Names: COMPARING NATURAL AND SYNTHETIC DYES Objectives To extract natural dyes To observe the effect of natural and synthetic dyes on a range of fabric types. Curriculum links English National Curriculum: Science 3: 2a, 2b Design Technology: 4a Approximate time required: 2 hours Resources needed Per class of 30 children: Dyeing naturally sheet Optional display of plants, vegetables and flowers used for natural dyes (see lists below) 30g Red cabbage (1 leaf) 30g Onion skins (5-6 onions) 5g Turmeric or 30g chamomile flowers Measuring jug (about 500 ml) Cooker hob Old pan Old spoon for stirring Rubber gloves Fine sieve 2m Strip of Multi-fibre strip (see List of Suppliers ) 3 Packets of synthetic dye (blue, yellow and brown) - from hardware/department stores Fixative (to be bought with cold water dyes only) Kitchen salt (a minimum of 15 tablespoons, to 'fix' natural dyes to the fabric) Washing line and pegs - optional Commercial dye colour chart -from hardware/department stores Note: Turmeric produces a vibrant shade of yellow but requires about 30 minutes settling time after boiling in the dyebath. Chamomile available as tea bags from health food shops) also produces a yellow dye and can be strained in seconds. SAFETY NOTE Extracting and using the dyes should be carried out with adult supervision and any part of the activity using boiling water must be carried out by the teacher. Rubber gloves should be worn whenever the dyes are handled. Organisation Initial class discussion followed by group work. Advance preparation The strip of multi-fibre should be cut into 10 x 10 cm squares. The 'acetate' end of each square should be marked in some way, e.g. indelible ink. Otherwise, it is hard to identify the fibre once the identification label has been removed. Names: If a lack of time, supervision or equipment does not permit the children to extract dyes, these can be prepared before the lesson and displayed in transparent, sealed containers alongside their sources. Carrying out the activity A display of plants, vegetables and flowers, whose colours are used in dyes, makes an attractive starting point for this activity, and provides a useful focus for discussion of natural dyes. For ideas on which plants to include, go to the Background Information below and Sources for Natural Dyestuffs. The children extract the natural dyes following the recipe given, and dye pieces of multi-fibre strip using natural and synthetic dyes. Each group uses the same colour of natural and synthetic dye, in order to make comparisons. So, in a class of 30 children divided into groups of five, two groups would use each colour. Recipe for a natural dye The leaves/flowers, etc. used to obtain the colour are referred to as the dyestuff. Ingredients: 30g dyestuff (5g if using turmeric) 250 ml water 1 tablespoon kitchen salt 1. 2. to 3. Pour the water in an old pan and add the dyestuff. Bring the mixture to the boil and boil for 15 minutes, topping up the water when necessary maintain a constant volume. Strain the dyebath and reserve for use with the fabric. Dyeing the fabric with a natural dye 1. Add hot or cold water to the dyebath to obtain a warm temperature to improve the take up of the dye . 2. Add 15g fabric, which has been pre-soaked in warm water, to the dyebath. 3. Bring the dyebath to the boil and simmer for 45 minutes. Even if the colour is quickly transmitted, leave for the required time so it becomes fast and even. 4. Cool the dyebath naturally and rinse the fabric in cool water. 5. Dry the fabric on a washing line across the room or on a radiator. Dyeing the fabric with a synthetic dye Instructions for use are given in the packet. A packet of fixative and kitchen salt (4 tablespoons per packet) are required when using cold water dyes. The fabric is steeped in the dyebath for an hour, stirring for the first 10 minutes. The fabric is rinsed in cold water (as for the natural dyes), rather than washed in soapy water. Comparing the dyes Once the fabric is dyed and dried, each group cut and attach strips of the fabric to their record sheet Dyeing naturally sheet, to make a visual comparison. Children also use the sheet to record their observations about the colours produced by the two dyes on the different fabric types.. A colourful collective display can be made of the results of the investigations, showing the colours and how they were obtained. Names: Background information Plants or flowers giving a colour-fast dye are called substantive and those needing a fixative are called fugitive. A classroom display of dyestuffs could be divided into these two categories. Substantive dyes coffee (used coffee grains) henna (powder or leaf) avocado (skins) seaweed (bladder-wrack) blackberries mustard acorns grass onion skins saffron red cabbage beetroot dahlia cochineal daffodil flowers turmeric Fugitive dyes elder (leaves and berries) bracken chamomile flowers There are many other plants, barks and flowers that can be used. Flowers offer interesting dyestuffs, as the majority give shades of yellow or green; even though the flowers themselves may naturally be bright and vivid! Natural dyes have been used for thousands of years. The first commercial synthetic dye was discovered in 1856 in the UK by William Henry Perkin. It was a purple dye, often referred to as Perkin's Purple. Until this dye was discovered, a dress dyed purple could start fading in a few hours! The book 'Mauve' by Simon Garfield tells the story (pub. Faber) ISBN 0-571-20197-0. Synthetic dyes give bright and vivid colours, many natural dyes do not. A greater range of colours and shades is available from synthetic rather than natural dyes. Comparing the colours produced with a commercial colour chart emphasizes this point. The same dye has quite different effects on different fabrics. For example, some synthetic dyes are made specifically to dye cotton, or others to dye acrylic, and will not colour other fabrics, or will not produce the desired colour on other fabrics. The multi-fibre fabric used in this activity is produced for the colour industry for testing dyes. It has a very high specification for each fabric, and industry uses it to test the quality and effectiveness of their dyes. In this way, they can ensure that the high standards required of their dyes are met. Extensions / links Science Quality testing of dyes has been written to follow this activity. Children test each dye's resistance to sunlight, detergents and friction. Names: SOURCES FOR NATURAL DYESTUFFS The table below provides information about plants suitable for use as a dyestuff. The procedure for making the dyestuffs is as outlined in the activity notes, unless stated differently here. In general, flowers and vegetables should be boiled for 15-45 mins. Leaves should be boiled for 30-120 mins (hard or tough leaves need the longer time, and an overnight soaking prior to boiling) and chopped bark for 1-2 hours (after soaking for 3 days). Dyestuff Colour Collection and preparation Soaking time Boiling time Strain Simmering time with fabric Acorns Brown As they ripen, and use immediately for deepest colour. Overnight 1 hour Yes 1 hour Avocado Cream to fawn 2 skins will dye 25g of cloth. Cut the skins into small pieces soak overnight 30 mins Boil for 30 mins Yes 45 mins Blackberries Bluegrey Fresh ripe fruit, None use immediately or freeze till required. 15 mins Yes 1 hour Coffee Cream to brown Used filter coffee grains (or instant coffee) Overnight (though not essential) 30 mins Yes 45 mins Daffodil Yellow Fresh heads just as they start to wilt None 20-30 mins Yes 45 mins Dahlia Yellow or gold Pick flowers as they show signs of dying None 20 mins Yes 45 mins Elder Yellow Leaves or green None 1 hour Yes 1 hour None 30 mins Yes 45 mins Honeysuckle Yellow Pick fresh shoots None (not woody stems) in mid-May before flowers appear. 30 mins Yes 45 mins Stinging nettle Creamy to yellow Chop nettle plant into small pieces None 45 mins Yes 45 mins Tea Brown/ orange Loose tea or teabags None 30 mins Yes 1 hour Pinkish violet Berries Names: Dyeing naturally? Stick pieces of your fabric in these spaces and write the name of the dyestuff used below. Fabric pieces coloured using natural dyes acetate cotton nylon polyester acrylic wool nylon polyester acrylic wool 1. Colour from 2. Colour from 3. Colour from Fabric pieces coloured using synthetic dyes acetate cotton 4. Colour from 5. Colour from 6. Colour from What do you like or dislike about these colours? What effect does the dye have on the different fabrics? What is the same about colours from natural and synthetic dyes? What is different about colours from natural and synthetic dyes?