Advanced Placement Chemistry Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 1-4 Unit Content and Activities (based on College Board course outline and audit requirements) Review of Matter, Measurements, Atoms and Elements, Molecules and Ions, and their Compounds. Basic Stoichiometry Content Calculations and Uncertainty Mole, molar mass, balancing molecular equations Limiting reagents Stoichiometry with mixtures – percentage purity Percent composition, empirical and molecular formulas Percent yield Stoichiometry with gas pressures and volumes – using Avogadro’s Law How to prepare solutions. Safety in the Laboratory including the use of MSDS forms Requirements for a formal laboratory report. Hands On Laboratory Experiences – 2 of the following Determination of the % of Phosphorus in Plant Food and Preparation of Alum and purification by crystallization (Vonderbrink) % of Calcium in Eggshells with related STS connection- DDT Assessments Quiz on safe practices in the laboratory Two Formal Laboratory Reports Focus Quiz on Ch. 4 Pre-Exam CD Quiz Ch 4 Summative Exam on Ch 4 Correlation to College Board Curricular Requirements The course provides instruction in Reactions, including Reaction Types, and Stoichiometry. The course emphasizes chemical calculations and the formulation of principles. The course provides instruction in Laboratory. Percent Hydrate in a Salt Lab and Empirical Formula of a Salt Lab are done in the preceding course, Honors Chemistry. Will be tested as a paper and pencil lab as part of the unit exam. 1 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 5 11 Unit Content and Activities (based on College Board course outline and audit requirements) Reactions in Aqueous Solution Content Introduction to Net Ionic Equations and the AP style for descriptive equation writing Reactions in Solution Stoichiometry including Molarity and Quantitative Analysis Precipitation Reactions including solubility and selective precipitation for qual analysis Redox Reactions including balancing in acidic and basic media Acid Base Reactions including Bronsted-Lowry Acid-Base Model Hands On Laboratory Experiences Oxidation States of Manganese with lab report sheet and Bleach Lab (Vonderbrink) with full lab report and Precipitation Lab – writing balanced net ionic equations (Ithaca College) with full lab report or Gravimetric Determination of a Chloride Ion (Hall) or Gravimetric Determination of Sulfate Ion (Hall) and Titration for the Analysis of Vit. C (National Science Foundation) with full lab report Assessments Focus Quiz Ch. 5 Pre-Exam CD Quiz Quiz on Writing Balanced Molecular and Net Ionic Equations for Precipitation, Acid/Base and Precipitation Reactions Summative Exam on Ch 5 with some questions from the AP Test Bank Quiz on Selective Precipitation Formal Laboratory Reports Manganese Lab Report Sheet Organic Content Organic Nomenclature Isomers Descriptive Equations for Organic Reactions including Addition and Condensation Polymerization Hands On Laboratory Experiences Preparation of three esters; wintergreen, banana, and fruity (Hall). Assessments Focus Quiz Ch 11 Pre-Exam CD quiz Ch 11 Quiz on descriptive equations some from the AP Test Bank Report Sheet for Esterfication Lab Correlation to College Board Curricular Requirements The course provides instruction in Reactions, including Reaction Types, and Stoichiometry. The course provides instruction in Descriptive Chemistry The course emphasizes chemical calculations and the formulation of principles. The course provides instruction in Laboratory. In the prerequisite chemistry course some of the students have laboratory experiences in acid/base titration with a phenolphthalein endpoint, titration to find % Ca in an eggshell or Analysis of Stomach Antacid Tablets. The course provides instruction in Reactions, including Reaction Types, and Stoichiometry. The course provides instruction in Descriptive Chemistry The course provides instruction in Laboratory. 2 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 15 Unit Content and Activities (based on College Board course outline and audit requirements) Kinetics Content The meaning of reaction rate and detectable quantities used in kinetic experiments Rate expressions from initial rate data Rate expressions from concentration-time data Graphically or mathematically determining concentration, half life, order. Reaction Mechanism Energy Diagrams with and without catalysis Activation Energy and the Arrhenius equation Hands On Laboratory Experiences Rate of Precipitation of Sulfur to Determine Order or Rate of Hydrogen Gas formation from Magnesium and hydrochloric acid to determine order and Lab using glow sticks and light meters to determine the activation energy for the reaction Using the Spectrophotometer to Analyze the Rate of Fading for Phenolphthalein is done later in the course Assessments Focus Quiz Chapter 15 Pre-Exam CD Quiz Ch 15 Summative Exam on Ch 15 - problem solving and multiple choice. Formal Laboratory Report Correlation to College Board Curricular Requirements The course provides instruction in Reactions, including Kinetics. The course provides instruction in Laboratory. The course emphasizes chemical calculations and the formulation of principles. 3 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 16 17 Unit Content and Activities (based on College Board course outline and audit requirements) Introduction to Equilibria Content Definition of dynamic equilibria Equilibrium expressions and Equilibrium Constants “ICE” tables Using K’s to determine direction of shift in equilibria LeChatelier’s Principle and predicting shift in equilibria Relating Kp to Kc Hands on Laboratory Experiences LeChatelier’s Principle and the equilibrium of CuCl4-2 with addition and removal of ions and temperature changes and Spectrophotometry of Co(II) (Flinn) Determination of K of CaCO3 or MgC2O4 (Hall) and Determination of K for [Fe(SCN)]+2 using Spectrophotometer (Flinn) Assessments Focus Quiz Ch 16 Pre-Exam CD Quiz Ch 16 Summative Exam on Ch 16 including MC and Free Response Questions with some from the AP Test Bank Formal Laboratory Report for Determination of K lab Report Sheet for LeChatelier’s lab. Acid Base Equilibria Content Water Ionization Constant pH and pOH Weak Acids and Ka Weak Bases and Kb percent ionization Indicators (here or Ch 18??) Acid – Base properties of salt solutions Hands On Laboratory Experiences Titration of a Weak Acid to determine Ka, Percent Ionization, and Molar Mass Assessments Focus Quiz on Ch 17 Pre-Exam CD Quiz on Ch 17 Summative Exam on Ch 17 including problem solving and multiple choice questions some from the AP Test Bank Formal Laboratory Report Correlation to College Board Curricular Requirements The course provides instruction in Reactions, including Equilibrium. The course provides instruction in Laboratory. The course emphasizes chemical calculations and the formulation of principles. The course provides instruction in Reactions, including Equilibrium. The course provides instruction in Laboratory. The course emphasizes chemical calculations and the formulation of principles. 4 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 18 23 Unit Content and Activities (based on College Board course outline and audit requirements) Salts, Buffers and Titrations and Solubility Product Constants of Solids Content Buffer action and choice pH of a buffer before, during and after titration Titrations with polyprotic acids Ksp calculations Solubility calculations Determination of precipitation Determination of selective precipitation Hands On Laboratory Experiences Titration of a Weak Base both unbuffered and buffered. Indicators (here or Ch 18??) Solubility of Calcium Hydroxide and the Common Ion Effect (Experimental Chemistry, 2nd Ed. Saliby, Desio, Wheeler. University of New Haven Press) Assessments Focus Quiz on Ch 18 Pre-Exam CD Quiz on Ch 18 Summative Exam on Ch 18 including problem solving and multiple choice questions some from the AP Test Bank Formal Laboratory Reports Nuclear Chemistry Content Alpha, beta and gamma particles Nuclear reactions Nuclear activity calculations Half-life calculations Assessment Pre-Exam CD Quiz on Ch 23 Take home Summative Exam on Ch. 23 consisting of short response and problem solving with some qtns from the AP Test Banks. Correlation to College Board Curricular Requirements The course provides instruction in Reactions, including Equilibrium. The course provides instruction in Laboratory. The course emphasizes chemical calculations and the formulation of principles. The course provides instruction in the Structure of Matter. The course provides instruction in Reactions. The course emphasizes chemical calculations and the formulation of principles. 5 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 7 and 8 Unit Content and Activities (based on College Board course outline and audit requirements) Electronic Structure and the Relationships on the Periodic Table Content Atomic spectra, Bohr atom, quantum numbers, electron configurations, orbital notations. The periodic Law and trends in the periodic table based on the form of the atoms. Hands On Laboratory Experiences Diffraction Grating Lab to determine wavelength associated with an element (?? – find a replacement-perhaps online simulation) Assessments Pre-Exam CD Quiz on Ch 7 Pre-Exam CD Quiz on Ch. 8 Take home Summative Exam on Ch 7 and 8 - short answer- “a rule is not an explanation”- how to write short answers for AP – periodic properties and connecting form to behavior. Correlation to College Board Curricular Requirements The course provides instruction in the Structure of Matter, including atomic theory and atomic structure. The course provides instruction in Descriptive Chemistry, including relationships in the periodic table. The course provides instruction in Laboratory. The course emphasizes chemical calculations and the formulation of principles. 9 and 10 Covalent Bonding and Molecular Geometry Content Lewis structures, Resonance and Formal Charges Molecular geometry and the Valence Shell Electron Pair Repulsion Theory Polarity of Bonds and Molecules Atomic Orbitals and Hybridization, sigma and pi bonds Assessments Focus Quiz Ch 9 Focus Quiz Ch 10 Pre-Exam CD Quiz Ch 9 Pre-Exam CD Quiz Ch 10 Summative Exam on Ch. 9 and 10 is short answers with emphasis on “a rule is not an explanation- connecting form to behavior. The course provides instruction in the Structure of Matter, including Chemical bonding. Can Fit in Lets Review Ch 7-11 here or later. Note that the Lets Review Ch 1-6 fits after the next unit or later so maybe consider doing both Let’s Review after the next unit. 6 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 6 Unit Content and Activities (based on College Board course outline and audit requirements) Thermochemistry Content State Functions Energy Diagrams Heat Capacity and Specific Heat Heat Flow Equation Hess’s Law Standard Heat of Formation Bond Energies Hands On Laboratory Experiences Determination of the Heat Capacity of a Coffee Cup Calorimeter (Institute for New AP Teachers) and Determination of the Heat of Reaction for two Acid/Base Reactions (Institute for New AP Teachers) and Determination of the Heat of Reaction for the Combustion of Mg (Institute for New AP Teachers) Assessments Focus Quiz on Ch. 6 Pre-Exam CD on Ch 6 Summative Exam on Ch 6 with Problem Solving based on AP Test Bank Questions. Correlation to College Board Curricular Requirements The course provides instruction in Reactions, including Thermodynamics. The course provides instruction in Laboratory. The course emphasizes chemical calculations and the formulation of principles. In the pre-requisite chemistry course the students have laboratory experiences in the heating curve of water, the heat of fusion of water, and the specific heat of a metal. Lab Reports Can Fit in Lets Review Ch 1-6 here or later. 7 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 22 19 Unit Content and Activities (based on College Board course outline and audit requirements) Coordinate Complexes Content Composition of Complex Ions Geometry of Complex Ions and Isomers Electronic Structure of Complex Ions Writing Net Ionic Equations for the reactions of Complex Coordinate Compounds Hands On Laboratory Experiences Preparation of Complex Coordinate Compounds of Copper (Hall) Assessments Pre-Exam CD Quiz Ch 22 Test includes vocabulary and function follows form emphasis w/short answer and multiple choice qtns - descriptive eqn writing with some questions from the AP Test Bank Chemical Thermodynamics, Free Energy and Equilibrium Constants Content Entropy Free Energy Gibbs-Helmholtz equation Effect of Temperature, Pressure, and Concentration on Reaction Spontaneity Hands On Laboratory Experience Gibbs Free Energy and an Elastic Band (?? Find something that works better?) Assessments Focus Quiz on Ch. 19 Pre-Exam CD on Ch. 19 Summative Exam on Ch 19 - short response and multiple choice questions some from the AP Test Bank. Formal Report for the Elastic Band Lab (?? Find a lab which works more consistently) Correlation to College Board Curricular Requirements The course provides instruction in the Structure of Matter, including Chemical bonding. The course provides instruction in Reactions, including Lewis Acid Base. The course provides instruction in Laboratory The course provides instruction in Reactions, including Thermodyamics. The course emphasizes chemical calculations and the formulation of principles. 8 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 20 12 Unit Content and Activities (based on College Board course outline and audit requirements) Electrochemistry, Free Energy and Electrochemisty Content Voltaic cells, oxidation and reduction half-cells and equations Standard Voltages Nernst Equation Faraday’s Law and electrochemical Stoichiometry Descriptive Chemistry- writing redox net ionic equations Hands On Laboratory Experiences Voltages of varying voltaic cells and Electroplating copper. Assessments Focus Quiz on Ch. 20 Pre-Exam CD on Ch 20 Summative Exam on Ch 20 - short response and multiple choice questions some from the AP Test Bank Shortened Versions of the Formal Laboratory Report Can Fit in Lets Review Ch 14-20 here or later. Gases and the Kinetic Molecular Theory Content The Ideal Gas Law The Kinetic Molecular Theory Dalton’s Law of partial pressures and collecting over water Avogadro’s Law Gas Stoichiometry Hands On Laboratory Experiences Molar Volume of Hydrogen Gas Lab (Bridges) or Molecular Weight of Butane Lab (Institute for New AP Teachers) or Mass Percent of CO2 in Alka Seltzer or Molar Mass of a Volatile Liquid These labs are divided among the class and data, calc, and conclusion presented as Power Points and then similar calculations required on test for whole group accountability for content of both experiments. Consequently each student does one of the activities, participates in the presentation of the lab but does not do a formal report. Correlation to College Board Curricular Requirements The course provides instruction in Reactions, including Thermodynamics. The course provides instruction in Laboratory The course emphasizes chemical calculations and the formulation of principles. The course provides instruction in the States of Matter, including Gases. The course provides instruction in Laboratory The course emphasizes chemical calculations and the formulation of principles. In the prerequisite chemistry course the students have laboratory experiences in the kinetic molecular theory, Boyles Law and Charles Law. Assessment Focus Quiz on Ch 12 Pre-Exam CD on Ch 12 Summative Exam on Ch 12 - short response with emphasis on “a rule is not an explanation and problem solving. Some AP test bank questions are used. 9 Chapters in Text (Kotz, Treichel and Weaver, 6th Enhanced Edition) 13 14 Unit Content and Activities (based on College Board course outline and audit requirements) Solids and Liquids Content Intermolecular Forces including Dipole-dipole interactions, hydrogen bonding, London forces and their effects on the physical properties of the 3 phases of matter Molecular Substances, Network Covalent and Ionic and Metallic Solids Liquid Vapor Equilibrium Phase Diagrams Hands On Laboratory Experiences Vapor Pressure and Heat of Vaporization of Water. Assessments Focus Quiz on Ch. 13 Pre-Exam CD on Ch. 13 Summative Exam on Ch 13 -short answer with emphasis on “a rule is not an explanation” and using some AP Test Bank Questions. Take Home Quiz on Phase Diagrams including MC questions from the AP Test Bank. Laboratory Report Can Fit in Lets Review Ch 12 and 13 here or later. Solutions with emphasis on Colligative Properties Content Concentration units Solubilities of substances in various solvents explained in terms of solute-solute, solvent-solvent, and solute-solvent attractive forces Henry’s Law to relate gas solubility to partial pressure Raoult’s Law to calculate the vapor pressure of a solution Freezing Point Depression and Boiling Point Elevation – van t’Hoff’s factor Osmotic Pressure of a solution Colligative properties to determine the Molar Mass of solutes Hands On Laboratory Experience Freezing point depression Lab to determine the molar mass of a molecular substance and the molar mass of an ionic substance. Correlation to College Board Curricular Requirements The course provides instruction in the States of Matter, including Solids and Liquids. The course provides instruction in Laboratory The course emphasizes chemical calculations and the formulation of principles. In the prerequisite chemistry course the students have laboratory experiences in the Nature of Water and the Effects of Intermolecular Bonding on the Properties of Solids. The course provides instruction in the States of Matter, including Solutions. The course provides instruction in Laboratory The course emphasizes chemical calculations and the formulation of principles. Assessments Focus Quiz on Ch 14 Pre-Exam CD on Ch 14 Summative Exam on Ch 14 - short answer with emphasis on “a rule is not an explanation” and problem solving using some AP Test Bank Questions. Report Sheet for the laboratory activity. 10