Experience of Using 100% Imported Coal for Coke Making in Bhilai Steel Plant B.C.Mandal , M.K.Solanki , J.Arjun Prasad, J.Dey, B.Phuse, P.Jha, Satya Prakash, G. S.Venkata Subramanian Abstract Coking coal is an invaluable natural resource for Iron and Steel Industries not only in terms of producing good quality metallurgical coke for BOF process for hot metal production, but also in terms of availability. World-wide efforts are being made to restrict its usage and take maximum benefit with minimum usage by retrofitting advanced technology like PBCC, stamp charging, usage of inert, coke breeze, etc. Indian steel industry is badly affected due to its inferior coal characteristics in terms of high ash content, inferior coking properties, heterogeneous petrographic make up and poor amenability to washing. Moreover, low prime coking coal reserve and uncertainty in supply, compels Indian steel makers to import coking coal from different sources to cope up growing demand of hot metal. In the year 1979, Bhilai Steel Plant, a subsidiary of Steel Authority of India Limited, started to use imported coking coal to the tune of 15% with indigenous Prime Coking Coal, Medium Coking Coal and Blend-able coal to study its compatibility with indigenous coal and impact on coke oven battery health. Under the present circumstances, considering the cost of blend optimization, coal availability and impact on oven health, usage of 78-80% of imported coal with 22-20% of indigenous coking coal is established in coal blend. But in the middle of 2014, with non-availability of indigenous coal, BSP was left with the option of having to use 100% imported coal for some time. With no prior experience of using 100% imported coal, it became an unknown journey in terms of oven wall pressure and operational difficulties. With its 56 years of experience in coke making, BSP coke plant managed the situation reasonably well by deploying various combinations of imported hard coal from Australia, USA and New Zealand and soft coal from Australia and New. Thus an unprecedented opportunity was available to us to experiment with what we had at hand. Some interesting and notable improvements in terms of hot and cold strength of coke were observed with due acknowledgement from the customer as well. This paper throws light on the experience of using 100% imported coal for coke making in the existing coke oven batteries of different age mix. Introduction: Bhilai Steel Plant, a flag ship unit of Steel Authority of India Limited (SAIL), is located at central India in the close vicinity of huge deposits of iron ore, Limestone and Dolomite in the state of Chhattisgarh. Hot metal and steel production started in a formal way in 1959 through coke dependent BF-BOF route. The blast furnace is a counter current packed bed chemical reactor in which ferrous and coke descend and are preheated by hot gases rising from the raceway combustion zone infront of the tuyeres where coke and injectants undergo combustion reactions deriving oxygen from the hot blast. Below the inner edge of the cohesive zone, coke is the only solid material in the blast furnace, playing three major roles: A fuel providing the energy required for endothermic chemical reactions and for melting of iron and slag A reductant by providing reducing gases for iron oxide reduction A permeable grid providing for passage of liquids and gases in the furnace, particularly in the lower part of the furnace Coke manufacture at BSP started with the commissioning of its 1st Coke Oven Battery on 31st January 1959; subsequently two more Batteries added under 1 MT stage. 5 more similar batteries came under 2.5 MT stage and two 7 M tall batteries came in 4MT stage. The third 7 MT tall battery marked the beginning of 7 MT stage. Presently seven 4.3 Meter tall batteries and two 7.0 tall batteries are in working. One 4.3 Meter tall battery and one 7.0 tall battery are under repair. BACKGROUND: India is bestowed with huge amount of coal reserve. But only about 17% of coal reserve is proved to be coking coal. High mineral content, poor caking and coking properties, wide fluctuation in quality parameters forced Indian coke makers to search for alternate sources of good coking coals in place of indigenous coals, for coke making. Moreover, coal washing in terms of ash reduction is not very effective, with the added disadvantage of escalating cost of production, in India. These situations led Indian coke makers to produce the coke of requisite quality by importing coals and judiciously incorporating maximum quantity of inferior indigenous coking coals. Considering the present circumstances, like BF productivity, volume of production, quality and compatibility, social and political obligation, demand and supply gap, competitive cost of production, existing infrastructure of coke making and other logistics, usage of about 80% of imported coal in the coal blend has been established with numerous industrial trials. BSP coke plant has witnessed many upswings and down trends s in quality parameters as well as in the receipt of right quantity and right quality of coking coal grades (both indigenous and imported). PHYLOSOPHY OF COAL BLENDING: Two basic parameters of coal i.e., coking and caking properties play key roles in determining the coke quality. Out of these, coking properties play the vital role in producing coke of desired quality. The prime factors that determine coking properties are ash, volatile matter, fluidity, reactive contents(%virtinite) and rank. Keeping the coal ash content to the minimum possible extent is the most significant parameter in coke manufacture. Coal ash affects the caking/coking properties of coals and in turn the strength of coke This unwanted constituent affects coke rate, slag volume, fluxes required and productivity of Blast Furnace. Fluidity of a coal which denotes formation of a semi-solid stage(plastic stage) on carbonization at a certain temperature softening to the maximum and then re-solidification with increasing temperature is an important parameter for coke making(coal blending). Softening of coal and its re-solidification does two important things. Firstly it allows volatiles to pass thus controlling the coking process and secondly enabling encompassing non-fluid part (inert rich coaly part) during re-solidification thus forming and strengthening the coke matrix. It can be seen that a fluidity of 200-1000 ddpm is the optimal range of blend for coke making. Reactive content (% of vitrinite, semi vitrinite and part of exinite) is very important as it can be considered as a cementing part where as organic inert (inertinite) can be considered as stone chips and inorganic inert (mineral matter) as sand on the same idea of making a mortar for construction. Volatile matter is one of most important parameter to classify the coals and an indirect indicator of the maturity of the coal. During coal carbonizing, VM is driven off as combustible gases like H2, CO, CH4 and other Hydro carbons as well as tar vapours and other incombustible gases as water vapour and CO2. In the course of coal carbonization the plastic layers swell, as a result of gas evolution and push the sides of charge against the heating walls. Thus the charge exerts pressure against the wall. Normally coal blend containing 2226% depicts good coking behavior. Blend having below 22% VM gives lesser shrinkage and causes difficulty in oven pushing and blend having higher VM% , causes higher wall pressure and produces weak structured coke with higher porosity. No individual coal inherently posses all the properties required for quality coke making. However a deficiency of particular property in any coal can often be supplemented by blending it with another compatible coal since many of the coal properties, like ash content, FSI,LTGK, petrography analysis of different coal are additive in nature.. Objective behind a blend preparation rests on keeping the quality parameters within the following range: Ash 13%,VM 22-26%,FSI 4-6%, Fluidity min 200-1000ddpm, vitrinite % min 45 and rank min 1.1. USUAGE OF 100% IMPORTED COAL IN COAL BLEND: Process of coal blend preparation starts from averaging of coal at stock yard, reclaiming it into Silos, discharging of coal at pre-set rate through Automatic Proportioning Device from Silos to make coal blend. It passes through hammer crushers to ensure uniform crushing and fed to coal tower of Battery and subsequently it is charged in coking chamber for coke making. In Bhilai steel plant, coal blend is prepared from Indigenous coal named as Prime coking coal (PCC),Medium coking coal(MCC) and imported coal consisting of hard and soft coal. There are 3 types of hard coal i.e Hard1, Hard2, Hard3 and soft coal (S1) used at BSP and corresponding quality parameters have been shown in Fig No 1 & 2. BSP is having two stock yards. Stock Yard -1 which feeds coal blend to six 4.3 tall batteries and one 7.0 tall battery is called Blend 1 and Stock Yard -2 feeds coal blend to two 4.3 tall batteries and two 7.0 tall batteries is called Blend -2. Coal Quality Hard-1 Hard-2 Hard-3 Ash, %db Soft PCC MCC 9.4 8.5 5.1 9.4 18.7 33.4 VM, %db Petrographic Analysis 27.6 26.6 28.2 24.9 28.5 25.8 Vitrinite 67.5 66.9 93.6 54.8 40.0 31.9 Semi-vitrinite 0.9 0.4 0.0 0.0 2.0 0.0 Exinite 3.4 4.2 0.8 1.3 3.5 7.4 22.7 23.5 2.6 38.4 37.1 40.5 5.5 5.0 3.0 5.5 17.4 20.2 100.0 100.0 100.0 100.0 100.0 100.0 28.2 28.5 5.6 43.9 54.5 60.7 Inertinite Mineral Matter Total Total Inerts Fig 1 Coal Quality Hard-1 Hard-2 Hard-3 Gieseler Fluidity Initial softening temp. C, (1ddpm) Maximum fluidity temp., C Solidification Temperature Plastic Range Maxi. Fluidity, ddpm Soft PCC MCC 403.0 411.0 421.0 424.0 402.0 414.0 445.0 447.0 451.0 451.0 459.0 441.0 484.0 486.0 475.0 475.0 492.0 468.0 81.0 75.0 54.0 51.0 90.0 54.0 627.0 393.0 7.0 16.0 149.0 44.0 Fig 2 Coke making process uses different coals in blend, blend preparation facilities, battery and coke handling facilities. Based upon several years of coke making experiences regarding the in-built discrepancies in installed facilities in coke oven batteries, battery operating parameters and working environment, for a specific set of blend composition, to a large extent coke quality is predicted. Any deviation in coke quality is taken care of by adjusting input coal constituents in coal blend. When limitation is imposed in the choice of input coal blend, it becomes a challenge to sustain required coke quality, battery health and other operational parameters and this happened to Bhilai Steel Plant. From the beginning of the year 2014, supply of indigenous coals- both Prime and Medium coking coals to Bhilai Steel Plant showed a downward trend due to some problems in Coal Mines and subsequently in the month of May 2014, the indigenous coal stock depleted to zero level. Hence, BSP was left with no choice but to use 100% imported coking coal. It became difficult to keep the coal blend as usual. Therefore, imported coal in blend was increased from a level of 78-80 % to 85, 89, 91 and 100%. This was a challenging task to increase the % of imported coal while maintaining the other operational parameter like shrinkage, pushing amperage at normal level. BSP’s Quality Performance with respect to usage of imported coal in 2013-14 100 % Imported coal in Blend (19.05.2014 to 27.05.2014) 1.0 Coal analysis at Plant end:% % % Fluidity Micro % Plant end Ash VM FSI Mositure (ddpm) Fines (%) Sulphur AUS-H 9.2 22.5 6.0 8.2 - 23.9 - USA 8.1 25.2 6.0 8.3 1794 29.1 - NZL 4.9 27.5 4.0 8.6 - 35.5 - SOFT 2.0 8.9 25.9 3.5 8.1 - 8.5 - Coal Blend composition (%) – (CHP-I & CPP-II): BLEND RATIO Aust. PCC MCC Hard Composition 0 New Soft Total Zeland Coal Imported 7 18 100 USA 0 58 17 3.0 Coal Blend Quality: % % % Coal Quality Crushing Index Fluidity -3.2mm - 0.5mm (ddpm) LTGK FSI Moisture Ash VM CHP-I 8.2 8.8 24.5 5.0-6.0 82.4 41.3 335 G-4&6 CPP-II 8.2 8.8 24.5 5.5-6.5 83.4 41.5 869 G-4 OVER ALL SHOP 8.2 8.8 24.5 5.0-6.5 83.0 41.4 602 G-4&6 4.0 Coke Quality at Coke Sorting plants(CSP) Coke % Coke Quality Moisture Ash M-40 M-10 CRI CSR Sulphur Porosity CSP-I 3.9 12.4 80.8 6.9 22.7 64.6 0.54 43.9 CSP-II 4.0 12.2 79.8 7.4 22.1 65.3 0.55 41.0 CSP-III 4.9 12.2 80.4 7.3 22.5 65.0 0.55 42.2 OVER ALL 4.3 12.2 80.3 7.3 22.3 65.1 0.55 42.4 5.0 BATTERY OBSERVATION:- DATE Control Vertical Temperature Coking Pushing Gas QI P/S C/S Time Index make 20.05.14 1239 1269 21.03 1.13 149.0 21.05.14 1236 1270 20.93 1.13 151.8 22.05.14 1238 1272 20.91 1.13 153.5 23.05.14 1241 1272 20.65 1.13 153.0 24.05.14 1237 1270 20.35 1.14 154.5 25.05.14 1232 1267 20.23 1.15 151.7 26.05.14 1239 1272 20.32 1.16 150.2 27.05.14 1236 1272 20.35 1.16 149.5 7.3 AVG 1237 1271 20.60 1.14 151.7 7.5 BATTERY OBSERVATION 100 % Imported Before After Batt.no. FST % shrinkage FST % shrinkage 1 868 5.65 853 5.48 2 814 5.75 844 5.45 3 846 6.63 845 3.45 4 906 3.62 904 4.14 5 900 5.00 911 4.80 6 901 4.70 890 4.90 8 837 6.40 8.32 6.15 10 783 5.72 791 5.90 Norm 850±25 6 % max 850±25 6 % max 7.6 6.0 Operational observation with use of 100 % Imported coal (i) Its handling : Normal (ii) Pushing amperage : Normal (iii) Coke shrinkage etc. : Normal (iv) Any other comment : All batteries working normal PERIOD 16-25 Mar-14 T.IMP. 81 PCC 8 20-27 May-14 100 0 COAL BLEND MCC AUS-H 11 55 0 58 PERIOD 16-25 Mar-14 ASH 12.0 COAL BLEND VM -3.2 mm 23.9 81.8 20-27 May-14 8.9 24.5 USA-H 13 NZL-H 7 AUS-S 6 NZL-S - 17 7 9 9 - 0.5 mm 39.0 MOIST. 4.5 ASH 15.7 BF COKE M40 M10 77.5 7.9 41.4 4.3 12.2 80.3 83.0 PERIOD 16-25 Mar-14 MOIST. 4.5 ASH 15.7 BF COKE M40 M10 77.5 7.9 20-27 May-14 4.3 12.2 80.3 7.3 QI 7.3 Pushing CRI 23.0 CSR 64.5 5.8 1.18 22.3 65.1 7.5 1.14 Index Usage of Indian and Imported coals at various compositions in BSP PCC (Prime Coking) MCC (Medium Coking) Indian component % Hard-1 (Australia Hard) Hard-2 (USA) Hard-3 (Newzealand) Soft Imported component % Total % 1 4 11 15 58 14 7 6 85 100 2 0 11 11 58 17 7 7 89 100 3 0 9 9 58 17 7 9 91 100 4 0 0 0 58 17 7 18 100 100 Sl CRI 23.0 22.3 Results and discussions: Parameters Effect on coal Coke Ash (Avg) Q.I. Effect on Coke M10 CSR Imported Coal Usage 100 % 12.10 7.60 81 % 15.59 4.80 Peaked at 91% then decreased reaching the minimum at 100 % Increased with corresponding increase in imported coal %, but decreased in the 89 to 91% imported coal usage zone; subsequently started increasing attaining the maximum at 100 % imported coal At 100 % - CSR 65.3 Conclusion: On increasing the imported coal percentage, the observations are as follows Coke ash decreased (by 22.38 %) Fixed carbon increased Q.I increased +80 fraction and -25 fraction decreased Coke quality like M10 and CSR increase with imported coal % but during blend design one must check the compatibility of different coals, otherwise in spite of increase in imported coal %, Coke quality shows downward trends. Hard –II is compatible with Soft-I coal MCC and Soft are compatible with Hard-2 for certain % range