Chapter 7 Notes Fluids and Viscosity 7.1 A fluid is any form of matter (substance) that flows. A review of the five major points of the particle theory of matter: 1. All matter is made up of very small particles. 2. All particles in a pure substance are the same. Different substances are made of different particles. 3. There is space between the particles. 4. The particles are always moving. As the particles gain energy, they move faster. 5. The particles in a substance are attracted to one another. The strength of the attractive force depends on the type of particle. Even though a solid does not appear to move, the particles are constantly vibrating in place. The particles in a liquid are in contact with each other, but they can slip and slide past one another, changing their position. This slipping and sliding means liquids take the shape of their container. Solids Shape Volume Particle arrangement Particle movement Definite shape Definite volume Particles close Vibrate in place Gas particles have very large spaces between them. Gases are quite different from liquids and solids because the particles in a gas can move freely in all directions. This is why gases always spread out or diffuse in their container Liquids Indefinite shape Gases Indefinite shape Definite volume Particles close Free flowing Indefinite volume Particles distant Random movement Since liquids and gases do not have a definite shape they are able to flow. Hence by definition, liquids and gases are fluids. 1 Examples of fluids in everyday life: (i) compressed air in tires (ii) water (iii) syrup Other examples include: - food fluids (syrup, honey, molasses, water, or oil.) - cleaning fluids (shampoo, liquid detergents, gels, abrasive creams like Vim™) - bodily fluids (blood, mucus) - industrial fluids (oils as lubricant, compressed air in tires) 7.2 Viscosity is a measure of a liquid’s resistance to flow. Liquids like molasses and maple syrup have a high viscosity, while other liquids like water and milk have a low viscosity. But what makes one fluid run faster or slower than another? Even though all fluids flow smoothly, they flow at different rates because they have different viscosities. The viscosity of a liquid is related to the amount of friction (a force that resists movement) between particles. The greater the friction or rubbing of particles in any fluid, the higher the viscosity. This can result from the size and shape of the liquid particles as well as the attraction between particles. The viscosity of liquids is an important property that must be measured very carefully in some industries. Many substances require the proper degree of viscosity to perform their intended function. For example,. Peanut butter kept in the fridge is often too viscous to spread. Examples of viscosity in everyday life: (i) motor oil in order for motor oils to be effective lubricants, they need to have the proper viscosity. (ii) (iii) paints Paints require an appropriate degree of viscosity in order to spread properly, they cannot be too thin and runny, nor can they be too thick. foods Peanut butter kept in the fridge is often too viscous to spread Canada’s maple syrup industry depends on controlling the viscosity of a liquid. The sap (from sugar maple trees) is thin, runny, and unsweetened but when the sap is heated and water evaporates, the result is a thick, sweet syrup that is highly viscous. 2 Comparing Viscosities Flow rate as the speed at which a fluid flows from one point to another. How fast a fluid flows can be determined by measuring its flow rate. This is often used to compare the viscosity of fluids since viscosity itself is a difficult property to measure directly. Examples of liquids with different flow rates include: (i) water (Low viscosity →fast flow rate) (ii) dishwashing liquid (medium flow rate) (iii) corn syrup (High viscosity →slow flow rate) Remember that viscosity is the measure of a liquid’s resistance to flow Fluids that have a high viscosity, or fluids that are more viscous, flow slowly. Whereas fluids that have a low viscosity, or fluids that are less viscous, flow freely or faster. Other examples of how flow rate can be affected: (i) Pancake batter If the batter is thick it is more viscous and has a slower flow rate, whereas if the batter if thin, it has a low viscosity and flows quickly. (ii) Motor oil For example, the temperature of engine oil would dictate how quickly it would drain from an engine during an oil change, or why different types of motor oil are used for different engines and different seasons. 7.3 Factors that Affect Viscosity A liquid’s resistance to flow can be explained in terms of the particle theory of matter: 1) strength of attraction between particles There is a force of attraction between particles that can be either strong or weak. There is an attraction of particles within one particular liquid itself and that there is an attraction between the particles of the liquid and the particles of the object on which it is flowing. For example, the droplets of rain that appear on a clothesline after a rainfall illustrate this. The fact that water particles remain together to form droplets is an example of attraction of particles within one particular liquid and the fact that the droplets remain on the clothesline is an example of an attraction between the particles of the liquid and the particles of the object on which it is flowing. 3 attractive forces strong → the liquid flows slowly (difficult for the particles to pull away from each other and slide past each other) →high viscosity → the liquid flows easily → low viscosity attractive forces weak (particles pull apart and slide past each other easily) 2) temperature Particles are constantly in motion. As they acquire more energy, they move faster. As liquids are heated the particles move faster and farther apart. As a result, the viscosity decreases because there is less friction and the attractive force between particles is reduced. For example, when honey or wax is heated it flows faster (viscosity decreases). On a very cold winter morning in Newfoundland and Labrador, it can be hard to start your car. One of the problems is that the oil that lubricates the engine can become very stiff and resistant to flow under cold conditions. In general, a liquid’s viscosity decreases as the fluid is heated and increases as the fluid is cooled. The effect of temperature on gas particles is opposite to the effect on liquids. The particle theory states that the particles in gases are already very far apart. When energy is added, gas particles speed up and collide with each other more often, causing an increase in internal friction, and therefore an increase in viscosity. A gases’ viscosity increases as the fluid is heated and decreases as the fluid is cooled. 3) concentration There is empty space between the particles. Concentration refers to the amount of substance in a given space. If a liquid is concentrated, it means that there are more particles in a given space. As a result, the viscosity increases because there is more friction and the attractive force between particles is increased. For example, skim milk, 1% milk, 2% milk, whole milk and cream. 4 For example, when making gravy, you may thicken the gravy by adding cornstarch. By increasing the concentration of cornstarch, you are also increasing the viscosity of the gravy. Generally, by increasing the concentration of a substance, the viscosity is also increased. 5