SWGS Chemistry Name:……………………………… Starting AS – Summer Work In the first unit of the course you will extend your current equation writing and calculation skills in addition to your knowledge of atomic structure and bonding. This work will give you chance to practise what you already know. Answer each question in the space provided. Some examples are given. Use the Periodic Table provided to help you and the table of formulae of ions. You will be handing in a hard copy of this work at the start of the course, so make sure you have it with you. 1. Writing Formulae of ionic compounds: complete the table below using the pdf from “creative chemistry” to help sodium carbonate potassium chloride sodium hydroxide aluminium oxide copper oxide magnesium chloride ammonium nitrate calcium sulfate (8) 2. Writing formulae of common covalent compounds. Some of these you can work out from their name, some you will know, others you need to look up and learn. nitrogen dioxide sulphuric acid ammonia ethanoic acid propane carbon tetrachloride ethane dihydrogen monoxide (8) 3. Writing Chemical Equations: write balanced symbol equations for each reaction: 1. sodium 2Na + + sulfuric acid H2SO4 sodium sulfate Na2SO4 + + hydrogen H2 2. hydrogen + steam oxygen 3. sodium hydroxide + copper II sulphate 4. calcium carbonate + hydrochloric acid 5. zinc + nitric acid (8) Formula Mass: Fill in the gaps in the first two columns and calculate the formula mass of each compound. name carbon dioxide CO2 formula ammonia NH3 formula mass 12 + (16*2) = 44 NaCl calcium sulfate butane C4H10 C2H4 (8) Reacting Masses: use the equation to work out the mass of reactant used or product formed . Mg + 2HCl MgCl2 + H2 Example: What mass of magnesium chloride is formed when 6g magnesium react? 1 mole of magnesium makes 1 mole of magnesium chloride, so we can use the ratios of mass in grams:relative formula mass of each substance so for Mg: 6/24 = x/95 for MgCl2 so x = (6*95)/24 so x = 23.75 g. This answer is sensible because the relative formula mass of MgCl2 is much greater than Mg Example 2: What mass of oxygen is needed to react with 8.5 g of hydrogen sulphide (H 2S)? 2 H2S + 3 O2 2 SO2 + 2 H2O Her the reacting mole ratio is 2H2S : 3O2 so we must multiply the relative formula masses (rfm) by these coefficients: So for H2S: 8.5/(2*34) = x/(3*32) so x = (8.5*96)/68 So x = 12g. This answer is sensible because although the rfm of H2S is higher than for O2, 3 moles of O2 are needed to react with 2 moles of H2S so mre grams of O2 will be required 1) What mass of potassium oxide is formed when 7.8 g of potassium is burned in oxygen? 4 K + O2 (3) 2O 2) Railway lines are welded together by the Thermitt reaction, which produces molten iron. What mass of iron is formed from 1 kg of iron oxide? Fe2O3 2O3 (3) 3) What mass of aluminium oxide is produced when 135 g of aluminium is burned in oxygen? 2 Al + 3 O2 (3) 2O3 5) 5.00 g of hydrated sodium sulphate crystals (Na2SO4.nH2O) gave 2.20 g of anhydrous sodium sulphate on heating to constant mass. Work out the relative molecular mass (M r) of the hydrated sodium sulphate and the value of n. Na2SO4.nH2 (3) 2SO4 + n H2O Percentage Composition: calculate the percentage (by mass) of the named element in the compound given. Percent composition = mass of the element X 100 formula mass of compound 1. Show that the percentage Nitrogen in ammonium chloride (NH4Cl) is 26.2% 2. Carbon in ethanol (C2H5OH) 3. Oxygen in zinc sulphate (ZnSO4) (6) Percentage Yield: work out the percentage yield for these reactions. % Yield = Mass of product actually made x 100 Maximum mass of product that could be made 1. Barium sulfate can be made by reacting barium chloride with ammonium sulfate. BaCl2 + 2NH4SO4 BaSO4 + 2NH4Cl If 2.00g of barium chloride are used the mass of barium sulfate produced should be 2.24g if the yield is 100%. Only 1.68g of barium sulfate was formed. Show that the percentage yield is 75%? (2) 2. Copper II carbonate decomposes when heated. Copper oxide and carbon dioxide are made. The mass of copper carbonate heated was 5.72g. The mass of copper II oxide produced was 3.32g. Write the symbol equation for the reaction. (1) Calculate the formula mass for a. Copper II carbonate b. copper II oxide (2) Calculate the mass of copper II oxide that would have been made if the yield was 100%. (2) Calculate the percentage yield. (1) Titration Calculations. As you saw on the taster day, a titration can be used to find the concentration of an unknown solution. There are many steps to these calculations: 1. Convert volumes in decimetres cubed to centimetres cubed 2. Use n = c x v (no. moles = concentration in moles per decimetre cubed x volume) for one solution 3. Calculate the number of moles required of the second solution using the mole ratios from the equation 4. Use c = v/n to find the unknown concentration Example: see attached file and try the exercise. (7) Follow this step and the ones on the next page to complete the calculation for the titration. Structure and Bonding: 1. Draw a labelled diagram of an atom, stating the name, mass and charge of each of the sub-atomic particles (3) 2. Complete the table below about bonding in the 3 different substances (12) TOTAL /80