CHEMISTRY PRETEST UNITS 3 and 4 DATA PAGE Use the data tables below and the periodic table over the page to help you answer the pre-test questions. Table 1: Formulae and charge of selected ions: Cations Na sodium Anions OH hydroxide NH4+ ammonium Cl chloride Ag+ silver NO3 nitrate Mg2+ magnesium O2 oxide Zn2+ zinc SO42 sulfate Cu2+ copper CO32 carbonate Pb2+ lead PO43 phosphate + Table 2: Solubility of ions in water: Ions that are soluble in water Compounds with the following ions are always soluble in water Ammonium NH4+ Sodium Na+ Potassium K+ Nitrate NO3 Compounds with the following ions are mostly soluble in water Chloride Cl except with silver, Ag+, or lead, Pb2+ Sulfate SO42 except with silver, Ag+, or lead, Pb2+ Ions that are not soluble in water Compounds with the following ions are mostly not soluble in water Hydroxide OH Sulfide S2 Carbonate CO32 Phosphate PO43 except with Ammonium NH4+ Sodium Na+ Potassium K+ Table 3: Molar mass of selected elements: Element Molar mass (g per mol) H C O Ne Na Cl Pb 1.0 12.0 16.0 20.1 23.0 35.5 207.2 Table 4: Molar mass of gases STP standard temperature and pressure temperature 0°C, pressure 101.3 kPa One mol of any gas occupies 22.4 litres at STP SLC standard laboratory conditions temperature 25°C, pressure 101.3 kPa One mol of any gas occupies 24.5 litres at SLC Before you start Page 2 CHEMISTRY UNITS 3 and 4 PRETEST QUESTIONS 1. Use the Periodic Table given on the previous page to help you answer the following questions. (a) What is the atomic number of the following elements (i) silver (ii) radon (iii) radium ½ + ½ + ½ = 1½ marks (b) What is the chemical symbol of the following elements (i) gold (ii) silicon (iii) sodium (iv) antimony ½ + ½ + ½ + ½ = 2 marks (c) Identify the element with 13 protons and 13 neutrons. 1 mark 2. Butane, C4H10 is commonly used in LPG and lighter fluid. It’s melting and boiling points are shown below. melting point/ freezing (solidification) point boiling (evaporation) point/ condensation point 138 ºC 0.5 ºC Circle the physical state of butane at room temperature, 25 C solid liquid gas at fridge temperature, 4 C solid liquid gas at 5 C solid liquid gas ½ + ½ + ½ = 1½ marks Use the table of ions (Table 1) on the data page to help you answer questions 3 and 4. 3. Identify the ions present in the following ionic compounds and name the compound. (a) MgCl2 (b) Na3PO4 (c) Ag2S 3 marks 4. Work out the chemical formula of the following compounds. (a) Silver hydroxide (b) Magnesium carbonate (c) Zinc nitrate 3 marks 5. Balance the following chemical equations. (a) Mg(s) + N2(g) Mg3N2(s) (b) Ca(S) + O2(g) CaO(s) (c) H2(g) + O2(g) H2O(l) (d) Al (s) + I2 (l) Al2I6(s) 4 marks Before you start Page 3 Pre-test questions continued… 6. Use the solubility table (Table 2) on the data page to determine which of the following ionic compound are soluble. (a) lead sulfate (b) silver chloride (c) ammonium chloride (d) zinc carbonate ½ + ½ + ½ + ½ = 2 marks 7. The compound Cu(NO3)2 dissolves in water by dissociation of ions (a) Identify the ions in the compound. (b) Write the ionic equation of the dissociation reaction. Show the state of each compound or ion. 1 + 2 = 3 marks Refer to the molar mass of elements (Table 3) on the data page to help you answer questions 8, 9 and 10. 8. Find the molar mass of the following compounds (a) H2O (b) NaCl 2 marks 9. Find the mass of 1.3 mol of CH4 1 mark 10. Calculate the number of mol contained in the following samples, rounded to three decimal places. (a) 50 g of lead (b) 62 g of NaCl 2 marks Refer to the molar volume of gases (Table 4) on the data page to help you answer the following question. 11. (a) (b) Work out the volume of 1.4 mol of chlorine (Cl2) at STP Work out the mass of 2.8 L of neon (Ne) gas at SLC 1 + 1 = 2 marks The table below summarises the different types of acid reactions: Reactions of acids 1. acid + metal salt + hydrogen This reaction does not occur with Cu, Hg, or Ag. 2. acid + metal carbonate salt + water + carbon dioxide 3. acid + metal oxide salt + water 4. acid + metal hydroxide salt + water Carbonates contain the CO32 ion The chemical formulae of selected compounds. HCl (aq) Na2CO3 (aq) NaCl (aq) H2O (l) CO2 (g) CuO (s) CuCl2 (aq) H2O (l) H2SO4 (aq) NaOH (aq) Na2SO4 (aq) Before you start Page 4 Pre-test questions continued… 12. Use the summary of acid reactions shown above to predict the products of the following reactions: (a) HCl (aq) + Mg (s) (b) HCl (aq) + Na2CO3 (aq) (c) HCl (aq) + CuO (s) (d) H2SO4 (aq) + NaOH (aq) 1 + 1 + 1 + 1 = 4 marks 13. Are the following reactions oxidation or reduction reactions? (a) Cl2(g) + 2e 2Cl (aq) (b) Pb (s) Pb2+ (aq) + 2e ½ + ½ = 1 mark 14. The reaction Zn(s) + S(s) ZnS (aq) can be written as two half reactions: Zn(s) Zn2+(aq) + 2e and S(s) + 2e S2 (aq) (a) Identify the oxidant in this redox reaction (d) Identify the reductant in this redox reaction ½ + ½ = 1 mark 15. Iron reacts with hydrochloric acid according to the ionic equation Fe(s) + 2H+(aq) Fe2+(aq) + H2(g) (a) What has been oxidised in this reaction? (b) Write a half equation for the oxidation reaction. (d) What has been reduced in this reaction? (e) Write a half equation for the reduction reaction. ½ + 1 + ½ + 1 = 3 marks 16. Hydrogen gas and oxygen gas react to form water according to the reaction 2H2 (g) + O2 (g) 2H2O (l) 10 g of oxygen is reacted in excess hydrogen. (a) How many mol of oxygen was reacted? (b) How many mole of hydrogen is required? (c) Work out the mass of hydrogen reacted. 1 + 1 + 1 = 3 marks END OF PRE-TEST Before you start Page 5 PRE TEST ANSWERS 1. (a) The atomic number of (i) (b) silver 47 2. 3. gold Au (ii) silicon Si 7. (iii) sodium Na (iv) antimony Sb at room temperature, 25 C solid liquid gas at fridge temperature, 4 C solid liquid gas at 5 C solid liquid gas Identify the ions present in the following ionic compounds and name the compound. MgCl2 (b) Na3PO4 (c) Ag2S Mg2+ Cl Na+ PO43 Ag+ S2 Magnesium chloride Sodium phosphate Silver sulfide Work out the chemical formula of the following compounds. (b) Magnesium carbonate AgOH 6. radium 88 The element with 13 protons and 13 neutrons is Aluminium (a) Silver hydroxide 5. (iii) Circle the physical state of butane (a) 4. radon 86 The chemical symbol of (i) (c) (ii) (c) Zinc nitrate MgCO3 Zn(NO3)2 Balance the following chemical equations. (a) 3Mg(s) + N2(g) Mg3N2(s) (b) 2Ca (s) + O2(g) 2CaO(s) (c) 2H2(g) + O2(g) 2H2O(l) (d) 2Al(s) + 3I2(l) Al2I6(s) Use the solubility table (Table 2) on the data page to determine which of the following ionic compound are soluble. (a) lead sulfate is insoluble (b) silver chloride is insoluble (c) ammonium chloride is soluble (d) zinc carbonate is insoluble The compound Cu(NO3)2 dissolves in water by dissociation of ions (a) The ions in the compound. Cu2+ NO3 (b) The ionic equation of the dissociation reaction, showing the state of each compound or ion. H 2O Cu(NO3)2 (s) Cu2+ (aq) + 2NO3(aq) Before you start 8. (a) Page 6 Mr(H2O) = 18.0 g/mol (b) Mr(NaCl) = 58.5 g/mol Pre-test answers continued… 9. The mass of 1.3 mol of CH4 = 1.3 16.0 = 20.8 grams 10. The number of mol, to three decimal places (a) 50 g of lead = 11. (a) (b) 50 207.2 mol = 0.241 mol (b) 62 g of NaCl = 62 58.5 mol = 1.059 mol The volume of 1.4 mol of chlorine (Cl2) at STP = 1.4 22.4 L = 31.36 Litres Work out the mass of 2.8 L of neon (Ne) gas at SLC = 2.8 24.5 20.18 = 2.306 grams 12. Use the summary of acid reactions shown above to predict the products of the following reactions: (a) 2HCl (aq) + Mg (s) MgCl2 (aq) + H2 (g) (b) 2HCl (aq) + Na2CO3 (aq) 2NaCl (aq) + H2O(l) + CO2(g) (c) 2HCl (aq) + CuO (s) CuCl2 (aq) + H2O(l) (d) H2SO4 (aq) + 2NaOH (aq) Na2SO4 (aq) + 2H2O(l) 13. Are the following reactions oxidation or reduction reactions? (a) Cl2(g) + 2e 2Cl (aq) Reduction reaction (b) Pb (s) Pb2+ (aq) + 2e 14. (a) 15. Oxidation reaction The oxidant in this redox reaction is S(s) (d) The reductant in this redox reaction Zn(s) (a) Fe(s) been oxidised in this reaction? (b) The oxidation reaction is Fe(s) Fe2+(aq) + 2e (d) H+(aq) has been reduced in this reaction? (e) The reduction reaction is 2H+(aq) + 2e H2(g) 16. (a) The mol of oxygen was reacted = 10 g 32.0 = 0.3125 mol (b) The mole of hydrogen required = 2 0.3125 = 0.625 mol (c) The mass of hydrogen reacted = 0.625 2.0 = 1.25 grams Before you start Page 7 Your pre-test result… What we recommend … If your score was less than 20 40 If you got less than half the pre-test right you will most likely need a lot of time and support to make a success of Year 12 Chemistry. Past experience has shown that students scoring less than 20 out of 40 are not able to continue with this subject because they find it too difficult. We strongly recommend that you contact the Chemistry teachers to discuss your options. If you scored between 20 and 30 you will most likely need revision support throughout the year to develop the skills expected. This means making extra time available for your studies, and perhaps finding a tutor to help you. We suggest that you consider realistically whether you will be able to make the extra study time available. Contact the Chemistry teachers to discuss your options. If your score was between 20 30 and 40 40 If you scored between 30 and 40 you should be able to cope with most of the skills expected. However, you will also need to make regular study time a part of your weekly schedule. If you have any concerns, contact the DECV, and speak to the Chemistry teachers.