Acids and Bases: Together again! Wilma Amaro Time: One class period, Week 3 Preparation Time: Approximately 1hour Materials: Board, dry erase markers or chalk; 500ml-graduated cylinder, approximately 500ml of 1M, NaOH and 500ml, 1M HCl, phenolphthalein and methyl red indicators, distilled water, balance, beakers, funnels, droppers, glass stirrers, funnels, wash bottles. Abstract Many chemical compounds are produced as industrial waste and discarded into the air and water. Understanding the physical and chemical properties of compounds (i.e. pH) allows the development of simple detection methods. This lesson is designed to engage students in the topic of acid-base reactions. At this point, students should have an understanding of molecular and structural formulas, atomic and molecular weights, the mole, and concentration (specifically in terms of molarity.) They should also have been exposed to the concept of chemical reactions. Objectives Students will be able to: 1. Identify principles behind acid-base reactions 2. Predict factors that may affect an acid-base reaction National Science Education Standards: Content Standard A: Inquiry o Identify questions and concepts that guide scientific investigations o Formulate and revise scientific explanations and models using logic and evidence Content Standard B: Physical Science o Structure and properties of matter reactions o Chemical reactions Content Standard F: Science in Personal and Social Perspectives o Personal and community health o Environmental quality o Natural and human-induced hazards Teacher Background: Strong acids (having a pH of 2 or less) and strong bases (having a pH of 12.5 or greater) are considered corrosive. Products with these properties are often generated in association with businesses such as vehicle maintenance and dismantling, printing, photo finishing labs, surface coating, metal finishing electronics, computers, and educational institutions. The release of products with such properties can often result in a threat to human health and the environment. Preventing disease involves understanding the cause of an illness and changing the conditions that permit it to occur. When chemicals are implicated, this is usually done by trying to minimize or eliminate the chemical in the environment or by minimizing the adverse effects of chemicals found in the environment and food supply (NIEHS, 2000). One of the environmental resources that need to be monitored closely is water. Water can be analyzed for acid/base content by doing titrations. Related and Resource Websites 1. http://www.chemistrycoach.com/acids.htm Review of fundamental concepts in acid/base reactions. Includes a discussion on electrolytes. 2. http://chemed.chem.purdue.edu/genchem/topicreview/bp/ch11/acidbaseframe.html Review of acid/base definitions. 3. http://members.aol.com/logan20/ionic_eq.html Acid/base equilibrium. 4. http://www.flinnsci.com/Documents/ProductPDFs/ChemTopicLabs/vol%2013/Demo_ Summaries_Concept_vol13.pdf Acid/base demonstrations 5. http://www.dec.state.ny.us/website/ppu/ecppsqg.pdf EPA regulations for small businesses 6. http://www.chemguide.co.uk/physical/acidbaseeqia/indicators.html Theoretical background on indicators 7. http://qldscienceteachers.tripod.com/junior/chem/acid.html Examples of bases and acids; includes examples of indicators and the pH range they detect 8. http://classes.aces.uiuc.edu/ACES100/Mind/CMap.html Information about concept maps. Includes different types Activity: Materials, for teacher: Two beakers, any size Triple-beam or any kind of balance Glass stirrer NaOH pellets Two 1-L volumetric flasks HCl, 15 M (molarity is commonly found on liquid reagent bottles. HCl is usually 15M when purchased through chemical supply companies. Some local companies may be able to prepare solutions of a specific molarity for a fee) Funnel Droppers Wash bottle Teacher prep: Solution preparation: CAUTION: Wear goggles, apron and rubber gloves when preparing these solutions. HCl solution must be prepared under a hood. NaOH Weigh 40.0g of NaOH in a beaker, add enough distilled water to dissolve it; do not add more than 200 or 300 ml. Transfer to 1-L volumetric flask using a funnel and wash bottle. Bring water level up to the 1-liter mark on the neck of the flask using a dropper. Label flasks clearly with NaOH, 1M, include date. HCl Measure 15ml of 15M HCl using a pipette and transfer into 1-L volumetric flask. Bring water level up to the 1-liter mark on the neck of the flask using a dropper. Label flask clearly with HCl 1M, include date. Class Demo: 1. Ask each student to generate a list of 15-20 words/ideas they relate to chemical reactions. Organize these into a concept or mind map. 2. In a 500mL-graduated cylinder, pour about 200mL of 1M NaOH. Add three or four drops of phenolphthalein. Gradually add 1M HCl, until the pink color disappears. The color change of phenolphthalein from pink to clear indicates an acidic solution. Use 1M NaOH to bring the color back to pink and then add more 1M HCl to make a clear solution again. Do this a few times. Write out the formula for HCl and NaOH, on the board. 3. Ask students to pair up and come up with an explanation for what they saw. Have them speculate about the reactants, concentration and what it takes for the color to change. 4. Add three or four drops of methyl red indicator to the mixture used in steps 1 and 2 above, and gradually add 1M NaOH until the color of the solution changes from red to yellow. The color change to yellow indicates that the solution now has a basic pH. 5. Repeat steps 1-3 a couple of times so students can see how the reaction goes back and forth, noting the color change. Have students make predictions about the color change (Will it turn pink, red, etc.?) as the demonstration progresses. Identify HCl and NaOH as an acid and a base. Class discussion 6. Start asking students: “What happens between HCl and NaOH?”, “Why do acids and bases matter to us?”, “What are some acids and bases used at home?”, “How do we discard them?”. Present facts about production of acids and bases by local businesses using provided teacher background. Ask students if they live, or know anyone, who lives near one of these businesses. 7. Have students add more terms on their concept maps this time using the demo and including class discussion. Closure: Students will exchange their concept maps with a classmate. They will write down three main ideas represented on their classmate’s concept map on a separate piece of paper. Teacher will ask students to volunteer some of the ideas. Embedded Assessment: The lesson will be assessed using the concept map. Collect and save concept maps for future reference. Homework: Find three examples of acids and three examples of bases commonly used at home. Determine how each is discarded. Answer the question: “What actually happens to them?”