Unit IC: INVESTIGATING MATTER ChemCom XTRA Electroplating Unit IC.12 Pennies today are no longer made of pure copper. When the price of copper skyrocketed in the 1980’s, the government began copper coating zinc pennies. The pennies look like the old, pure copper pennies, but are actually made mostly of zinc which is significantly less expensive. Sometimes metal plating is also used for jewelry and silverware. In this lab you will try to copper plate a key by reducing copper ions and oxidizing chlorine ions. Procedure: Clean a key by rubbing it steel wool and then rinsing it with water. Set up the electroplating beaker similar to figure 1 below. Use a 250mL beaker filled with about 75 mL of CuCl2. Make sure your power supply is turned off and unplugged. Hook the key you want to copper plate to the negative terminal. Hook a carbon electrode to the positive terminal. MAKE SURE THE KEY AND CARBON ELECTRODE DON’T TOUCH! Call your teacher over to approve your set-up before you turn on the power. Slowly increase the power. Let the key get plated for about five minutes. If you don’t see a change, increase the power a little more and let it sit for another five minutes. The slower you plate on the copper, the better the copper will bond with the key. Work on the questions below while waiting for the copper to finish electroplating. When the key has been plated, turn off and unplug the power supply. After the power supply is unplugged, remove the key and carbon rod. Rinse the key with water and dry it completely. Use your book to help you answer the questions below. Name _______________________________ Pd. ______ Questions 1. What is the correct name of CuCl2? used to make the solution? (Remember to use the stock system to show the charge on the copper. See page 70.) 2. What does the (aq) and (s) stand for in the formulas in question #1? Answers, work and calculations (aq)= (s) = 3. What is the molar mass of the CuCl2? Work: 4. What is the % composition by mass of the Cu in the CuCl2? Work: 5. What is the cation and anion in the ionic solid compound CuCl2(s)? (Include the charge on each.) Cation _______________________ Anion _______________________ 6. Are electrons gained or lost from copper atoms when they become copper ions with a +2 charge? 7. Are electrons gained or lost from chlorine atoms when they become chloride ions with a -1 charge? 8. During the electroplating process the copper ions turn into copper atoms coating the key. Cu(s) Arrange the symbols to the right into a halfreaction that shows the dissolved copper ions changing into the neutral solid copper atoms on the key during the reaction. (Hints on page 102) (Use only one of the + and – symbols.) 9. Does the equation you wrote show oxidation or reduction? 10. How many protons, neutrons, electrons in a copper-64 +2 ion? P N E Cu+2(aq) 2e- + -