knowledge of psychology assures that these decisions also can have a human character. 792 Extreme Physics (l)NASA, (r)Sam Ogden/Photo Researchers Going Further 1. Debate the Issue Are there ethical limits to the development of artificial intelligence? 2. Recognize Cause and Effect What problems might cause an expert system to make a poor decision? 3. Critical Thinking In what situations must artificial intelligence be absolutely rational, and in what situations should it include human biases? 29.1 Conduction in Solids Vocabulary Key Concepts • semiconductors (p. 775) • band theory (p. 776) • intrinsic semiconductors • • (p. 780) • dopants (p. 781) • extrinsic semiconductors (p. 781) • • • • • • • • • Electric conduction may be explained by the band theory of solids. In solids, the allowed energy levels for outer electrons in an atom are spread into broad bands by the electric fields of electrons on neighboring atoms. The valence and conduction bands are separated by forbidden energy gaps; that is, by regions of energy levels that electrons may not possess. In conductors, electrons can move through the solid because the conduction band is partially filled. Electrons in metals have a fast random motion. A potential difference across the metal causes a slow drift of electrons, called an electric current. In insulators, more energy is needed to move electrons into the conduction band than is generally available. Conduction in semiconductors is enhanced by doping pure crystals with small amounts of other kinds of atoms, called dopants. n-type semiconductors are doped with electron donor atoms, and they conduct by the response of these donor electrons to applied potential differences. Arsenic, with five valence electrons, is an example of a donor atom. p-type semiconductors are doped with electron acceptor atoms, and they conduct by making holes available to electrons in the conduction band. Gallium, with three valence electrons, is an example of an acceptor atom. 29.2 Electronic Devices Vocabulary Key Concepts • • • • • diode (p. 784) depletion layer (p. 784) transistor (p. 787) microchip (p. 788) • • • • • • • • A pn-junction diode consists of a layer of a p-type semiconductor joined with a layer of an n-type semiconductor. Diodes conduct charges in one direction only. They can be used in rectifier circuits to convert AC to DC. Electrons and holes near either side of the diode junction combine to produce a region without charge carriers known as the depletion layer. Applying a potential difference of the proper polarity across the diode makes the depletion layer even wider, no current is observed, and the diode is said to be reverse-biased. Reversing the polarity of the applied potential across the diode greatly reduces the depletion layer, current is observed, and the diode is said to be forward-biased. A transistor is a sandwich of three layers of semiconductor material, configured as either npn- or pnp-layers. The center base layer is very thin compared to the other layers, the emitter and collector. A transistor can act as an amplifier to convert a weak signal into a much stronger one. The ratio of the collector-emitter current to the base current is known as the current gain and is a useful measure of transistor amplification. Conductivity of semiconductors increases with increasing temperature or illumination, making them useful as thermometers or light meters. Diodes that emit light when a potential is applied are used in optical devices. physicspp.com/vocabulary_puzzlemaker 793 Concept Mapping 33. Complete the concept map using the following terms: transistor, silicon diode, emits light, conducts both ways. 41. For the energy-band diagrams shown in Figure 29-16, which have half-full conduction bands? 42. For the energy-band diagrams shown in Figure 29-16, which ones represent semiconductors? Circuit Components 43. The resistance of graphite decreases as temperature rises. Does graphite conduct electricity more like copper or more like silicon does? copper wire 44. Which of the following materials would make a LED conducts one way better insulator: one with a forbidden gap 8-eV wide, one with a forbidden gap 3-eV wide, or one with no forbidden gap? amplifies 45. Consider atoms of the three materials in problem 44. From which material would it be most difficult to remove an electron? 46. State whether the bulb in each of the circuits of Mastering Concepts Figure 29-17 (a, b, and c) is lighted. 34. How do the energy levels in a crystal of an element differ from the energy levels in a single atom of that element? (29.1) 35. Why does heating a semiconductor increase its conductivity? (29.1) 36. What is the main current carrier in a p-type semiconductor? (29.1) 37. An ohmmeter is an instrument that places a potential difference across a device to be tested, measures the current, and displays the resistance of the device. If you connect an ohmmeter across a diode, will the current you measure depend on which end of the diode was connected to the positive terminal of the ohmmeter? Explain. (29.2) a b c ■ Figure 29-17 47. In the circuit shown in Figure 29-18, state whether lamp L1, lamp L2, both, or neither is lighted. 38. What is the significance of the arrowhead at the emitter in a transistor circuit symbol? (29.2) L1 L2 39. Describe the structure of a forward-biased diode, and explain how it works. (29.2) ■ Applying Concepts Figure 29-18 48. Use the periodic table to determine which of the 40. For the energy-band diagrams shown in Figure 29-16, which one represents a material with an extremely high resistance? following elements could be added to germanium to make a p-type semiconductor: B, C, N, P, Si, Al, Ge, Ga, As, In, Sn, or Sb. 49. Does an ohmmeter show a higher resistance when a pn-junction diode is forward-biased or reverse-biased? 50. If the ohmmeter in problem 49 shows the lower resistance, is the ohmmeter lead on the arrow side of the diode at a higher or lower potential than the lead connected to the other side? a ■ 794 b Figure 29-16 Chapter 29 Solid-State Electronics c 51. If you dope pure germanium with gallium alone, do you produce a resistor, a diode, or a transistor? For more problems, go to Additional Problems, Appendix B. 52. Draw the time-versus-amplitude waveform for point A in Figure 29-19a assuming an input AC waveform, as shown in Figure 29-19b. 57. Diode A silicon diode with I/V characteristics, as shown in Figure 29-10, is connected to a battery through a 270- resistor. The battery forward-biases the diode, and the diode current is 15 mA. What is the battery voltage? a 58. Assume that the switch shown in Figure 29-21 is off. a. Determine the base current. b. Determine the collector current. c. Determine the voltmeter reading. A b AC voltage A ■ Time 1500 15 V 120,000 Figure 29-19 A Mastering Problems V 3.5 V 29.1 Conduction in Solids ■ Figure 29-21 53. How many free electrons exist in a cubic centimeter of sodium? Its density is 0.971 g/cm3, its atomic mass is 22.99 g/mol, and there is 1 free electron per atom. 54. At a temperature of 0°C, thermal energy frees 1.55109 e/cm3 in pure silicon. The density of silicon is 2.33 g/cm3, and the atomic mass of silicon is 28.09 g/mol. What is the fraction of atoms that have free electrons? 59. Assume that the switch shown in Figure 29-21 is on, and that there is a 0.70-V drop across the baseemitter junction and a current gain from base to collector of 220. a. Determine the base current. b. Determine the collector current. c. Determine the voltmeter reading. 29.2 Electronic Devices Mixed Review 55. LED The potential drop across a glowing LED is 60. The forbidden gap in silicon is 1.1 eV. about 1.2 V. In Figure 29-20, the potential drop across the resistor is the difference between the battery voltage and the LED’s potential drop. What is the current through each of the following? a. the LED b. the resistor R 240 Battery V 6.0 V 1.2 V LED Electromagnetic waves striking the silicon cause electrons to move from the valence band to the conduction band. What is the longest wavelength of radiation that could excite an electron in this way? Recall that E 1240 eVnm/. 61. Si Diode A particular silicon diode at 0°C shows a current of 1.0 nA when it is reverse-biased. What current can be expected if the temperature increases to 104°C? Assume that the reverse-bias voltage remains constant. (The thermal carrier production of silicon doubles for every 8°C increase in temperature.) 62. Ge Diode A particular germanium diode at 0°C ■ Figure 29-20 56. Jon wants to raise the current through the LED in problem 55 up to 3.0101 mA so that it glows brighter. Assume that the potential drop across the LED is still 1.2 V. What resistor should be used? physicspp.com/chapter_test shows a current of 1.5 A when it is reverse-biased. What current can be expected if the temperature increases to 104°C? Assume that the reverse-biasing voltage remains constant. (The thermal charge-carrier production of germanium doubles for every 13°C increase in temperature.) Chapter 29 Assessment 795 63. LED A light-emitting diode (LED) produces green light with a wavelength of 550 nm when an electron moves from the conduction band to the valence band. Find the width of the forbidden gap in eV in this diode. 66. Apply Concepts The I/V characteristics of two LEDs that glow with different colors are shown in Figure 29-24. Each is to be connected through a resistor to a 9.0-V battery. If each is to be run at a current of 0.040 A, what resistors should be chosen for each? 64. Refer to Figure 29-22. a. Determine the voltmeter reading. LED Current v. Voltage b. Determine the reading of A1. Current (A) c. Determine the reading of A2. 220 All diodes are silicon. 0.04 0.02 0 V 0.5 1 10.0 V 2 2.5 Voltage (V) A1 ■ 1.5 A2 ■ Figure 29-24 67. Apply Concepts Suppose that the two LEDs in Figure 29-22 problem 66 are now connected in series. If the same battery is to be used and a current of 0.035 A is desired, what resistor should be used? Thinking Critically 65. Apply Concepts A certain motor, in Figure 29-23, runs in one direction with a given polarity applied and reverses direction with the opposite polarity. a. Which circuit (a, b, or c) will allow the motor to run in only one direction? b. Which circuit will cause a fuse to blow if the incorrect polarity is applied? c. Which circuit produces the correct direction of rotation regardless of the applied polarity? d. Discuss the advantages and disadvantages of all three circuits. M c b M ■ 796 Figure 29-23 Chapter 29 Solid-State Electronics life of Wolfgang Pauli. Highlight his outstanding contributions to science. Describe the application of the exclusion principle to the band theory of conduction, especially in semiconductors. 69. Write a one-page paper discussing the Fermi energy level as it applies to energy-band diagrams for semiconductors. Include at least one drawing. 70. An alpha particle, a doubly ionized (2) helium M 68. Research the Pauli exclusion principle and the Cumulative Review a Writing in Physics atom, has a mass of 6.71027 kg and is accelerated by a voltage of 1.0 kV. If a uniform magnetic field of 6.5102 T is maintained on the alpha particle, what will be the particle’s radius of curvature? (Chapter 26) 71. What is the potential difference needed to stop photoelectrons that have a maximum kinetic energy of 8.01019 J? (Chapter 27) 72. Calculate the radius of the orbital associated with the energy level E4 of the hydrogen atom. (Chapter 28) For more problems, go to Additional Problems, Appendix B. Multiple Choice 1. Which statement about diodes is false? Diodes can ___________. amplify voltage emit light detect light rectify AC 7. Which line in the following table best describes the behavior of intrinsic silicon semiconductors to increasing temperature? Effect of Increasing Temperature on Intrinsic Silicon Semiconductors 2. Cadmium has two free electrons per atom. How many free electrons are there per cm3 of cadmium? The density of cadmium is 8650 kg/m3. 1.241021 9.261024 9.261022 1.171027 3. The base current in a transistor circuit measures 45 A and the collector current measures 8.5 mA. What is the current gain from base to collector? 110 205 190 240 4. In problem 3, if the base current is increased by 5 A, how much is the collector current increased? 5 A 10 mA 1 mA 190 A 4.75 mA 18.9 A 1190 mA Resistance Increases Increases Increases Decreases Decreases Increases Decreases Decreases 8. Thermal electron production in silicon doubles for every 8°C increase in temperature. A silicon diode at 0°C shows a current of 2.0 nA when reverse-biased. What will be the current at 112°C if the reverse-bias voltage is constant? 11 A 33 A 44 A 66 A Extended Answer 9. A silicon diode is connected in the forwardbiased direction to a power supply though a 485- resistor, as shown below. If the diode voltage drop is 0.70 V, what is the power supply voltage when the diode current is 14 mA? R 485 5. A transistor circuit shows a collector current of 4.75 mA, and the base to collector current gain is 250. What is the base current? 1.19 A Conductivity I 14 mA Vb Vd 0.70 V 6. Which line in the following table best describes both n- and p-type silicon semiconductors? n-type p-type Gallium-doped Added electrons Added electrons Arsenic-doped Arsenic-doped Added holes Added holes Gallium-doped physicspp.com/standardized_test Focus If students near you are talking during a test, you should move. Respond only to the instructor when taking a test. Talking is a distraction and the instructor might think that you are cheating. Don’t take the chance. Focus on the test. Chapter 29 Standardized Test Practice 797