Prescriptive Activities: Facet Cluster 1.6: PF#50-53 Teacher Page Prescriptive #50-53: 50 The student does not use the periodic table accurately to predict bonding behavior. 51 The student predicts that nonmetals form ionic bonds. 52 The student predicts that a metal and a nonmetal form covalent bonds. (sharing electrons). 53 The student confuses metallic bonds with ionic bonds. Materials: Student handout Internet Access Background: In understanding and applying chemical principles it is important to be able to distinguish between different categories of elements and compounds which are based on the types of bonds between neighboring atoms. The three categories of bonding that you will differentiate between in this activity include ionic, covalent and metallic bonds. You must first, however, know how to identify metals and nonmetals on the periodic table. 1 Prescriptive Activities: Facet Cluster 1.6: PF#50-53 Teacher Page Covalent bonding When two or more nonmetal atoms bond together they share electrons forming a covalent bond. They do this so that each atom will attain a noble gas electron configuration with 8 electrons in its outermost shell (except for hydrogen which will have two electrons in its outermost shell). Examples: In hydrogen bromide (HBr), the two atoms share an electron from H Br hydrogen and an electron from bromine. Bromine now has 8 valence electrons around it and the hydrogen atom has two electrons to fill its outermost energy level. In PCl3, valence electrons are shared such that all 4 atoms have 8 valence electrons. There are a few molecules with beryllium (Be) and boron (B) that are exceptions to the octet rule and will have fewer than 8 electrons around the central atom. Ionic bonding When a metal atom and a nonmetal atom bond together, the nonmetal atom removes the valence electrons from the metal atom, thereby becoming a negatively charged ion containing more electrons than protons. (Notice that the Cl- ion is larger than the Cl atom. This is because there is more electron repulsion due to the extra electron. It is important to realize that the added electron is in the same energy level as the other valence electrons). The metal atom is now a positively charged ion because it has fewer electrons than protons. (Notice that the Na+ ion is much smaller than the Na atom. It has one less energy level). The transfer of electrons results in two oppositely charged ions that are now held together by their mutual electrostatic attraction, thus forming an ionic bond. Ionic crystals exist as huge numbers of these ions attracted to each other, forming a regular lattice structure. 2 Prescriptive Activities: Facet Cluster 1.6: PF#50-53 Teacher Page Metallic bonding Metal atoms are held together by the electrostatic attraction between free mobile outer electrons moving within a lattice of positively charged metal ions containing the nuclei and inner electrons of each metal atom. The metal ions exist in layers which can slide over each other as the metal is bent or hammered. Directions of Activity: Watch the video at this link. Video distinguishing between ionic and covalent bonding: Ionic and covalent bonding animation (1:56) http://www.youtube.com/watch?v=QqjcCvzWwww&feature=player_detailpage Video of metallic bonding (1:54): Chemical Bonding and Atomic Structure (2nd Ed.) (clip) http://www.youtube.com/watch?v=ijw8OBt4btM&feature=player_detailpage Questions: 1. Give an example of two atoms that would form ionic bonds. 2. Give an example of two atoms that would bond covalently. 3. What are two properties of an ionic compound that result from an ionic bond? 4. What are two properties of a metallic compound that result from metallic bonds? 3 Prescriptive Activities: Facet Cluster 1.6: PF#50-53 Teacher Page References Video distinguishing between ionic and covalent bonding: Ionic and covalent bonding animation (1:56) http://www.youtube.com/watch?v=QqjcCvzWwww&feature=player_detailpage Video of metallic bonding: Chemical Bonding and Atomic Structure (2nd Ed.) (clip) (1:54): http://www.youtube.com/watch?v=ijw8OBt4btM&feature=player_detailpage Ionic bond Image from: http://wps.prenhall.com/wps/media/objects/165/169289/blb9ch0207.html Metallic bond Image from: http://www.bbc.co.uk/scotland/learning/bitesize/higher/chemistry/energy/bsp_rev1.shtml Periodic Table Image from: http://andromeda.rutgers.edu/~huskey/images/periodic_table_color1_1024x768_w.png Teacher Notes: This activity is best viewed on the computer because the colors show up better on the screen than in print. 4