Report 4: Metathesis – To Exchange or Not Hopefully here for the Report Form Note: In preparing this report you are free to use references and consult with others. However, you may not copy from other students’ work (including your laboratory partner) or misrepresent your own data (see honor code). Name: ___________________________________________ Section: __________________________________________ Part 1: Metathesis Reactions 1. Copper (II) sulfate + sodium carbonate Observations Molecular equation Complete ionic equation Net ionic equation 2. Copper(II) sulfate + barium chloride Observations Molecular equation Complete ionic equation Net ionic equation 3. Copper(II) sulfate + sodium phosphate Observations Molecular equation Complete ionic equation Net ionic equation 4. Sodium carbonate + sulfuric acid Observations Molecular equation Complete ionic equation Net ionic equation 5. Sodium carbonate + hydrochloric acid Observations Molecular equation Complete ionic equation Net ionic equation 6. Cadmium chloride + sodium sulfide Observations Molecular equation Complete ionic equation Net ionic equation 7. Cadmium chloride + sodium hydroxide Observations Molecular equation Complete ionic equation Net ionic equation 8. Nickel chloride + silver nitrate Observations Molecular equation Complete ionic equation Net ionic equation 9. Nickel chloride + sodium carbonate Observations Molecular equation Complete ionic equation Net ionic equation 10. Hydrochloric acid + sodium hydroxide Observations Molecular equation Complete ionic equation Net ionic equation 11. Ammonium chloride + sodium hydroxide Observations Molecular equation Complete ionic equation Net ionic equation 12. Sodium acetate + hydrochloric acid Observations Molecular equation Complete ionic equation Net ionic equation 13. Sodium sulfide + hydrochloric acid Observations Molecular equation Complete ionic equation Net ionic equation 14. Lead nitrate + sodium sulfide Observations Molecular equation Complete ionic equation Net ionic equation 15. Lead nitrate + sulfuric acid Observations Molecular equation Complete ionic equation Net ionic equation 16. Potassium chloride + sodium nitrate Observations Molecular equation Complete ionic equation Net ionic equation Part 2: Solubility, Temperature and Crystallization Table 3 Molar Solubilities of NaCl, NaNO3 , KCl, and KNO3 (mol/L) 0°C 20°C 40°C 60°C 80°C 100°C NaCl 5.4 5.4 5.5 5.5 5.5 5.6 NaNO3 6.7 7.6 8.5 9.4 10.4 11.3 KCl 3.4 4.0 4.6 5.1 5.5 5.8 KNO3 1.3 3.2 5.2 7.0 9.0 11.0 Compound 1. Calculate the initial molarities of NaNO3 , KCl, NaCl, KNO3 . First Batch of Crystals 2. The first batch of crystals is formed at 10C. Describe these crystals in terms of shape, color, consistency, etc. 3. Use the solubility chart to determine the identity of the crystals. Explain your answer. Second Batch of Crystals 4. What was the temperature of the filtrate when the second batch of crystals formed? 5. Describe these crystals in terms of shape, color, consistency, etc. 6. Assuming that the first batch of crystals crystallized completely, removing all of it’s ions from solution, what is the identity of the second batch of crystals? (use your solubility chart and explain your answer) Third Batch of Crystals 7. The reason that we see a third batch of crystals is that we don’t get complete crystallization of the salts in the 1st and 2nd batches of crystals. Assuming there is a small concentration of each ion left in solution after the second batch of crystals is formed, what is the identity of the third batch of crystals according to your solubility chart? 8. Describe these crystals in terms of shape, color, consistency, etc. BONUS QUESTION: Describe two different tests that we could use to determine the identity of each set of crystals. To receive full credit you must give the name of the test, a description of the theory, and describe the results that you would for your proposed identity of each set of crystals. (5 points max.)