Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 1 of 76 FRIENDS OF THE SAN GABRIEL RIVER WATERSHED QUALITY ASSURANCE PROJECT PLAN (QAPP) OUTLINE PREPARED BY: First Edition: Gwen Starrett, SWRCB, 1998 Second Edition: Dominic Gregorio, SWRCB, 2001 COMPLETED PLAN PREPARED BY: W. Richard Laton, Ph.D, Calfornia State University, Fullerton Refer correspondance to: Friends of the San Gabriel River www.sangabrielriver.org P.O. Box 3725 South El Monte, CA 91733 Fax: 562- 695- 8248 Email:sangabrielriver@aol.com Approvals: Agency / Organization: ________________________________________________ Signature: __________________________________________Date: ____________ Agency / Organization: ________________________________________________ Signature: __________________________________________Date: ____________ Agency / Organization: ________________________________________________ Signature: __________________________________________Date: ____________ Agency / Organization: ________________________________________________ Signature: __________________________________________Date: ____________ Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 2 of 76 2. Table of Contents page 2. TABLE OF CONTENTS PAGE .............................................................................. 2 3. DISTRIBUTION LIST ............................................................................................. 6 4. PROJECT ORGANIZATION .................................................................................. 6 4.1. Management (Monitoring Leaders and Trainers) ......................................................................................... 6 4.2. Field Monitors and Team Captains (Volunteers and Staff) .......................................................................... 6 4.3. Data Managers .................................................................................................................................................. 6 4.4. Quality Assurance Personnel ........................................................................................................................... 6 4.5. Technical Advisors............................................................................................................................................ 6 5. PROBLEM DEFINITION/BACKGROUND ............................................................. 7 5.1. Problem Statement....................................................................................................................................... 7 5.1.1. Citizen Monitoring Mission and Goals .............................................................................................. 7 5.1.1.1. Mission.................................................................................................................................... 7 5.1.1.2. Program Goals ....................................................................................................................... 7 5.2. 6. Intended Usage of Data ............................................................................................................................... 8 PROJECT/TASK DESCRIPTION .......................................................................... 9 6.1. General Overview of Monitoring ................................................................................................................... 9 Table 6.1 Summary of Monitoring Design .................................................................................................... 9 6.2. 7. Project Timetable ....................................................................................................................................... 10 Table 6.2 identifies the schedule of major activities associated with this project. ........................................... 10 Table 6.2 Project Schedule ........................................................................................................................... 10 DATA QUALITY OBJECTIVES ........................................................................... 11 Table 7.1. Data Quality Objectives for Conventional Water Quality Parameters .................................. 11 Table 7.2. Data Quality Objectives for Nutrients Using Colorimeters or Spectrophotometers .............. 11 Table 7.3. Data Quality Objectives for Nutrients Using Comparators ..................................................... 12 Table 7.4. Data Quality Objectives for Urban Pollutants Using Field Kits .............................................. 12 Table 7.5. Data Quality Objectives for Biological Parameters .................................................................. 12 Table 7.5. Data Quality Objectives for Biological Parameters .................................................................. 13 7.1. Accuracy ..................................................................................................................................................... 13 7.1.1. Chemical and Physical Parameters ........................................................................................................ 13 7.1.2. Biological Parameters .............................................................................................................................. 13 7. 2. Comparability ............................................................................................................................................ 14 7. 3. Completeness .............................................................................................................................................. 14 7. 4. Precision ..................................................................................................................................................... 14 Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 3 of 76 7. 4. Precision ..................................................................................................................................................... 15 7.4.1. Chemical and Physical Parameters ........................................................................................................ 15 7.4.2. Biological Parameters .............................................................................................................................. 15 7. 5. Representativeness ..................................................................................................................................... 15 7. 6. Method Detection Limit and Sensitivity .................................................................................................. 15 8. TRAINING REQUIREMENTS .............................................................................. 16 9. DOCUMENTATION AND RECORDS .................................................................. 17 10. SAMPLING PROCESS DESIGN ......................................................................... 17 10. SAMPLING PROCESS DESIGN ......................................................................... 18 10.1. Rationale for Selection of Sampling Sites ............................................................................................ 18 10.2. Sample Design Logistics ........................................................................................................................ 18 11. SAMPLING METHOD REQUIREMENTS ............................................................... 19 Table 11.1 Sampling Method Requirements................................................................................................ 19 Table 11.1 Sampling Method Requirements................................................................................................ 20 12. SAMPLE HANDLING AND CUSTODY PROCEDURES ..................................... 21 12.1. Sample Handling .................................................................................................................................... 21 12.2. Custody Procedures ............................................................................................................................... 21 12.3. Disposal ................................................................................................................................................... 21 13. ANALYTICAL METHODS REQUIREMENTS ...................................................... 22 Table 13.1 Analytical Methods for Water Quality Parameters ................................................................ 22 Table 13.2 TARGET REPORTING LIMITS FOR CONVENTIONAL WATER QUALITY CONSTITUENTS (Laboratory) ................................................................................................................... 23 14. QUALITY CONTROL REQUIREMENTS ............................................................. 27 14.1. Cautions Regarding Test Procedures .................................................................................................. 27 14.1.1. Winkler Method for Dissolved Oxygen ............................................................................................ 27 14.1.2. Nutrients ............................................................................................................................................. 27 14.1.3. Urban Pollutants ................................................................................................................................ 27 14.2. Blanks, Replicates, Split Samples, and Standardization..................................................................... 27 Table 14.1 Summary of Quality Control Requirements ............................................................................ 29 15. INSTRUMENT/EQUIPMENT TESTING, INSPECTION AND MAINTENANCE ... 30 15.1. Temperature ........................................................................................................................................... 30 Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 4 of 76 15.2. Dissolved oxygen .................................................................................................................................... 30 15.3. Conductivity and pH ............................................................................................................................. 30 15.4. Turbidity ................................................................................................................................................. 30 15.5. Nutrients and Urban Pollutants ........................................................................................................... 30 16. INSTRUMENT CALIBRATION / STANDARDIZATION AND FREQUENCY ....... 31 Table 16.1 Instrument Calibration and Frequency ................................................................................... 31 17. INSPECTION/ACCEPTANCE REQUIREMENTS ................................................ 32 18. DATA ACQUISITION REQUIREMENTS ............................................................. 32 18.1. Professional Analytical Data ................................................................................................................. 32 18.2. Geographical Information/ Mapping ................................................................................................... 32 19. DATA MANAGEMENT ......................................................................................... 32 20. ASSESSMENT AND RESPONSE ACTIONS ...................................................... 33 21. REPORTS ............................................................................................................ 33 22. DATA REVIEW, VALIDATION AND VERIFICATION .......................................... 33 23. VALIDATION AND VERIFICATION METHODS .................................................. 33 24. RECONCILIATION WITH DQOS ......................................................................... 33 APPENDIX 1. SAN GABRIEL RIVER WATERSHED MONITORING MANUAL ......... 34 APPENDIX 2. QUALITY ASSURANCE / QUALITY CONTROL DATA FORMS ......... 35 Data Quality Form: Accuracy .............................................................................................................................. 36 Data Quality Form: Completeness ....................................................................................................................... 37 Data Quality Form: Precision ............................................................................................................................... 38 APPENDIX 3. FIELD DATA AND OBSERVATION SHEETS ...................................... 39 APPENDIX 4. MAPS OF SAMPLING LOCATONS ..................................................... 40 APPENDIX 5. ACRONYMS ......................................................................................... 41 Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 5 of 76 APPENDIX 6. GLOSSARY .......................................................................................... 52 APPENDIX 7. LIST OF RECOMMENDED CRITICAL FIELD EQUIPMENT/SPARE PARTS .......................................................................................................................... 72 Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 6 of 76 3. Distribution List All group leaders, and technical advisors will receive copies of this Quality Assurance (QA) plan, and any approved revisions of this plan. Once approved, this QA plan will be available to any interested party by requesting a copy from the project management. 4. Project Organization This QAPP is a multi-organization project. The following citizen monitoring group will monitor and assess the streams, storm drains, lakes, bays, etc. within the San Gabriel River Watershed: 1. 2. 3. 4. 5. San Gabriel River Coyotee Creek San Jose Creek East Fork West Fork This QA plan reflects the diversity of monitoring and organizational support involved in this project. For the elements of this QA plan, we have addressed aspects that are shared with all groups as well as those aspects that are unique to individual groups. While the goals of monitoring may vary, the data quality objectives are consistent allowing us to compare data collected by different organizations. The specific organizational structure for each of the participating organizations is given below. Friends of the San Gabriel River Watershed 4.1. Management (Monitoring Leaders and Trainers) 1) 2) 4.2. Field Monitors and Team Captains (Volunteers and Staff) 1) 2) 4.3. Data Managers 1) 2) 4.4. Quality Assurance Personnel 1) 2) 4.5. Technical Advisors 1) 2) 3) W. Richard Laton, Ph.D., RG, CPG Assistant Professor of Hydrogeology, California State University, Fullerton 714-278-7514; wlaton@fullerton.edu Tom McClain, MS Adjunct Professor, California State University, Fullerton tmcclain@fullerton.edu John Foster, Ph.D., CEG Professor of Geology, California State University, Fullerton 714-278-7096; jfoster@fullerton.edu Refer to other sections of this QAPP to further understand these different roles or functions within your group. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 7 of 76 5. Problem Definition/Background 5.1. Problem Statement The San Gabriel River lies at the heart of our region, bringing us the water, vegetation and wildlife that enrich our valley. Our river is central to the geography and economy of our region, but too often it has been ignored and abused. Now the San Gabriel River is making a comeback. Communities are looking to the river for revitalization and to restore the natural beauty that has drawn so many to this area. Residents are revaluing it for the fun and environmental awareness it can give. And throughout its length, people are rolling up their sleeves to carve out pocket parks, restored streams, bike and hiking trails, and nature centers. With the new Joint Rivers and Mountains Conservancy and enhanced state funding for parks and rivers, we have the tools to restore the majesty of the San Gabriel River. From high in the San Gabriel Mountains all the way to the Pacific Ocean, the San Gabriel River unites our communities in a unique way. There is insufficient information to adequately assess the status of aquatic resources in the San Gabriel River Watershed. There are concerns over the status and maintainance of the quality of water resources in this watershed. Citizen monitoring organizations have been formed in local watersheds to address these water quality concerns. If quality assurance is adequate, valuable information will be provided for watershed management and pollution prevention. 5.1.1. Citizen Monitoring Mission and Goals 5.1.1.1. Mission The mission of citizen monitoring is to produce environmental information which is needed to protect California’s watersheds and aquatic resources. Citizen monitoring will also inform and engage the community in effective watershed stewardship. The vision is for the San Gabriel River become a corridor of an integrated watershed system while providing protection, benefit and enjoyment to the public. 5.1.1.2. Program Goals The general goals of citizen monitoring are: Identifying valued resources and watershed characteristics for setting management goals, Identifying physical watershed characteristics influencing pollutant inputs, transport and fate, Identifying the status and trends of biological resources in and around an aquatic environment, Screening for water quality problems, Identifying pollution sources and illegal activities (spills, wetland fill, diversions, discharges), Establishing trends in water quality for waters that would otherwise be un-monitored, Evaluating the effectiveness of restoration or management practices, Evaluating the effect of a particular activity or structure, and Evaluating the quality of water compared to specific water quality criteria To educate residents and energize communities To serve as an advocate and catalyst for effective action To clean up and restore the river To protect water quality through better understanding. In addition, citizen monitors build awareness of water quality issues, aquatic resources and pollution prevention. This project will supplement existing agency information by monitoring streams in the San Gabriel River watershed. The focus of the project is on habitat and chemical, physical and biological water quality measures that will identify the status of these aquatic resources. This information obtained will be provided to the regulatory agencies. It is the responsibility of the regulatory agencies to ensure that adequate and valid data are collected to meet their regulatory requirements. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 8 of 76 5.2. Intended Usage of Data The data will be used by the Friends of the San Gabriel River Watershed for general watershed assessment purposes. This assessment of this data will be useful in providing information for watershed management and pollution prevention. The data will be made available to the public for purposes of watershed education. It will also be made available to the regulatory and resource management agencies to supplement their existing data collection efforts. One potential application of the data will be to provide information to the Regional and State Boards for their use, if they so choose, in Section 305(b) reporting. Data will be compiled and maintained at P.O. Box 3725, South El Monte, CA 91733. The information will be shared with the State Water Resources Control Board, the Los Angeles Regional Water Quality Control Board, and upon request to other state, federal, and local agencies and organizations. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 9 of 76 6. Project/Task Description 6.1. General Overview of Monitoring The citizen monitors are monitoring water quality in the San Gabriel River Watershed. Table 6.1 summarizes the monitoring design, including the physical, chemical and biological parameters to be measured, whether the samples will be analyzed by the monitoring group or sampled for later analysis by a professional lab, and the frequency of measurement. Table 6.1 Summary of Monitoring Design Parameter Type of monitoring Frequency of monitoring Flow Temperature Dissolved Oxygen pH Conductivity (fresh water) or Salinity (marine) Turbidity Ammonia Nitrate Ortho-Phosphate Chlorine Phenols Copper Detergents Total Organic Carbon Metals Oil and Grease Pesticides Bacteria Benthic Macroinvertebrates Odor and Visual Observations Codes for Table 6.1: Type: F: field analysis, L: in-house lab analysis, P: sample only, send to outside professional lab Frequency: M: monthly, S: seasonal, X: irregular All of the water quality data will be compared to the Los Angeles Regional Water Quality Control Board Basin Plan. For results that are not comparable to the Basin Plan we will review those data with our Technical Advisors. This QA plan only addresses data quality objectives for the following parameters: Flow Phenols Temperature Copper Dissolved Oxygen Detergents pH Total Coliform Bacteria Conductivity E. coli Bacteria Salinity Enterococcus Bacteria Turbidity Benthic Macroinvertebrates Ammonia (nitrogen) Pesticides Nitrate (nitrogen) Trash Ortho-Phosphate Metals Chlorine Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 10 of 76 For stream and urban storm drain environments flow will be determined by using the protocol described in the San Gabriel River Watershed Monitoring Manual. Chemistry, physical, and bacterial parameters will be monitored using protocols outlined in the San Gabriel River Watershed Monitoring Manual. Benthic macro-invertebrate monitoring will be performed according to the California Stream Bioassessment Procedure. This program has a systematic method for visual and other sensory observations. A Stream/Shore Walk Visual Assessment observation sheet, with instructions, is included in the San Gabriel River Watershed Monitoring Manual. Observations using the Stream/Shore Walk Visual Assessment observation sheet will be made, at a minimum, on a monthly basis. Observational data include color, Secchi depth, odor, presence of oil or tar, trash, foam, and algae. In addition, the stream habitat quality will be assessed, at least once per year, using the California Dept. of Fish and Game Physical Habitat Assessment Form. Observational data include epifaunal substrate/available cover, embeddedness, velocity/depth regimes, sediment deposition, channel flow status, channel alteration, frequency of riffles, bank stability, vegetative protection, and riparian vegetative zone width. Analytical methods and data quality objectives for the following parameters are not addressed in this QA plan. Samples for these and other parameters will be taken by volunteers and staff, and sent to an agency, commercial, or academic laboratory for analysis: Total Organic Carbon Metals Oil and Grease and PAH’s Pesticides and other synthetic organic compounds Toxicity 6.2. Project Timetable Table 6.2 identifies the schedule of major activities associated with this project. Table 6.2 Project Schedule Activity Identify monitoring leaders Obtain training for monitoring leaders Recruit monitors Obtain and check operation of instruments Train monitors Initiate monitoring Initiate data entry Calibration and quality control sessions Review data with technical advisors Date Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 11 of 76 7. Data Quality Objectives This section identifies how accurate, precise, complete, comparable, sensitive and representative our measurements will be. These data quality objectives were derived by reviewing the QA plans and performance of other citizen monitoring organizations (e.g. Chesapeake Bay, Texas Watch, Coyote Creek Riparian Station, Southern California Citizen Monitoring Steering Committee, Heal the Bay Malibu StreamTeam), by considering the specifications of the instruments and methods which we will employ, and by considering the utility of the data. For purposes of this QAPP the data quality is considered adequate for the determination of general water quality conditions, with a potential application of the data to Section 305(b) reporting purposes. Data quality objectives are summarized in Tables 7-1 to 7-5. Whenever possible the methods with the greatest sensitivity and lowest detection limit will be employed as the primary methods. Methods with lesser sensitivity and higher detection limits will be used for field confirmations or as back-up methods in the case that the primary methods are not available or functioning properly for a particular sampling event. Specific DQOs were not given for in-situ continuous monitoring devices. See Section 14 for quality control protocols to be followed when continuous monitoring devices are employed. Table 7.1. Data Quality Objectives for Conventional Water Quality Parameters Parameter Method/range Units Detection Limit Sensitivity* Precision Accuracy Completeness Thermometer o o o o C -5 0.5 C 80% 0.5 C 0.5 C (-5 to 50) Dissolved Electronic mg/l 0.1 mg/l 0.1 mg/l 80% 10% 10% oxygen meter/probe Dissolved Micro-Winkler mg/l 0.2 mg/l 0.2 mg/l 80% 10% 10% oxygen Titration Vacuum Dissolved 1.0 (1.0-6.0) ampoule mg/l 1.0 mg/l + 1.0 mg/l + 1.0 mg/l 80% 2.0 (6.0-12.0) oxygen Indigo carmine pH pH meter pH units 2.0 0.1 unit 80% 10% 10% Non-bleeding pH strips (range pH units 4.5 0.5 unit + 0.5 units + 0.5 units 80% 4.5-10.0) conductivity Conductivity µS/cm 10 10 µS/cm 80% 10% 10% meter Turbidity Nephelometer NTUs 0.1 0.1 80% 10% 10% Dual Tube Turbidity JTUs 5 5 JTUs NA 80% 5 JTUs Optical NA: not applicable * Note: Some test kits vary in sensitivity over the range of detection. The specific range of readings is noted in parentheses. Temperature Table 7.2. Data Quality Objectives for Nutrients Using Colorimeters or Spectrophotometers Parameter Ammonia Nitrogen Nitrate Nitrogen OrthoPhosphate Method/range Units Detection Limit Sensitivity Nessler method mg/l 0.05 0.01 Cadmium reduction mg/l 0.05 0.01 Ascorbic acid mg/l 0.07 0.01 Precision Accuracy 0.2 (<2.0) 10% (>2) 0.2 (<2.0) 10% (>2) 0.2 (<2.0) 10% (>2) 0.2 (<2.0) 10% (>2) 0.2 (<2.0) 10% (>2) 0.2 (<2.0) 10% (>2) Completeness 80% 80% 80% Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 12 of 76 Table 7.3. Data Quality Objectives for Nutrients Using Comparators Detection Limit Sensitivity* Precision Accuracy Completeness mg/l 0.25 0.25 (0-0.5) 0.5 (0.5-1.0) 1.0 (1.0-2.0) 2.0 (2.0-4.0) 0.5(<2.0) 1.0(>2.0) 1.0 80% Zinc reduction mg/l 1.0 1.0 1.0 1.0 80% Ascorbic acid mg/l 0.2 0.2 (0-1.0) 0.5 (1.0-2.0) 0.5 1.0 80% Parameter Method/range Ammonia Nitrogen Salicylate method Nitrate Nitrogen OrthoPhosphate Units * Note: Some test kits vary in sensitivity over the range of detection. The specific range of readings is noted in parentheses. Table 7.4. Data Quality Objectives for Urban Pollutants Using Field Kits Parameter Method/range Units Detection Limit Sensitivity* Precision Accuracy Completeness Total Residual Chlorine Colorimetric (0.2 - 3.0) mg/l 0.2 0.2 (0.2-1.0) 0.5 (1.0-2.0) 1.0 (2.0-3.0) 0.5(<2.0) 1.0(>2.0) 0.5(<2.0) 1.0(>2.0) 80% Phenols Direct Photometric (0.5 - 5.0) mg/l 0.5 0.5 (0.5-3.0) 1.0 (3.0-5.0) 0.5(<3.0) 1.0(>3.0) 0.5(<3.0) 1.0(>3.0) 80% Total Copper Neocuproine (0.25 - 4.0) mg/l 0.25 0.25 (0-0.5) 0.5 (0.5-2.0) 1.0 (2.0-4.0) 0.5(<2.0) 1.0(>2.0) 0.5(<2.0) 1.0(>2.0) 80% Detergents Anionic Surfactants as MBAS (0.1) mg/l 0.1 0.1 0.1 0.1 80% * Note: Some test kits vary in sensitivity over the range of detection. The specific range of readings is noted in parentheses. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 13 of 76 Table 7.5. Data Quality Objectives for Biological Parameters Parameter Method/range Units Detection Limit Sensitivity Precision Accuracy Completeness Benthic Macroinvertebrates Calif. Stream Bioassessment Protocol N/A Family level N/A < 5% difference < 5% difference 80% Duplicates within 95% confidence limits Duplicates within 95% confidence limits Duplicates within 95% confidence limits Positive standard within ½ of an order of magnitude Positive standard within ½ of an order of magnitude Positive standard within ½ of an order of magnitude Total Coliform Bacteria Colilert 18 hour MPN/ 100ml 10 See IDEXX quantitray tables E. coli Bacteria Colilert 18 hour MPN/ 100ml 10 See IDEXX quantitray tables Enterococcus Bacteria Enterolert 24 hour MPN/ 100ml 10 See IDEXX quantitray tables 7.1. 80% 80% 80% Accuracy 7.1.1. Chemical and Physical Parameters Accuracy describes how close the measurement is to its true value. Accuracy is the measurement of a sample of known concentration and comparing the known value against the measured value. The accuracy of chemical measurements will be checked by performing tests on standards at the quality control sessions held twice a year. A standard is a known concentration of a certain solution. Standards can be purchased from chemical or scientific supply companies. Standards might also be prepared by a professional partner, e.g. a commercial or research laboratory. The concentration of the standards, known to the volunteer leader, will be unknown to the monitors until after measurements are determined. The concentration of the standards should be within the midrange of the equipment. The Data Quality Form: Accuracy, found in Appendix 1, will be used to record accuracy. 7.1.2. Biological Parameters Accuracy for bacteria will be determined by analyzing a positive control sample twice annually. A positive control is similar to a standard, except that a specific discreet value is not assigned to the bacterial concentrations in the sample. This is due to the fact that bacteria are alive and capable of mortality and reproduction. Instead of a specific value, an approximate target value of the bacterial concentration is assigned to the sample by the laboratory preparing the positive control sample. For benthic macroinvertebrate analysis, accuracy will be determined by having 20% of the samples (annually) re-analyzed and validated to CSBP Level 3 (genus level) by a professional taxonomist. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 14 of 76 7. 2. Comparability Comparability is the degree to which data can be compared directly to similar studies. Citizen monitoring groups will use the methods described in the following resource documents to ensure that their data can be compared to others: U.S. EPA’s Volunteer Monitoring Manuals for Streams, Lakes or Estuaries, SWRCB Clean Water Team Compendium for Water Quality Monitoring and Assessment, and California’s Department of Fish and Game’s (CDFG) California Stream Bioassessment Protocol (CSBP) for Citizen Monitors. Heal the Bay’s Malibu Creek Stream Team Pilot Project, Shattering the Myths of Volunteer Monitoring San Francisco Estuary Institute’s Volunteer Monitoring Protocols. Before modifying these methods, or developing alternative or additional methods, technical advisors will evaluate and review the effects of the potential modification. It will be important to address their concerns about data quality before proceeding with the monitoring program. 7. 3. Completeness Completeness is the fraction of planned data that must be collected in order to fulfill the statistical criteria of the project. Volunteer data will not be used for legal or compliance uses. There are no statistical criteria that require a certain percentage of data. However, it is expected that 80% of all measurements could be taken when anticipated. This accounts for adverse weather conditions, safety concerns, and equipment problems. We will determine completeness by comparing the number of measurements we planned to collect compared to the number of measurements we actually collected that were also deemed valid. An invalid measurement would be one that does not meet the sampling methods requirements and the data quality objectives. Completeness results will be checked quarterly. This will allow us to identify and correct problems. The Data Quality Form: Completeness, found in Appendix 1, will be used to record completeness. Coyote Creek San Gabriel River Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 15 of 76 7. 4. Precision 7.4.1. Chemical and Physical Parameters The precision objectives apply to duplicate and split samples taken as part of a QC session or as part of periodic in-field QC checks. Precision describes how well repeated measurements agree. The evaluation of precision described here relates to repeated measurements taken by either different volunteers on the same sample (at quality control sessions) or the same volunteer analyzing replicate samples (in the field). Sampling variability will not be covered in this section. The Data Quality Form: Precision, found in Appendix 1, will be used to record precision. 7.4.2. Biological Parameters Precision for bacterial parameters will be determined by having the same analyst complete the procedure for laboratory duplicates of the same sample. At a minimum this should be done once per day, or run duplicates on a minimum of 5% of the samples if there are over 20 samples run per day. The results of the duplicates should be within the confidence limits supplied by the manufacturer. For benthic macroinvertebrate analysis, precision will be determined by having the technical advisor annually perform an evaluation on the citizen analysts as discussed in Section 14.2 of this QAPP. 7. 5. Representativeness Representativeness describes how relevant the data are to the actual environmental condition. Problems can occur if: Samples are taken in a stream reach that does not describe the area of interest (e.g. a headwaters sample should not be taken downstream of a point source), Samples are taken in an unusual habitat type (e.g. a stagnant backwater instead of in the flowing portion of the creek), Samples are not analyzed or processed appropriately, causing conditions in the sample to change (e.g. water chemistry measurements are not taken immediately). Representativeness will be ensured by processing the samples in accordance with Section 10, 11 and 12, by following the established methods, and by obtaining approval of this document. 7. 6. Method Detection Limit and Sensitivity The Method Detection Limit is the lowest possible concentration the instrument or equipment can detect. This is important to record because we can never determine that a pollutant was not present, only that we could not detect it. Sensitivity is the ability of the instrument to detect one concentration from the next. Detection Limits and Sensitivities are noted in Tables 7.1. - 7.5. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 16 of 76 8. Training Requirements All citizen monitoring leaders must participate in a minumum of three days of hands-on training sessions on water quality monitoring conducted by the Clean Water Team of the State Water resources Control Board. For macroinvertebrate bioassessment citizen monitoring leaders must also participate in a three day training course provided by the California Department of Fish and Game, the Sustainable Lands Stewardship Institute, the American Fisheries Society, or the State Water Resources Control Board. Trained citizen monitoring leaders may then train their rank-and-file volunteers. Individual trainees are evaluated by their performance of analytical and sampling techniques, by comparing their results to known values, and to results obtained by trainers and other trainees. In addition to completion of the above described training course, the citizen monitoring leaders must participate in semi-annual Quality Control Sessions. These Quality Control Sessions will be supervised by Quality Control Trainers and will provide an opportunity for citizen monitors to check the accuracy and precision of their equipment and techniques. Quality Control Trainers are defined as water quality professionals from the U.S. Environmental Protection Agency, the State Water Resources Control Board, and the Regional Water Quality Control Boards. Additional qualified trainers may be recruited and designated by the above agencies from experienced citizen monitoring organizations, universities and colleges, commercial analytical laboratories, and other federal, state, and local agencies. The monitor will bring his/her equipment to the Quality Control Session. The monitor will conduct duplicate tests on all analyses and meet the data quality objectives described in Section 7. If a monitor does not meet the objectives, the trainers will re-train and re-test the monitor. If there is insufficient time at the QC session to retrain and re-test monitors, the monitor will be scheduled for an additional training session. The monitor will be encouraged to discontinue monitoring for the analysis of concern until training is completed. The Quality Control Trainers will examine kits for completeness of components: date, condition, and supply of reagents, and whether the equipment is in good repair. The Trainers will check data quality by testing equipment against blind standards. The trainers will also ensure that monitors are reading instruments and recording results correctly. Sampling and safety techniques will also be evaluated. The trainer will discuss corrective action with the volunteers, and the date by which the action will be taken. The citizen monitoring leader is responsible for reporting back that the corrective action has been taken. Certificates of completion will be provided once all corrective action has been completed. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 17 of 76 9. Documentation and Records All field results will be recorded at the time of completion, using the field data sheets (see Appendix 2). Data sheets will be reviewed for outliers and omissions before leaving the sample site. Data sheets will be signed after review by the citizen monitoring leader. Data sheets will be stored in hard copy form at the location specified in Section 5.2. Field data sheets are archived for three years from the time they were collected. If data entry is ever performed at another location, duplicate data sheets will be used, with the originals remaining at the headquarters site. Hard copies of all data as well as computer back-up disks are maintained at headquarters. All voucher collections, completed data quality control forms and maintenance logs will also be kept at the headquarters location specified in Section 5.2. The mainenance log details the dates of equipment inspection, battery replacement and calibrations, as well as the dates reagents and standards are replaced. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 18 of 76 10. Sampling Process Design 10.1. Rationale for Selection of Sampling Sites Sampling sites are indicated on the maps in Appendix 3. The following criteria were evaluated when choosing sampling locations: access is safe, permission to cross private property is granted, sample can be taken in main river current or where homogeneous mixing of water occurs, sample is representative of the part of the water body of interest, location complements or supplements historical data, location represents an area that possesses unique value for fish and wildlife or recreational use. Any reference sites are chosen upstream of any potential impact. A site chosen to reflect the impact of a particular discharge, tributary or land use is located downstream of the impact where the impact is completely integrated with the water, but upstream of any secondary discharge or disturbance. Prior to final site selection, permission to access the stream was obtained from all property owners. If access to the site becomes a problem, the citizen monitoring leader will select a new site. Safety issues are included in the San Gabriel River Watershed Monitoring Manual . Sample sites will be reviewed by the leader before sending volunteers out to the site. The monitoring leader will document permission and terms obtained from landowners, and will complete and file a Stream/Shore Walk form for the site, which will include a map and photographs. 10.2. Sample Design Logistics Volunteers are instructed to work in teams of at least two people. If a scheduled team cannot conduct the sampling together, the team captain is instructed to contact the citizen monitoring leader so that arrangements can be made for a substitute trained volunteer. Prior to final site selection, permission to access the stream is obtained from all property owners. If access to the site is a problem, the citizen monitoring leader will select a new site following the site selection criteria identified in Section 10.1. Safety measures will be discussed with all volunteers. No instream sampling will be conducted if there are small creek flood warnings or advisories. These can be found at http://cdec.water.ca.gov/weather.html#Warnings. It is the responsibility of the citizen monitoring organization to ensure the safety of their volunteer monitors. Safety issues are included in the San Gabriel River Watershed Monitoring Manual . Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 19 of 76 11. Sampling Method Requirements The San Gabriel River Watershed Monitoring Manual describes the appropriate sampling procedure for collecting samples for water chemistry. Water sampling apparatus may include Van Dorn Samplers, Niskin Bottles, Kemmerer Tubes, LaMotte Oxygen Samplers, DH 48 Sediment Samplers, extension pole type sampling devices, and hand held plastic containers. Benthic invertebrates will be collected with a D shaped kick net (0.5 mm mesh) mounted on a pole. For a complete list of approved sampling instrumentation see Appendix 7. In those cases where glass bottles are required in Table 11.1, plastic samplers are allowed as long as the hold time in the sampling device is minimal before transfer to the glass sample bottle. Sampling devices and sample bottles (that are not pre-sterilized and do not contain preservatives/fixing agents) will be rinsed three times with sample water prior to collecting each sample. For sterile bottles, whirl-paks, and sample bottles which do contain preservatives/fixing agents (e.g., acids, etc.) never rinse with sample water prior to collecting the sample. Also, never use a sample bottle containing preservatives/fixing agents for sampling; in these cases always use a sampling device to collect the sample prior to transferring the sample into the bottle. Whenever possible, the collector will sample from a bridge so that the water body is not disturbed from wading. All samples are taken approximately in mid-stream, at least one inch below the surface. If it is necessary to wade into the water, the sample collector stands downstream of the sample, taking a sample upstream. If the collector disturbs sediment when wading, the collector will wait until the effect of disturbance is no longer present before taking the sample. Never wade into a lined channel system. Collection of samples should be perfomed from the dry bank area. The following table describes the sampling equipment, sample holding container, sample preservation method and maximum holding time for each parameter. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 20 of 76 Table 11.1 Sampling Method Requirements Parameter Sample Bottle Preferred / Maximum Holding Times Conventional Parameters Temperature Dissolved oxygen clear plastic bottle or sample directly plastic bottle or sample directly pH conductivity turbidity plastic bottle or sample directly plastic bottle or sample directly plastic bottle Nutrients Ammonia N plastic bottle Nitrate N Ortho-Phosphate plastic bottle plastic bottle Total Residual Chlorine Phenols Total Copper Detergents plastic bottle Total Organic Carbon Metals acid and d.i. water rinsed glass sampling bottle, teflon liner in lid plastic sampling bottle Oil and Grease acid and d.i. water rinsed glass sampling bottle, teflon liner in lid acid and d.i. water rinsed glass sampling bottle, teflon liner in lid acid and d.i. water rinsed glass sampling bottle, teflon liner in lid PAH’s Pesticides and other synthetic organic compounds Toxicity Bacteria Benthic macroinvertebrates plastic bottle plastic bottle plastic bottle immediately immediately / for wet chemistry fix per protocol instructions, continue analysis within 8 hr. immediately immediately / refrigerate up to 24 hours immediately / store in dark for up to 24 hr. immediately / up to 8 hours if the sample is acidified with sulfuric acid to less than 3.0 pH immediately / refrigerate in dark for up to 48 hours. immediately / refrigerate in dark for up to 8 hours Urban Pollutants – Field Measurements immediately immediately immediately immediately Laboratory Analysis of Chemical Parameters refrigerate to 4 degrees C, send to lab immediately fix with Ultrapure (or comparable) nitric acid, send to lab immediately refrigerate to 4 degrees C, send to lab immediately refrigerate to 4 degrees C, send to lab immediately refrigerate to 4 degrees C, send to lab immediately acid and d.i. water rinsed glass refrigerate to 4 degrees C, send to lab immediately sampling bottle, teflon liner in lid Biological Samples sterile plastic sampling bottle or whirl-pak wide mouth plastic bottles Refrigerate to 4 degrees C in the dark; deliverd to the lab within 4 hours, start analysis within 6 hours Fixed with ethanol immediately Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 21 of 76 12. Sample Handling and Custody Procedures 12.1. Sample Handling Identification information for each sample will be recorded on the field data sheets (see Appendix 2) when the sample is collected. Samples that are not processed immediately in the field will be labeled with the waterbody name, sample location, sample number, date and time of collection, sampler’s name, and method used to preserve sample (if any). 12.2. Custody Procedures The conventional water quality monitoring tests do not require specific custody procedures since they will, in most cases, be conducted immediately by the same person who performs the sampling. In certain circumstances (such as driving rain or extreme cold), samples will be taken to a nearby residence for analysis. Samples requiring chemical preservation will be fixed prior to transport. When samples are transferred from one volunteer to another member of the same organization for analysis, or from the citizen monitoring group to an outside professional laboratory, then a Chain of Custody form should be used. This form identifies the waterbody name, sample location, sample number, date and time of collection, sampler’s name, and method used to preserve sample (if any). It also indicates the date and time of transfer, and the name and signature of the sampler and the sample recipient. In cases where the sample remains in the custody of the monitoring organization, then the field data sheet may be allowed to double as the chain of custody form. It is recommended that when a sample leaves the custody of the monitoring group, then the Chain of Custody form used be the one provided by the outside professional laboratory. Similarly, when quality control checks are performed by a professional lab, their samples will be processed under their chain of custody procedures with their labels and documentation procedures. For benthic macroinvertebrate samples, the California Department of Fish and Game Aquatic Bioassessment Laboratory Chain of Custody form will be used. 12.3. Disposal All analyzed samples or spent chemicals (except for waste from the nitrate/cadmium reduction test and the Nessler ammonia test) including used reagents, buffers or standards will be collected in a plastic bottle clearly marked “Waste” or “Poison”. This waste material will be disposed of according to appropriate state and local regulations. This will usually mean disposal into a drain connected to a sewage treatment plant. Liquid waste from the cadmium reduction nitrate test will be kept separate and disposed of at a facility that is permitted to handle, transport, or dispose Cd waste. Liquid waste from the Nessler ammonia test (which contains mercury) will likewise be kept separate and disposed of at a facility that is permitted to handle, transport, or dispose Hg waste. Waste from the zinc reduction nitrate test and the salicylate ammonia test can be held in the regular waste container and disposed of as described in the previous paragraph. Whenever possible, if waste includes reagents from the detergent test, these wastes will be poured down a drain underneath a flume hood. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 22 of 76 13. Analytical Methods Requirements Water chemistry is monitored using protocols outlined in the San Gabriel River Watershed Monitoring Manual . The methods were chosen based on the following criteria: capability of volunteers to use methods, provide data of known quality, ease of use, methods can be compared to professional methods in Standard Methods. If modifications of methods are needed, comparability will be determined by side-by-side comparisons with a US EPA or APHA Standard Method on no less than 50 samples. If the results meet the same precision and accuracy requirements as the approved method, the new method will be accepted. Table 13.1 outlines the methods to be used, any modifications to those methods, and the appropriate reference to a standard method. Table 13.1 Analytical Methods for Water Quality Parameters Parameter Temperature Method Thermometric Dissolved Oxygen Dissolved Oxygen Dissolved Oxygen Winkler Method, Azide Modification Membrane Electrode Colorimetric indigo carmine Modification Alcohol-filled thermometer marked in 0.5oC increments Prepackaged reagents, 20 ml sample size none Vacuum ampoules pH pH Conductivity Turbidity Turbidity Electrometric Litmus indicator strips Electrometric Dual tube optical comparisons Nephelometric none Non-bleeding none none none Ammonia N Phenate Salicylate with Color Comparator 4500 - NH3 F. Ammonia N Nessler or Phenate/Salicylate prepackaged reagents, colorimeter or spectrophotometer Nitrate N Cadmium Reduction or Zinc reduction Cadmium Reduction or Zinc Reduction Ascorbic acid Ascorbic acid Color Comparator 4500 – NH3 C 18th edition only (1992) 4500 – NO3 E. 4500 – NO3 E. 4500 – P E. 4500 – P E. Nitrate N Ortho-Phosphate Ortho-Phosphate Total Residual Chlorine Phenols Total Copper Detergents Total Coliform Bacteria E. coli Bacteria Enterococcus Bacteria Benthic Macroinvertebrates DPD Colorimetric Direct Photometric Neocuproine Anionic Surfactants as MBAS Colilert 18 hour Colilert 18 hour Enterolert 24 hour California Stream Bioassessment Protocol prepackaged reagents, colorimeter or spectrophotometer Color Comparator prepackaged reagents, colorimeter or spectrophotometer none Reference (a) 2550 B. 4500-O C. 4500-O G. ASTM D 88887 4500-H B. Whatman Co. 2520 B. None 4500 - Cl G. Color Comparator Color Comparator none none 5530 D. 3500 -Cu D. 5540 C. 9223 none none Level 2 (to family only) 9223 IDEXX Corp. Harrington, Jim, CDFG, 1997 Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 23 of 76 (a) All of the above methods, with the exception of dissolved oxygen via indigo carmine, pH via non-bleeding indicator strips, turbidity via dual tube (JTUs), enterococcus bacteria, and benthic macroinvertebrates are described in Standard Methods for the Examination of Water and Wastewater 20 th Edition. American Public Health Association et al, 1998. Table 13.2 TARGET REPORTING LIMITS FOR CONVENTIONAL WATER QUALITY CONSTITUENTS (Laboratory) Analysis Matrix Reporting Units *Suggested Analytical Methods (See *Note, and see References 1-13, at bottom of table) Target Reporting Limit (TRL) CONVENTIONAL CONSTITUENTS AMMONIA (as N) water (dissolved) mg/L EPA 350.3 EPA 350.2 SM 4500-NH3B, C BIOCHEMICAL OXYGEN DEMAND water mg/L EPA 405.1 SM 5210B BORON water (dissolved) mg/L EPA 200.7 EPA 6010A SM 4500 B-19 CALCIUM water (dissolved) mg/L EPA 200.7 EPA 6010A SM 3111B 0.05 CHLORIDE (iodometric) water (dissolved) mg/L EPA 300.0A SM 4500 Cl C 0.25 CHLOROPHYLL a PHEOPHYTIN a CHEMICAL OXYGEN water (dissolved) µg/L SM 10200H 2.0 (500 ml filtration) water mg/L EPA 410.1-.4 5 CONDUCTIVITY water µS/cm SM 2510B EPA 120.1 2.5 FIXED & VOLATILE DISSOLVED SOLIDS (500C) water mg/L EPA 160.4 SM 2540E 5 FLUORIDE water (dissolved) mg/L EPA 300.0A EPA 6010A 0.123 IRON water (dissolved) mg/L EPA 300.0A EPA 6010A 0.02 mg/L EPA 200.7 EPA 6010A SM 3111B 0.02 DEMAND (titrametric) MAGNESIUM water (dissolved) 0.1 2 0.010 (500 ml filtration) MANGANESE water (dissolved) mg/L EPA 200.7 EPA 6010A SM 3111B 0.02 NITRATE (as N) water (dissolved) mg/L EPA 300.0A EPA 353.3 SM 4500-NO3E, F (Flow injection analysis) 0.01 water mg/L EPA 353.2 SM 4500-NO3E, F 0.1 water (dissolved) mg/L EPA 300.0A EPA 353.2 SM 4500-NO2B (Flow injection analysis) 0.01 NITRATE+NITRITE NITRITE (as N) Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 24 of 76 Analysis Matrix Reporting Units *Suggested Analytical Methods (See *Note, and see References 1-13, at bottom of table) Target Reporting Limit (TRL) CONVENTIONAL CONSITUENTS OIL AND water mg/L GREASE (HEM) mg/L (dissolved) water (total) water ORTHOPHOSPHATE (as P) (dissolved) E. Coli water Enterococcus water Fecal Coliform water Total Coliform water POTASSIUM water (dissolved) SEDIMENT GRAIN SIZE ANALYSIS 1.4 SM 5520 B water ORGANIC CARBON EPA 1664A EPA 415.1-.2 SM 5310 C mg/L EPA 415.1-.2 SM 5310C mg/L EPA 300.0A EPA 365.3 SM 4500-P E&F (Flow injection analysis) PATHOGENS MPN/100 ml SM 9221B/E mod. MUG, SM 9223B colonies/100 ml SM 9230C, ASTM D6503 MPN/100 ml SM 9221E, SM 9222D (25-tube dilution) MPN/100 ml SM 9221B, SM 9222B (25-tube dilution) mg/L EPA 200.7 sediment % gravel % sand EPA 6010A SM 3111B SM 3500-K D (6), (7) ASTM (sieve-hydrometer) (4-fraction) % silt % clay 0.6 0.6 0.01 2 1 2 2 0.1 1% (8) Plumb 1981, (9) EPA 1995 (abbrev. pipette) Particle Size sediment (full phi analysis) g (grams-weight) (8) Plumb 1981, (9) EPA 1995, (10) Folk 1980 (full phi pippette analysis) <0.002 mm >0.002 mm >0.0039 mm >0.0078 mm >0.0313 mm >0.0625 mm >0.125 mm >0.25 mm >0.5 mm >1 mm >2 mm >3.2 mm >4 mm >8 mm Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 25 of 76 Analysis Matrix Reporting Units *Suggested Analytical Methods (See *Note, and see References 1-13, at bottom of table) Target Reporting Limit (TRL) CONVENTIONAL CONSTITUENTS SEDIMENT TOTAL sediment %OC (dry weight) ORGANIC CARBON EPA 9060, and water (dissolved) water (dissolved) mg/L water (dissolved) mg/L water mg/L (11) ASTM 2000 D3977 (12) Gray et al 2000 water mg/L EPA 310.1-2 water mg/L water mg/L TOTAL KJELDAHL NITROGEN water mg/L TOTAL PHOSPHATE water mg/L water mg/L TURBIDITY water NTU VOLATILE SUSPENDED water mg/L SILICA SODIUM SULFATE SUSPENDED mg/L (as P) SOLIDS (103-105 C) SOLIDS 0.1 EPA 300.0A 1.0 0.5 1 SM 2320B (as CaCO3) TOTAL SUSPENDED EPA 200.7 SM 4500-SO4, E ASTM D516 SOLIDS TOTAL HARDNESS 0.1 EPA 6010A SM 3111B (as CaCO3) TOTAL DISSOLVED EPA 200.7 SM 3111B SEDIMENT CONCENTRATION TOTAL ALKALINITY 0.01 (13) EPA 1986 (Kahn Method) EPA 160.1 SM 2540C EPA 200.7 EPA 130.1-2 SM 2340C EPA 351.1-.4 4500-NorgB, 4500-NorgB, C SM 4500-NH3C, E, F EPA 365.1-4 SM 4500-P B(5), E&F EPA 160.2 SM 2540D APHA 1997 EPA 180.1 SM 2130B EPA 160.4 10 1 0.5 0.05 0.5 0.5 ntu 1.0 SM 2540E *NOTE REGARDING SUGGESTED METHODS LISTED ABOVE All analytical methods listed above are suggested. Other methods may be employed, and modifications of standard methods are encouraged, as long as the methods used: 1) meet the sensitivity requirements of the TRL's, and 2) are contained in 40CFR36, the most current version of Standard Methods, or another reliable procedure as documented to produce results that are equal to or more stringent than the method being modified (modifications made according to CFR (Title 40, Part 136.4). Any changes in procedures due to equipment changes or to improved precision and accuracy will be documented. Analyses and determinations must be performed by qualified personnel in conformance with the United States Environmental Protection Agency (EPA) or DHS approved test procedures described in the current Code of Federal Regulations (CFR) (Title 40, Part 136); "Test Methods for Evaluating Solid Waste," SW-846; or Title 22, CFR, Article 11, as appropriate. The test procedures may be modified subject to the application and approval of alternate test procedures under the CFR (Title 40, Part 136.4). The SWAMP Program strongly encourages the use of "performance-based Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 26 of 76 methodology" (PBM) for conducting analytical procedures and therefore recognized the use of modified standard procedures, as appropriately documented following CFR 40, Part 136.4. The use of PBM allows for approved procedures to be modified according to these guidelines, which provide results that are equal to or better than (more stringent than) the standard protocol that was modified. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 27 of 76 14. Quality Control Requirements Quality control samples will be taken to ensure valid data are collected. Depending on the parameter, quality control samples will consist of blanks, replicate samples, and split samples. In addition, quality control sessions (a.k.a. intercalibration exercises) will be held twice a year to verify the proper working order of equipment, refresh volunteers in monitoring techniques and determine whether the data quality objectives are being met. Responsible laboratories will follow all approved procedures and quality control measures as outlined in this QAPP. Only those laboratories approved by the State of California shall be used. 14.1. Cautions Regarding Test Procedures 14.1.1. Winkler Method for Dissolved Oxygen The Winkler method is not appropriate for highly alkaline waters. Other citizen monitoring groups have noted problems with short shelf-life of the sodium thiosulfate reagent. Field measurements should be evaluated immediately to determine whether they are reasonable. The validity of the dissolved oxygen test will also be assured by taking these steps: Care is taken not to aerate water samples during collection, Water is added gently to the dissolved oxygen bottle, No air bubbles are present in the sample, The titration sample will be measured carefully with a graduated cylinder, The sample is swirled thoroughly after each drop of titrant, if the endpoint is overrun, another 20 ml. of the sample will be titrated. 14.1.2. Nutrients The nitrate test measures nitrite as well as nitrate. Therefore the results for the nitrate test are actually mg/l Nitrite + Nitrate Nitrogen. When mixing nitrate reagents take care not to agitate aggressively. The LaMotte phosphate reagents have been shown to degrade well within their listed shelf life once opened. 14.1.3. Urban Pollutants The tests for detergent, chlorine and phenol should not be conducted on saline waters. Suspended matter and algae may give false positive results for detergent. The low sensitivity of the copper test may preclude detecting copper as most falls out of solution forming copper carbonate. 14.2. Blanks, Replicates, Split Samples, and Standardization Field/Laboratory Blanks: For all conventional water quality analyses, except temperature, dissolved oxygen and pH, field blanks will be analyzed once daily. For nutrients using comparators, a field blank will be analyzed every sampling trip. Color can sometimes appear in these nutrient blanks, suggesting that the real samples may be overestimating the true nutrient concentration. When colorimeters or spectrophotometers are used at the group’s facility for nutrient analysis, a laboratory reagent blank will be analyzed and recorded for each day of analysis. For urban pollutants field blanks will be run daily. For bacterial analysis performed at a group’s facility, a laboratory blank will be performed for each sampling/analysis event. Blanks do not apply to benthic macroinvertebrate sampling. (see Table 14.1) Instructions for Field and Lab Blanks: Distilled water is taken into the field or used in the laboratory and handled just like a sample. It will be poured into the sample container and then analyzed. When reagents are used in a test method, then the reagents are added to the distilled water and these types of blanks are referred to as reagent blanks. Field blanks are recorded on the field data sheet. For nutrients measured with comparators, results from the field reagent blanks should be “not detected”. If nutrients are detected, corrective action will be taken to eliminate the problem. For nutrients measured with colorimeters, the lab reagent blanks should be less than 0.05 ppm and the specific value should be recorded and subtracted from the field sample result. For bacterial analysis, the reagents are added to distilled water (in the same manner as for a field sample) and that Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 28 of 76 blank is then sealed in a quantitray and incubated along with the field samples. The blank should be below detection limits (i.e., no positive wells) at the end of the incubation period. Field Confirmations: When a second method for measuring temperature, dissolved oxygen, and pH is available in the field, then the monitors are encouraged to perform both measurements on a split sample at least once daily. Examples of this sort of redundant measurement would be: for temperature, the use of an electronic thermometer (such as those that are built into dissolved oxygen meters) and an armored thermometer; for dissolved oxygen, the use of an oxygen meter and an indigo carmine colorimetric kit; for pH, a meter and a non-bleeding indicator strip. This will serve to provide backup capability if the more sensitive electronic meters fail, and will provide additional confidence as to the quality of the data. The results of both measurements will be recorded along with the procedure used on the field data sheet. If both results are comparable then the result produced using the method of greater sensitivity will be the one entered in the final data set by the data manager in consultation with the monitoring leader. If the two results are inconsistent, then the monitoring leader will note on the data sheet which of the results will be entered on the final data set by the data manager. Replicate Samples: Replicate samples are two or more samples collected at the same time and place. When there are only two replicates then these are referred to as duplicates. For conventional water quality, nutrients, and urban pollutant analyses duplicate field samples will be taken once every 20 samples, or quarterly whichever comes first. Duplicate samples will be collected as soon as possible after the initial sample has been collected, and will be subjected to identical handling and analysis. For bacterial analysis lab duplicates will be run at least once per sampling day, and when there are more than 20 samples run per day then there will be a minimum 5% of the samples analyzed in duplicate. For benthic macroinvertebrate sampling, instead of duplicate sampling, each sampler will be evaluated annually by measuring the area sampled upstream of the net. The area should be two square feet and should be verified by using a two square foot pvc frame. Split Samples: Twice a Year, split spiked samples (standards) will be analyzed as part of the Quality Control Session. The split standard is one sample, containing a known concentration of an analyte, that is divided equally into two or more sample containers. Split standards will be analyzed by the volunteers, and sent to a professional laboratory (except for dissolved oxygen, temperature, and pH), before the maximum sample handling time is exceeded. Volunteers will analyze the split standard normally and will perform at least three analyses on that same sample. From these results accuracy and precision will be determined. The professional laboratory will analyze the sample using the method referenced in Table 13.1 For turbidity using the dual tube (JTU) method, split field samples will be analyzed as part of the Quality Control Session. The laboratory receiving the split sample will analyze it using the nephelometric method, even though these results are not strictly comparable to the visual JTU comparators. The results of turbidity using the two methods will be plotted to determine if there is a linear correlation. If this correlation is significant, then it will be used to estimate and compare results of the turbidity tubes with nephlometric results. The Technical Advisory Committee for all groups will use the product-moment correlation coefficient (r) to determine the adequacy of the correlation. For bacteria, split field samples or split positive controls will be analyzed by the citizen monitoring group and an outside professional laboratory twice annually. In addition, at the quality control session different analysts from the citizen monitoring group(s) will each read a minimum of the three quantitrays and compare their results. These results should be within + one well for concentrations of less than 1000 MPN/100 ml, and within + two wells for concentrations of greater than 1000 MPN/100ml. A minimum 20% of the benthic macroinvertebrate samples will be subjected to validation by a outside professional taxonomist. Following analysis by the citizen group the selected samples will be reconstituted and sent out for professional level 3 taxonomic analyses. Reconstituted means opening the vials containing the 100 identified specimens, pouring the specimens back into the original sample jar, and gently stirring the contents. In addition, once a year citizen macroinvertebrate analysts will participate in an intercalibration exercise in which their subsampling/sorting and taxonomic skills will be evaluated. A minimum of two teams of analysts will each inspect each other’s processed grids immediately following completion of the subsampling procedure. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 29 of 76 There should be no more than 10% missed organisms. A technical advisor should then evaluate each of the citizen analysts by testing their identification to order and family level on at least 20 specimens, including at least one representative from each of the major orders and families as determined by the technical advisor for that watershed. Accuracy and precision can be determined by the results of these validation and evaluation measures. Standardization of Instruments and Procedures: At the Quality Assurance Sessions the temperature measurements will be standardized by comparing our thermometers to a NIST-certified or calibrated thermometer in ice water and ambient temperature water. All meters (pH, conductivity, oxygen) will be evaluated at the Quality Assurance Session using standards provided with the assistance of a professional laboratory and/or the technical advisors. For oxygen meters the standard will be distilled water saturated with oxygen. The Winkler kits for dissolved oxygen will be checked by standardizing the sodium thiosulfate solution in the test kit, and/or by comparing the entire kit to a saturated oxygen standard. Instructions for checking the sodium thiosulfate are included in the test kit. (Additional reagents and glassware must be purchased separately however.) If the result is unsatisfactory, as indicated in the instructions, the sodium thiosulfate and/or other reagent will be discarded and replaced with new reagents. Continuous Monitoring Devices: Should continuous monitoring devices be used for any parameters then such devices must be calibrated and deployed according to the manufacturer’s specifications and field confirmation will be performed using replicate sampling (for laboratory analysis) or standardized instruments. For example, there is the possibility of using in-situ continuous monitoring devices for flow or temperature measurements. Confirmations using a flow meter or a standardized field thermometer will be perfomed at the time of deploying and retrieving the device. This will serve to determine the accuracy of the continuous monitoring device. Table 14.1 summarizes the quality control regimen. Table 14.1 Summary of Quality Control Requirements Parameter Temperature Dissolved oxygen pH conductivity turbidity Ammonia Nitrate Ortho-Phosphate Ammonia Nitrate Ortho-Phosphate Total Residual Chlorine Phenols Total Copper Detergents Total Coliform and E. coli Bacteria Enterococcus Bacteria Benthic Invertebrates Blank Duplicate Sample Split Sample to lab Water quality 5% or a minimum of once a year none 5% or a minimum of once a year none 5% or a minimum of once a year none 5% or a minimum of once a year twice a year 5% or a minimum of once a year twice a year Nutrients (comparators) daily 5% or a minimum of once a year twice a year daily 5% or a minimum of once a year twice a year daily 5% or a minimum of once a year twice a year Nutrients (colorimeters or spectrophotometers) daily 5% or a minimum of once a year twice a year daily 5% or a minimum of once a year twice a year daily 5% or a minimum of once a year twice a year Urban Pollutants daily 5% or a minimum of once a year twice a year daily 5% or a minimum of once a year twice a year daily 5% or a minimum of once a year twice a year daily 5% or a minimum of once a year twice a year Biological Parameters daily 5% or a minimum of once per day twice a year none none none daily daily daily none 5% or a minimum of once per day None, instead conduct evaluation of sampling area annually twice a year 20% per year QC session twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year twice a year once a year Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 30 of 76 15. Instrument/Equipment Testing, Inspection and Maintenance A maintenance log is kept by the monitoring group leader. This log details the dates of instrument and sampling gear inspection, calibrations performed in the laboratory, battery replacement, the dates reagents and standards are replaced, and any problems noted with instruments, samplers, or reagents. 15.1. Temperature Before each use, thermometers are checked for breaks in the column. If a break is observed, the alcohol thermometer will be placed in nearly boiling water so that the alcohol expands into the expansion chamber, and the alcohol forms a continuous column. verify accuracy by comparing with a calibrated or certified thermometer. 15.2. Dissolved oxygen Dissolved Oxygen Winkler Titration: Before each use, bottles, droppers, and color comparators are checked to see if they are clean and in good working order. Reagents are replaced annually according to manufacturer’s recommendation. Dissolved Oxygen Meters: Membranes and solutions should be replaced according to manufacturer’s specifications, but no less frequently than quarterly. Membranes should be checked for bubbles after replacement. Before each use, D.O. meters are checked to see if they are clean and in good working order. 15.3. Conductivity and pH Before each use, conductivity and pH meters are checked to see if they are clean and in good working order. Conductivity and pH meters are calibrated before each use. Conductivity standards and pH buffers are replaced at least annually. Conductivity standards are stored with the cap firmly in place and in a dry place kept away from extreme heat. Do not re-use pH or conductivity standards. 15.4. Turbidity Dual Tube Turbidity (JTU’s): Before each use, turbidity tubes are checked to ensure that they are clean. The turbidity standard will be replaced annually. Nephelometers: Meters and tubes should be checked for cleanliness and proper operation. The tubes should not be smudged or scratched. 15.5. Nutrients and Urban Pollutants Before each use, test kits are checked to ensure that droppers, sample containers, and color comparators are clean and in working condition. Colorimeter tubes should be checked to make sure they are clean and are not scratched. Reagents are replaced annually according to manufacturer’s instructions. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 31 of 76 16. Instrument Calibration / Standardization and Frequency Instruments will be calibrated and reagents checked against standards accordingly to the following schedule. Standards will be purchased from a chemical supply company or prepared by (or with the assistance of) a professional laboratory. Calibration records will be kept in the maintenance log at the headquarters location (described in Section 5.2.) where it can be easily accessed before and after equipment use. Calibrations that are performed by monitors in the field are recorded on the field data sheets, also archived at the headquarters. The frequency of calibration is described in Table 16.1. Table 16.1 Instrument Calibration and Frequency Equipment Type Temperature Dissolved Oxygen (Winkler) Dissolved Oxygen meter pH conductivity Turbidity meter (nephelometer) Dual TubeTurbidity Conventional Water Quality Parameters Calibration Frequency Standard or Calibration Instrument Used Every 6 months NIST calibrated or certified thermometer Every 6 months Check sodium thiosulfate and/or against a saturated oxygen standard every 6 months. Every sampling day At a minimum, water saturated air, according to manufacturer’s instructions. Every sampling day pH 7.0 buffer and one other standard (4 or 10) Every sampling day Conductivity standard and distilled water Every sampling day For clear ambient conditions use an 1.0 NTU standard, for turbid conditions use an 10.0 NTU standard Every sampling day Distilled water Equipment type Ammonia Nitrate Ortho-Phosphate Nutrients (using comparators) Checked against Standard every 6 months or when reagents replaced every 6 months or when reagents replaced every 6 months or when reagents replaced Equipment type Ammonia Nitrate Ortho-Phosphate Nutrients (using colorimeters or spectrophotometers) Checked against Standard Standard Used Every day of analysis ammonia standard Every day of analysis nitrate standard Every day of analysis ortho-phosphate standard Equipment type Total Residual Chlorine Phenols Total Copper Detergents Urban Pollutants Checked against Standard every 6 months or when reagents replaced every 6 months or when reagents replaced every 6 months or when reagents replaced every 6 months or when reagents replaced Standard Used ammonia standard nitrate standard phosphorous standard Standard Used sodium hypochlorite phenol standard copper standard MBAS surfactant standard Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 32 of 76 17. Inspection/Acceptance Requirements Upon receipt, buffer solutions, standards, and reagents used in the field kits will be inspected by the citizen monitoring leader for leaks or broken seals, and to compare the age of each reagent to the manufacturer’s recommended shelf-life. All other sampling equipment will be inspected for broken or missing parts, and will be tested to ensure proper operation. Before usage, thermometers are inspected for breaks. Breaks can be eliminated by heating (see Section 15.1). If not, they will be returned to the manufacturer. Reagents are replaced before they exceed manufacturer’s recommended shelf life. These shelf lives are typically one to two years. However, specific replacement dates can determined by providing the reagent lot number to the manufacturer. Reagent replacement dates are noted in the maintenance log. 18. Data Acquisition Requirements 18.1. Professional Analytical Data Only certified analytical laboratories or academic laboratories (with approval of State and/or Regional Board staff) will be used for quality assurance checks and analysis of field samples. The Technical advisory Committee (TAC) or technical advisors will review these laboratories’ data as well as the volunteers. They may also review the lab’s own quality control data to ensure data validity. 18.2. Geographical Information/ Mapping USGS maps will be used to verify watershed boundaries and river courses. NOAA navigation charts can be used for mapping marine sampling sites. Additional information on distribution of natural resources will be obtained from the National Park Service and the CDFG’s Biodiversity database. Land use information will be obtained from local planning offices. When information is requested, the agency will be asked to provide appropriate megadata and any information on data limitations. This information will be maintained with the data files. For further information please refer to San Gabriel River Watershed Atlas. 19. Data Management Field data sheets are checked and signed in the field by the citizen monitoring leader. The citizen monitoring leader will identify any results where holding times have been exceeded, sample identification information is incorrect, samples were inappropriately handled, or calibration information is missing or inadequate. Such data will be marked as unacceptable by the monitoring leader and will not be entered into the electronic data base. Independent laboratories will report their results to the citizen monitoring leader. The leader will verify sample identification information, review the chain-of-custody forms, and identify the data appropriately in the database. These data are also reviewed by the technical advisors quarterly. The data management coordinator will review the field sheets and enter the data deemed acceptable by the citizen monitoring leader and the technical advisors. Upon entering the data the data management coordinator will sign and archive the field data sheets. Data will be entered into a spreadsheet (MS Excel) or a database (MS Access) in a way that will be compatible with EPA’s STORET and the Regional WQCB’s database guidelines. Following initial data entry the data coordinator will review electronic data, compare to the original data sheets and correct entry errors. After performing data checks, and ensuring that data quality objectives have been met, data analysis will be performed. Raw data will be provided to the State WQCB and Regional WQCB in electronic form at least once every two years so that it can be included in the 305(b) report. Appropriate quality assurance information may be provided upon request. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 33 of 76 20. Assessment and Response Actions Review of all field and data activities is the responsibility of the citizen monitoring leader, with the assistance of the technical advisory committee. Volunteers will be accompanied by the citizen monitoring leader, or a technical advisor on at least one of their first 5 sampling trips. If possible, volunteers in need of performance improvement will be retrained on-site. All volunteers must attend a refresher course offered by the citizen monitoring group. If errors in sampling technique are consistently identified, retraining may be scheduled more frequently. Within the first three months of the monitoring project, the State Water Board or Regional Board staff, or its designee, will evaluate field and laboratory performance and provide a report to the citizen monitoring group. All field and laboratory activities, and records may be reviewed by State and EPA quality assurance officers as requested. 21. Reports The technical advisors will review draft reports to ensure the accuracy of data analysis and data interpretation. Raw data will be made available to data users per their request. The citizen monitoring organization(s) will report their data to its (their) constituents after quality assurance has been reviewed and approved by their technical advisors. Every effort will be made to submit data and/or a report to the State and/or Regional Board staff in a fashion timely for their data uses, e.g. 305(b) reports. 22. Data Review, Validation and Verification Data sheets or data files are reviewed quarterly by the technical advisors to determine if the data meet the Quality Assurance Project Plan objectives. They will identify outliers, spurious results or omissions to the citizen monitoring leader. They will also evaluate compliance with the data quality objectives. They will suggest corrective action that will be implemented by the citizen monitoring leader. Problems with data quality and corrective action will be reported in final reports. 23. Validation and Verification Methods As part of standard field protocols, any sample readings out of the expected range will be reported to the citizen monitoring leader. A second sample will be taken as soon as possible to verify the condition. If the data is invalid, then the data will be noted (flagged) on the data sheet. We will take further actions to trace the sources of error, and to correct those problems. If the error is a result of improper monitoring procedures, then we may re-train monitors until their performance is acceptable. It is the responsibility of the citizen monitoring leader to re-train volunteers until performance is acceptable. 24. Reconciliation with DQOs The Technical Advisory Committee working with the monitoring leader(s) will review data quarterly to determine if the data quality objectives (DQOs) have been met. A quorum of 1/2+1of the technical advisory committee will be required for committee decisions. If a quorum is not met at the meeting, work will still proceed. The work product (e.g., review and comments on data or reports) will then be sent out to the whole technical advisory committee for approval with a 30-day review period. If data do not meet the project’s specifications, the following actions will be taken. First, the technical advisors working with the monitoring leader(s) will review the errors and determine if the problem is equipment failure, calibration/maintenance techniques, or monitoring/sampling techniques. They will suggest corrective action. If the problem cannot be corrected by training, revision of techniques, or replacement of supplies/equipment, then the technical advisors and the TAC will review the DQOs and determine if the DQOs are feasible. If the specific DQOs are not achievable, they will determine whether the specific DQO can be relaxed, or if the parameter should be eliminated from the monitoring program. Any revisions to DQOs will be appended to this QA plan with the revision date and the reason for modification. The appended QAPP will be sent to the quality assurance panel that approved and signed this plan. When the appended QAPP is approved, the citizen monitoring leader will work with the data coordinator to ensure that all data meeting the new DQOs are entered into the database. Archived data can also be entered. Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 34 of 76 APPENDIX 1. San Gabriel River Watershed Monitoring Manual Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 35 of 76 APPENDIX 2. Quality Assurance / Quality Control Data Forms Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 36 of 76 Data Quality Form: Accuracy Monitoring Group Name Your Name Date Parameter/ units Temperature o C Dissolved Oxygen (mg/l) pH standard units Conductivity (umhos/cm) Comments: Sensitivity Type of Session (field or lab) Quality Assurance Leader Accuracy Objective Standard Conc. Analytical Result Estimated Bias Meet Objective? Yes or No Corrective action planned Date Corrective Action taken Friends of the San Gabriel River Watershed - Draft Date: 3/7/2016 Page 37 of 76 Data Quality Form: Completeness Monitoring Group Name Your Name Date Parameter Temperature o C Dissolved Oxygen (mg/l) pH standard units Conductivity (umhos/cm) Comments: Type of Session (field or lab) Quality Assurance Leader Collection Period No. of Samples Anticipated No. Valid Samples Collected and Analyzed Percent Complete Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 38 of 76 Data Quality Form: Precision Monitoring Group Name Your Name Date Parameter/ units Temperature o C Dissolved Oxygen mg/l pH standard units Conductivity (umhos/cm) Comments: Mean (x) Type of Session (field or lab) Quality Assurance Leader Standard Deviation (s.d.) s.d./x Precision Objective Meet Objective? Yes or No Corrective action planned Date Corrective Action taken Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 39 of 76 APPENDIX 3. Field Data and Observation Sheets Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 40 of 76 APPENDIX 4. Maps of Sampling Locatons Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 41 of 76 APPENDIX 5. Acronyms Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 42 of 76 Acronyms ACO ACOPS Act 307 ADQ ADR AI AL ALR ARARs AS ASC AST ASTM ATSDR BACM BACT BADT BaP Administrative Consent Order (CERCLA) Advisory Committee on Oil Pollution of the Sea the Environmental Response Act Audits of Data Quality Alternative Dispute Resolution Active Ingredient Acceptable Level Action Leakage Rate Applicable, Relevant, Appropriate Reports Area Source Area Source Category above Ground Storage Tank American Society for Testing and Materials Agency for Toxic Substances and Disease Registry Best Available Control Measures Best Available Control Technology Best Available Demonstrated Technology Benzo(a)Pyrene BAT Best Available Technology or Best Available Technology Economically Achievable (CWA) BATEA BCPCT BCT BDAT BDCT BDT BEJ BGL/BGS BMP BMR BOD BOD BP BPJ BPT BPWTT BSE BSNH BSO BT BTEX BTZ CA Best Available Technology Economically Achievable Best Conventional Pollutant Control Technology Best Conventional Technology Best Demonstrated Available Technology (RCRA) Best Demonstrated Control Technology Best Demonstrational Technology Best Engineering Judgment Below Ground Level/ Below Ground Surface Best Management Practice(s) Baseline Monitoring Report Biochemical or Biological Oxygen Demand Biochemical Oxygen Demand. Biological Oxygen Demand Boiling Point Best Professional Judgment Best Practicable Technology. Pest Practicable Treatment Best Practical Wastewater Treatment Technology Base flood elevation Headwater basin Benzene Soluble Organics Base Topo Benzene, Toluene, Ethylbenzene, Xylene Below the Treatment Zone California Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 43 of 76 Cal. Cal/EPA Calif. Cal-OSHA CalTrans CAMU CAO CAP CAS CCP CCR CDC CDD CDF CDFG CDMG CDWR CEB CEQ CEQA California California Environmental Protection Agency California California Division of Occupational Safety and Health California Department of Transportation Corrective Action Management Units (RCRA) Corrective Action Order (RCRA) Corrective Action Plan. Cost Allocation Procedure. Criteria Air Pollutant Chemical Abstract Service Commercial Chemical Product California Code of Regulations Centers for Disease Control Chlorodibenzodioxin Chlorodibenzofuran California Department of Fish and Game California Div. of Mines and Geology California Dept. of Water Resources Chemical Element Balance Council on Environmental Quality California Environmental Quality Act, Public Resources Code Section 21000 et seq; Title 14 CCR Section 15000 et seq CERCLA Comprehensive Environmental Response, Compensation, and Liability Act CERCLIS Comprehensive Environmental Response, Compensation, and Liability Information System CERES California Environmental Resource Evaluation System CESPL OM Corps of Engineers, South Pacific Division, LA District, Operations Manual COE United States Army Corps of Engineers CESQG Conditionally Exempt Small Quantity Generator of hazardous wastes CFC Chlorofluorocarbons CFCs chlorofluorocarbons (refrigerants whose reactions in the atmosphere destroy stratospheric ozone) CFM Chlorofluoromethanes CFR Code of Federal Regulations CFS cubic feet per second (units of flow rate, also see MGD) CGL Comprehensive General Liability Insurance CHEMTREC Chemical Transport Emergency Center (1-800-424-9300) CHIPS Chemical Hazards Information Profiles (EPA CIMIS California Irrigation Management Information System CIRSS California Integrated Remote Sensing System cm Centimeter CO Carbon monoxide COD Chemical Oxygen Demand CPSC Consumer Product Safety Commission (16 CFR) CRKT Tidal creek Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 44 of 76 CRWQCB CSO CSP CSWMP CTG CWA CWA CWAP CWPPRA CZMA DC&A DCE DCO DDT DEIS DES DMR DNA DNAPL DO DOC DOD DOE DOJ DOT DQO DRE EA EAP EB EBS ED EDB EDC EDTA EH EHS EIA EIS EL EMR EMS EO EOP California Regional Water Quality Control Board Combined Sewer Overflow Certified Safety Professional County Solid Waste Management Plan (California) Control Techniques Guidelines Clean Water Act or FWPCA, 33 USC Section 1251 et seq;CA Water Code Section 13200 et seq (Porter-Cologne Act) Clean Water Act Clean Water Action Project Coastal Wetlands Planning, Protection & Restoration Act Coastal Zone Management Act Data Collection and Analysis Dichloroethene Delayed Compliance Order Dichlorodiphenyltrichloroethane - a toxic pesticide Draft Environmental Impact Statement (NEPA) Diethylstilbesterol Discharge Monitoring Report Deoxyribonucleic acid Dense Non-Aqueous Phase Liquid Dissolved Oxygen dissolved organic carbon Department of Defense Department of Energy Department of Justice Department of Transportation Data Quality Objective Destruction and Removal Efficiency Environmental assessment Environmental Action Plan Environmental Benefits Environmental Baseline Survey Effective Dose Ethylene Dibromide Ethylene Dichloride Ethylene Diamine Triacetic Acid Redox Potential Extremely Hazardous Substance Environmental Impact Assessment. Economic Impact Assessment Environmental Impact Statement (required under NEPA) Exposure Level Environmental Management Report Environmental Management System (also see ISO14000) Ethylene Oxide End of Pipe Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 45 of 76 EP EPA ESA ESA ESH FDA FFCA FID FIFRA FIRM FIRMS FR FS FU FWS GAC GC/MS GIS GLC GMCC GPM GPS GRAS GWM HA ha HASWA HAZMAT HazWoper HBM HBMN HCCPD HCFC HFA HFC HHS HIU HLL HLLS HRS HUA HW HWM IB Extraction Procedure U.S. Environmental Protection Agency Endangered Species Act Environmental Site Assessment Environmental Safety and Health Food and Drug Administration (21 CFR) Federal Facility Compliance Act MS Gas Chromatograph/ Mass Spectrograph Federal Insecticide, Fungicide and Rodenticide Act Flood Rate Insurance Map Flood Rate Insurance Maps Federal Register Feasibility Study Field unit Fish and Wildlife Service (U.S.) granular activated carbon Gas Chromatography/Mass Spectrometry Geographic Information System Gas Liquid Chromatography Global Monitoring for Climatic Change Gallons per Minute Geographic Positioning System Generally Recognized as Safe Groundwater Monitoring Hydrologic Atlas Hectare Hazardous and Solid Waste Amendments Hazardous Materials 29 CFR 1910.120 - the OSHA / EPA requirement to have all employees trained if they will be handling, managing or shipping hazardous wastes. Hydrologic bench mark Hydrologic Bench Mark Network Hexachlorocyclo-pentadiene Hydrochlorofluorocarbon Hydrologic field assistant Hydrofluorocarbon Department of Health and Human Services Hydrologic Information Unit Hill Hills Hazard Ranking System Hydrologic Unit Area Hazardous Waste Hazardous Waste Management Isobar Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 46 of 76 ID in INUR ITC IWMB km L/C LAER Lat LCA LD50 LDS LEPC LFG LGN LK LKS LOD LOEL Long LQG LUFT LUST m M. MACT MATC mB MCL (SDWA) MCLGs MDL MGD MHW Mi Min MLW MP MRQ (as in ID number) - Hazardous Waste Identification Number assigned to RCRA generators, transporters, and TSDFs Inch; inches Inventory Update Rule Interagency Testing Committee California Integrated Waste Management Board (Cal/EPA) Kilometer Land cover Lowest Achievable Emission Rate Latitude Life Cycle Analysis/ Assessment Lethal Dose Level 50% Leak Detection System Local Emergency Planning Committee Landfill Gas Lagoon Lake Lakes Limit of Detection Lowest Observed Effect Level Longitude Large Quantity Generator of hazardous wastes - this term has a specific definition under RCRA! Leaking Underground Fuel Tank Leaky Underground Storage Tank Meter Mile; mille (1,000) Maximum Achievable Control Technology Maximum Acceptable Toxic Concentration Millibar Maximum Concentration Limits or Maximum Contaminant Levels Maximum Contaminant Level Goals (SDWA) Maximum Detection Level million gallons per day (units of flow rate) Mean High Water Mile(s) Minute Mean low water Measuring point Monthly Hotline Report Q&A, The Hotline prepares a monthly report that contains questions and answers on common or difficult RCRA topics. EPA publishes this report. The questions and answers can be usually used as EPA guidance. Beware: the hotline is run by an EPA contractor and their answers are often erratic and not legally binding. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 47 of 76 MRSH MSDS MSE MSL MSW MT Mt MTBE MTD Mtn. N N2O NAA NAAQS NAPL NCP NDVI NEPA NESHAP NFIP NFRAP NFS NFWS NIMBY NIOSH NIPDWR NO NOV NOx NPDES NPL NPS NPS Nr. NRC NRWS NSDWR NSPS NSR NTU NWQS Marsh Material Safety Data Sheet (under OSHA) Mean square error Mean sea level Municipal Solid Waste Mountain; Montana Mount; Mountain; Mont methyl tert-butyl ether (gasoline additive to reduce emissions, now a common groundwater contaminant) Maximum Tolerated Dose Mountain North Nitrous Oxide Non-Attainment Area National Ambient Air Quality Standards Non-Aqueous Phase Liquid National Contingency Plan Normalized Difference Vegetation Index National Environmental Policy Act National Emissions Standard for Hazardous Air Pollutants National Flood Insurance Program (U.S.) No Further Remedial Action Planned National Forest Service (U.S.); National Forest System; Network File System National Fish and Wildlife Service (U.S.) "Not In My Backyard" Syndrome National Institute of Occupational Safety and Health National Interim Primary Drinking Water Regulations Nitric Oxide Notice of Violation Nitrogen Oxides National Pollutant Discharge Elimination System (permits for discharges to lakes, rivers or streams under CWA) National Priorities List (list of ranked hazardous waste sites established under Superfund) National Park Service (U.S.) Non-Point Source number National Response Center Narrows National Secondary Drinking Water Regulation New Source Performance Standards New Source Review Nephlometric Turbidity Unit National Water Quality Standards (CWA) Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 48 of 76 O3 OPA OPM ORD OSHA OSW OSWER P PAA PAH PAIR Pb PCB PCDF PCE PCP PEL PFC PGM pH PK PM-10 PNA PND PNDI PNIN PNRS POC POE POI POTW ppb PPE ppm PPM/PPB ppt PPTH PRP PS PSA PSAM PSD PSM PSU Ozone Oil Pollution Act Operation and Maintenance Office of Research and Development Occupational Safety and Health Administration (29 CFR) Office of Solid Waste Office of Solid Waste and Emergency Response Precision Priority abatement areas Polynuclear Aromatic Hydrocarbons Preliminary Assessment Information Rule Lead polychlorinated biphenyls (former used in industrial fluids, now common food chain contaminant) Polychlorinated Dibenzofurans Perchloroethylene Pentachlorophenol Permissible Exposure Limit Perfluorated Carbon Permanent ground monument -log (hydrogen ion activity) Peak Particulate Matter < 10 Micrometers Polynuclear Aromatic Hydrocarbons Pond Intermittent pond Premanufacture Notification Preliminary Natural Resources Survey Point Of Compliance Point Of Exposure Point Of Interception Publicly Owned Treatment Works Parts per billion Personal Protective Equipment Parts per million Parts per million/ parts per billion Parts Per Trillion Parts Per Thousand Potentially Responsible Party (Superfunds) Point Source Preliminary Site Assessment Point Source Ambient Monitoring Prevention of Significant Deterioration Point Source Monitoring Primary sampling unit Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 49 of 76 PT Point PTFE Polytetrafluoroethylene (Teflon) Pts. Points PVC Polyvinyl Chloride QA Quality assurance QA/QC Quality Assurance/Quality Control QAC Quality Assurance Coordinator QAMIS Quality Assurance Management and Information System QAO Quality Assurance Officer QAPP Quality Assurance Program (or Project) Plan QAT Quality Action Team QBS Quality-based selection QC Quality Control QCI Quality Control Index QCP Quality Control Plan QL Quantification Limit QW Quality of water R&D Research and Development RACM Reasonably Available Control Measure RACT Reasonably Available Control Technique RAP Remedial Action Plan (Superfunds) RAPS Remedial Action Plans RBI River Basin Investigation RCH Reach RCRA Resource Conservation and Recovery Act RI Remedial Investigation RI/FS Remedial Investing/Feasibility Study (CERCLA) ROWD Report of Waste Discharge RPCC Release Prevention, Control and Countermeasure RPDS Rapids RQ Reportable Quantity RSV Reservoir RTK Right-to-Know RUST RCRA Underground Storage Tanks RWQCB Regional Water Quality Control Board (California) S&A Sampling and analysis SARA Title III Emergency Preparedness and Community Right-to-Know Section of SARA, aka EPCRA SARA Superfund Amendment Reauthorization Act SARWQCB Santa Ana Regional Water Quality Control Board SCCWRP Southern California Coastal Water Research Project SCWRP Southern California Wetlands Recovery Project SDWA Safe Drinking Water Act of 1974 SDWIS Safe Drinking Water Information System SERC State Emergency Response Commission Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 50 of 76 SIC SIP SLP SMCL SO SOC SOW SPCC SPDES SQG Superfund SW-846 SWPPP SWQTF SWRCB T/RS TCDD TCDF TCE TCF TCLP TCP TCRI TD TDS TEG TEL THC THM TLV TMDL TNT TOA TOC TOX Tp. TPTH TRI TRIP TRIS TSCA TSDF TSP TSS Standard Industrial Classification State Implementation Plan Slope(s) Secondary Maximum Contamination Level Sulfur Dioxide Schedule of Compliance Scope Of Work Spill Prevention Control and Countermeasures State Pollutant Discharge Elimination Small Quantity Generator of hazardous wastes (has a specific definition!) CERCLA Test Methods for Evaluating Solid Waste, Physical/Chemical Methods Stormwater Pollution Prevention Program Stormwater Quality Task Force State Water Resources Control Board (Cal/EPA) Township/Range System Tetrachlorodibenzodioxin Tetrachlorodi-benzofurans Tetrachloroethylene, perchloroethylene Total Chlorine Free Toxic Characteristic Leaching Procedure Trichloropropane; Toxic Chemical Release Inventory Toxic Dose Total Dissolved Solids Tetraethylene Glycol Tetraethyl Lead Total Hydrocarbons Trihalomethane Threshold Limit Value Total Maximum Daily Limit; Total Maximum Daily Load Trinitrotoluene Trace Organic Analysis Total Organic Carbon/ Compound Tetradichloroxylene Township Triphenyltinhydroxide Toxic Release Inventory Toxic Release Inventory Program Toxic Chemical Release Inventory System Toxic Substances Control Act Treatment, Storage, or Disposal Facility (permitted hazardous waste facility) Total Suspended Particulates Total Suspended (non-filterable) Solids Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 51 of 76 TTHM TTO TVOC TWA U.S. U/R UA ug/m3 UGB UIC Univ. UP USA USC USCG USDA USDW USPS UST VCM VCP VOC VP VSS WAP WCRD WDMS WET WIS WMA WMD WQMP WQS Total Trihalomethane Total Toxic Organics Total Volatile Organic Compounds Time Weighted Average United States of America Urban/rural Urbanized area Micrograms Per Cubic Meter Urban growth boundary Underground Injection Control University Urban planning United States of America; United States Army Unified soil classification United States Coast Guard United States Department of Agriculture Underground Source of Drinking Water United States Postal Service Underground Storage Tanks Vinyl Chloride Monomer Voluntary Cleanup Program Volatile Organic Compounds Vapor Pressure Volatile Suspended Solids Waste Analysis Plan Watershed & Coastal Resources Division Watershed Data Management System Wetland Evaluation Technique Watershed Information System Watershed Management Areas Water management district Water Quality Management Plan Water Quality Standard Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 52 of 76 APPENDIX 6. Glossary Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 53 of 76 GLOSSARY acre-foot (acre-ft) - The volume of water required to cover 1 acre of land (43,560 square feet) to a depth of 1 foot. Equal to 325,851 gallons or 1,233 cubic meters. abatement debris - Waste from remediation activities. abatement - Reducing the degree or intensity of, or eliminating, pollution. absorption - The process by which substances in gaseous, liquid, or solid form dissolve or mix with other substances. acidic - The condition of water or soil that contains a sufficient amount of acid substances to lower the pH below 7.0. action levels - 1. Regulatory levels recommended by EPA for enforcement by FDA and USDA when pesticide residues occur in food or feed commodities for reasons other than the direct application of the pesticide. 2. In the Superfund program, the existence of a contaminant concentration in the environment high enough to warrant action or trigger a response under SARA and the National Oil and Hazardous Substances Contingency Plan. The term is also used in other regulatory programs. activated sludge - Product that results when primary effluent is mixed with bacteria-laden sludge and then agitated and aerated to promote biological treatment, speeding the breakdown of organic matter in raw sewage undergoing secondary waste treatment. advanced treatment - A level of wastewater treatment more stringent than secondary treatment; requires an 85-percent reduction in conventional pollutant concentration or a significant reduction in non-conventional pollutants. Sometimes called tertiary treatment. aeration - A process which promotes biological degradation of organic matter in water. The process may be passive (as when waste is exposed to air), or active (as when a mixing or bubbling device introduces the air). aerobic - Bacteria or processes active only in the presence of molecular oxygen. agricultural pollution - Farming wastes, including runoff and leaching of pesticides and fertilizers; erosion and dust from plowing; improper disposal of animal manure and carcasses; crop residues, and debris. alkalinity - The total measurable bases (OH, HCO3, CO3) in a volume of water; a measure of a material's capacity to neutralize acids. When soil or water contains sufficient amounts of alkali substances to raise the pH above 7.0, it is said to be alkaline. alluvium - A general term for clay, silt, sand and gravel, or similar unconsolidated material deposited by a river as a sorted or semi-sorted sediment in the bed of the river or on its floodplain. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 54 of 76 applicable or relevant and appropriate requirements (ARARs) - Any state or federal statute that pertains to protection of human life and the environment in addressing specific conditions or use of a particular cleanup technology at a Superfund site. aqueous solubility - The maximum concentration of a chemical that will dissolve in pure water at a reference temperature. aromatics - A type of hydrocarbon, such as benzene or toluene, with a specific type of ring structure. Aromatics are sometimes added to gasoline in order to increase octane. Some aromatics are toxic. artificial recharge - A process where water is put back into ground-water storage from surface-water supplies such as irrigation, or induced infiltration from streams or wells. assay - A test for a specific chemical, microbe, or effect. assessment endpoint - In ecological risk assessment, an explicit expression of the environmental value to be protected; includes both an ecological entity and specific attributed thereof entity (e.g. salmon are a valued ecological entity; reproduction and population maintenance--the attribute--form an assessment endpoint.) attractant - A chemical or agent that lures insects or other pests by stimulating their sense of smell. background level - 1. The concentration of a substance in an environmental media (air, water, or soil) that occurs naturally or is not the result of human activities. 2. In exposure assessment the concentration of a substance in a defined control area, during a fixed period of time before, during, or after a data-gathering operation. backyard composting - Diversion of organic food waste and yard trimmings from the municipal waste stream by composting hem in one's yard through controlled decomposition of organic matter by bacteria and fungi into a humus-like product. It is considered source reduction, not recycling, because the composted materials never enter the municipal waste stream. bacteria - (singular: bacterium) Microscopic living organisms that can aid in pollution control by metabolizing organic matter in sewage, oil spills or other pollutants. However, bacteria in soil, water or air can also cause human, animal and plant health problems. baseflow - That part of a stream discharge not attributable to direct runoff from precipitation or snowmelt, usually sustained by groundwater discharging into the stream. bed load - Sediment particles, or bed material resting on or near the channel bottom that are pushed or rolled along by the flow of water. Bed Material also refers to bottom sediments of lakes, ponds, rivers or estuaries. bedrock - The solid rock beneath the soil and superficial rock. A general term for solid rock that lies beneath soil, loose sediments, or other unconsolidated material. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 55 of 76 benefit-cost analysis - An economic method for assessing the benefits and costs of achieving alternative health-based standards at given levels of health protection. best available control measures (BACM) - A term used to refer to the most effective measures (according to EPA guidance) for controlling small or dispersed particulates and other emissions from sources such as roadway dust, soot and ash from woodstoves and open burning of rush, timber, grasslands, or trash. biological processes – bioaccumulants - Substances that increase in concentration in living organisms as they take in contaminated air, water, or food because the substances are very slowly metabolized or excreted. biochemical oxygen demand (BOD) - A measure of the quantity of dissolved oxygen [mg/l] necessary for the decomposition of organic matter in water by organisms (chiefly bacteria). bioconcentration - The accumulation of a chemical in tissues of a fish or other organism to levels greater than in the surrounding medium. biodegradable - Capable of decomposing under natural conditions biodegradation - A subset of biotransforination, it is the biologically mediated conversion of a compound to more simple products. biogenic - Formed biologically by organisms or within organisms. biological contaminants - Living organisms or derivates (e.g. viruses, bacteria, fungi, and mammal and bird antigens that can cause harmful health effects when inhaled, swallowed, or otherwise taken into the body. biological magnification - Refers to the process whereby certain substances such as pesticides or heavy metals move up the food chain, work their way into rivers or lakes, and are eaten by aquatic organisms such as fish, which in turn are eaten by large birds, animals or humans. The substances become concentrated in tissues or internal organs as they move up the chain. (See: bioaccumulants.) biological oxygen demand (BOD) - An indirect measure of the concentration of biologically degradable material present in organic wastes. It usually reflects the amount of oxygen consumed in five days by biological processes breaking down organic waste. biological stressors - Organisms accidentally or intentionally dropped into habitats in which they do not evolve naturally; e.g. gypsy moths, Dutch elm disease, certain types of algae, and bacteria. biosensor - Analytical device comprising a biological recognition element (e.g. enzyme, receptor, DNA, antibody, or microorganism) in intimate contact with an electrochemical, optical, thermal, or acoustic signal transducer that together permit analyses of chemical properties or quantities. Shows potential development in some areas, including environmental monitoring. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 56 of 76 biotechnology - Techniques that use living organisms or parts of organisms to produce a variety of products (from medicines to industrial enzymes) to improve plants or animals or to develop microorganisms to remove toxics from bodies of water, or act as pesticides. bioassay - A test to determine the relative strength of a substance by comparing its effect on a test organism with that of a standard preparation. bioaugmentation - Similar to bioremediation, but involving the introduction of organisms to affect cleanup. biological control - In pest control, the use of animals and organisms that eat or otherwise kill or out-compete pests. biological oxidation - Decomposition of complex organic materials by microorganisms. Occurs in self-purification of water bodies and in activated sludge wastewater treatment. biological treatment - A treatment technology that uses bacteria to consume organic waste. biomonitoring – The use of living organisms to test the suitability of effluents for discharge into receiving waters and to test the quality of such waters downstream from the discharge. bioremediation - The process by which bacteria remove contaminant from a groundwater system. extrinsic bioremediation - In this process bacteria are added to the system. intrinsic bioremediation - In this process we rely on bacteria already existing in the system. biodiversity - Refers to the variety and variability among living organisms and the ecological complexes in which they occur. biomass - All of the living material in a given area; often refers to vegetation. biome - Entire community of living organisms in a single major ecological area. (See: biotic community.) biota - The total assemblage of plants and animals in an area. The biota is the sum of the plant life (flora) and animal life (fauna). biotic community - A naturally occurring assemblage of plants and animals that live in the same environment and are mutually sustaining and interdependent. (See: biome.) bloom - A proliferation of algae and/or higher aquatic plants in a body of water; often related to pollution, especially when pollutants accelerate growth. brackish water - Mixed fresh and salt water; ≈ (103 - 104 mg / l). breathing zone - Area of air in which an organism inhales. brine - Water with a salinity > 104 mg / l. brownfields - Abandoned, idled, or under used industrial and commercial facilities/sites where expansion or redevelopment is complicated by real or perceived environmental contamination. They can be in urban, suburban, or rural areas. EPA's Brownfields initiative Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 57 of 76 helps communities mitigate potential health risks and restore the economic viability of such areas or properties. buffer - Asolution or liquid whose chemical makeup is such that it minimizes changes in pH when acids or bases are added to it. cadmium (Cd) - A heavy metal that accumulates in the environment. CAS registration number - A number assigned by the Chemical Abstract Service to identify a chemical. carbon monoxide (CO) - A colorless, odorless, poisonous gas produced by incomplete fossil fuel combustion. carbon tetrachloride (CC14) - Compound consisting of one carbon atom ad four chlorine atoms, once widely used as a industrial raw material, as a solvent, and in the production of CFCs. Use as a solvent ended when it was discovered to be carcinogenic. carcinogenic - Event, condition, or effect that produces cancer. catalyst - A substance that changes the speed or yield of a chemical reaction without being consumed or chemically changed by the chemical reaction. central collection point - Location were a generator of regulated medical waste consolidates wastes originally generated at various locations in his facility. The wastes are gathered together for treatment on-site or for transportation elsewhere for treatment and/or disposal. This term could also apply to community hazardous waste collections, industrial and other waste management systems. chemical oxygen demand (COD) - A measure of chemically oxidizable material in water. COD is an approximation of the amount of organic and reducing material present. chemical stressors - Chemicals released to the environment through industrial waste, auto emissions, pesticides, and other human activity that can cause illnesses and even death in plants and animals. chlorinated hydrocarbons - 1. Chemicals containing only chlorine, carbon, and hydrogen. These include a class of persistent, broad-spectrum insecticides that linger in the environment and accumulate in the food chain. Among them are DDT, aldrin, dieldrin, heptachlor, chlordane, lindane, endrin, Mirex, hexachloride, and toxaphene. Other examples include TCE, used as an industrial solvent. 2. Any chlorinated organic compounds including chlorinated solvents such as dichloromethane, trichloromethylene, chloroform. chlorinated solvent - An organic solvent containing chlorine atoms (e.g. methylene chloride and 1,1,1-trichloromethane). Uses of chlorinated solvents are included in aerosol spray containers, highway paint, and dry cleaning fluids. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 58 of 76 cleanup - Actions taken to deal with a release or threat of release of a hazardous substance that could affect humans and/or the environment. The term "cleanup" is sometimes used interchangeably with the terms remedial action, removal action, response action, or corrective action. climate change (also referred to as 'global climate change') - The term 'climate change' is sometimes used to refer to all forms of climatic inconsistency, but because the Earth's climate is never static, the term is more properly used to imply a significant change from one climatic condition to another. In some cases, 'climate change' has been used synonymously with the term, 'global warming'; scientists however, tend to use the term in the wider sense to also include natural changes in climate. global warming - An increase in the near surface temperature of the Earth. Global warming has occurred in the distant past as the result of natural influences, but the term is most often used to refer to the warming predicted to occur as a result of increased emissions of greenhouse gases (greenhouse effect). coastal zone - Lands and waters adjacent to the coast that exert an influence on the uses of the sea and its ecology, or whose uses and ecology are affected by the sea. coliform bacteria - A group of bacteria that mostly inhabits the intestinal tract of humans and animals, but also found in soil. While harmless in themselves, coliform bacteria are used as indicators of the possible presence of pathogenic organisms. therefore, the coliform index is a rating of the purity of water based upon a count of fecal bactera. colloid - Particles so small that they do not settle gravitationally, but are kept suspended by Brownian motion. For colloids in water, they range in size from 10-9 to 10-6 m (or 10-3 to 1 microns). combined sewer overflows - Discharge of a mixture of storm water and domestic waste when the flow capacity of a sewer system is exceeded during rainstorms. combined sewers - A sewer system that carries both sewage and storm-water runoff. Normally, its entire flow goes to a waste treatment plant, but during a heavy storm, the volume of water may be so great as to cause overflows of untreated mixtures of storm water and sewage into receiving waters. Storm-water runoff may also carry toxic chemicals from industrial areas or streets into the sewer system. comparative risk assessment - Process that generally uses the judgment of experts to predict effects and set priorities among a wide range of environmental problems. compost - The relatively stable humus material that is produced from a composting process in which bacteria in soil mixed with garbage and degradable trash break down the mixture into organic fertilizer. conductance - A rapid method of estimating the dissolved solids content of water supply by determining the capacity of a water sample to carry an electrical current. Conductivity is a measure of the ability of a solution to carry and electrical current. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 59 of 76 conservation - Preserving and renewing, when possible, human and natural resources. The use, protection, and improvement of natural resources according to principles that will ensure their highest economic or social benefits. conservation solute - A non-reactive constituent that does not undergo chemical reduction. constituent(s) of concern - Specific chemicals that are identified for evaluation in the site assessment process consumptive use - That part of water withdrawn that is evaporated, transpired by plants, incorporated into products or crops, consumed by humans or livestock, or otherwise removed from the immediate water environment. Also referred to as water consumed. contamination - The degradation of natural water quality as a result of man's activities. There is no implication of any specific limits, since the degree of permissible contamination depends upon the intended end use of the water. corrective action - EPA can require treatment, storage and disposal (TSDF) facilities handling hazardous waste to undertake corrective actions to clean up spills resulting from failure to follow hazardous waste management procedures or other mistakes. cryptosporidium - A protozoan microbe associated with the disease cryptosporidiosis in man. The disease can be transmitted through ingestion of drinking water, person-to-person contact, or other pathways, and can cause acute diarrhea, abdominal pain, vomiting, fever, and can be fatal as it was in the Milwaukee episode. decomposition - The breakdown of matter by bacteria and fungi, changing the chemical makeup and physical appearance of materials. decontamination - Removal of harmful substances such as noxious chemicals, harmful bacteria or other organisms, or radioactive material from exposed individuals, rooms and furnishings in buildings, or the exterior environment. DDT - The first chlorinated hydrocarbon insecticide chemical name: Dichloro-DiphenylTrichloroethane). It has a half-life of 15 years and can collect in fatty tissues of certain animals. EPA banned registration and interstate sale of DDT for virtually all but emergency uses in the United States in 1972 because of its persistence in the environment and accumulation in the food chain. degradation - To wear down, reduce to lower quality, by erosion or reduce the complexity of a chemical compound diffusion - The movement of suspended or dissolved particles (or molecules) from a more concentrated to a less concentrated area. The process tends to distribute the particles or molecules more uniformly. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 60 of 76 dioxin - Any of a family of compounds known chemically as dibenzo-p-dioxins. Concern about them arises from their potential toxicity as contaminants in commercial products. Tests on laboratory animals indicate that it is one of the more toxic anthropogenic (man-made) compounds. dissolved oxygen (DO) - The oxygen freely available in water, vital to fish and other aquatic life and for the prevention of odors. DO levels are considered a most important indicator of a water body's ability to support desirable aquatic life. . diversion - 1. Use of part of a stream flow as water supply. 2. A channel with a supporting ridge on the lower side constructed across a slope to divert water at a non-erosive velocity to sites where it can be used and disposed of. divide - A topographic high (or ridge) separating surface watersheds (catchments). domestic water use - Water used for household purposes, such as drinking, food preparation, bathing, washing clothes, dishes, and dogs, flushing toilets, and watering lawns and gardens drainage basin - Land area where precipitation runs off into streams, rivers, lakes, and reservoirs. Also called a watershed. drought - A prolonged period of low (lower than average) rainfall. drinking water equivalent level - Protective level of exposure related to potentially noncarcinogenic effects of chemicals that are also known to cause cancer. ecological impact - The effect that a man-caused or natural activity has on living organisms and their non-living (abiotic) environment. ecology - The relationship of living things to one another and their environment, or the study of such relationships. ecological indicator - A characteristic of an ecosystem that is related to, or derived from, a measure of biotic or abiotic variable, that can provide quantitative information on ecological structure and function. ecological integrity - A living system exhibits integrity if, when subjected to disturbance, it sustains and organizes self-correcting ability to recover toward a biomass end-state that is normal for that system. ecological risk assessment - The application of a formal framework, analytical process, or model to estimate the effects of human actions(s) on a natural resource and to interpret the significance of those effects in light of the uncertainties identified in each component of the assessment process. Such analysis includes initial hazard identification, exposure and dose-response assessments, and risk characterization. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 61 of 76 ecosystem structure - Attributes related to the instantaneous physical state of an ecosystem; examples include species population density, species richness or evenness, and standing crop biomass. ecosystem - The interacting system of a biological community and its non-living environmental surroundings. effluent - Wastewater, treated or untreated, that flows out of a treatment plant, sewer, or industrial outfall. Generally refers to wastes discharged into surface waters. effluent guidelines - Technical EPA documents which set effluent limitations for given industries and pollutants. effluent limitation - Restrictions established by a state or EPA on quantities, rates, and concentrations in wastewater discharges. effluent standard - (See: effluent limitation.) emergency (chemical) - A situation created by an accidental release or spill of hazardous chemicals that poses a threat to the safety of workers, residents, the environment, or property. enforceable requirements - Conditions or limitations in permits issued under the Clean Water Act Section 402 or 404 that, if violated, could result in the issuance of a compliance order or initiation of a civil or criminal action under federal or applicable state laws. If a permit has not been issued, the term includes any requirement which, in the Regional Administrator's judgment, would be included in the permit when issued. Where no permit applies, the term includes any requirement which the RA determines is necessary for the best practical waste treatment technology to meet applicable criteria. EPA - The Environmental Protection Agency. The federal authority responsible for enforcing the various laws dealing with environmental standards. estimated environmental concentration - The estimated pesticide concentration in an ecosystem. estuary - Region of interaction between rivers and near-shore Ocean waters, where tidal action and river flow mix fresh and salt water. Such areas include bays, mouths of rivers, salt marshes, and lagoons. These brackish water ecosystems shelter and feed marine life, birds, and wildlife. (See: wetlands.) ethylene dibromide (EDB) - A chemical used as an agricultural fumigant and in certain industrial processes. Extremely toxic and found to be a carcinogen in laboratory animals, EDB has been banned for most agricultural uses in the United States. eutrophication - The slow aging process during which a lake, estuary, or bay evolves into a bog or marsh and eventually disappears. During the later stages of eutrophication the water body is choked by abundant plant life due to higher levels of nutritive compounds such as nitrogen and phosphorus. Human activities can accelerate the process. exceedance - Violation of the pollutant levels permitted by environmental protection standards. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 62 of 76 exotic species - A species that is not indigenous to a region. fecal coliform bacteria - Bacteria found in the intestinal tracts of mammals. Their presence in water or sludge is an indicator of pollution and possible contamination by pathogens. flocculation - The aggregation of particles (colloids or precipitates) suspended in a solution to a size that they can settle gravitationally. flood peak - The highest stage or discharge during a given flood event. floodplain - The flat or nearly flat land along a river or stream or in a tidal area that is covered by water during a flood. flow rate - The rate, expressed in gallons -or liters-per-hour, at which a fluid escapes from a hole or fissure in a tank. Such measurements are also made of liquid waste, effluent, and surface water movement. fluvial - Referring to processes occurring in a river. fresh water - Water with a salinity < 1000 mg/l of dissolved solids; drinkable or potable water is implied. Ghyben-Herzberg (or freshwater) lens - A body of freshwater buoyantly overlying marine water. hardness - A water-quality indication of the concentration of alkaline salts in water, mainly calcium and magnesium. If the water you use is "hard" then more soap, detergent or shampoo is necessary to raise a lather. Soft mineral grains/gallon >1.0 ,50 CaCO3 Moderately Slightly Moderately Soft Hard Hard 51-100 1.0-3.5 101-150 3.5-7.5 151-250 Hard Very Hard 7.5<10.5 10.5 251>350 350 headwater(s) - 1. The source and upper reaches of a stream; also the upper reaches of a reservoir. 2. The water upstream from a structure or point on a stream. 3. The small streams that come together to form a river. Also may be thought of as any and all parts of a river basin except the mainstream river and main tributaries. Hjulstrom Diagram - A plot of stream velocity versus stream bed grain size with the fields of deposition (sedimentation), erosion, and transportation. household hazardous waste - Hazardous products used and disposed of by residential as opposed to industrial consumers. Includes paints, stains, varnishes, solvents, pesticides, and Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 63 of 76 other materials or products containing volatile chemicals that can catch fire, react or explode, or that are corrosive or toxic. hydrological cycle - The cyclic transfer of water vapor from the Earth's surface via evapotranspiration into the atmosphere, from the atmosphere via precipitation back to earth, and through runoff into streams, rivers, and lakes, and ultimately into the oceans. hydrologic unit - A geographic area representing all or part of a surface drainage basin or a distinct hydrologic feature. In the U. S. these units have 8-digit identification numbers. hydrology - 1. The study of the waters of the Earth (or other planetary bodies); 2. A distinct geoscience interactive on a wide range of spatial and temporal scales with the oceanic, atmospheric, and solid earth sciences as well as with many biological sciences. indicator - 1. In biology, any biological entity or processes, or community whose characteristics show the presence of specific environmental conditions. 2. In chemistry, a substance that shows a visible change, usually of color, at a desired point in a chemical reaction. 3. A device that indicates the result of a measurement; e.g. a pressure gauge or a moveable scale. interflow - Water which infiltrates the land surface and flows into a stream but never recharges the local water table. isotropy - The condition in which the properties of interest (generally hydraulic properties of the aquifer) are the same in all directions. lacustrine - Relating to processes occurring in a lake. lag time - The time between the middle of the precipitation event in a watershed (or catchment) and the arrival of the flood peak at a given location. lagoon - Shallow body of water, often separated from the sea by coral reefs or sandbars. lead (Pb) - A heavy metal that is hazardous to health if breathed or swallowed. Its use in gasoline, paints, and plumbing compounds has been sharply restricted or eliminated by federal laws and regulations. lithology - Mineralogy, grain size, texture, and other physical properties of granular soil, sediment, or rock. lowest observed adverse effect level (LOAEL) - The lowest level of a stressor that causes statistically and biologically significant differences in test samples as compared to other samples subjected to no stressor. managerial controls - Methods of nonpoint source pollution control based on decisions about managing agricultural wastes or application times or rates for agrochemicals. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 64 of 76 marine water - Water in the ocean (or sea) or groundwater which has recently been part of an ocean (or sea) and which retains the essential chemistry of the ocean water. maximum contaminant level (MCL) - The designation given by the U.S. Environmental Protection Agency (EPA) to water-quality standards promulgated under the Safe Drinking Water Act. The MCL is the greatest amount of a contaminant that can be present in drinking water without causing a risk to human health. mechanical dispersion - Process whereby solutes are mechanically mixed during advective transport, caused by the velocity variations at the microscopic level; synonymous with hydraulic dispersion. mercury (Hg): -Heavy metal that can accumulate in the environment and is highly toxic if breathed or swallowed. (See: heavy metals.) methyl orange alkalinity - A measure of the total alkalinity in a water sample in which the color of methyl orange reflects the change in level. microbial growth - The amplification or multiplication of microorganisms such as bacteria, algae, diatoms, plankton, and fungi. mitigation - Measures taken to reduce adverse impacts on the environment. monitoring - Periodic or continuous surveillance or testing to determine the level of compliance with statutory requirements and/or pollutant levels in various media or in humans, plants, and animals. municipal discharge - Discharge of effluent from waste water treatment plants which receive waste water from households, commercial establishments, and industries in the coastal drainage basin. Combined sewer/separate storm overflows are included in this category. national estuary program - A program established under the Clean Water Act Amendments of 1987 to develop and implement conservation and management plans for protecting estuaries and restoring and maintaining their chemical, physical, and biological integrity, as well as controlling point and nonpoint pollution sources. new source - Any stationary source built or modified after publication of final or proposed regulations that prescribe a given standard of performance. nitrate - A compound containing nitrogen that can exist in the atmosphere or as a dissolved gas in water and which can have harmful effects on humans and animals. nitrilotriacetic acid (NTA) - A compound now replacing phosphates in detergents. nitrogenous wastes - Animal or vegetable residues that contain significant amounts of nitrogen. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 65 of 76 non-aqueous phase liquid (NAIL) - Contaminants that remain undiluted as the original bulk liquid in the subsurface, e.g. spilled oil. (See: fee product.) non-point source (NPS) pollution - Pollution discharged over a wide land area, not from one specific location. Non-point source pollution is contamination that occurs when rainwater, snowmelt, or irrigation washes off plowed fields, city streets, or suburban backyards. As this runoff moves across the land surface, it picks up soil particles and pollutants, such as nutrients, and pesticides. non-potable - Water that is unsafe or unpalatable to drink because it contains pollutants, contaminants, minerals, or infective agents. nutrient pollution - Contamination of water resources by excessive inputs of nutrients. In surface waters, excess algal production is a major concern. odor threshold - The minimum odor of a water or air sample that can just be detected after successive dilutions with odorless water. oligotrophic lakes - Deep clear lakes with few nutrients, little organic matter and a high dissolved-oxygen level. outfall - The place where a sewer, drain, or stream discharges; the outlet or structure through which reclaimed water or treated effluent is finally discharged to a receiving water body. overland flow - The flow of water over the land surface created by direct precipitation. Also called Horton overland flow. oxygen demand - The need for molecular oxygen to meet the needs of biological and chemical processes in water. oxidation - The chemical addition of oxygen to break down pollutants or organic waste; e.g., destruction of chemicals such as cyanides, phenols, and organic sulfur compounds in sewage by bacterial and chemical means. oxidation pond - A man-made (anthropogenic) body of water in which waste is consumed by bacteria, used most frequently with other waste-treatment processes; a sewage lagoon. pH - A measure of the relative acidity or alkalinity of water. Water with a pH of 7 is neutral; lower pH levels indicate increasing acidity (H+), while pH levels higher than 7 indicate increasingly basic (OH-) solutions. particle size - The diameter, in millimeters, of suspended sediment or bed material. Particlesize classifications are: Clay - 0.0000094-0.0001575 inch (0.00024-0.004 mm) Silt - 0.0001575-.0024409 inch (0.004-0.062 mm) Sand - 0.0024409-0.0787402 inch (0.062-2.0 mm) Gravel - 0.0787402-2.519685 inch (2.0-64.0 mm) Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 66 of 76 pathogen - A disease-producing agent; usually applied to a living organism. Generally, any viruses, bacteria, or fungi that cause disease. periphyton - Microscopic underwater plants and animals that are firmly attached to solid surfaces such as rocks, logs, and pilings. persistence - Refers to the length of time a compound stays in the environment, once introduced. A compound may persist for less than a second or indefinitely. phenols - Organic compounds that are byproducts of petroleum refining, tanning, and textile, dye, and resin manufacturing. Low concentrations cause taste and odor problems in water; higher concentrations can kill aquatic life and humans. phosphates - Certain chemical compounds containing phosphorus. Phosphogypsum Piles (Stacks): Principal byproduct generated in production of phosphoric acid from phosphate rock. These piles may generate radioactive radon gas. phosphorus - An essential chemical food element that can contribute to the eutrophication of lakes and other water bodies. Increased phosphorus levels result from discharge of phosphorus-containing materials into surface waters. photosynthesis - The manufacture by plants of carbohydrates and oxygen from carbon dioxide mediated by chlorophyll in the presence of sunlight. point-source pollution - Water pollution coming from a single point, such as a sewageoutflow pipe. plume - A three-dimensional body of fluid emanating from a point source or point sources with a chemistry or physical composition differing from the ambient groundwater, atmosphere, or surface water body. pollution prevention - 1. Identifying areas, processes, and activities which create excessive waste products or pollutants in order to reduce or prevent them through, alteration, or eliminating a process. Such activities, consistent with the Pollution Prevention Act of 1990, are conducted across all EPA programs and can involve cooperative efforts with such agencies as the Departments of Agriculture and Energy. 2. EPA has initiated a number of voluntary programs in which industrial, or commercial or "partners" join with EPA in promoting activities that conserve energy, conserve and protect water supply, reduce emissions or find ways of utilizing them as energy resources, and reduce the waste stream. potable water - Water of a quality suitable for drinking. precursor - In photochemistry, a compound antecedent to a pollutant. For example, volatile organic compounds (VOCs) and nitric oxides of nitrogen react in sunlight to form ozone or other photochemical oxidants. As such, VOCs and oxides of nitrogen are precursors. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 67 of 76 prescriptive - Water rights which are acquired by diverting water and putting it to use in accordance with specified procedures; e.g. filing a request with a state agency to use unused water in a stream, river, or lake. prior appropriation doctrine - The system for allocating water to private individuals used in most Western states. The prior appropriation doctrine is based on the concept of "First in Time, First in Right." The first person to take a quantity of water and put it to beneficial use has a higher priority of right than a subsequent user. The rights can be lost through nonuse; they can also be sold or transferred apart from the land. PRPs - Potential responsible parties. Waste generators who are responsible for the ultimate fate of toxic wastes. Includes property owners, industries, government agencies, etc. The current federal laws make the PRPs liable in perpetuity for these wastes. reaeration - Introduction of air into the lower layers of a reservoir. As the air bubbles form and rise through the water, the oxygen dissolves into the water and replenishes the dissolved oxygen. The rising bubbles also cause the lower waters to rise to the surface where they take on oxygen from the atmosphere. receiving waters - A river, lake, ocean, stream or other watercourse into which wastewater or treated effluent is discharged. recharge - The process by which water is added to the groundwater system or, more precisely, enters the phreatic zone. Can be expressed as a rate (i.e., in/yr) or a volume. recharge basin - A basin or pit excavated to provide a means of allowing water to soak into the ground at rates exceeding those that would occur naturally. relative ecological sustainability - Ability of an ecosystem to maintain relative ecological integrity indefinitely. release - Any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping, leaching, dumping, or disposing into the environment of a hazardous or toxic chemical or extremely hazardous substance. remedial action (RA) - The actual construction or implementation phase of a Superfund site cleanup that follows remedial design. remediation - The process by which contaminated groundwater systems are cleansed of their pollutants or in which the pollutants are managed to avoid their deleterious release to the biosphere. reservoir - 1. An impoundment of surface water behind a dam; 2. A porous and permeable subsurface formation or part of a formation containing a natural, individual, and separate accumulation of hydrocarbons (oil or gas). Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 68 of 76 safe water - Water that does not contain harmful bacteria, toxic materials, or chemicals, and is considered safe for drinking even if it may have taste, odor, color, and certain mineral problems. saline water - Water that contains significant amounts of dissolved salts. Salinity is defined as: Fresh water - Less than 1,000 parts per million (ppm) Slightly saline water - From 1,000 ppm to 3,000 ppm Moderatly saline water - From 3,000 ppm to 10,000 ppm Highly saline water - From 10,000 ppm to 35,000 ppm sediment - Usually applied to material in suspension in water or recently deposited from suspension. In the plural the word is applied to all kinds of deposits from the waters of streams, lakes, or seas. sedimentary rock - Rock formed of sediment, and specifically: 1. Sandstone and shale, formed of fragments of other rock transported from their sources and deposited in water; and 2. Rocks formed by or from secretions of organisms, such as most limestone. semi-arid - Pertaining to climatic conditions in which the precipitation, although slight, is sufficient for growth of short sparse grass. A semiarid climate is sometimes referred to as a steppe climate. spring melt/thaw - The process whereby warm temperatures melt winter snow and ice. Because various forms of acid deposition may have been stored in the frozen water, the melt can result in abnormally large amounts of acidity entering streams and rivers, sometimes causing fish kills. storm sewer - A system of pipes (separate from sanitary sewers) that carries water runoff from buildings and land surfaces. stream - A flowing body of water which is generally confined to a specific channel or channels. effluent stream - A steam which is receiving baseflow. ephemeral stream - A stream which flows only briefly after rainfall events. gaining stream - A stream which increases in discharge along its channel because of groundwater inflow. influent stream - A stream with its water flowing into the groundwater system. intermittent stream - A stream which typically does not flow all year long. losing stream - A stream which loses discharge along its channel. perennial stream - A stream which flows all year long. sinking steam - A stream which loses discharge because its water is infiltrating into the ground. submerged aquatic vegetation - Vegetation that lives at or below the water surface; an important habitat for young fish and other aquatic organisms. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 69 of 76 subwatershed - Topographic perimeter of the catchment area of a stream tributary. Superfund - The program operated under the legislative authority of CERCLA and SARA that funds and carries out EPA solid waste emergency and long-term removal and remedial activities. surface runoff - Precipitation, snow melt, or irrigation water in excess of what can infiltrate the soil surface and be stored in small surface depressions; a major transporter of non-point source pollutants in rivers, streams, and lakes. surface water - All water naturally open to the atmosphere (rivers, lakes, reservoirs, ponds, streams, impoundments, seas, estuaries, etc.) surface-water treatment rule - Rule that specifies maximum contaminant level goals for Giardia lamblia, viruses, and Legionella and promulgates filtration and disinfection requirements for public water systems using surface-water or ground-water sources under the direct influence of surface water. The regulations also specify water quality, treatment, and watershed protection criteria under which filtration may be avoided. suspended loads - Specific sediment particles maintained in the water column by turbulence and carried with the flow of water. suspended solids (SS) - Small particles of solid pollutants that float on the surface of, or are suspended in, sewage or other liquids. They resist removal by conventional means. SVOC - Semivolatile organic chemicals, such polyaromatic hydrocarbons, PCBs, etc. tail water - The runoff of irrigation water from the lower end of an irrigated field. tertiary wastewater treatment - Removal of sesidual suspended solids (after secondayr treatment), usually by granualr medium filtration or microscreens. Disinfections is also typically a part of tertiary treatment. Nutrient removal is often included in this definition. total dissolved phosphorous - The total phosphorous content of all material that will pass through a filter, which is determined as orthophosphate without prior digestion or hydrolysis. Also called soluble P. or ortho P. total dissolved solids (TDS) - All material that passes the standard glass river filter; now called total filterable residue. Term is used to reflect salinity. total suspended solids (TSS) - A measure of the suspended solids in wastewater, effluent, or water bodies, determined by tests for "total suspended non-filterable solids." toxic chemical - Any chemical listed in EPA rules as "Toxic Chemicals Subject to Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986." toxic pollutants - Materials that cause death, disease, or birth defects in organisms that ingest or absorb them. The quantities and exposures necessary to cause these effects can vary widely. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 70 of 76 toxicity - The degree to which a substance or mixture of substances can harm humans or animals. . toxicological profile - An examination, summary, and interpretation of a hazardous substance to determine levels of exposure and associated health effects. transport - The movement of solute, suspended matter, or heat in a porous medium, in a surface stream, or through the atmosphere. treatment - 1. Any method, technique, or process designed to remove solids and/or pollutants from solid waste, waste-streams, effluents, and air emissions. 2. Methods used to change the biological character or composition of any regulated medical waste so as to substantially reduce or eliminate its potential for causing disease. turbidity - A measure of water cloudiness caused by suspended solids. VOC - Volatile organic chemical, such as benzene, gasoline, etc. wastewater - The spent or used water from a home, community, farm, or industry that contains dissolved or suspended matter. water quality--a term used to describe the chemical, physical, and biolo. gical characteristics of water, usually in respect to its suitability for a particular purpose. wetland - Areas under or contiguous to open water or with a shallow water table. Wetlands are characterized by water-loving vegetation (phreatophytes or, in areas with brackish water, halophytes). Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 71 of 76 units to convert units converting to formula for conversion inch (in) millimeter (mm) # in x 24.4= # mm foot (ft) mm # ft x 304.8 = # mm mile (mi) kilometer (km) # mi x 1.609344 = # km acre-foot (acf) gallon (gal) # acf x 325,851 = # gal cubic-foot (ft3) acre-foot (acf) # acf x .000023 = # ft3 pound (lb) gram (g) # lb x 453.59 = # g degree Farenheit (°F) degree Celcius (°C) °F x 5/95 = °C part-per-billion (ppb) microgram-per-liter (µg/L) # ppb = # µg/L part-per-million (ppm) milligram-per-liter (mg/L) # ppm = # mg/L gallon (gal) liter (L) # gal x 3.79 = # L microgram (µg) gram (g) # µg x 10-6 = # g Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 72 of 76 APPENDIX 7. List of Recommended Critical Field Equipment/Spare Parts Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 73 of 76 List of Recommended Critical Field Equipment/Spare Parts Field Data Measurements 1. Multiprobe Sensor Instrument and various analytical probes/accessories (may have capability of unattended, automated monitoring at hourly intervals over at least a 24-hour period). Possible options include: Hydrolab Surveyor 3/H20, Surveyor 4/minisonde, or Surveyor 4/datasonde 4 Hydrolab Datasonde 3 or 4 YSI 610DM/YSI 600 XLM Minilogger YSI 650 MDS YSI 600XL Long cord (and short cord) for multiprobe instrument(s) YSI internal thermometer for water temp All Maintenance Parts, Electrolyte Solutions, pH storage solution, etc. for Multiprobe Sensors Back-up Multiprobe Sensor in working condition 2. Turbidity meter (i.e. LaMotte 2020) 3. Weather Radio 4. Pocket Calculator 5. Flow Meter/Top-setting Wading Rods/Digital Counter (i.e. Scientific Instruments Digimeter)/100 ft. Measuring Tape 6. Digital Camera 7. Global Positioning System (GPS) Water Sampling 1. Plastic Buckets with Rope 2. Battery-powered or Car-converter-powered Peristaltic Pump (needed only for depth integrated sampling and filtrations) 3. TM clean in-line filters (0.45 micron, disposable) 4. Powder-free Nitrile Gloves 5. Polyethylene Gloves (wrist and shoulder long) 6. Clean plastic sampling device (beaker) on extendable sampling pole 7. Pre-printed labels with station info 8. See table with sample bottles/containers in water sampling SOP 9. Metals-in-Water Kit: Plastic bottles, tubing, syringes, syringe filters, metals-free water and filters for metals-in-water sampling prepared by the laboratory 10. Chlorophyll filtration kit (manifold, pump, filters etc.) Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 74 of 76 Sediment Sampling 1. 2. 3. 4. 5. Modified Van Veen grab, cleaning reagents for cleaning grab, davit (for boat) Polyethylene/Polycarbonate Scoops (pre-cleaned at laboratory) Homogenizing jar and stirring rods Labels with station info See table with sample bottles/containers in sediment sampling SOP Biological Sampling 1. 2. 3. 4. 5. "D" or "Y" Frame Kick Net (mesh size < 800µm x 900µm) Surber Sampler Seines (short 6-10' 1/8-inch mesh; long 20-25' 1/4-inch mesh) Gill Net Backpack Shocker - Smith Root Type VII or equivalent (for regions where conductivity allows use) and Extra Battery 6. 5-Gallon Plastic Buckets 7. Chest Waders 8. Heavy Weight Rubber Gloves for Shocking 9. Non-conductive Dip Nets for Fish (both medium and small mesh sizes) 10. Glass Jars/Vials for Biological Specimens 11. Ethyl Alcohol 12. Isopropyl Alcohol 13. Rose Bengal 14. Formalin 15. Forceps 16. Lopping Shears for Snag Samples 17. Sorting Sieves (U.S. Std. Sieve No. > 20) 18. Sorting Trays for Benthics 19. Mason Jar Lids (for isolating sub-sample in sorting tray) 20. Fish Measuring Board 21. Heavy Weight Aluminum Foil (for shipping tissue samples) 22. Plastic Bags (for shipping tissue samples) 23. Trawl (for coastal regions) 24. Plankton Net 25. Compound Microscope 26. Dissection Microscope Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 75 of 76 Habitat Assessment 1. 2. 3. 4. 5. 6. Map Measuring Wheel or Planimeter Clinometer Densiometer Optical Range Finders (short and long distance) Survey Range Pole Long Tape (100 meters) Other Office/Field Equipment 1. Refrigerator/Freezer 2. Ice Machine, Ice and dry ice Delivery, supply Contract 3. Boat/Motor/Trailer/PFDs – Refer to “Minimum Health and Safety Guidelines” Appendix H, for a boating safety checklist. 4. Battery Charger 5. Waders Shipping 1. 2. 3. 4. 5. 6. 7. 8. Insulated coolers Cube ice/blue ice/dry ice Duct tape (for sealing coolers) Packaging tape (for taping labels) Prewritten FedEx labels/ shipping tags COCs (prewritten, if possible) Bubble wrap/ packaging foam Zip bags for COCs Health and Safety Refer to “Minimum Health and Safety Guidelines” (Appendix H) for a list of essential equipment. Friends of the San Gabriel River Watershed - Revision 1 Date: 3/7/2016 Page 76 of 76 Personal and Travel Equipment and Supplies 1. Rain gear 2. Change of clothes 3. Heavy Duty Flashlight 4. Cell phone and charger 5. Maps 6. Hiking Boots 7. Extra batteries 8. Contact phone numbers 9. Sun glasses/ sun block/ hat 10. Drinking water 11. Work gloves 12. Insect repellent 13. Backpacks/ tote bin for carrying gear Additionally, all necessary forms, calibration logbooks, procedures manuals, equipment instructional manuals, and identification manuals for biological specimens will be kept on hand by all SWAMP personnel. APPENDIX 8. References and Internet Addresses