Unit 6 Name _______________________________ # ________ Section 1: Into to Acids and Bases 1. When water self-ionizes, what two ions does it break up into (Give both formula and name)? 2. Explain why HCl would be classified as both an Arrhenius and a Brønsted-Lowry acid. 3. Explain why NH3 would be classified as a Brønsted-Lowry base but not an Arrhenius base. 4. Explain the relationship between the strength of an acid and its conjugate base. 5. For each of the following, label the acid, base, conjugate acid, and conjugate base. a. H2PO4- + H2O H3PO4 + OHb. HCl + H2O H3O+ + Cl6. List the strong acids and the strong bases. Why are they considered strong? Section 2: Naming Acids Write the formula for each of the acids listed below: 1. Nitric acid 2. Chloric acid 3. Acetic acid 4. Hydrobromic acid 5. Sulfurous acid 6. Chlorous acid 7. Hydrochloric acid 8. Phosphoric acid 9. Nitrous acid 10. Hydrofluoric acid 11. Perchloric acid 12. Hydroiodic acid 13. Phosphorous acid 14. Carbonic acid 15. Sulfuric acid Name each of the following acids: 16. HClO4 17. H3PO4 18. HCl (aq) 19. H2SO4 20. HNO2 21. HI (aq) 22. HC2H3O2 23. HF (aq) 24. H3PO3 25. HClO3 26. H2CO3 27. H2SO3 28. HClO2 29. HNO3 30. HBr (aq) Section 3: pH and pOH 1. What is the equilibrium expression for water? What is the value for Kw? 2. In neutral water, what is the concentration of H3O+ and OH-? 3. What is the [OH-] if the [H3O+] is 1.0 x 10-9 M? 4. List the range of values for pH. Which values are considered acids? bases? 5. List the range of values for pOH. Which values are considered acids? bases? 6. Complete the table. Substance Concentration [H3O+] 1.00 X 10-9 [H3O+] [H3O+] 1.00 X 10-2 [H3O+] [H3O+] [H3O+] 2.00 X 10-4 [H3O+] [H3O+] 3.50 X 10-10 [H3O+] 5.80 X 10-2 + [H3O ] 9.50 X 10-11 [OH-] 1.00 X 10-9 [OH ] [OH-] 1.00 X 10-2 [OH-] 1.00 X 10-11 [OH ] 1.00 X 10-7 [OH-] [OH-] 5.60 X 10-7 [OH-] 3.50 X 10-10 [OH ] 5.80 X 10-2 [OH-] 9.50 X 10-11 pH pOH Acid, base or neutral? 8.00 11.0 neutral 6.25 6.00 10.3 7. What is the pH of an aqueous solution that contains 25 grams of hydrochloric acid dissolved in 1.5 liters of solution? 8. What is the pH of an aqueous solution that contains 1.2 moles of nitric acid and 1.7 moles of hydrochloric acid dissolved in 1000 liters of solution? Section 4: Titration 1. Complete and balance the following neutralization reactions. a. HF + LiOH → b. HClO3 + Mg(OH)2 c. HNO3 + Ba(OH)2 d. HC2H3O2 + → → Sr(OH)2 → 2. What is the purpose of titration? 3. What is an indicator? 4. What is the color of litmus when exposed to basic substances? acidic substances? 5. What is the color of phenolphthalein in acidic solutions? basic solutions? 6. What is the concentration of the 25 mL of hydrochloric acid that neutralized 30 mL of 0.1 M sodium hydroxide? 7. How many mL of 0.20 M HBr is needed to neutralize 23.45 mL of 0.11 M KOH? 8. In a titration of vinegar (a solution of acetic acid, CH3COOH), you find that it requires 11.10 mL of 0.748 M NaOH to neutralize a 10.0 mL sample of vinegar. What is the concentration of acetic acid in the sample of vinegar?