Particulate Pollution Levels and Source Apportionment in Six Asian Cities: Preliminary Findings of AIRPET a Kim Oanh N.T., aNabin U., bZhuang Y-H., bHao Z., cMurthy D.V.S., cSwaminanthan T. ,dLestari P., eVillarin J.T., eChengchua K., fCo H.X., fDung N.T., gLindgren E.S. a Environmental Engineering and Management Program, Asian Institute of Technology, Thailand; bResearch Center for Eco-Environmental Sciences, Graduate School, University of Science and Technology of China, Beijing; cDepartment of Chemical Engineering, Indian Institute of Technology, Madras; dDepartment of Environmental Engineering, Institute of Technology of Bandung, Indonesia; eManila Observatory, Quezon City, Philippines; fFaculty of Environmental Sciences, Hanoi University of Science, Hanoi; gHogskolan I Boras, Sweden Abstract AIRPET, an Asian regional air pollution research network, which is coordinated by the Asian Institute of Technology, involves six cities: Bandung, Bangkok, Beijing, Chennai, Manila, and Hanoi. One of the objectives of the network is to provide a comprehensive assessment of PM air quality though monitoring and receptor modeling tools jointly by 6 research teams in these cities. This paper presents the results within the scope of this monitoring and modeling objective in phase 1 (2001-2003). In total, the network collected over 2500 PM2.5 and PM10 samples from characteristic urban sites. The samples were analyzed for ionic, element and BC or/and OC/EC composition. QA/QC for sampling and analysis was followed to produce reliable and comparable data produced by the research teams. In all these cities the levels of PM10 and PM2.5 were found high especially during the dry season which the frequently exceeded the US EPA standard for PM10 and PM2.5, especially at the traffic sites. Source apportionment by receptor models (CMB and PMF) shows high contribution of traffic, secondary aerosol and biomass burning to PM2.5 in most of the cities. For the PM10 or coarse fraction the substantial contributions are from soil dust, construction and sea salt. Industrial contribution varies from city to city. Keywords: Fine PM, coarse PM, composition, source apportionment, comparative analysis, six Asian Cities 1 1. Introduction There has been growing concern on monitoring and characterization of size-segregated particulate matter (PM) in the recent years. More efforts and resources are being spent to understand the fate and develop mechanism that would help control this harmful substance in the ambient air. In many developing countries, though TSP is still a regulated pollutant, there is a clear tendency toward monitoring of fine particles. The atmospheric particles below 10 m (PM10) have long been implicated to have adverse health impacts such as respiratory disease and increased mortality (Dockery et al., 1994). Very small particles, PM2.5, and their associated “high risk” have been discussed (Schwartz and Neas, 2000; Donaldson et al., 1998). Aerosols interact directly and/or indirectly with solar radiation and change the global climate (Preining, 1991; Liu and Peter, 2002). Fine particles impair visibility by absorbing and/or scattering solar radiation (Kim et al., 2001). This paper presents some preliminary findings on PM levels and source apportionment of an air pollution research network “Improving Air Quality in Asian Developing Countries (AIRPET)” during phase 1, 2001-2004. AIRPET (http://www.serd.ait.ac.th/airpet), now in phase 2, is a regional coordinated effort with one of the research objectives being to provide comprehensive assessment of PM pollution in selected cities in Asia with the focus on PM2.5 and PM10/PM102.5. The network is coordinated by the Asian Institute of Technology (AIT) and funded by the Swedish International Development Cooperation Agency (Sida). The network covers six cities, namely Bangkok Metropolitan Region (Thailand), Bandung (Indonesia), Beijing (China), Chennai (India), Manila (Philippines), and Hanoi (Vietnam). 2. Methodology 2.1 Monitoring design in the regional network Six institutions are involved in this network, including AIT; Institute of Technology of Bandung; Research Centre for Eco-Environmental Sciences, Beijing; Manila Observatory; Hanoi University of Science; and Indian Institute of Technology, Madras. Each institution conducts monitoring for one city in the country. 2 The selected cities are different in terms of geographical locations, topography, energy use, industry, vehicular mixes and density. The climate of the region is dominated by monsoon with two distinct seasons, dry and wet. Though each dry and wet season may cover different months of the year in different countries, it has been decided to have only these two broad categories of seasons for the consistency in inter-country comparison of the monitoring results. The summary of PM monitoring schemes in the six cities is given in Table 1. Sampling sites across the six cities are characterized into seven categories based on the activity and influence of the emission sources, and their surroundings. Each city has 4-6 sites out of total 7 site types. The common selected sites in all cities are upwind, mixed, traffic, residential and industrial sites. It was intended to have the sampling intake located at the height of 3-5 m for all cities. However, due to siting difficulty a few sites were located higher than 5 m, especially at BNU (Beijing) the site is at 40 m above the ground, which may cause some inconsistency in the result comparison. All cities conducted PM2.5 and PM10 monitoring using low volume samplers, dichot, minivol or other equivalent samplers depending upon the samplers available. For the consistency in comparison, we present and discuss the 24h PM2.5 and PM10 monitoring results. Fine (PM2.5) and coarse (PM10-2.5) fraction particles by dichot were summed up to get PM10 in those cases where these fractions of PM have been collected. Filter media were selected to suit the selected analytical methods that follow. All the samples were conditioned for about 24h (temperature 20±5oC, relative humidity 40±10%) before and after sampling for the gravimetric mass determination. The quartz filters were fired at 550oC for about 6 hours before conditioning and sampling. The treatment of quartz filters at this temperature is necessary to remove any carbonaceous/organic pollutants and is recommended for samples to be analyzed for organic components. Detail on QA/QC is presented latter. 2.2 Sample analysis The particle samples after gravimetric mass measurements were subjected to compositional analyses such as ions by IC, elements by ICP-MS, PIXE, XRF, and NAA, organic and elemental carbons (OC/EC) by thermal method, and/or black carbon (BC) by optical reflectometer. Usually 3 sections of quartz filters were analyzed for ions and OC/EC while samples on mixed cellulose or Teflon filters were analyzed for elements. Numbers of parameters analyzed are slightly different for different cities due to the availability of the equipment. The network aims at getting as complete datasets as possible on PM composition for receptor modeling purpose which primarily include mass, water soluble ions, elements and EC/BC. 2.3 Quality assurance and quality control Data quality is of the foremost concern. Common methodology for sampling and analyses were aimed at to maintain the regional data inter-comparison. The quality assurance and quality control (QA/QC) of the monitoring scheme were followed at all possible levels from monitoring, siting, sampling method selection, sampling execution, sampler calibration co-located sampling, selection of filter media, filter preparation, sample weighing to the analysis. The analytical methods for elements used by different institutions within the network were checked by a standard reference material (SRM). The coarse flow of dichotomous samplers was corrected for the fine fraction carried over. One filter for about every 20 filters was used as blank. All the analyzed data were blank corrected. Most of the cities collected samples over a 24h period. Some samples in Beijing were taken for 4-8 h, which were subsequently normalized to 24h and the datasets for all cities are 24h averaged concentrations. Results of co-located sampling between samplers used in the research teams are presented in Table 2. Dichot is used as the reference sampler in the network hence all other samplers are compared with the dichot. At AIT dichots were only samplers used hence a dichot was compared to the US EPA FRM sampler and a Minivol sampler. The results showed that dichot agrees well with the FRM and most of the low-vol used in different institutions with the R2 commonly 0.980.99 except for Bandung and Hanoi (PM10) cases which need to be further examined. The medium samplers used by India (APM550) and China show a rather good agreement with the dichot samplers. However, the APM550 seems to collect about 25% higher PM2.5 and 13% higher PM10-2.5 than the dichot. 4 2.4 Source-receptor analysis The seasonal averages of PM2.5 and PM10 from the six cities were subject to CMB analyses for the source apportionment purpose. Each city used the source profiles independently. However, a few sources are common to all while some sources are city specific such as fugitive dust and coal burning in Beijing; solid waste disposal in Bandung, or industries and sea salt in Chennai. For the receptor modeling purpose, missing data, data below detection limit (BDL), and the data uncertainties were mostly treated according to Polissar (1998). Thus, missing values were substituted with the mean of measured values; BDL with the half of the detection limit of a parameter. Accordingly, assigned uncertainties for data points in each sample differ from one parameter to another. 3. Results and discussion 3.1 PM levels Totally in phase 1 the AIRPET research teams have collected over 2550 samples in the 6 cities of which 1500 are PM2.5 samples. More samples were collected in dry season than in the wet season, with higher numbers of samples collected for 2-3 intensive sites in each city. All samples were analyzed for mass and most of samples were analyzed for chemical composition. Seasonal averages of 24h PM2.5 and PM10 as well as major compositions over all monitoring sites in each city are shown in Table 3. Significant difference in concentrations of PM2.5 and PM10 has been observed over the two seasons. The results show that Beijing has the highest average PM2.5 and PM10 during the dry season, followed by Hanoi and Chennai (PM10). In the wet season the PM2.5 level in Beijing is still the highest. PM10 in the wet season is the highest in Beijing and second highest in Chennai. Averages for PM2.5 and PM10 in Beijing exceed the 24h PM US EPA standards in both seasons, in Hanoi the standards exceedance of both PM2.5 and PM10 are observed in dry season while in Chennai PM10 exceeds the standard in the dry season. High fluctuations in PM levels were observed in most sites in Beijing. 5 Sample size is an important factor for assessing the reliability of the average data. As seen from Table 1, the sample size varies from one site to another and from one city to another. Chennai has the smallest number of samples taken for averaging; hence the averages produced may not be statistically significant. High PM levels in Beijing may be attributed mainly to coal burning as major energy source, dust storms, and traffic re-entrained road side dust (Sun et al., 2004). PM2.5/PM10 ratios at different sites in a city vary with seasons. The average for the dry season ranged 0.58-0.72 in Bangkok, 0.51-0.66 in Beijing, 0.31-0.52 in Chennai, 0.52-0.73 in Bandung, 0.62-0.86 in Manila, and 0.58-0.84 in Hanoi. For Bandung and Manila the PM2.5/PM10 ratios are almost the same in both seasons, while for Chennai, Beijing, Hanoi and Bangkok the ratios in dry season were higher than in wet season by 6, 9, 12, and 17%, respectively. 3.2 Major chemical components Analyzed chemical concentrations are divided into some major groups according to their nature and source of origin (Table 3). We present here the compositions of samples as crustal, organic matter (OM), EC/BC, NH4+, SO4=, NO3-, K+, sea salt and ‘others’ (the rest trace elements). Such major groups of chemical compositions have been used in the mass reconstruction in various studies, for example, Ho et al. (2003) and Chan et al. (1997). It is noted that, Chennai samples were digested in acids (HCl, H2SO4) and analyzed by UV-Spectrometer. Hence the total ions were probably obtained rather than the water soluble ions as in other cities. There were also no PM10 composition data for Manila presented. A significant of fractions of NO3- and SO4= were also found in coarse fraction (PM10-2.5) of particles which suggest that not all NO3- and SO4= in the samples are in the form of ammonium nitrate and ammonium sulfate. Crustal fraction includes Al, Ca, Si, Ti, Fe, and K and their oxides. Organic carbon multiplied by the factor 1.4 is assumed to represent all organic compounds. Sea salt is calculated as 2.54Na assuming all Na comes from the marine source. A reference ratio Na/Al=0.3 for crustal composition was applied to check the marine origin of Na in all average sample data. It was seen that most samples average Na/Al ratios were moderately 6 to significantly higher than crustal ratio 0.3, indicating the marine contribution. Trace elements in the ‘others’ group include all elements except crustal elements, Na, and S. OM, crustal, NO3-, SO4= and EC/BC have been found as major components of PM2.5 and PM10. OC was not analyzed in most sites, except for BMR and Beijing, hence the comparison is not possible. Crustal content of PM2.5 is low in most of the cities except for Beijing, Chennai and Hanoi (wet season only). For PM10, the crustal content is also highest in Beijing in both season, second highest in Chennai and Hanoi. Trace elements/compounds were also the important components of Beijing particles, ranging from 3.4-14.5 μg/m3 in PM2.5 and 5.5-16.0 μg/m3 in PM10. In all six cities, the highest contribution of crustal components to PM10 was found for traffic sites, followed by mixed sites and industrial sites. Higher concentrations of crustal elements are thought to be associated with the road side dust, and some local construction/demolition activities. NH4+ concentration was highest in Beijing PM2.5 ranging from 6.1-39.0 μg/m3. Chennai, Bandung and Hanoi were other cities followed by Beijing with high ammonium: NH4+ ranged 1.3-17.1 μg/m3 in Chennai; 1.9-11.5 μg/m3 in Bandung, and 0.8-8.0 μg/m3 in Hanoi. Most NH4+, NO3- and SO4= are present in PM2.5 in all cities, except higher NO3- in PM10-2.5 in Bangkok, Chennai and Bandung; and higher NH4+ in Chennai, which need to be further investigated. The detail results of element analysis show that S, Se, and Br are highest in PM2.5 than in coarse fraction. Pb, Zn, and Cu are found in both fine and coarse fractions of PM10. Very high and nearly the same range of S were found in Beijing and Hanoi. Bangkok had relatively low average S in PM10 in both seasons. S in PM2.5 in Manila ranged 0.1-2.1 μg/m3 in dry and 0.2-1.0 μg/m3 the wet seasons. Higher S in the dry season at all sites could be attributed to the increased coal use, and biomass burning during this season as compared to the wet season. 3.3 Source apportionment results The results of chemical mass balance receptor modeling on city wise average PM2.5, PM10-2.5 and PM10 are presented in Table 4. The ambient data compositions were not complete in many 7 cases. Here we present the attempt to compile the results obtained by different cities using the source profiles generated based on literature. It is important that the receptor model with some important signatures missing from either the source profiles or the ambient data could have misleading results. Furthermore, lack of in-depth knowledge on the contributing sources in a specific area and their subsequent exclusion from the model run do not help to produce good quantitative source apportionment. The results presented here are meant to give some overviews on the major contributing PM sources in the six cities. Traffic has the highest PM2.5 contribution in most cities with the exceptional high share (>70%) in Manila. Biomass burning appears to contribute substantially to PM2.5 in BMR, Beijing (both dry and wet season), Hanoi and Bandung (dry season). PM2.5 from the secondary formation (in the atmosphere) also has high shares in BMR, Bandung and Hanoi. Industry has a high contribution in Chennai and coal combustion has a substantial contribution in Beijing. For coarse fraction, it is shown that construction, soil and biomass have substantial contributions in all 3 cities (BMR, Bandung and Chennai) where the source apportionment was made for PM10-2.5. Industry and traffic also have high contributions in Chennai while in Bandung has high contribution from other sources including solid waste and lime. High NaNO3 (which is thought to be secondary particles formed in the reaction between seasalt and secondary nitric acid) contribution to coarse fraction was found for BMR. For the 2 cities that source apportionment was made for PM10 the high contributions were found from biomass, secondary formation and soil for both cities. Traffic and coal combustion have high contribution in Beijing while NaNO3 was found high in Hanoi. 4. Conclusions The levels of PM2.5 and PM10 in the cities are higher in dry than in wet season. Highest levels were found in Beijing in both seasons followed by Hanoi and Chennai. The PM2.5 constitutes a larger fraction of PM10 in most of the cities and the fraction is higher in dry season than in the wet season. The major chemical components in PM2.5 across six cities are BC/EC fractions followed by NH4+, NO3- and SO4=. Similarly, PM10 comprised of mainly crustal elements (Al, Si, Ca, Fe), and BC. Preliminary receptor modeling results indicated that traffic, secondary aerosols, and biomass burning were the major sources of PM2.5 while soil dust, construction activities, biomass burning, NaNO3, and traffic are among the major sources of PM10. 8 Acknowledgement We would like to thank the Swedish International Development Agency for the generous financial support without which the study would not be possible. The California Air Resource Board (CARB) is acknowledged for donating 7 dichot samplers to AIT for the use in the network. Tom Parsons, Tom Cackette, Dick Baldwin, Bill Loscutoff, Douglas Fox, and many other colleagues who helped in the process of acquisition, preparation and shipment of the samplers from CARB to AIT are cordially thanked. References Dockery, D.W., and Pope III, C.A., 1994. Acute respiratory effects of particulate air pollution. Annual Revision Public Health 15, 107-132. Donaldson, K., Li, X.Y., MacNee, W., 1998. Ultrafine (nanometer) particle mediated lung injury. Journal of aerosol science 20, 1453-1456. Kim, Y.J., Kim, K.W., and Oh, S.J., 2001. Seasonal characteristics of haze observed by continuous visibility monitoring in the urban atmosphere of Kwangju, Korea. Environmental Monitoring and Assessment 70: 35-46. Liu, Y., and Peter, H.D., 2002. Anthropogenic aerosols: Indirect warming effect from dispersion forcing; Nature 419, 580 – 581. Polissar, A.V., Hopke, P., Paatero, P., Malm, W.C., and Sisler, J.F., 1998. Atmospheric aerosol over Alaska - 2. Elemental composition and sources. Journal of Geophysical Research, vol. 103(D15): p. 19045-19057. Schwartz, J., Neas, L.M., 2000. Fine particles are more strongly associated than coarse particles with acute respiratory health effects in schoolchildren. Epidemiology 11, 6-10. Sun, Y., Zhuang, G., Wang, Y., Han, L., Guo, J., Dan, M., Zhang, W., Wang, Z., and Hao, Z., 2004. The air-borne particulate pollution in Beijing—concentration, composition, distribution and sources. Atmospheric Environment 38, 5991–6004. 9 Table 1. Number of PM samples at different characteristic sites of six cities in dry and wet seasons. a Site b City Site types symbol n in dry season n in wet season Samplers Filter PM2.5 PM10 PM2.5 PM10 BMR upwind AIT 91 91 32 32 Dichot Q, M mixed site BN 46 46 10 10 Dichot Q, M traffic site DD 14 14 27 27 Dichot Q, M residential/centre BS 10 10 27 27 Dichot Q, M Total 161 161 96 96 Beijing upwind MY 43 65 PM2.5-II Q traffic mixed BNU 42 47 27 40 PM2.5-II Q residential/centre YH 10 10 20 21 PM2.5-II Q industrial CS 10 10 21 21 PM2.5-II Q commercial PG 6 7 PM2.5-II Q Total 105 132 74 89 Chennai upwind IIT 17 15 3 3 Dichot/APM550 Q, M traffic mixed TNG 19 20 3 3 Dichot/APM550 Q, M residential/centre KT Dichot/APM550 Q, M industrial MAMB 10 10 4 4 Dichot/APM550 Q, M Total 46 45 10 10 Bandung upwind DP 42 42 11 11 Dichot Q, M mixed site TG 46 46 9 9 Dichot Q, M traffic site LP 6 6 6 6 Dichot Q, M residential/centre BT 6 6 6 6 Dichot Q, M industrial CRT 6 6 6 6 Dichot Q, M Total 106 106 38 38 Manila upwind GS 55 10 44 6 MinVol TF mixed site MO 188 32 165 36 MinVol/Dichot NP/TF traffic site NPO 55 29 63 26 MinVol TF industrial PAS 47 46 MinVol TF commercial PGH 61 19 58 30 MinVol TF Total 406 90 376 98 Hanoi upwind GL 58 11 LowVol Q, M mixed site TD 58 58 11 Dichot Q, M traffic site CD 10 5 LowVol Q, M residential/centre BK 10 10 5 5 LowVol Q, M commercial DX 7 7 5 5 LowVol Q, M Total 75 143 10 37 Total 899 677 604 368 aSite description—BMR: BN, Bang Na; DD, Dindang; BS, Ban Somdej; Beijing: MY, MiYun; BNU, Beijing Normal University; YH, YiHai; CS, Capital Steel; PG, Ping Gu; Chennai: IIT, Indian Institute of Technology; TNG, T. Nagar; KT, Kottur; AMB, Ambatpur; Bandung: DP, Dagopakar; TG, Tegalega; LP, Lapan Pasteur; BT, Batununggal; CRT, Cisaranten; Manila: GS, Good Shepherd Retreat House; MO, Manila Observatory; NPO, National Printing Office; PGH, Philippine General Hosptal; Hanoi: GL, Gia Lam; TD, Thuong Dinh; CD, Chuong Duong; BK, Bach Khoa, DX, Dong Xuan. bFilters: Q, quartz fiber; M, mixed cellulose ester; TF, ringed Teflon; NP, nucleopore filter 10 Table 2. Colocated sampling results y Dichot MinVol MedVol MedVol MedVol2 MedVol2 APM550 APM550 x FRM Dichot Dichot Dichot MedVol1 MedVol1 Dichot Dichot n 41 47 6 6 5 5 13 13 PM PM2.5 PM2.5 PM2.5 PM10-2.5 PM2.5 PM10-2.5 PM2.5 PM10-2.5 R2 0.98 0.44 0.99 0.99 0.97 0.99 0.97 0.99 equation y=1.04+1.70 y=0.85+14.52 y=1.02x-1.68 y=1.05x-0.62 y=1.06x-4.41 y=1.05x-0.54 y=1.13x-5.12 y=1.25x-3.95 Indonesia LowVol LowVol Dichot Dichot 20 26 PM2.5 PM10 0.60 0.61 y=1.08x-3.08 y=0.74x+21.87 Philippines Vietnam MinVol LowVol Dichot Dichot 29 50 PM2.5 PM10 0.86 0.3 y=0.93x+4.77 y=0.69x+65.55 NRIs AIT China India 11 Table 3. City wise average mass and major components of PM2.5 and PM10 (μg/m3) particles during the dry and wet seasons. a Mass Crustal Cities Dry season PM2.5 BMR 50 0.7 Beijing 190 22.4 Chennai 50 15.8 Bandung 50 2.7 Manila 44 2.9 Hanoi 177 6.8 Dry season PM10 BMR 74 7.61 Beijing 262 93.3 Chennai 141 29.2 Bandung 83 7.3 Manila 54 Hanoi 186 21.2 Wet season PM2.5 BMR 19 0.7 Beijing 108 9.0 Chennai 38 3.4 Bandung 38 1.7 Manila 43 2.7 Hanoi 59 11.1 Wet season PM10 BMR 33 5.9 Beijing 180 53.3 Chennai 145 7.6 Bandung 62 5.4 Manila 54 Hanoi 74 21.2 a average of the mass of all samples; OM EC(BC) Sea salt NH4+ NO3- SO4= K+ Trace metals % mass explained 0.8 2.3 2.0 0.5 0.25 10.1 6.7 1.6 1.0 7.4 47.36 86.7 91.3 65.1 64.4 13.3 17.34 53.0 na 5.51 18.7 2.8 9.8 18.6 1.44 2.7 5.8 0.7 0.7 1.1 0.68 17.1 1.3 3.3 1.06 14.2 6.1 5.8 6.8 4.46 20.8 7.1 8.8 15.5 32.41 9.34 1.0 9.8 3.68 2.4 12.0 4.5 0.97 13.4 12.7 3.8 2.86 19.0 16.8 8.7 6.83 29.3 13.7 11.4 1.2 2.7 3.4 0.8 0.54 12.7 16.2 2.9 63.24 64.5 70.0 59.2 1.4 2.6 6.6 12.2 28.3 1.5 13.6 41.3 15.8 4.71 5.3 0.7 5.1 19.6 0.8 1.11 0.5 1.3 0.4 0.8 0.0 0.38 10.4 3.5 5.2 0.27 12.0 0.5 4.0 18.6 1.90 17.9 0.7 4.2 12.1 0.6 1.3 3.0 0.2 0.27 4.8 2.7 3.2 1.1 1.2 94.26 81.1 31.0 62.7 74.6 44.9 7.03 3.67 1.1 3.6 1.0 0.60 12.2 17.1 6.6 1.05 19.1 1.1 5.4 3.19 25.1 3.8 5.4 0.65 6.9 8.2 6.2 90.90 66.9 34.5 57.2 0.00 0.69 2.40 6.57 0.8 1.7 6.5 0.5 0.4 6.04 41.77 na 2.0 5.6 1.21 not analyzed 12 na Table 4. City wise average source apportionment results for PM2.5, PM10-2.5 and PM10 by chemical mass balance receptor modeling. _Beijing________ __Beijing____ __Chennai_ ___ _Bandung__ __ _Manila_____ _Hanoi________ D W A D W A D W A D W A D W A D W A PM2.5 Vehicle 35 21 28 22 34 22 28 22 7 15 72 78 75 18 18 Biomass 31 29 30 30 13 18 16 27 8 18 9 9 9 32 32 Secondary 29 36 32 15 29 39 34 11 6 9 33 33 NaNO3 10 10 Coal comb 18 Fuel oil 3 3 4 11 7 7 4 6 1 1 Industries 3 9 6 3 35 35 35 5 9 7 10 10 Soil 2 2 2 10 14 20 17 4 11 7 Minor sources 2 2 2 2 4 5 5 6 6 6 14 14 PM10-2.5 Const Soil Biomass Industry Fuel oil NaNO3 Vehicle Minor sources PM10 Vehicle Biomass Secondary NaNO3 Coal comb Fuel oil Industries Soil Minor sources 39 16 19 0 0 15 4 6 27 29 10 2 2 20 3 8 33 23 14 2 2 17 4 7 20 14 24 38 4 13 12 36 30 9 16 13 30 34 7 22 13 20 15 2 2 24 7 17 15 8 16 22 5 12 8 6 14 4 0 3 51 12 10 11 10 22 4 31 16 23 17 10 1 13 17 8 4 27 22 15 19 24 21 5 1 1 14 13 11 14 Note: D, dry season; W, wet season; A, annual; Beijing and Hanoi present results of PM2.5, and PM10; other cites present results of PM2.5 and PM10-2.5. 13