PROQUIMAC PFC S.A. Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Product Coloration of Fertilizers: Main Reasons: 1. Coloration of fertilizers helps end users to their right identification and usage, as it enables to easily distinguish the different types of products. 2. It is a very good tool to hide their formulation and protect the products against competition. 3. As tool of marketing, fertilizer can be coloured with the corporative colours of the company. 4. We use the coloration to improve the aspect and the uniformity of the product. 5. To differentiate clearly the different blends that we can manufacture. 6. For all these reasons, coloration provides to the fertilizers an important added value, and it is a field with a great projection in the short and medium term. Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Processes of Coloration Processes of Coloration (they mainly answer to the physical state of fertilizer). 1. Liquid fertilizers: By means of solubility of the colour in the different solutions or emulsions. 2. Crystalline fertilizers: By means of mixture of colours in powder form, not water soluble. 3. Solid fertilizers like NPK type: For this type of fertilizers, probably the most common, two different processes are used for the coloration : • PROCESS IN MASS This process consists of colouring the paste of the fertilizer before the process of granulation, that is to say, before the formation of the granule of fertilizer: for it we must apply the dispersed pigment in liquid form in the blender. • TROMMER or CONDITIONER In this case the dye is applied once the fertilizer has passed through the blender and through the granuler, that is to say, it is applied in the conditioner or TROMMER once we have the fertilizer in grain. It is a superficial application of colour, on the surface of the granule. Occasionally we can colour different mixtures of fertilizers (Blendings) in the same Trommer. Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Product ® FERTIMAC Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Product FERTIMAC® - Pigments and Dispersions for the Coloration of Fertilizers Proquimac presents his series of dispersed pigments FERTIMAC®, ideal to colour and coat all type of fertilizers (e.g. NPK). FERTIMAC® is a registered trademark which formulation is made both in liquid and in powder. It has been developed essentially to avoid interferences among its components to guarantee the non pollution in the treatments of lands. Proquimac offers a wide range of colours in his pigmented dispersions as the Black, Blue, Green, Red and Yellow, being able to supply also any colour formulated by our customers, including likewise corporative colours, and also pigments 100%. The range FERTIMAC® covers all kinds of fertilizers like NPK, Urea, Nitrates and Blendings. Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Liquid Fertimac PRODUCT (LIQUID) FULL REDUCED C.I. PIGMENT % PIGMENT LIGHT FASTNESS (1-8) pH FULL REDUCED CHEMICAL RESISTANCE ALKALI ACIDS Fertimac Yellow 14-L PY14 30-40 7-9 6 6 4-5 5 Fertimac Orange -L PO13 30-40 7-9 6 6 2 3 Fertimac Red 2-L PR2 30-40 7-9 6 6 5 5 Fertimac Brown 62-L PBR6 50 7-9 8 8 5 5 Fertimac Green 7-L PG7 30-40 7-9 8 6 5 5 Fertimac Blue 15-L PB15:0 30-40 7-9 8 6 5 5 Fertimac Black 7-L PBK7 30-40 7-9 8 6 5 5 Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Fertimac in Powder PW PRODUCT (POWDER) LIGHT FASTNESS (1-8) FULL REDUCED CHEMICAL RESISTANCE C.I. PIGMENT FULL REDUCED ALKALI ACIDS Fertimac Yellow 1 PW PY1 8 5 5 5 Fertimac Rojo 2 PW PR2 4-5 2-3 5 4-5 Fertimac Orange PW PO13 5 2-3 5 4-5 Fertimac Blue 153 PW PB153 8 5 5 5 Fertimac Green PW PG7 8 5 5 5 Fertimac Prussian Blue PW PB27 8 5 5 5 Fertimac Black PW PBK7 6-7 4-5 4-5 4-5 Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Fertimac in Powder PW-15 PRODUCT (POWDER) LIGHT FASTNESS (1-8) FULL REDUCED CHEMICAL RESISTANCE C.I. PIGMENT FULL REDUCED ALKALI ACIDS Fertimac Yellow 1 PW15 PY1 8 5 5 5 Fertimac Red PW15 PR2 4-5 2-3 5 4-5 PO13 4-5 2-3 5 4-5 Fertimac Blue PW15 PB15 8 5 5 5 Fertimac Green PW15 PG7 8 5 5 5 Fertimac Prussian Blue PW15 PB27 8 5 5 5 Fertimac Black PW15 PBK 7 6-7 4-5 4-5 4-5 Fertimac Orange PW15 Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Product CONACERT WATER SOLUBLE SYNTHETIC DYES Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Range WATER SOLUBLE SYNTHETIC DYES (Food grade) PROQUIMAC presents his series of water soluble Synthetic Dyes for applications, between others, in liquid fertilizers. These are organic dyes obtained by chemical synthesis, and they are supplied in powder for being solved or dispersed in the product. These dyes have a purity of 70-85% being the majority of the remaining percentage organic salts produced during the manufacturing process, which maximum allowed quantities are fixed in the corresponding European directives. Therefore, synthetic dyes do not have toxicological effects, they possess a uniform quality that guarantees a very precise shade, which makes much easier their application. We have a wide range of ideal dyes to work at any pH condition. Conacert: pH 4-8 Proquidet: to consult stabilities. Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Synthetic dyes: CONACERT SOLUBLE SYNTHETIC DYES EEC APPLICATIONS EEC Food & Pharma Cosmetics INCI U.S.A. FDA Quinoleine Yellow 70% Conacert E-104 C.I. 47005 NP E-102 C.I. 19140 FD & C YELLOW 5 E-110 C.I. 15985 FD & C YELLOW 6 Ponceau 4R Conacert E-124 C.I. 16255 NP Carmoisine 85% Conacert E-122 C.I. 14720 NP Brilliant Blue Conacert E-133 C.I. 42090 FD & C BLUE 1 Patent blue V 85% Conacert E-131 C.I. 42051 NP Tartrazine 85% Conacert Sunset yellow 85% Conacert Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Synthetic dyes: CONACERT SOLUBLE SYNTHETIC DYES EEC APPLICATIONS EECNº Food & Pharma Cosmetics INCI U.S.A. FDA Mint Green Conacert Consult formule (Several formules) consult Violet Consult formule consult Black PN Conacert E-151 C.I 28440 NP Brown HT Conacert 70% E-155 (C.I. 20285) NP NP Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Range ® PROQUIDET Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Product PROQUIDET® - Water Soluble Technical Dyes The PROQUIDET dyes range include dyes of different types: acid, basic and direct. They are water soluble dyes with a wide field of application: fertilizers and phytosanytary products, colouring of seeds and artificial flowers and other products where it is required water soluble dyes. The difference against the water soluble synthetic dyes is that the PROQUIDET range can be used at more extreme pH conditions, being in this case more effective than the CONACERT range. The range of colours and shades is very wide. Stabilities depend on each product, and the technical department can advise the most suitable depending on the characteristics of composition and pH of the fertilizer which has to be coloured. Some of the PROQUIDET dyes can also be supplied in liquid form. PROQUIDET dyes are packed in cardboard drums, with inner polyethylene bag. All PROQUIMAC dyes are labelled in agreement with the labelling norms of the EEC. Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Proquidet dyes ORIENTATIVE FASTNESS SOLUBLE TECHNICAL DYES NEUTRAL Fluorescein Proquidet C-126 ( fluorescent) ACID BASIC Low light stability Colourless Medium Good Good Good Good Good Colourless Good Good Good Good Good Good Good Good Medium Low light stability Blue Medium Yellow Proquidet 1227 Orange Proquidet 1433 Red Proquidet 1132 Red Proquidet 1289 Green Proquidet 3177 Fluorescent Green Proquidet 163 Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Proquidet dyes ORIENTATIVE FASTNESS SOLUBLE TECHNICAL DYES NEUTRAL ACID BASIC Good Green pH<11 Medium Medium Medium Good Good Medium( violet ) Good Good colourless Blue Proquidet 1814 Blue Proquidet 1390 Black Proquidet 1031 Violet Proquidet 1045 Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com Quality and Services • Quality control of all products and raw materials. • UNE-EN ISO 9001 : 2000 BY TÜV. • Service of Customer’s Orientation. • Technical Assistance. • R + D in new products. Proquimac PFC S.A./ C/Berlín, 3 Pol. Ind. Can Torrella, 08233-Vacarisses, BARCELONA, SPAIN www.proquimac.com