Questions Bank Practical organic chemistry 231chem Q1: Write the chemical structure of the following compounds? Compound Structure Compound Calcium oxalate. Calcium tartarate Fehling B Fehling A Aniline hydrochloride. Aniline sulphate Urea Deing’s 1 Amm. benzoate Sodium salicylate Phthalic acid Citric acid Deing’s 2 α-napthol Barfoed reagent Amm. Citrate Sod. Tartarate Oxalic acid Citric acid β-naphthol Structure Q2: How can differentiate between each pair from the following compounds (by one chemical experiment)? Lactose and sucrose. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………...………………………… Ammounium benzoate and sodium phthalate. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ………………………………………………………………………………………………...……… Starch and oxalic acid. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………...………………………… Urea and ammonium benzoate. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………...………………………… Aniline hydrochloride and aniline sulphate. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………...………………………… Sodium oxalate and oxalic acid. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………...………………………… Ammounium citrate and citric acid. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………...………………………… Tartaric acid and salicylic acid. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………...………………………… Oxalic acid and aniline hydrochloride. ……………………………………………………………………………………………………… ……………………………………………………………………………………………………… ……………………………………………………………………………...………………………… Q3: Complete the following tables? a. ………………… Experiment Observation Results Molish test …………………. There is no carbohydrates Acidity test -ve ……………………. Effect of NaOH ……………………. FeCl3 ……………………. White ppt after boiling Ammonium salt Ammonium oxalate or tartarate or citrate ……………………. ……………………. Ammonium citrate Observation Results Molish test …………………. Acidity test ……………………. Azo-dye test ……………………. There is no carbohydrates Carboxylic acid or aniline salt Aniline salt White ppt ……………………. ……………………. Aniline hydrochloride Observation Results Violet ring spread by shaking ……………………. ……………………. Mono or disaccharide +ve ……………………. Rapid furfural d. …………………. ……………………. Fructose Experiment Observation Results …………………. -ve -ve There is no carbohydrates ……………………. ……………………. Sodium phthalate or benzoate Sodium phthalate With my best wishes CaCl2 test Deing's test b. ………… Experiment AgNO3 BaCl2 c. ………….. Experiment Molish test I2 test Barfoed test Molish test Acidity test Effect of NaOH FeCl3 ……………………. Phthaline test …………………….