Review Sheet for Chemistry First Semester Final Refer to your class notes, worksheets, and the textbook to complete this review sheet. Study early so that you will have time to ask questions about what you don’t understand. For the exam, you will need to bring 2 number 2 pencils, a scientific calculator (there will be NO sharing and NO cell phones for calculations) and you may bring a 4x6 card with formulas, equations etc that you feel you need. This will be collected with your test and must have your name on it. (MUST be a 4x6 CARD, no paper cut to 4x6- MUST be HAND written) Things you need to know: In addition to the sections below: SI Base Units- Pg 73 Metric Prefixes- Page 74 Know how to convert from one unit to another (ie: kilometers to millimeters) KNOW YOUR ELEMENTS – The ones you were tested on! (name, symbol and spelling counts!) KNOW the Polyatomic Ions on Pg 257 (charge, name, formula) KNOW the Common Metal Ions with more than one charge (table on page 255) KNOW the Prefixes for Covalent molecule names (page 269) BE ABLE TO USE the Significant Figures rules Ch. 1: Introduction to Chemistry manipulated (independent) variable responding (dependent) variable observation theory steps in scientific method problem solving in chemistry Ch. 2: Matter and Change chemical change chemical property chemical reaction compound element filtration gas heterogeneous mixture homogeneous mixture conservation of mass liquid mass mixture phase physical change physical property product reactant Properties of Matter Mixtures Elements and Compounds Chemical Reactions Matter: Anything that takes up space and has mass Physical Changes and Chemical Changes Define each. How can you tell the difference between the two? solid solution substance vapor volume Classify the following as physical or chemical changes: a. spoiling of milk ___________________ b. bending wire _____________________ c. cutting paper _____________________ d. rusting of a nail ___________________ Identify the following as pure substances, homogeneous mixtures or heterogeneous mixtures: a. copper ______________________ b. sweetened tea ________________ c. sand and water _______________ d. calcium carbonate (CaCO3) ________________________ Sketch particles in the three states of matter. How close are the particles and how much do they move? Solid Liquid Gas Calculations using the Law of Conservation of Mass for Reactions 4g H2 + ?? g O2 → 36g H2O Ch. 3: Scientific Measurement absolute zero accepted value Celsius scale density energy error experimental value gram International System of Units (SI) joule (J) Kelvin scale (K) kilogram (kg) liter (L) meter (m) percent error scientific notation significant figures and rules weight vs. mass Be able to calculate percent error, density, and convert between Kelvin and Celsius Be able to convert between scientific notation and decimal or integer numbers Identify the number of sig figs; addition, subtraction, multiplication and division with sig figs. Ch. 4: Atomic Structure atom atomic mass atomic mass unit electron group in Periodic Table isotopes mass number neutron proton period in Periodic Table Be able to find the atomic mass and atomic number on the Periodic Table. Be able to calculate the number of neutrons. Know how to identify the number of electrons. Know how to identify isotopes and write their formulas. Atom For this Carbon–14 isotope, 146 C • Atomic number = _____, Mass number = _____, • # of protons = _____, # of electrons = _____, # of neutrons = _____. Atomic Masses: What is the difference between the mass number for Carbon–14 and carbon’s atomic mass of 12.011 amu? Calculate the atomic mass of lithium is one isotope has a mass of 6.0151 amu and a percent abundance of 7.59% and a second isotope has a mass of 7.0600 amu and a percent abundance of 92.41%. Ch. 5: Models of the Atom atomic orbitals aufbau principle electromagnetic radiation electron configurations energy levels ground state of electron sublevels types of sublevels (s, p, d, f) Hund’s Rule photons quantum Pauli exclusion principle spectrum principal energy level Heisenberg uncertainty principle (Honors) Be able to identify the electron configuration of elements. Electron Configurations. What element has the electron configuration [Ne]3s23p1? _____ • What does the 3 mean in 3s2 ? • What does the s mean? • What does the 2 mean? • How many valence electrons will an atom of this element have? • How many electrons will an atom of this element lose to form an ion? Why? • Write out the orbital configuration according to the Aufbau principle, Hund’s rule and the pauli exclusion principle. Emission (or bright-line) Spectrums (Honors only) • What is needed for an electron to “jump” to a higher energy level? • What happens when an “excited” electron falls back to its ground state? • What does an emission spectrum allow one to do? Characteristics of subatomic particles Particle Mass Charge Location in atom Proton Neutron Electron Ch. 6: The Periodic Table alkali metals alkaline earth metals anion atomic radius cation electronegativity halogens inner transition metals ionization energy metalloids metals noble gases nonmetals transition metals Know the four periodic trends of ionization energy, electronegativity, ionic size and atomic size. Periodic trends Locate or define parts of the periodic table: • Groups • Periods • Transition metals (d & f blocks) vs. Representative Elements (s & p blocks) • Alkali metals, Alkaline Earth metals, Halogens, Noble Gases Periodic Trends: Increasing or Decreasing from top to bottom or left to right? Top to Bottom in a Group Left to Right across a Period electronegativity ionization energy atomic size Ionic size Elements in the same ___________ have similar physical and chemical characteristics because the (group, period) they have the same number of _____________________. (atoms, protons, neutrons, electrons, valence electrons) Draw a electron dot diagram (or Lewis Dot structure) for Be and for N correct number of valence electrons showing the From their positions on the periodic table, what charges would the ions of Be and N have? Gains or loses electrons? Be Symbol for ion Gains or loses electrons? Symbol for ion N Properties of Metals vs. Nonmetals vs. Metalloids Metals Nonmetals Luster? Malleable vs. Brittle Conducts electricity & heat? Typical state(s) at room temperature Metalloids Ch. 7: Ionic and Metallic Bonding chemical formula electron dot structure for ions halide ion ionic bonds ionic compounds metallic bonds octet rule valence electrons p. 192 Common Anions Key concepts: Ions Ionic Bonds and Ionic Compounds Bonding in Metals Ch. 8: Covalent Bonding covalent bond coordinate covalent bond diatomic molecule double covalent bond hydrogen bonds molecular compound Key concepts: molecule nonpolar covalent bond polar bond polar covalent bond polyatomic ion electron dot structures 8.1 Molecular Compounds 8.2 Nature of Covalent Bonding 8.4 Polar Bonds and Molecules triple covalent bond unshared electron pair structural bond molecular formula single covalent bond VSPER (8.3 Honors) Ionic vs. Molecular Compounds: Ionic bonds are formed when a ____________ and a _________________ combine. Metals lose electrons and form _____________ while nonmetals gain and electrons form __________. Molecular compounds form when a ______________ and a _______________ combine as they share electrons. Identify the following pairs of atoms as potentially forming an ionic or molecular compound: Mg and Cl ____________ I and F _________________ P and Cl _______________ Ag and S _____________ K and Br ________________ Sn and O _______________ Covalent Bonding in Molecules Draw Lewis Structures (dot diagrams) for HCl, H2S, CH2Cl2, and O3. Use Lewis Structures to predict molecular shapes and polarity of molecules • Identify shapes of the molecules as: Linear, Bent, Pyramidal, Trigonal Planar, or Tetrahedral. • Use electronegativity values to determine if the individual bonds in the molecules above are polar. • Look at the polarity of the bonds and the symmetry of the molecules above to determine if the molecules are polar (if one side of the molecule will be more negative than another). H 2.1 Li 1.0 Na 0.9 K 0.8 He Be 1.5 Mg 1.2 Ca 1.0 Lewis Structures & Total # of Valence Electrons Structural Formula B 2.0 Al 1.5 Ga 1.6 C 2.5 Si 1.8 Ge 1.8 N 3.0 P 2.1 As 2.0 O 3.5 S 2.5 Se 2.4 N2 F 4.0 Cl 3.0 Br 2.8 Ne Ar Kr HCl Electronegativity Difference (x) Type of Bond 0.0 ≤ x ≤ 0.4 Non–polar covalent 0.4 < x < 2.0 Polar covalent 2.0 ≤ x Ionic H2 S CH2Cl2 How do you know if a Bond is polar or nonpolar? How do you know if a molecule is polar or nonpolar? Properties of Ionic and Molecular Compounds Molecular Compounds Combination of elements involved (metals? nonmetals?) How is bond formed? Ionic Compounds O3 Typical state(s) at room temperature Melting and boiling points (relatively high or low?) Conduct electricity if dissolved in water? Ch. 9: Chemical Names and Formulas Know how to name ionic compounds, molecular compounds, and polyatomic ions. p. 257 Naming Molecular and Ionic Compounds Naming molecular compounds • Name: N2O: ___________________________ and NO2 ____________________________ • Naming Ionic Compounds Name: Li2O ___________________________ and (NH4)2SO4 __________________________ • Name: FeO __________________________ and Sn3(PO4)4 ___________________________ • Name: NaHCO3 ______________________ and CuCl2 _______________________________ Formulas of Molecular and Ionic Compounds Write formulas for the following molecular compounds: Water _____________________________________ silicon dioxide _________________________ Phosphorous trihydride _______________________ dioxygen difluoride _____________________ Lead (II) hydroxide __________________________ chromium (III) sulfate ___________________ Write formulas for: _________________ Ba2+ with OH– ___________ iron (III) sulfide Na+ with OH– ___________ NH4+ with PO43– ______________ magnesium oxide____________