Mock Exam I – Chemistry 101 The exam will consist of both short answer and problem-solving questions. This is a practice exam, with problem-solving questions involving material that could be on the exam. It is NOT a guarantee that the real exam will have the same problems or types of problems. In addition to this practice exam, you should do the HW, re-do the workshops, and look at online exams. 1. The atomic ion 190Os2+ contains ___________ neutrons, ___________ protons, and ___________ electrons. 2. A student prepared a stock solution by dissolving 20.0 g of KOH in enough water to make 150.0 mL of solution. She then took 15.0 mL of the stock solution and diluted it with enough water to make 65.0 mL of a final solution. What is the concentration of KOH for the final solution? 3. What is the percent mass of carbon in ethyl fluoride, C2H5F? 4. What is the formula for: a. heptane b. nickel (II) chloride 5. What is the name for: a. CS2 b. Cu(SO3) 6. What is the oxidation state of the chlorine atom in perchlorate anion? 7. Determine the empirical formula of a compound that contains 36.86% N and 63.14 % O by mass. 8. Answer the following questions about the redox reaction shown below: Cu(s) + 2 AgCl(aq) → 2 CuCl2(aq) + 2 Ag(s) (a) What is the oxidation state of Cu on the product side of the equation?______ (b) What is the oxidation state of Cu on the product side of the equation?_________ (c) What is the oxidation state of Ag on the reactant side of the equation?__________ (c) What is the oxidizing agent?_______________ (d) Which species was reduced?________________ 1 Problem Solving: To get full credit, you must show a neat, thorough logical method of solving the problem. Each number must have the appropriate unit, and follow the rules of significant figures throughout your calculation. 9. A 0.02346 g sample of an organic compound (molar mass = 62.0 g/mol) containing only carbon, hydrogen and oxygen was burned completely in air to produce 20.42 mg of CO2 and 33.27 mg of H2O. What is the molecular formula of the compound? 2 10. Powdered Aluminum can react with iron(III)oxide in the “thermite reaction” to form molten iron and aluminum oxide: 2Al(s) + Fe2O3(s) → 2 Fe(l) + Al2O3(s) Liquid iron is formed because the reaction releases so much energy. The liquid iron is commonly used to weld steel railroad rails. (a) What is the limiting reactant when a mixture of 100.0 g Al and 100.0 g Fe2O3 react? (b) What is the theoretical yield of liquid iron? (c) How many grams of the excess reactant remain after the reaction is complete? 3 11. For each of the following reactions, write the molecular, ionic, and net ionic equations. Also circle the appropriate category to which the reaction belongs. (a) Aqueous barium chloride is mixed with aqueous sodium sulfate. Formula of barium chloride: ______________ Formula of sodium sulfate: _________ Molecular Equation: Ionic Equation: Net Ionic Equation: Spectator ions (if any): (b) Hydrochloric acid is added to solid ammonium carbonate. Formula of hydrochloric acid: ____________ Formula of ammonium carbonate: ___________ Molecular Equation: Ionic Equation: Net Ionic Equation: Spectator ions (if any): 4 12. A flask containing 450 mL of a 0.500 M HBr solution was accidentally knocked to the floor during lab. In order to neutralize the spill, the instructor poured aqueous K2CO3 over the spill until the reaction was complete (neutralized) according to the following equation. How many grams of the K2CO3 solution did the instructor need for the reaction to be complete? (Hint: balance the equation before doing anything else!) 5