Chemistry Unit 8 Worksheet 4 Samples of Every Kind of Problem On a separate sheet of paper, write a complete solution to each of the problems below. Follow the procedure outlined in class. Be sure to circle your final answer. 1. Calculate the number of moles of potassium chlorate, KClO3 (s), that must decompose to produce potassium chloride, KCl (s), and 1.8 moles of oxygen gas. Equation: 2 KClO3 Before: 1.2 0 Change: -1.2 +1.2 +1.8 0 1.2 1.8 After: 2 KCl + 3 O2 1.2 moles KClO3 needed 0 2. In a single displacement reaction, magnesium metal reacts with hydrochloric acid to produce magnesium chloride and hydrogen gas. How many moles of hydrochloric acid are needed to completely react with 2.43 g of magnesium? Equation: Mg + Before: 0.100 Change: -0.100 After: MgCl2 + H2 2 HCl ? -0.200 + 0 ? 0 0 0.100 + 0.100 0.100 0.100 0.200 moles HCl needed 3. Ethane, C2H6 reacts with oxygen gas to produce carbon dioxide gas and water vapor. What mass of oxygen gas is required to react with 2.20 moles of ethane? 2 C 2H 6 Before: 2.20 xs 0 Change: -2.20 - 7.70 + 4.40 + 6.60 0 xs 4.40 6.60 After: + Equation: 7 O2 O2 needed: 7.70 mole x 32.0 g 1 mole 4 CO2 + 6 H 2O 0 = 246 g O2 required 4. Determine the mass of sodium nitrate produced when 0.73 g of nickel (II) nitrate reacts with sodium hydroxide according to the following equation: Ni(NO3)2 + 2 NaOH --> Ni(OH)2 + 2 NaNO3 0.73 g x 1 mole = .0040 mole 183 g 2 NaOH Ni(OH)2 + 0.0040 XS 0 - 0.0040 - 0.0080 +0.0040 +0.0080 0 XS 0.0040 0.0080 Equation: Ni(NO3)2 Before: Change: After: + NaNO3 produced: 0.0080 mole x 85.0 g 1 mole Modeling Chemistry 1 2 NaNO3 0 = 0.68 g U8 ws 4 v1.5 5. In the copper–silver nitrate lab copper metal and silver nitrate solution reacted to produce silver metal and copper(II) nitrate in solution. A student placed a copper wire with a mass of 2.93 g in the reaction test tube. The silver nitration solution contained 1.41 g of silver nitrate. He obtained 0.87 g of silver metal. Calculate the percent yield. 2.93 g x 1 mole = 0.0461 mole Equation: Cu + Before: 0.0461 Change: - 0.00415 After: 2 AgNO3 2 Ag 0.00830 0 - 0.00830 XS + 0 + 0.00830 +0.00461 0.00830 0.00461 0 63.5 g Cu(NO3)2 theoretical yield: 0.00830 mole x 107.9g = 0.896 g 1 mole Cu 1.41 g x 1 mole = 0.00830 mole 170 g AgNO3 percent yield: = 0.87 g x 100% = 97% 0.896 g 6. When hydrochloric acid (HCl) is added to sodium hydrogen carbonate, water, aqueous sodium chloride and carbon dioxide gas are the products. What is the percent yield if 4.68 g of CO2 are collected when 10.0 g of sodium hydrogen carbonate reacts with excess HCl? 10.0 g x 1 mole = 0.119 mole 84 g Equation: HCl Before: XS Change: After: + NaHCO3 H 2O 0.119 0 + 0 NaCl + 0 0 - 0.119 - 0.119 + 0.119 + 0.119 XS 0 0.119 0.119 theoretical yield: 0.119 mole x 44.0g = 5.24 g 1 mole NaHCO3 CO2 + 0.119 0.119 percent yield: = 4.68 g x 100% = 89.3% 5.24 g 7. Phosphorus and bromine react vigorously together to form phosphorus tribromide. If 5.0 g of phosphorus and 35 g of bromine react, how many grams of PBr3 could be produced? 5.0 g x 1 mole = 0.161 mole Equation: 2P + 3 Br2 2 PBr3 Before: 0.161 0.219 Change: - 0.146 - 0.219 + 0.146 0.015 0 0.146 After: 31.0 g 0 35 g x 1 mole = 0.219 mole 160 g 0.146 mole x 271 g = 40. g PBr3 1 mole 8. Zinc sulfide and oxygen gas react to form zinc oxide and sulfur dioxide. Determine the amount of ZnO that should be produced in a reaction between 46.5 g of ZnS and 13.3 g 46.5 g x 1 mole = 0.477 mole ZnS of oxygen. What is the mass of the xs reactant? 97.5 g Equation: 2 ZnS + 3 O2 Before: 0.477 0.416 Change: - 0.277 After: 0.200 2 ZnO + 2 SO2 0 0 - 0.416 + 0.277 + 0.277 0 0.277 0.277 13.3 g x 1 mole = 0.416 mole O2 32 g 0.277 mole x 81.4 g = 22.5 g ZnO 1 mole 0.200 mole x 97.5 g = 19.5 g ZnS 1 mole Modeling Chemistry 2 U8 ws 4 v1.5