Your Ref:
Ms. Elizabeth Leacy,
EnvironmentalProtection Agency,
P.O. Box 3000,
Johnstown Castle Estate,
Co.Wexford.
Our Ref:
I
Date:
--
M672
14* October 2004.
I
Dear Sir or Madam:
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.
Please see attachedthe MSDS sh$ets for the glues that we use onsite, as requested by the Agency
as part of our IPC licence reviewYlto
determine if Finsa Forest Products Ms under the Solvents
I
Directive (1 9!39/13/EC).
~
do not hesitate to contact me.
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Should you require further in
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SALES OFFICES
Spain
Alicante
Barcelona
Logrotio
Madrid
Muxika
Santiago
Sevilla
Valencia
Dubai
France
Nederland
Ireland
Italy
Poland
Portugal
United Kingdom
FINSA FOREST PRODUCTS Ltd.
N
0
W
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a
SCARIFF County Clare
Ireland
Tel.: + 353 / 0 61 92 10 38
Fax: + 353 I O 61 92 11 29
e-mail: ffp@finsa.es
Registered in Ireland No. 98769
Vat Nn IF 4736935W
1
LS.EN IS0 9002
System
l i Directors:SjLircia iSDanishl. J.M. Rornos 1S~onishl.V. Romero ISganish),E.Sbntos (Spanish).G. Frey (Spanish).J. ischner (German)
EPA Export 25-07-2013:18:58:12
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7-
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4
I
UREA FORMALDEHYDE
CONCENTRATE
I
I
I
I
EPA Export 25-07-2013:18:58:12
EPA Export 25-07-2013:18:58:12
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1. IDENTIFICATION OF THE MATERIAL AND OF THE COMPANY/ENTERPRISE
1.1. Identification of the Material :
1.2. Identification of the Company Enterprise
...........................................
9 8 540014
~
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Emergency Phone
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FORESA,Industrias Quimicas del Noroeste,S.A.
Avda. de Doiia Urraca,94
FAX+34986540855
CALDAS DE REYES (Pontevedra)
e-mail :foresa @ finsa.es
2. COMPOSITION/ INFORMATION ABOUT COMPONENTS
Formaldehyde (CH20)
>I= 25 %
R 23125-40-43
S %-26-36137-51
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Substance:
Concentration (YO):
Hazard Symbol; IUS-Phrases:
3. HAZARDS IDENTIFICATION
3.1 Toxic bv inhalation:
Provoking breathing dficulties, loss of sense o f smell, palpitation (rapid heart
' beat), headdache.
3.2 Toxic bv ingestion:
Provoking nausea and vomiting, abdominal pain, diarrhea.
3.3 Toxic bv skin contact:
Provoking skin burns and allergic reactions.
3.4 Eve irritate:
Provoking lacrimation, conjunctivitis and corneal burns
1
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4.FIRSTAlD
4.1 General princiDIe:
Remove the victim from the contaminated area
4.2 Contact with skin and mucous membranes:
Wash the contaminated areas abundantly with water for at least 15 minutes, do it
under an emergency shower if available.
Contaminatedclothing and shoes should be removed under shower
4.3 Eve contact:
Irrigate inmediately with large amounts of water for a minitnunof 15 minutes
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Held apart the eyelids during irrigation to insure water contact with all of tissues
of the surface of eyes and lids
The victim should be sent to a physician, preferably an eye specialist, as rapidly
as possible
4.4 Ingiestion:
Do not induce vomits
Calla physician
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swallow 2 r; 3 drops of water or milk
4.5 Inhalation:
Removed the exposed persons from the contaminated area, they should be kept
warm but not hot
If the victim lost concioousness put him laterally
If the victim is no breathing, an e&ctive means of artificial respiration should
be initiated inmediately. If oxigen inhalation apparatus is available, oxygen
should be administered but only by a person authorized for such duty.
If the victim stop breathing or seem to have an heart attack, immediately start
giving him artilicial ventilation and external cardiacal compression, only by a
person authorized todo it
Call a physician
2
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5. FIRE F'IGI€I'ING
5.1 Recommended means:
Water spray, dry chemical, carbon dioxide, foam and halon
5.2 Not advisable means:
Water jets.
5.3 Protection equipment:
Waterproof coats, boots in PVP material, goggles and helmet
When fighting indoor fires, self-contained breathing apparatus is necessary.
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5.4 Procedureon combat to fire :
Avoid product spreading
Refkigerate with water the exterior parts of the tanks exposed to fire
,Keep away the unnecesary persons
Co
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to
Fire fighters should remain with the wind to their backis and apart from low
areas and tanks.
6. MEASURES IN CASE OF' ACCIDENTAL LEAK
Use adequate respiratory protection, goggles, gloves and boots in PVC material
Cheek the valves bolt and cover leaks
Avoid the product projection over the skin, eyes respiratory system and clothes
Prevent the drain of the product to the sewer, water course, permeable or agriculture
lands and dwelling areas
Throw big quantities of pulverized water over the product
In case of small quantities, clean with a towel that should be burned after
Warn the authorities in case of serious contamination
3
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7.- HANDLING AND STORAGE
7.1 Handling:
No breath o f vapors
Wear protection wardrobe, goggles and gloves
When severely exposed use adequate respiratory mask
Keep vessels tiightly sealed
Workplaces and working methods must be designed to prevent driect contact
with formaldehyde solutions
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Emergency showers and eyes washing facilities must be available at the
workplace
to
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7.2 Storage:
Store in well ventilated places
Store in drums or tanks in a temperature range between 16 - 35 "C
Avoid contact with oxidizing and alkaline materials
Co
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Storage tanks should be adequately grounded to discharge static electricity and
to reduce other electrical hazard
Indoor storage areas should be in areas havhg floors pitched toward a trapped
diain or in cubed retention areas.
8.- INDIVIDUAL EXI'OSITION/PROTE~ONCONTROL
8.1 ResDiratorv protection:
Severe exposure to formaldehyde may occur in tanks during equipment cleaning
and reapirs, when decontaminating areas following spills, or in case o f failure of
piping or equipment. Employees who may be subject to such exposures should
be provided with proper respiratory protection and trained in its use and care.
Available types are described bellow:
. Sefl-contained breathing apparatus
. Positive pressure hose masks
. Air line masks
. Industrial canister type gas masks
. Chemical cartridge respirators.
4
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8.2 Hand protection:
Use gloves made of rubber or the other impervious material
8.3 Eve protection:
Cup type fiamed goggles, equipped with the approved impact resistant glass or
plastic lenses, should be worn whenever there is danger of UF coming in contact
with the eyes
Metal or plastic rim safety spectacles with unperforated side shields with safety
lenses or suitable all plastic safety goggles may be used where continuous eye
protection in desirable, as in laboratories
8.4 Another Drotections:
to
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Plastic shields with forehead protection may be worn where complete face
protection is desirable
“Hard”hats or soft-brimmed hats or caps may be worn to give protection against
falling objects or liquid leaks an splashes, respectively.
Leather or rubber or other imprevious may be worn to protect the body against
formaldehyde splashes.
ns
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Note : All the equipment of protection must be carellly kept, insppected,
cleaned and sterilized periodically.
Co
I
9.- cHEMI[CAL
AND PHYSICAL PROPERTIES
Colorless at 20 “C
Color:
Odor:
Pungent and irritating
> 100 “C
Boiling Point:
Inflammation Temperature (in closed recipiente):N.D.
Autoignition Temperature:
N.A.
Explosive Limits::
N.D.
Density at 25/25 “C:
1.20-1.30(depending on concentration
1
Solubility:
Soluble in water
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5
10.- STABILITY AND REACTIVITY
Concentrate of UF solutions can undergo a nonhazardous self-polymerization to form
paraformaldehyde which precipitates out of the solution
Oxigen fiom the air can oxidize concentrate of UF to formic acid, which is corrosive
Avoid contact with strong oxidizing agents, phenols, strong bases and copper, iron and
silver salts.
se
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11.- TOXICOLOGICAL INFORMATLON
to
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Acute inhalation effects:
Excesive vapor concentrations are readily attainable and may cause serious
adverse effects
Excessive exposure may cause severe irritation to upper respiratory tract and
lugs
Co
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Sings and symptoms of excessive exposure may be abdominal cramps and/or
diarrhea
12.-ECOLOGICAL INF'ORMATION
Noxious for aquatic life
Do not drain down a sewer or surface waters
Formaldehyde can be degraded by certain bacteria in soil to carbon dioxide and
water
Bioaccumulation does not occur
13.-ELIMINATlON SUBJET
The waste disposals resulting fkom this product, must be manager according to
the present legislation, specially in installations of eliminationlvaluation
properly authorized.
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6
14.- TRANSPORT INFORMATION
Usual tanks : Stainless steel cistern with variable capacity
15.- INFORMATION ABOUT REGULATIONS
Exposure limits values : VLE - CM 1 ppm Portugese Norm NP - 1796 (1988)
se
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16.- OTHER INF’ORMATIONS
ru
$6.1 Recommendations:
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The employees working in the handling, storage and shipping of formaldehyde
should be qualify and possess officiallicenses for such job.
16.2 Bibliographv:
A.- “Toxic and Hazardous - Industrial Chemicals Safety Manual” The
International Technical Information Insitute, Tokyo, Japan, 1978
- 1 - Formaldehyde” Manufacturing
Chemists Association Inc. Washington, 1960
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B.- ‘%hemica1 Safety Data Sheet SD
C.-“Product data sheet - Formalin LM 42” Perstorp Formox, Swedwn, May 22
1995
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I
ESPE.CIFICACI0
*
Fecha:
17/01/01
Revision:
Pkgina
FORESA
Control de
1
I
CONCENTRADO UF-80
Parametro
Rango
Unidades
-
WO en peso
-
O/O
56 57
Urea
23 24
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(E.L.1 0 8 - 59)
en peso
ru
(E.L.110 - 59)
.
Formaldehido
Wscosidad a 25 OC
-
(E.L. 102 59)
CP
1,300
- 1,310
ns
en
Densidad a 25 OC
(E.L.103- 59)
-
90 200
Co
:alidad
1
1 de
pH a 25 O C
6,5
- 8,O
(E.L.
104-59)
-
Materia reactiva
79 81
Coeficiente de
expansi6n ccbica
0,0006
O/O
en peso
gfcm3.0C
Observaciones:
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. ..
. ..
.
MELAMINE
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*
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;
r
,
Issue date: January 1". 1996
Version: 2
Page 1 of 7
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
e>-.
Chemical product name
: Melamine
Common chemical name
: 2,4,6-triamino-l,3,5-triazine
Chemical formula
: C,H,N,
CAS n o
: 108-78-1
EINECS n o
: 203-615-4
se
.
Supplier's name and address
. DSM Melamine Americas, Inc
ru
DSM Melamine Limburg
P.O. Box 43
6130 A A Sittard
The Netherlands
(31 46 4773854
Tslefax (31) 46 4773049
Telex 36777
to
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P.O. Box 327
Addis, Louisiana 70710-0327
USA
. (1) 504 685 3015
Telefax (1)504 585 3003
c
Emergency tele'phone
I'
*
. : (31) 46 4765555
ns
en
Emergency telefax
,",i.
P.T. DSM Kaltim Melamine
P.O. Box 4834 J K T M
Jakarta 12510
Indonesia
(62) 21 7984261
Telefax (62) 2'1 7984266
Telex 66075 D K M Jkt I A
: (311 46 4766440
Co
Transport emergencies for North and South America: CHEMTREC, (800) 424 9300
2. COMPOSlTlON/lNFORMATION ON INGREDIENTS
Chemical name of substance
CAS no.
% (w/w)
2,4,6-triamino-l,3,5-triazine
108-78-1
>
Impurities contributing t o the hazard:
99.8
Symbol
R phrases
none
none
N o t applicable
3. HAZARDS IDENTIFICATION
Physicallchemical hazards
: Melamine is non-combustible and melaine dust is
weakly explosible.
Environmental hazards
: None.
Effect(s1 of (overlexposure
: Above threshold limit value of nuisance dust of 10
mg/m3, irritating t o nose, throat and respiratory
tract. Mildly irritating t o eyes.
EPA Export 25-07-2013:18:58:13
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7
i
I
Safety Data Sheet
Conforms to /SO
I
11014-lr1994(Eland 91/155/EEC
Melamine
Page 2 of 7
Issue date: Januay 1". 1996
Version:
2
Symptom(s1 of (overlexposure
Inhalation
: Irritating.
Ingestion
:
Skin contact
: Not irritating.
Eye contact
: Redness, pain.
> 10 g may result in abdominal pain.
4. FIRST AID MEASURES
: Rinse mouth with plenty of water. Consult a doctor
in event of complaints.
Inhalation
: Remove victim to fresh air. Consult a doctor in event
of complaints.
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Ingestion
Skin contact
: Wash off with water and soap.
: .Wash out with plenty of water. Consult a doctor in
event of complaints.
Eye contact
5. FIRE FIGHTING MEASURES
Suitable
se
Extinguishing media
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~~~
: Melamine is non-combustible, use water to cool. In
case of fire in immediate vicinity: use any extinguishing agent
Unusual fire and explosion hazards
: Melamine is non-combustible. It can however
decompose when exposed to fire. In case of a lack
of oxygen, ammonia and hydrogen cyanide can be
formed upon decomposition.
Protection of firefighters
: Self-contained breathing equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
: As mentioned under heading 8.
Environmental precautions
: Not applicable.
Methods for cleaning up
: Collect spilled material in sealable containers.
Remarks
: Prevent formation of melamine dust.
Disposal according to local, provincial and federal
regulations.
0
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i
I
Issue date: Januay 1". 1996
Version: 2
Page 3 of 7
!
7. HANDLING A N D STORAGE
Handling
: Provide mechanical or natural ventilation to maintain
nuisance dust concentrations within acceptable levels.
Safe handling advise
: Avoid eye contact, Avoid breathing dust.
Storage
: Do not stack more than two bulk-bags > 1000 kg
on top of each other because of tear risk.
Storage conditions
: Store away from highly flammable substances. Keep
in a dry place.
Incompatible products
: None.
to
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Technical measures
Packagitig materials
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Technical measures
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.
. c
-
Safety Data Slreef
Conforms to IS0 1 1014-I: 7 994 (Eland 9 7/155/EEC
Melamine
Issue date: Januay
Version: 2
Page 4 of 7
la, 1996
9. PHYSICAL AND CHEMICAL PROPERTIES
: Crystalline powder
Colour
: White
Odour
: Odourless
Molecular weight
: 126.13
Melting point
: 354
Boiling point
: sublimes
Decomposition temperature
: 354oc
Density
: 1573 kg/m3 (20O C I
oc
Solubility in water
to
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Appearance
: 3 g/ I(20O C )
: 0.204 mbar (20 OC)
Vapour pressure
pH (10 % slurry in water)
: typically 8.4 to 8.9
1
:
>
280 OC
Autoignition temperature
:
>
1050 OC
Dust explosion class
according to VDI 3673
: St. 1 (weakly explosible)
Ignition energy
:
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Flash point
J)
>
8700 mJ
10. STABILITY AND REACTIVITY
Stability
: Stable under normal storage conditions.
Conditions to avoid
: Avoid temperatures above 300
Hazardous decomposition products
: Melamine is stable under normal conditions.
-
Hazardous reactions
OC.
In addition to carbon dioxide, carbon monoxide,
nitrogen and, to a little extent, nitrogen oxides, the
following decomposition products can be formed in
case of a lack of oxygen:
above 350 OC: ammonia.
above 550 O C : hydrogen cyanide.
I
: Will not occur.
DSM (?,
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z
-.-
Safety Data Sheet
Conforms to IS0 1 1014-1: 1994 (E) and 9 7 / 1
Melamine
1
-
I
Page 5 of 7
11. TOXICOLOGICAL INFORMATION
Acute toxicity
LD,
LD,
LD,
LD,
Oral
male rat: 3,100 mg/kg
female rat: 3,800 mg/kg
male mouse: 3,300 mg/kg
female mouse: 7,000 mg/kg
Mildly irritating.
Skin irritation
Not irritating.
Sensitization
Not sensitizing.
Chronic toxicity
No relevant chronic toxicity.
to
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Eye irritation
Environmental Protection Agency 1988: the risk on
bladder tumour promotion, posed by melamine, is
non-existent or at worst, extremely low.
Carcinogenicity
Not mutagenic.
Mutagenicity
ns
en
:. .1 ’
lk, 1996
12. ECOLOGICAL INFORMATION
Co
”
Issue date: Januay
Version: 2
Mobility
Persistence and degradability
: Adsorption on soil is not expected.
‘
: The substance is not readily biodegradable. It is
however inherently biodegradable.
Ecotoxicity
: Melamine has been shown to have low toxicity t o
aquatic life.
96 h LC, (for fish): > 3,000 mg/l
( = solubility melamine in water)
NOEC fish chronic test: > 1,000 mg/l
48 h LC, (for Daphnia): > 2,000 mg/l
NOEC Daphnia magna 21 days: 18 mg/l
EC, Algae: 940 mg/l
NOEC Algae: 320 mg/l
EC, bacteria: > 10,000 mg/l
EPA Export 25-07-2013:18:58:13
Page 6 of 7
Issue date: Januay Id,
1996
Version: 2
13. DISPOSAL CONSIDERATIONS
Responsibility of the receiver to have knowledge of national and local regulations.
Methods of disposal
Please comply with all local, provincial and federal
regulations
;
14. TRANSPORT INFORMATION
-
: Not restricted.
Inland waterways
: Not restricted.
Sea
: Not restricted.
Air
: Not restricted.
co For
py in
rig sp
ht ect
ow ion
ne pu
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eq os
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Land RoadlRailway
15. REGULATORY INFORMATION
Responsibility of the receiver to have knowledge of national and local regulations.
of
EC Classification
Co
ns
en
t
Label name
: Not classified as a dangerous substance accor
EC criteria.
Hazard symbol
: None.
Risk phrases
: None.
,
Safety phrases
+
: None.
,.
- ."
HMIS rating:
Health
: I
Flammability
: o
Reactivity
: o
WHMlS class
: D2B
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.-
Co
* .8
"8
UREA FORMALDEHYDE
RESIN THAT WE
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EPA Export 25-07-2013:18:58:13
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.
Dynea Ireland Ltd
Marino Point,
Cobh,
Co. Cork.
Telephone:
+353-21-4855100
Facsimile:
+353-21-4855156
Emergency No: +353-21-4855120
Ireland Ltd.
i
SAFETY DATA SHEET
m
Liquid Urea Formaldehyde Resin
1. IDENTIFICATION OF THE PREPARATION AND THE COMPANY
SYNONYMS, TRADE NAMES:
Prefere 10F219 (L-219), Prefere 71 1485J (Urex 3485), Prefere 87 01640H
(CFL-3), Prefere 1OF057 (C57), Prefere 1 1F3 11 (L-3 11) Prefere 10F5818
SUPPLIER:
Dynea Ireland Ltd, Marino Point, Cobh, Co. Cork
TELEPHONE:
t-353-(0) 21 4855100
EMERGENCY TELEPHONE:
Tel: t-353 (0) 21 4855120 (24 Hours)
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se
.
Liquid Urea Formaldehyde Resin
2. COMPOSITION~NFORMATIONON INGREDIENTS
INGREDIENT NAME:
CAS No.
CONTENTS
HEALTH
(class)
RISK (R.No.)
FORMALDEHYDE:
50-00-0
<1%
T,
23/24/25
34,40,43
60-75%
se
nt
o
UREA-FORMALDEHYDE POLYMER:
3. HAZARDS IDENTIFICATION
Co
n
a
CHEMICAL NAME:
Not regarded as a health hazard under current legislation.
4. FIRST AID MEASURES
EYES:
Promptly wash eyes with lots of water while lifting the eye lids. Contact
physician if irritation persists.
SKIN :
Remove affected person from source of contamination. Promptly wash
contaminated skin with soap or mild detergent and water. Promptly
remove clothing if soaked through and wash as above.
INHALATION:
Move the exposed person to fresh air at once.
INGESTION:
Promptly let affected person drink lots of water to dilute the swallowed
chemical. Do not induce vomiting. Get medical attention immediately.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA:
This material is not flammable. Use extinguishing media appropriate for
surrounding fire.
UNUSUAL FIRE & EXPLOSION
No unusual f i e or explosion hazards noted.
EPA Export 25-07-2013:18:58:13
.
Page 2 o f 4
Urea Formaldehyde Resin
HAZARDS:
HAZARDOUS DECOMPOSITION
PRODUCTS:
I
.
High temperatures generate Carbon Monoxide (CO) and Carbon
Dioxide (COz).
6. ACCIDENTAL RELEASE MEASURES
SPILL CLEANUP METHODS:
GENERAL:
Runoff or release to sewer, waterway or ground is forbidden.
ABSORB:
Absorb in vermiculite, dry sand or earth and place into containers.
COLLECT:
Shovel into dry containers. Cover and move the containers. Flush the area
with water.
Prior to flushing, consult Local Water Authorities.
7. HANDLING AND STORAGE
Avoid skin and eye contact. Ventilate well, avoid breathing
vapours. Use approved respirator if air contamination is above
Accepted level.
STORAGE PRECAUTIONS:
Keep in cool, ventilated storage and closed containers.
to
f c Fo
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.
USAGE PRECAUTIONS:
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
CASNo. STD
INGREDIENT NAME:
FORMALDEHYDE
50-00-0
No std.
Co
PROTECTIVE EQUIPMENT:
N o std.
ns
en
UREA FORMALDEHYDEPOLYMER:
MEL
LTEXP STEXP
(8hrs)
(10mh)
2 ppm 2ppm
RESPIRATORS
N o specific recommendation made, but respiratory protection must be used
if the general level exceeds the Occupational Exposure Level (OEL).
PROTECTIVE GLOVES
Chemical resistant gloves required for prolonged or repeated contact. Use
protective gloves made o f rubber or plastic.
EYE PROTECTION
Wear chemical safety goggles where eye exposure is reasonably probable.
OTHER PROTECTION
Use engineering controls to reduce air contamination to permissible level.
9. PHYSICAL AND CHEMICAL PROPERTIES
COLOUR:
APPEARANCE:
ODOUR/TASTE:
SOLUBILITY DESCRIPTION:
VISCOSITY (25C):
White
Liquid.
Formaldehyde
Soluble in water
0.1-2 Pas
EPA Export 25-07-2013:18:58:13
b
- -
. Urea Formaldehyde Resin
Page 3 o f 4
-
pH VALUE:
10. STABILITY AND REACTIVITY
Ca. 8
~~
~~
~
STABILITY:
Avoid contact with acids.
HAZARDOUS DECOMPOSITION:
PRODUCTS:
High temperatures generate Carbon Monoxide (CO) and Carbon Dioxide
(CO,).
11. TOXICOLOGICAL INFORMATION
>5000 mg/kg (oral rat)
No data available
HEALTH WARNINGS:
Exposure: This chemical has good warning properties.
MEDICAL SYMPTOMS:
Irritation of eyes and mucous membranes
TOXICOLOGICAL INFORMATION:
Information relevant to formaldehyde toxicity. In the
EU formaldehyde is classified as a Category 3 carcinogen. This means that
formaldehyde is not known to be carcinogenic to man (Category l), or
regarded to be carcinogenic to man (Category 2). Although at high
concentrations, formaldehyde has been shown to cause cancer in rats, there
is no convincing evidence that the substance induces cancer in man. For
this reason formaldehyde has been placed in the lowest Category 3.
CARCINOGENICITY:
Formaldehyde is classified as a Cat.3 Carcinogen (EU)
to
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TOXIC DOSE - LD50:
TOXIC CONC. LC50:
12. ECOLOGICAL INFORMATION
~
~
~~
Urea formaldehyde Polymer: Slowly, but not readily biodegradable.
TOC - removal 28 days: 6 1% BOD28: 0.62 mg/mg substance.
Nitrification 28 days: 0.45 mg N03-N/mg substance. Formaldehyde; No
bioconcentration. Biodegradation: BODSEOD: 0.68 (readily
biodegradable).
ns
en
DEGRADABILITY:
ACUTE FISH TOXICITY:
Co
I
Formaldehyde - LC50 1.OOO - 100 mg/L (96h)
Urea-Formaldehydepolymer - very low toxicity, no inhibition
of activated sludge at 140 mg/L suspended solids.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
When cured, the resin may be disposed on an ordinary landfill.
Dynea material must be disposed of in accordance with EPA (or other
relevant legislative) requirements. Advice, if required, on the disposal of
waste Dynea Products is available from Dynea Ireland Ltd.
14. TRANSPORT INFORMATION
LABEL FOR CONVEYANCE:
No transport warning sign required.
15. REGULATORY INFORMATION
LABEL FOR SUPPLY:
No classification given.
RISK PHRASES:
Not Classified
SAFETY PHRASES:
S-26
In case of contact with eyes, rinse
EPA Export 25-07-2013:18:58:13
Urea Formaldehyde Resin
Page 4 o f 4
s-36137/39
s-44
S-51
,
Immediately with plenty of water and seek medical
advice.
Wear suitable protective clothing, gloves and
Eye/€ace protection.
If you feel unwell, seek medical advice (show label if
possible)
Use only in well ventilated areas.
16. OTHER INFORMATION
INFORMATION SOURCES
Dynea UK Safety Manual NO. AD2 “Handling Precautions for
Formaldehyde-based Products, Vinyl Emulsions and Hot-melt adhesives”
0
Co
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.
REVISION DATE: 28/01/04
EPA Export 25-07-2013:18:58:13
1.
" ' 2
,
,
z .
,
SAFETYDATASHEET
Liquid Urea Formaldehyde Resin
I IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY
Liquid Urea Formaldehyde Resin
PRODUCT NAME:
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TEL:
ru
Dynocheni UK Ltd,
Alyn Works,
Denbigh Road.
Mold, Flintshire, CH7 1BF Wales.
(01352) 757657
SUPPLIER:
he
(.i
.
SYNONYMS, TRADE NAMES: Aerolite 300, Aerolite G, Aerolite U,
Aerolite UL 4330, Aerolite UL 5144,
Aerolite V, Resin DUL 5289, DUL 5342, DUL 5639, DUL 5678.
EMERGENCY TELEPHONE@):
Tel: 01352 750416 (21 Hours)
2 COMPOSITION/INFORMATION ON INGREDIENTS
CAS No.
ns
en
INGREDIENT NAME
FORMALDEHYDE
HEALTH
1 -3 Y O l \ h V
(class)
T
Co
50-00-0
CONTENTS
UREA-FORMALDEHYDE POLYMER
e
RISK
(R No.)
23/24/25, 34, 40,
13
60-75 o/;,w/w
3 HAZARDS IDENTIFICATION
Irritating to eyes, respiratory system and skin.
Possible risk of irreversible effects.
May cause sensitisation by skin contact.
INHALATION:
Move tlie exposed person to fresh air at once.
INGESTION:
Promptly get affected personnel to drink large volumes of water to dilute the
swallowed chemical. Do not induce vomiting (induction of vomiting should
only be performed upon lhe advicc of qualified medical personnel). Get medical
attention immediately. and rinsc tlie mouth repeatedly with water.
SKIN:
Remove aflecled person froin sourcc or contamination. Wash the skin
immediately with soap and uater.
Safechem N o :11019
Page 115
>>>
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, . r
Liquid Urea Formaldehyde Resin
EYES:
'
EXTINGUISHING MEDIA:
Promptly \vas11 eyes with plenty o f water while lifting the eye lids. Contact
physician if irritation persists.
This material is not flammable. Use extinguishing media appropriate for
surrounding fire.
UNUSUAL FIRE & EXPLOSION HAZARDS:
No unusual fire or explosion hazards noted.
6 ACCIDENTAL RELEASE MEASURES
GENERAL.
Runoff or release to sewer, watenvay or ground is forbidden.
ABSORB.
Absorb in vermiculite, dry sand or earth and place into containers.
COLLECT.
Shovel into dry containers. Cover and move the containers. Flush the area with
water. Prior to flushing, consult Local Water Authorities.
DLING AND STORAGE
to
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op r i
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ht ct
ow ion
ne pu
r r rp
eq os
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fo y.
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se
.
SPILL CLEANUP METHODS:
Avoid skin and eye contact. Ventilate well, avoid breathing vapours. Use
approved respirator if air contamination is above accepted level.
STORAGE PRECAUTIONS:
Keep in cool, dry, ventilated storage and closed containers.
Co
ns
en
USAGE PRECAUTIONS:
8 EXPOSURE CONTROLS AND PERSONAL PROTECTION
INGREDIENT NAME
CAS No
STD
LT EXP
FORMALDEHYDE
50-00-0
MEL.
(8 hrs)
2 PPm
N o Std
UREA-FORMALDEHYDE POLYMER
ST EXP
(15 min)
2 PPm
N o Std.
PROTECTIVE EQUIPMENT:
RESPIRATORS:
N o specific recommendation made, but respiratory protection must be used if the
general level esceeds the Occupational Esposure Level (OEL).
PROTECTIVE GL-VES:
Chemical resistant gloves required for prolonged or repeated contact. Use
protective gloves made of: Rubber, neoprene or PVC.
EYE PROTECTION.
Wear approved chemical safety goggles where eye exposure is reasonably
probable.
Safechem No : I 1019
Page 2 1 5
>>>
EPA Export 25-07-2013:18:58:13
-~
Liquid Urea Formaldehyde Resin
Liquid.
Formaldehyde
COLOUR
White.
SOLUBILITY DESCRIIPTION:
pH-VALUE:
VISCOSITY:
Soluble in water.
8.0-8.5
1.00 11.00 Pas @ 25 "C
l)H-VALUE,CONC:
8.5-8.8
FLASH POINT ("C):
> 100
STABILITY:
See Technical Information - Dynochem UK Ltd.
CONDITIONS TO AVOID:
Avoid contact with acids.
-
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
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d nl
fo y.
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se
.
HAZARDOUS DECOMPOSITION PRODUCTS:
High temperatures generate: Carbon monoxide (CO). Carbon dioxide (C02).
Ammonia or amines.
11 TOXICOLOGICAL INFORMATION
TOXIC DOSE1- LD50:
>5000mg/kg (oral rat)
No data available.
TOXIC C0NC.- LC50:
TOXICOLOGICAL INFORMATION:
Information relevant to formaldehyde toxicity:' In the EU formaldehyde is
classified as a Category 3 Carcinogen. This means that formaldehyde is not
known to be carcinogenic to man (Category I), or regarded to be carcinogenic to
man (Category 2). Although at high concentrations, formaldehyde has been
shown to cause cancer in rats, there is no convincing evidence that the substance
induces cancer in man. For this reason formaldehyde has been placed in the
lowest Category 3.'
en
to
II
APPEARANCE:
ODOURITASTE:
ns
I
Use engineering controls to reduce air contamination to permissible exposure
level.
Co
,
OTHER PROTECTION:
HEALTH WARNINGS:
Exposure; This chernical has good warning properties. Irritant of eyes and
mucous membrancs.
Mild dermatitis. allergic skin rash.
3THER HEALTH EFFECTS:
Formaldehyde is classified as a Category 3 Carcinogen (EEC).
rIEDICAL SYMPTOMS:
Irritation of eyes and mucous membranes.
2 ECOLOGICAL INFORMATION
EGFUDABILITY:
Cechem No :11019
Formaldehyde: No bioconcentration.
Urea formaldehyde polymers are slowly,but no1 readily biodegradable.
Page 3 15
>>>
EPA Export 25-07-2013:18:58:13
Liquid Urea Formaldehyde Resin
Dynochem materials must be disposed of in accordance with the requirements
of 'The Special Waste Regulations 1996'. Advice if required, on the disposal of
waste Dynochem Products is available from Dynochem UK Ltd.
LABEL FOR CONVEYANCE:
No transport warning sign required.
ROAD:
ROAD TRANSPORT NOTES:
No label required for Road Transport
RAIL:
RAIL TRANSPORT NOTES:
N o label required for Rail Transport
SEA:
SEA TRANSPORT NOTES:
N o label required for Sea Transport
AIR:
AIR TRANSPORT NOTES:
No label required for Air Transport
f c Fo
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.
DISPOSAL METHODS:
LABEL FOR SUPPLY:
Possible risk of irreversible effects.
May cause sensitisation by skin contact.
S-26
In case of contact with eyes, rinse immediately with plenty
of \vater and seek medical advice.
Wear suitable protective clothing. gloves and eydface
protection.
Use only in well ventilated areas.
ns
R-40
R-43
Co
RISK PHRASES:
en
to
HARMFUL
SAFETY PHRASES:
S-36137f 39
S-5 1
UK REGULATORY REFERENCES:
The Control of Substances Hazardous to Health Reguht'ions.
The Chemicals (Hazard Information and Packaging for Supply) Regulations.
EH40 Occupational Esposure Limits.
Carriage of Dangerous Goods (Classilicalion, Packaging, and Label1ing)and use
of Pressure Receptacle Regulations.
Carriage of Dangerous Goods by Road Regulations.
Special Waste Regulations 1996 (SI 1996 No. 972).
Health and Safety at Work Act 1974.
INFORMATION SOURCES:
Dynochem UK Ltd Safety Manual No.AD2
'Handling Precautions for Fornmaldehyde-based Products.Vinyl Emulsions and
b
3;
Safechem No :11019
Page 4 1 5
>>>
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-”
Liquid Urea Formaldehyde Resin
REVISION DATE:
Co
ns
en
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f
A
Safechem No :11019
Page 5 1 5
EPA Export 25-07-2013:18:58:14
se
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*'
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EPA Export 25-07-2013:18:58:14
se
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UREA FORMALDEHYDE
VENEERING RESIN
,
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EPA Export 25-07-2013:18:58:14
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EPA Export 25-07-2013:18:58:14
I
REVISION DATE :04-03-2004
--
U
i
SAFETY DATA SHEET
Prefere 4152 (Aerolite
I IDENTIFICATIONOF THE SUBSTANCE/PREPARATIONAND
COMPANYlUNDERTAKlNG
PRODUCT NAME
Prefere 4152 (Aerolite V)
APPLICATION
Urea formaldehyde resin used for veneering.
SUPPLIER
Dynea UKLtd.
Alyn Works,
Denbigh Road,
Mold, Flintshire CH7 IBF
Tel: 01352 757657
Emergency Tel: 01352 750416
- - ~
EC No.
-
__
CAS-NO.
Content
Classification
200-001-8
50-00-0
I-5%
Carc3;R40 T;R23/24/25C;R34 R43
SODIUM HYDROXIDE
215-185-5
1310-73-2
< 1%
C,R35
he
7732-18-5
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WATER
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FORMALDEHYDE
ru
...%
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_ _ _ _ _ _ _ - ~Name
UREA-FORMALDEHYDE POLYMER
6807145-4
3 HAZARDS IDENTIFICATION
30-60%
60-100%
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4 FIRST-AID MEASURES
nt
o
Limited evidence of a carcinogenic effect. May cause sensitisation by skin contact.
CLASSIFICATION
Carc 3;R40. R43.
GENERAL INFORMATION
Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any
discomfort continues. Keep affected person under observation. If unconcious, loosen tight clothing. Place unconscious
person on the side in the recovery position and ensure breathing can take place. Perform artificial respiration if breathing
has stopped.
INHALATION
Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.
INGESTION
Rinse mouth thoroughly. DO NOT induce vomiting. Get medical attention immediately.
SKIN CONTACT
\
Wash skin with soap and water. Remove contaminated clothing.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical
attention promptly if symptoms occur after washing.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Use fireextinguishing media appropriate for surrounding materials.
SPECIAL FIRE FIGHTING PROCEDURES
Cool containers exposed to flames with water until well after the fire is out.
SPECIFIC HAZARDS
Fire creates: Carbon dioxide (C02). Carbon monoxide (CO). Nitrous gases (NOx).
EPA Export 25-07-2013:18:58:14
.
.
c]
:*
d'
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Product is partly soluble in water. Stop leak without risk. Do not discharge into drains, water courses or onto the ground.
SPILL CLEAN UP METHODS
Absorb in vermiculite, dry sand or earth and place into containers. Remove containers and flush area with water. Inform
Authorities if large amounts are involved. For waste disposal, see section 13.
7 HANDLING AND STORAGE
f c Fo
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se
.
USAGE PRECAUTIONS
Avoid spilling, skin and eye contact. Provide good ventilation. Eye wash facilities should be available when handling this
product.
USAGE DESCRIPTION
Read and follow manufacturetsrecommendations.
STORAGE PRECAUTIONS
Keep containers tightly closed.
se
nt
o
INGREDIENT COMMENTS
MEL = Maximum Exposure Limit. OES = Occupational Exposure Standard. Sk = Skin Absorption
PROTECTIVE EQUIPMENT
Co
n
PROCESS CONDITIONS
Provide eyewash station.
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
Respiratory protection must be used if air contamination exceeds acceptable level.
HAND PROTECTION
Chemical resistant gloves required for prolonged or repeated contact. Polyvinyl chloride (PVC). Rubber (natural, latex).
Neoprene.
EYE PROTECTION
Wear approved safety goggles.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Liquid
COLOUR
Colourless to White
ODOUR
Formaldehyde
SOLUBILITY
Slightly soluble in water.
BOILING POINT ("C)
pH-VALUE, CONC. SOLUTION
FLASH POINT ("C)
>loo
8-9
> 100 CC (Closed cup).
RELATIVE DENSITY
VlSCOSlTY
1.28-1.31 @ 25 "C
1000-2200mPas @ 25 "C
EPA Export 25-07-2013:18:58:14
REVISION DATE : 04-03-2004
Prefere 4152 (Aerolite I()
STABILIlY
Stable under normal temperature conditions. Storage at higher temperatures will give increased viscosity. This gives a
decrease in shelf-life.
HAZARDOUS DECOMPOSITION PRODUCTS
None at ambient temperatures. Fire or high temperatures may form harmful vapours (CO, C02, NOx).
f c Fo
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TOXICOLOGICAL INFORMATION
LD50 (oral,rat): 800mglkg (formaldehyde)
Formaldehyde is a category 3 carcinogen.
GENERAL INFORMATION
Irritant properties are the main hazard.
INHAlATlON
Vapour may irritate respiratory system or lungs. Gas Or vapour is harmful on prolonged exposure or in high
concentrations.
INGESTION
May cause stomach pain or vomiting.
SKIN CONTACT
Slightly irritating. Prolonged or repeated exposure may cause severe irritation.
EYE CONTACT
Irritatingto eyes. Repeated exposure may cause chronic eye irritation.
HEALTH WARNtNGS
Mild dermatitis, allergic skin rash.
Inhalation of high volume of vapour may cause: Irritation of nose and throat. Ingestionmay cause: Stomach pain.
MEDICAL SYMPTOMS
Nausea, vomiting. Sneezing. Eczematous irritation.
MEDICAL CONSIDERATIONS
Skin disorders and allergies.
Co
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o
ECOTOXICITY
The product is not expected to be hazardous to the environment.
MOBILITY
Partially water soluble.
BIOACCUMULATION
No bioaccumulationexpected.
DEGRADABILITY
The product is expected to be slowly biodegradable.
ACUTE FISH TOXICITY
Polymer: Low toxicity expected.
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements. Confirm disposal procedures with
environmental engineer and local regulations.
ADR CLASS
Not classified for transport:
ADRIRIDIIMDGIIATAICDG
CPU
LABELLING
EPA Export 25-07-2013:18:58:14
Prefere 4152 (Aerolite)!b
Harmful
CONTAINS
FORMALDEHYDE ...%
RISK PHRASES
R40
R43
Limited evidence of a carcinogenic effect.
May cause sensitisation by skin contact.
S36137139
Wear suitable protective clothing, gloves and eyelface protection.
This material andlor its container must be disposed of as hazardous waste.
SAFETY PHRASES
S60
UKREGULATORYREFERENCES
EH40 Occupational Exposure Limits.
EU DIRECTIVES
Dangerous Substance Diredive 67/548/EEC. Dangerous Preparations Directive 88/379/EEC. Safety data sheet directive
91/155.
16 OTHER INFORMATION
Co
ns
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to
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RISK PHRASES IN FULL
NC
Not classified.
Toxic
by inhalation, in contact with skin and if swallowed.
R23124125
R34
Causes bums.
R35
Causes severe bums.
R37
Irritating to respiratory system.
Limited evidence of a carcinogenic effect.
R40
May cause sensitisation by skin contact.
R43
.
04-03-2004
se
RNlSlON COMMENTS
Change of product name.
REVISION DATE
4
14
I
EPA Export 25-07-2013:18:58:14
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HOT MELT ADHESIVE
FOR EDGE BANDING
EPA Export 25-07-2013:18:58:14
EPA Export 25-07-2013:18:58:14
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.
Co
I.
.L
'I
FIRST
me-d
1
1
faformtion
hsshiSb hazard ariees $rom the solid P U h 6 k n d e . Because
\e high working temperature. the danger of b u r n s e x i s t s .
I
EPA Export 25-07-2013:18:58:14
EC-Safety data sheet
W
Date printed :
KDNR.
. .
4.3
Amended oh:
13 . 0 4 , 9 4
2
Version;
1
:
Trade name:
4.2
6.10.94
Page:
-
RAKOLL-SK K4/ssULV
8 ,E .Fuller GmbH Nienknurg
-
O n hbdatian
are izlhded when working on the melt, p r o v i d e f r e s h
air. In case of i r r i t a t i o n of the respiratory system, seek
medical attention,
If vapours
On contact with
the skin
Treat as f o r b u r n s : an contact with the molten product, cool
quickly with cold water. Do not remove solidified p r a d u c t
from the s k i a . Seek medical attention.
O n oantaet with the eye
After c o n t a c t of h o t melt with the e y e s , wash immediahely
u n d e r running water for 115 minutes and seek medical attention!
4.5
On
4.6
Information for the phyeician
8WdOWhlg
Consult a p h y s i c i a n .
- I
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
4.4
Suitable, extinguishers
Adapt t o fire's surroundings: w a t e r , foam, p o w d e r , C 0 2 , sand
5.2
Exti~~guiehers
uneuitahle on safety grounds
n o t spplieable
5.3
Particular hazards assodated with the substance, its combustion products or
Co
ns
en
5.1
resulting gases
Main combustjon p r o d u c t s : C O , C02. a c r o l e i n and acetic acid.
5.4
Particular protective equipment
Wear breathing protection which i s independent of the
surrounding air.
-
6
5 -1
MEASURES TO BE TAIUZN ON ACCIDENTALRELEASE
PtecauWonary measuresl for humans
a r e needed far spilt grssulate.
If melt leaks aut, take precautibns to avoid burns.
N o particular precautions
i- 2
Precautionary mearruxes for the snvirohlaent
N o spacial precastiona n e c e s s a r y ,
8.3
Method for cleasing/spillagc
Clean up a n y spilt granula'
- L , i m v ' :
.'.leu ' r a k e d melt t o cool.
EPA Export 25-07-2013:18:58:14
E C - S a f e t y data aheet
W
Date p r h t t e d :
KDNB. . . :
1
Trade name:
7.1.
Amerrded on:
6.10.94
Page:.
13 . 0 4 . 9 4
RAKOLL-SK #4/58YLV
Version:
H . B.Fuller GmbH
3
1
-
Nian 1) urg
I
Bandling
8 a f O handling
special protective measures zleeded.
l[nfOrmatiQn OD.
ND
se
.
Ihforruatioa on protection agabxst fire and explosion
he
ru
nscesaary.
7.2
Storage
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
N o special precautions
Bequiremeats for storerooms and containers
Store d r y .
Infarmation on storage together with other s u b ~ t a n c s e
not applicable
10
-
20 ' C
Co
n
se
nt
o
Storage temperature:
8
L m T S OF EXPOSURE AND
8.1
Additiond informatioh OR the nature of technical equipment
Provide adequate ventilation at the workplace.
8.2
Componemts with workplace-relevsat concentratbh limits
8 -3
Personal protective equipment
EQUIPMENT FOR PERSON& PROTECTION
General proteation and hygiene
px886ure8
W h e n handling the melt, CID not inhale vapours and avoid
c o n t a c t with the s k i n ,
Breathisg protection
Not Decedsarp where roam is adequately ventilated.
Eland protection
Weat-resistant gIoves are to be worn only when bandling t h e
melt.
Eye protection
Fully enclosed protective glaases for handling the melt,
Body protection
W e a r suitable industrial c l o t h i n g .
i
I
EPA Export 25-07-2013:18:58:14
EC-Safety data sheet
Date printed :
KDNR.
-
IS ,04 ,94
OD:
Version:
1
Appearance
granulate
Beige, RAL 1001
neutral
Form:
Colour :
Odour:
Data relevant to safety
CHANGE OF CONDITION
se
.
ru
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
96
I
Inflammability :
Ignition terpper - :
approx.
Self-igniting properties:
-
"C
QC
nt
o
Fire promotihag properties:
'C (at
81 " C
'C
"C
104 " C
73 -
he
apptox ,
Softening p . / r a n g e : a p p r o x .
Hardening p . /range : a p p r o x .
Dropping p ./ t a a g e : approx.
Melting p . /range:
approx Flame point:
approx
TESTED ACCORbXNG TO
ot
Boiling p ./range:
TEMPERATURE
Co
n
9.2
A=~?hded
6.10.94;
:
4
se
9.1
.
Page:
Explosion hazard :
lower:
EXPLOSION LUECTS
Vapour pressure
...
-
Bulk deasity.
-
Deneity
. .
..-
upper:
n.a.
I
:
20
:
kg/ms
'C)
HBF
(at
S alubility
in water
"C)
insoluble.
ih
app.
PE value:
(at
g/l
(at
g / i water) (at ZS'C)
.--
Dis trib UCion coeffioiea t B -octanol/aratez
log POW
Components :
Viscosity
approx.
80000 rnPa5
5
20'. ' 0 Brookfield R V T
C
HBF
'c1
EPA Export 25-07-2013:18:58:14
-
EC-Safety data sheet
Date printed:
KDNR.
.
Amended o n ; 13 . 0 4 . 9 4
6.10.94
. :
Trade name:
Page:
RAKOLL-SK K4/58ULV
Versiofr:
1.
-
INFOBMATION ON ECOLOGY
12.1
Details of elimination fpereistehce aad decazppoaitiion)
12.2
Properties relevant t o the ecology
12.4
Further d e d s ob ecology
13
INFOEMATION ON DISPOSAL
-
Product
Waste kev:
Waste:
to
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
12
15.1
6
H . B . F u l l e r GmbH Nienburg
I
--
Duty a€ ptoviding evidence:
Recommaadation :
,Contazninrrted PackaPing
Rec ammendation :
R e c o m e n d a t i o a : Empty package of all reBiduee ( d r i p f r e e ,
run free, scraped but). Channel package preferably into
lccal reuse / r e c y c h g while a b Berving local/ Bational
ns
en
13 - 2
Co
I
,
regulatiohs .
Raeomnr- cleaning agent:
not applicable
14
WOKMATION
14.1
Overland transport AnR/RID and GGVS /GGvJE
-
ON TRANSPQBT
Warning notice ->
Class
:
Hazard-nr :
Number/letter;
b u b s t . -nr:
Description af goods :
Bemarkcs :
Not a hazardous substance in term6 of transport regulations.
24.2
Transport on domeekic waterways AnNIADN'B
ADNf ADN R
Warning uotice ->
Claes
Category:
Numb er / let t er :
beocrip tlas of goods :
Remarks :
not a p p l i c a b l e
EPA Export 25-07-2013:18:58:14
0 ‘94
o&:55
N.A.A.
a 3 5 3 18731952
-
+++ F I N S A FOREST
+++ NAA I R L W
-
EIBF-NI EXPORT
rploo1/ooa $
-
@ O06/009
- -.-
I-
SAFETY DATA SHEET IPI ACCOmANCE WITH 911/1$5/EEC
E C -Sa fe t y data sheet
Date printed :
. . :
Amended on:
8.10.94
13 . 0 4 , 9 4
KDNR.
Trade name:
RAKOLL-SK K4fSVLV
Paga:
5
Version:
1
H.B .Fuller GmbH
-
Wienhurg
TESTED ACCORDING, TO
Solvent separation test . - .
Soltent content - . . . . . -
n.B,
Further iuformatinn
---
be avoided
ru
COAditioIX8 t o
not applicable
se
.
STABILITY A X D REACTIVITY
he
10.1
n.a.
%
ot
10
%
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
9.3
- .:
. .:
10.2
Snbatances t o be avoided
n o t applicable
10.3
Hazardoat3 decomposition pmdacts
10.4
Further information
Zinc and c o p p e r in any form accelerate t h e reaction and
the thermal decomposition.
11
I;N”EOBMATION
Co
n
se
nt
o
If severely overheated, acrolein, acetic acid, carbon monoside
and carbon dioxide can be formed,
ON TOXICITY
Data for eamponent:
11.1
not tip F lica ble
Acute toxicity
Sensibilisation :
Not known.
11.2
Subacute to chronic toxicity
11.3
Experience in hamane :
According to p r e a e n t knowledge, no damage
expected w h e n u s e d c o r r e c t l y .
11.4
to
health is t o be
Further information:
none
I
EPA Export 25-07-2013:18:58:14
aSAFETY DATA SHEET IN ACCORDAMCE WITH 9V155/EEC
EC-Safety data sheet
Date printed :
JmNR..
.
:
6.10,94
Amended oa:
13 . 0 4 , 9 4
W O L L - S K K4/58utV
T r a d e name:
T A Air
Class:
8
Version:
1
H . B .Fuller GmbH Nienburg
Number:
Water ctsaztamination risk chssr
Page:
.$zaportion in %;
0
( SI elf
(f .liquids )
- clase ifi cation
I .
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
ot
he
ru
se
.
Other regdatiws, Limitatione and acts of prohibition:
Ohserve Berufsgenossenschaft UVV (VBG 81) :
“Working with adhesiveen.
This information is based oa our preeent-day knowledge, b u t
P U ~h p l y any aesarance P f product charaetsriotica.
does
-5
en
to
-
ns
.
rjot applicable
not determined
ZF = Method of K.B. Fuller GmbH
1
Co
n
EPA Export 25-07-2013:18:58:14
EC-SafeCy data sheet
te p r i n t e d :
1NR. .
:
.
rde name:
Amended on:
6.10.94
13.04.94
R13XOLL-SK K4/58VtV
Page:
7
Version:
1
H4B.Fuller GmbH Nien burg
-
3
-
Sea transport IBIDGjGGVSee
W G l GGVSee
Class
MFAG.
Correct t e c h a . name:
.
UN-NO.
:
PG :
EMS -NO.
:
Marim pollutant:
:
Remarks :
not applicable
Air tnmsport ICAO-TI and IATA-DEB
se
.
4
ot
he
ru
$CA0/ IATA
Class
C o r r e c t techa - name:
f c Fo
op r i
yr ns
ig pe
ht ct
ow ion
ne pu
r r rp
eq os
ui es
re o
d nl
fo y.
ra
ny
Remarks :
not applicable
Farther information
S t o r e in a dry place.
EC guidelines
se
Marking according t o
nt
o
REGULATIONS
-
Co
n
5
Identification letter and hazard description for the ptoduct:
Labelling as defined b y Chemical Act n o t mandatory
COmpObePt(8) responsible
not ap p lidable
Ear hazard Labelling: contains:
Particular. designation fnr certain preparertiona (acscardiag t o Appendix 11 of
the Guidelines on Preparations 89/379/EEC
not applicable
National reg daticma
Additional classification according
not applicable
to
Dangerous Goods Act Appendix I1
No. :
Remarkg :
not applicable
Information 09 working limitations !
not applicable
A ot ap plica b 1e
Malfanctiaae A c t :
VbF Class:
Temperature class s c c o ~ d .t o DIN 57165:
B
Fire c h i w according to DIN l b o l l :
i
EPA Export 25-07-2013:18:58:14