SACCHARIC ACID MONOPOTASSIUM (D-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 576421 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2360.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SACCHARIN SODIUM A B C D CAS # 82385420 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . Dermal Hazard Corrosive Eye Damage STEL . . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 14200.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bladder. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SACCHAROLACTONE A B C D CAS # 00107 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. . Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SAFRANIN O A B C D CAS # 477736 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 41 Risk Statements: Risk of serious damage to eyes. S: 26-39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .25 mg/m3 DOE Short Term Exposure Limit .75 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SAFROLE A B C D CAS # 94597 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1950.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .0472 mm Hg @ 20 °C FLASH POINT 212 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 22 68 Risk Statements: May cause cancer. Also harmful if swallowed. Also possible risks of irreversible effects. S: 53 45 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 100 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SALICIN A B C D CAS # 138523 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX ACUTE TOXICTY RISK INDEX 2.7 - LD50 980.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin absorption. SENSITIZATION skin: May cause allergic skin reaction. The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 43 Risk Statements: May cause sensitization by skin contact. Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SALICYLALDEHYDE A B C D CAS # 90028 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 ACUTE TOXICTY RISK INDEX 3 - LD50 . I J K L . . . 0 520.0 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . INHALATION RISK INDEX 1.9 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .610 mm Hg @ 20 °C FLASH POINT 170.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong reducing agents, Metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Avoid prolonged or repeated exposure. Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22 36/38 Risk Statements: Harmful in contact with skin and if swallowed. Irritating to eyes and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 12.5 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SALICYLALDOXIME A B C D CAS # 94677 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SALICYLAMIDE A B C D CAS # 65452 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 980.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: XIDENITROGEN OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SALICYLANILIDE A B C D CAS # 87172 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7741.9 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SALICYLHYDROXAMIC ACID A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 89736 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SALICYLIC ACID A B C D CAS # 69727 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 ACUTE TOXICTY RISK INDEX 5 - LD50 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX 1.3 - LC50 . I J K L G . I 0 891.0 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers 300.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. J K . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Mild chronic salicylate intoxication is termed salicylism. Symptoms include: headache, dizziness, ringing in the ears, difficulty in hearing, dimness of vision, mental confusion, lassitude, drowsiness, sweating, thirst, hyperventilation, nausea, vomiting, and occasionally diarrhea. A more severe degree of salicylate intoxication is characterized by more pronounced CNS disturbances (including generalized convulsions and coma), skin eruptions, and marked alterations in acid-base balance. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .180 mm Hg @ 20 °C FLASH POINT 314.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Iodine Iron and iron salts. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 41 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .3 mg/m3 DOE Short Term Exposure Limit .75 mg/m3 DOE Ceiling Limit 6 mg/m3 Immediately Dangerous to Life and Health 400 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SALICYLIC ACID SODIUM A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 54217 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 930.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Salicylic acid and other salicylates are transferred into breast milk. Animal and human data suggest that the reduced clearance PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-41 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. S: 26-39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 40 mg/m3 DOE Short Term Exposure Limit 100 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SAMARIUM A B C D CAS # 7440199 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . 1 . W I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Heart. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Rare earth compounds may cause delayed blood clotting leading to hemorrhages. Exposure can cause: Abdominal pain, nausea, vomiting. Salivation. Fatigue. Dizziness. Confusion. Heart palpitations. Ataxia. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Halogens, Strong acids, Strong oxidizing agents, Water. FIRE EXTINGUISHER: Sand or dry powder type agents specially designed formetal powder fires. Use approved class D extinguishers orsmother with dry sand, dry ground limestone, or dry clay. Do not use water. Do not use halocarbon extingui TOXIC EMISSIONS WHEN BURNED: Hydrogen gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Fire: Under fire conditions, material may decompose to form flammable and/or explosive mixtures in air. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air and moisture sensitive. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: R F Indication of Danger: Radioactive. Highly Flammable. R: 11 15 33 Risk Statements: Highly flammable. Contact with water liberates extremely flammable gases. Danger of cumulative effects. S: 16 30 33 Safety Statements: Keep away from sources of ignition - no smoking. Never add water to this product. Take precautionary measures against static discharges. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SAMARIUM(II) IODIDE A B C D CAS # 32248434 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. . Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under argon\. SPECIAL REQUIREMENTS Air and moisture sensitive. Store under inert gas. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SAND A B C D CAS # 14464461 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: NONCOMBUSTIBLE. SURROUNDING FIRE CONDITIONS. USE EXTINGUISHING MEDIA APPROPRIATE TO US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .05 mg/m3 DOE Short Term Exposure Limit .15 mg/m3 DOE Ceiling Limit 7.5 mg/m3 Immediately Dangerous to Life and Health 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SAND A B C D CAS # 14808607 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Immediately Dangerous to Life and Health 50 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .3 mg/m3 DOE Short Term Exposure Limit .3 mg/m3 DOE Ceiling Limit .3 mg/m3 Immediately Dangerous to Life and Health 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SAPONIN A B C D CAS # 8047152 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37 Risk Statements: Irritating to eyes and respiratory system. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SARCOSINE A B C D CAS # 107971 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 F 0 G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SARCOSINE HYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 637967 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place\. SPECIAL REQUIREMENTS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SCANDIUM TRIFLUOROMETHANESULFONATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE CAS # 144026799 . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Hydrogen sulfide gas Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEBACIC ACID A B C D CAS # 111206 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 14375.0 mg/Kg INHALATION RISK INDEX <1 - LC50 4500.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .110 mm Hg @ 20 °C SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. STORAGE: Keep container closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEBACOYL CHLORIDE A B C D CAS # 111193 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 400.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. J K . Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Alcohols, Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Phosgene gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under argon\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 22-24-34 Risk Statements: Harmful if swallowed. Toxic in contact with skin. Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEDOHEPTULOSE ANHYDRIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 469909 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SELECTFLUOR FLUORINATING REAGENT A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 140681556 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 ACUTE TOXICTY RISK INDEX 3 - LD50 . I J K L . . . 0 500.0 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K L INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Liver. Blood. Central nervous system. Reproductive system. Stomach. Teeth. SIGNS AND SYMPTOMS OF EXPOSURE Toxicity reported for borates in humans: ingestion or absorption may cause nausea, vomiting, diarrhea, abdominal cramps, anderythematous lesions on the skin and mucous membranes. Other symptoms include: circulatory collapse, tachycardia, cyanosis, delirium, convulsions, and coma. Death has been reported to occur in infants from less than 5 grams and in adults from 5 to 20 grams. Stomach irritation. Damage to the kidneys. Exposure can cause drowsiness, fatigue, lethargy, muscular incoordination, ataxia, dizziness, aggression, hyperactivity, irritability, difficulty in concentration, increased salivation, abnormal eye movements, skin rash, and chest congestion. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Boron trifluoride Amines REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid contact with metals, moisture, oxidizing agents and acids STORAGE: Keep tightly closed. Store under nitrogen. Store in a dry area. Unsuitable: sensitive to moisture. Do not pack in metal containers. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 41 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. Risk of serious damage to eyes. S: 26 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SELENIC ACID A B C D CAS # 7783086 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . G NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Chronic contact with selenium compounds may cause garlic odor of breath and sweat, dermatitis, and moderate emotional instability. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): f - Inorganic Acid (Non-Oxidizing) WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Selenium/selenium oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Store under inert gas. Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 23/25 33 50/53 Risk Statements: Toxic by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 20/21 28 45 60 61 Safety Statements: When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SELENIUM A B C D CAS # 7782492 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . . . I . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 6700.0 mg/Kg NEUROTOXIC - RISK INDEX 3.0 INHALATION HAZARD INHALATION RISK INDEX 1.2 - LC50 . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Spleen. G.I. System. Teeth. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Anemia. Stomach pains, vomiting, diarrhea. Coughing, chest pains, difficulty in breathing. Acute selenium poisoning produces central nervous system effects, which include nervousness, convulsions, and drowsiness. Other signs of intoxication can include skin eruptions, lassitude, gastrointestinal distress, teeth that are discolored or decayed, odorous ("garlic") breath, and partial loss of hair and nails. Chronic exposure by inhalation can produce symptoms that include pallor, coating of the tongue, anemia, irritation of the mucosa, lumbar pain, liver and spleen damage, as well as any of the other previously mentioned symptoms. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE***** mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents Avoid contact with acid. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. Noncombustible. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/25 33 53 Risk Statements: Toxic by inhalation and if swallowed. Danger of cumulative effects. May cause long-term adverse effects in the aquatic environment. S: 20/21 28 45 61 Safety Statements: When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .2 mg/m3 DOE Short Term Exposure Limit .6 mg/m3 DOE Ceiling Limit 1 mg/m3 Immediately Dangerous to Life and Health 1 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SELENIUM DIOXIDE A B C D CAS # 7783008 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 OX INHALATION HAZARD INHALATION RISK INDEX <1 I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. Heart. SIGNS AND SYMPTOMS OF EXPOSURE Selenious acid is the most toxic form of selenium, ingestion is almost invariably fatal. Stupor, respiratory depression, hypotension, and death can result several hours post ingestion. Severe hypotension develops secondary both to decreased contractility from a toxic cardiomyopathy and to inappropriately low peripheral vascular resistance. Laboratory abnormalities include thrombocytopenia, moderate hepatorenal dysfunction, and elevated serum kinase levels. Chronic contact with selenium compounds may cause garlic odor of breath and sweat, dermatitis, and moderate emotional instability. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 2.0 mm Hg @ 20 °C Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Organic materials, Finely powdered metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Selenium/selenium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 23/25 33 50/53 Risk Statements: Toxic by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 20/21 28 45 60 61 Safety Statements: When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .327 mg/m3 DOE Short Term Exposure Limit .98 mg/m3 DOE Ceiling Limit 1.6 mg/m3 Immediately Dangerous to Life and Health 1.6 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SELENIUM OXYCHLORIDE A B C D CAS # 7791233 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . G . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. Causes blisters on contact with skin. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Central nervous system. Kidneys. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Acute selenium poisoning produces central nervous system effects, which include nervousness, convulsions, and drowsiness. Other signs of intoxication can include skin eruptions, lassitude, gastrointestinal distress, teeth that are discolored or decayed, odorous ("garlic") breath, and partial loss of hair and nails. Chronic exposure by inhalation can produce symptoms that include pallor, coating of the tongue, anemia, irritation of the mucosa, lumbar pain, liver and spleen damage, as well as any of the other previously mentioned symptoms. Stupor, shock, abdominal cramps, vomiting, burning epigastric distress, central nervous system and cardiovascular disturbances, cyanosis, leukocytosis, hyperglycemia, lethargy, and pulmonary edema. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE .0500 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Antimony/antimony oxides, Potassium, Phosphorus, Strong oxidizing agents, Water. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Selenium/selenium oxides Hydrochloric acid REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 14-23/25-33-35-50/53 Risk Statements: Reacts violently with water. Toxic by inhalation and if swallowed. Danger of cumulative effects. Causes severe burns. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26-36/37/39-45-60-61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .42 mg/m3 DOE Short Term Exposure Limit 1.26 mg/m3 DOE Ceiling Limit 4.41 mg/m3 Immediately Dangerous to Life and Health 4.41 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SELENIUS ACID A B C D CAS # 7446084 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . . . I J NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.9 - LD50 68.1 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 K L ROUTE OF EXPOSURE skin Contact: Skin irritant. May be toxic in contact with skin. skin Absorption: Toxic if absorbed through skin. Eye Contact: Eye irritant. Inhalation: Toxic if inhaled. Ingestion: Toxic if swallowed. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. TARGET ORGAN(S) OR SYSTEM(S) Eyes. Central nervous system. Liver. Spleen. G.I. System. Teeth. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Selenium dioxide can cause skin burns as well as dermatitis. It causes conjunctivitis leading eventually to an allergic type reaction of the eyes. If it penetrates under the free edge of fingernails and toenails, excruciating pain results. Acute selenium poisoning produces central nervous system effects, which include nervousness, convulsions, and drowsiness. Other signs of intoxication can include skin eruptions, lassitude, gastrointestinal distress, teeth that are discolored or decayed, odorous ("garlic") breath, and partial loss of hair and nails. Chronic exposure by inhalation can produce symptoms that include pallor, coating of the tongue, anemia, irritation of the mucosa, lumbar pain, liver and spleen damage, as well as any of the other previously mentioned symptoms. Anemia. Dermatitis. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .130 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Organic materials, Strong acids, Ammonia. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 23/25 33 50/53 Risk Statements: Toxic by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 20/21 28 45 60 61 Safety Statements: When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .281 mg/m3 DOE Short Term Exposure Limit .843 mg/m3 DOE Ceiling Limit 1.4 mg/m3 Immediately Dangerous to Life and Health 1.4 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEMICARBAZIDE HYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 563417 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 725.8 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 20 mg/m3 DOE Short Term Exposure Limit 60 mg/m3 DOE Ceiling Limit 100 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHACRYL A B C D CAS # 82785748 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. TARGET ORGAN(S) OR SYSTEM(S) Damage to the heart. Nerves. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Can cause CNS depression. Exposure can cause: Nausea, headache, and vomiting. Narcotic effect. Damage to the heart. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 100.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Oxidizing agents, Peroxides, Acids, Acid chlorides, Acid anhydrides, Alkali metals, Ammonia. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. Store at 2-8°C US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHACRYL S-200 A B C D CAS # 65546954 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 n Sn Sn Sn Sn Sn Sn Sn Sn Sn S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 57.2 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE PROPERTIES STORAGE Store at 2-8°CSTORAGE Store at 2-8°CSTORAGE Store at 2-8°CSTORAGE Store at 2-8°CSTORAGE Store at 2-8°CSTORAGE Store at 2-8°CSTORAGE Store at 2-8°CSTORAGE Store at 2-8°CSTORAGE Store at 2-8°CSTORAGE Store at 2-8°C US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHADEX A B C D CAS # 11081406 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 F G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHADEX A B CAS # 9041365 Special Carcinogen Human Terato\Repro Haz E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . K L . . Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHADEX A B C D CAS # 9048719 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 Safety Statements: Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHADEX G-10 A B C D CAS # 9050684 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 Safety Statements: Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHADEX G-75 A B C D CAS # 37224296 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: appropriate foam. Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 Safety Statements: Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHADEX-SP C-25 A B C D CAS # 61840628 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHAROSE CL-2B A B C D CAS # 65099798 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ATURE OF DECOMPOSITION PRODUCTS NOT KNOWNHAZA The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHAROSE CL-4B A B C D CAS # 61970089 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHAROSE CL-6B A B C D CAS # 62610508 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7060.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . . skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 102.2 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEPHAROSE CM A B C D CAS # 68894075 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . . I . . . 0 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: Store at 2-8°C REACTIVE PROPERTIES STORAGE Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SERINE (DL-) A B C D CAS # 302841 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: oxide and nitrogen oxides HAZAR Store at 2-8°C Keep container closed. Keep away from heat, sparks, REACTIVE PROPERTIES HANDLING Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SERINE (L-) A B C D CAS # 56451 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SERINE METHYL ESTER HYDROCHLORIDE (D-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 5874577 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SERINE METHYL ESTER HYDROCHLORIDE (L-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 5680808 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at -20°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SERINOL A B C D CAS # 534032 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SEROTONIN A B C D CAS # 153980 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.7 - LD50 103.4 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Smooth muscle. Vascular system. Endocrine system. Liver. Damage to the heart. SIGNS AND SYMPTOMS OF EXPOSURE Can cause CNS depression. Exposure can cause: Nausea, headache, and vomiting. Narcotic effect. Damage to the heart. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SESAME OIL A B C D CAS # 8008740 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated HANDLING: Avoid inhalation. Avoid prolonged or repeated Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: Avoid contact with exposure. STORAGE: eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. eyes, skin, and clothing. Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SESAMOL A B C D CAS # 533313 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . C . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: Severe irritation or burns. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Damage to the eyes. SIGNS AND SYMPTOMS OF EXPOSURE Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Prolonged contact can cause: Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 onclothing. Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 3 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SHIKIMIC ACID A B C D CAS # 138590 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 F G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SIGMACOTE A B C D CAS # 28 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: S PRODUCT RAPIDLY HYDROLYZES TO FORM HYDROCHLORIC The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICA GEL A B C D CAS # 10279579 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be . irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure o destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and "sufficient evidence" of carcinogenicity by the NTP. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon dioxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICA GEL A B C D CAS # 112926008 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3160.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. . Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure o destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and "sufficient evidence" of carcinogenicity by the NTP. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon dioxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICA GEL A B C D CAS # 1343982 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3160.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure o destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and "sufficient evidence" of carcinogenicity by the NTP. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 10.0 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon dioxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICA GEL A B C D CAS # 63231674 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1.9 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure o destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and "sufficient evidence" of carcinogenicity by the NTP. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 10.0 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon dioxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICA GEL A B C D CAS # 7631869 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure o destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and "sufficient evidence" of carcinogenicity by the NTP. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon dioxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37 Risk Statements: Irritating to eyes and respiratory system. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Immediately Dangerous to Life and Health US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 3000 mg/m3 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICA GEL A B C D CAS # 9050946 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX ROUTE OF EXPOSURE I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . - LC50 . . skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure o destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and "sufficient evidence" of carcinogenicity by the NTP. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon dioxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 Safety Statements: Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICIC ACID A B C D CAS # 7699414 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA Eyes Rabbit 8.3 mg 48H PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): f - Inorganic Acid (Non-Oxidizing) WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Silicon oxide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37 Risk Statements: Irritating to eyes and respiratory system. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 10 mg/m3 DOE Ceiling Limit 75 mg/m3 Immediately Dangerous to Life and Health 400 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICIC ANHYDRIDE A B C D CAS # 112945525 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3160.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure or destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and "sufficient evidence" of carcinogenicity by the NTP. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Hydrogen fluoride, Oxidizing agents, Ammonia, Oxygen difluoride, Chlorine trifluoride, Strong acids, Exothermic in contact with water, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. FIREFIGHTIN Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. S TOXIC EMISSIONS WHEN BURNED: Silicon oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. Immediately Dangerous to Life and Health 3000 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 mg/m3 DOE Short Term Exposure Limit 6 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICOMOLYBDIC ACID A B C D CAS # 11104895 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ACGIH TLV-TWA: 10MG/M3, INSOLUBLE MOLYBDENUM COMPOUNDS AS (MO). MOLYBDENUM. ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): f - Inorganic Acid (Non-Oxidizing) WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: S NOT KNOWN The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICOMOLYBDIC ACID HYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 11089206 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICON A B C D CAS # 7440213 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3160.0 mg/Kg . . . INHALATION RISK INDEX 1.5 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE***** mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 250 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICON DIOXIDE A B C D CAS # 60676860 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 INHALATION HAZARD INHALATION RISK INDEX ROUTE OF EXPOSURE skin Contact: May cause skin irritation. I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J - LC50 K . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs, a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work. Advanced silicosis may result in death due to cardiac failure or destruction of lung tissue. Crystalline silica is classified as group 1 "known to be carcinogenic to humans" by IARC and "sufficient evidence" of carcinogenicity by the NTP. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Hydrogen fluoride, Oxidizing agents, Oxygen difluoride, Chlorine trifluoride, Ammonia, Acetylene. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICON NITRIDE A B C D CAS # 12033895 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Silicon oxide Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37 Risk Statements: Irritating to respiratory system. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICON TETRACHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 10026047 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C D . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 2 - LD50 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 . . 55477.6 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 222.2 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong bases, Potassium, Strong acids, Sodium, Alcohols Avoid contact with metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Silicon oxide Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Handle and store under nitrogen\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 14 36/37/38 Risk Statements: Reacts violently with water. Irritating to eyes, respiratory system and skin. S: 7/8 26 Safety Statements: Keep container tightly closed and dry. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .25 ppm DOE Short Term Exposure Limit .75 ppm DOE Ceiling Limit 5 ppm Immediately Dangerous to Life and Health 37 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICONE DIFFUSION PUMP OIL A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 3390612 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 214 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon oxide Formaldehyde REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICONE OIL A B C D CAS # 63148629 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX 1.7 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA skin Rabbit 0.5 ml 24H Remarks: Mild irritation effect Eyes Rabbit 0.1 ml 24H Remarks: Mild irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 3.7 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon dioxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 50 mg/m3 DOE Ceiling Limit 350 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICONE OIL, HIGH TEMPERATURE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 63148583 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. . Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 4.0 mm Hg @ 20 °C FLASH POINT 600 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 10 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILICOTUNGSTIC ACID HYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 11130204 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. . Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Very hygroscopic.HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Very hygroscopic.HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Very hygroscopic.HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Very hygroscopic.HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Very hygroscopic.HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Very hygroscopic. Very hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER A B C D CAS # 7440224 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 175.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. J K . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxygen, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silver/silver oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Air sensitive. Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .01 mg/m3 DOE Short Term Exposure Limit .3 mg/m3 DOE Ceiling Limit .5 mg/m3 Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER ACETATE A B C D CAS # 563633 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silver/silver oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER BENZOATE A B C D CAS # 532310 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARD INDEX . . . . NFPA HAZARD CODES (H,F,R,O) 0 Dermal Hazard Corrosive Eye Damage STEL . 0 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER BROMIDE A B C D CAS # 7785231 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE . May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Sodium, Potassium. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER CARBONATE A B C D CAS # 534167 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3731.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: A FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: Silver/silver oxides REACTIVE PROPERTIES HANDLING skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0128 mg/m3 DOE Short Term Exposure Limit .0383 mg/m3 DOE Ceiling Limit .0639 mg/m3 Immediately Dangerous to Life and Health 12.8 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER CHLORIDE A B C D CAS # 7783906 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. . Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0200 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under argon\. SPECIAL REQUIREMENTS Handle and store under inert gas. Light sensitive. Moisture sensitive. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0133 mg/m3 DOE Short Term Exposure Limit .0399 mg/m3 DOE Ceiling Limit .0664 mg/m3 Immediately Dangerous to Life and Health 13.3 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER CHROMATE A B C D CAS # 7784012 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 4 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 1 I J K L H OX Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K L Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Alcohols, Strong acids. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material\. SPECIAL REQUIREMENTS Light sensitive. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O T N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 49 8 43 50/53 Risk Statements: May cause cancer by inhalation. Contact with combustible material may cause fire. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 17 45 60 61 Safety Statements: Avoid exposure - obtain special instructions before use. Keep away from combustible material. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 15 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER CYANIDE A B C D CAS # 506649 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 123.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Blood. Liver. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE May cause blindness. Exposure can cause: Nausea, headache, and vomiting. Blood effects. Dizziness. Confusion. Heart palpitations. Unconsciousness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Aluminum. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen cyanide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 25 32 33 41 50/53 Risk Statements: Toxic if swallowed. Contact with acids liberates very toxic gas. Danger of cumulative effects. Risk of serious damage to eyes. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 7 26 45 60 61 Safety Statements: Keep container tightly closed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 25 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25.7 mg/m3 DOE Short Term Exposure Limit 25.7 mg/m3 DOE Ceiling Limit 25.7 mg/m3 Immediately Dangerous to Life and Health 129 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER LACTATE A B C D CAS # 128007 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 F G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure STORAGE: Keep container closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER NITRATE A B C D CAS # 7761888 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 3 0 1 OX ACUTE TOXICTY RISK INDEX 2.6 - LD50 1173.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Ingestion can cause severe gastroenteritis that may be fatal. Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Eyes. Nerves. Blood. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Alcohols, Ammonia, Magnesium, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silver/silver oxides Nitrogen oxides Oxygen REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C N Indication of Danger: Corrosive. Dangerous for the environment. R: 34 50/53 Risk Statements: Causes burns. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 60 45 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. This material and its container must be disposed of as hazardous waste. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0157 mg/m3 DOE Short Term Exposure Limit 15.7 mg/m3 DOE Ceiling Limit 15.7 mg/m3 Immediately Dangerous to Life and Health 15.7 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER NITRITE A B C D CAS # 7783995 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Smooth muscle. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Finely powdered metals, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silver/silver oxides Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xn N Indication of Danger: Oxidizing. Harmful. Dangerous for the environment. R: 8 22 36/38 50/53 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 45 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0143 mg/m3 DOE Short Term Exposure Limit .0428 mg/m3 DOE Ceiling Limit .0713 mg/m3 Immediately Dangerous to Life and Health 14.3 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER OXIDE A B C D CAS # 1301968 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong reducing agents, Finely powdered metals. FIRE EXTINGUISHER: Water spray. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Do not get in eyes, on skin, onclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER OXIDE A B C D CAS # 20667123 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX ACUTE TOXICTY RISK INDEX 2.2 - LD50 2820.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong reducing agents, Finely powdered metals. FIRE EXTINGUISHER: Water spray. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Do not get in eyes, on skin, onclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER PERCHLORATE A B C D CAS # 14242058 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 INHALATION RISK INDEX <1 - LC50 . . 1 . . . . . OX ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Organic materials, Finely powdered metals, Strong reducing agents, Alcohols. FIRE EXTINGUISHER: Water spray. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O C Indication of Danger: Oxidizing. Corrosive. R: 8 34 Risk Statements: Contact with combustible material may cause fire. Causes burns. S: 17 26 27 36/37/39 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER PERCHLORATE A B C D CAS # 7783939 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Organic materials, Finely powdered metals, Strong reducing agents, Alcohols. FIRE EXTINGUISHER: Water spray. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O C Indication of Danger: Oxidizing. Corrosive. R: 8 34 Risk Statements: Contact with combustible material may cause fire. Causes burns. S: 17 26 27 36/37/39 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER PROTEIN A B C D CAS # 9008428 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 172.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER STAIN A B C D CAS # 37604903 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 3 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . L 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Eyes. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): c - Inorganic Base/Oxidizer/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Alkalies, antimony salts, arsenites, bromides, carbonates, chlorides, iodides, thiocyanates, ferrous salts, hypophosphites, morphine salts, oils, creosote, phosphates, tannic acid, tartrates, vegetable extracts. TOXIC EMISSIONS WHEN BURNED: May emit highly toxic fumes of nitrogen oxides and metallic silver upon heating to decomposition or combustion Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 40 42/43 Risk Statements: Harmful if swallowed. Causes burns. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER SULFATE A B C D CAS # 10294265 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER TETRAFLUOROBORATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 14104202 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Handle and store under inert gas. Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 250 mg/m The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER TETRATUNGSTATE CAS # 13465935 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Chemical pneumonitis. May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SILVER TRIFLUOROMETHANESULFONATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 2923286 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Store under inert gas. Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SIMAZIN PESTANAL A B C D CAS # 122349 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 971.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.5 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Spleen. Adrenal gland. Blood. Thyroid. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE 8.1 mm Hg @ 20 °C FLASH POINT 212 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn-N Indication of Danger: Harmful. Dangerous for the environment. R: 40-50/53 Risk Statements: Limited evidence of a carcinogenic effect. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 46-36/37-60-61 Safety Statements: If swallowed, seek medical advice immediately and show this container or label. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SITOSTEROL (BETA-) A B C D CAS # 83465 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Long-term effects of beta-sitosterol are unknown. Adverse effects include anorexia, abdominal cramps, a mild laxative effect with occasional nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODA LIME A B C D CAS # 8006288 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Calcium oxide Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 35 Risk Statements: Causes severe burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM A B C D CAS # 7440235 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 INHALATION RISK INDEX <1 - LC50 . G 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable VAPOR PRESSURE .0500 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Use approved class D extinguishers or smother with drysand, dry ground limestone, or dry clay. Do not use water. Do not use carbon dioxide extinguisher on this material. TOXIC EMISSIONS WHEN BURNED: H REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Handle and store under inert gas. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 14/15 34 Risk Statements: Reacts violently with water, liberating extremely flammable gases. Causes burns. S: 8 43 45 Safety Statements: Keep container dry. In case of fire, use special powder for metal fire. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit .5 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ACETATE A B CAS # 127093 Special Carcinogen Human Terato\Repro Haz E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL K L Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3530.0 mg/Kg INHALATION RISK INDEX <1 - LC50 30000.0 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Abdominal pain, nausea, vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 480 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 40 mg/m3 DOE Ceiling Limit 300 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ACETATE TRIHYDRATE CAS # 6131904 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 40 mg/m3 DOE Ceiling Limit 300 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ACRYLATE A CAS # 7446813 Special Carcinogen E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . J K L . . Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Peroxides, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. Heat sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM AMMONIUM PHOSPHATE TETRAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 7783133 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Ammonia Phosphorous oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ARSENATE DIBASIC HEPTAHYDRATE HAZARDOUS CHEMICAL OF CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL CAS # 10048950 I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 INHALATION HAZARD INHALATION RISK INDEX . <1 . J K L - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: Causes dermatitis. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. G.I. System. Bladder. Lungs. Skin. CONDITIONS AGGRAVATED BY EXPOSURE Exposure to arsenic compounds can cause burning and dryness of the oral and nasal cavities, muscle spasms, irritation of the gastrointestinal tract, nausea, vomiting and diarrhea which can progress to shock and death. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Arsenic oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 45-23/25-50/53 Risk Statements: May cause cancer. Also toxic by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-60-45-61 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. This material and its container must be disposed of as hazardous waste. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 35 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM AZIDE CAS # 26628228 HAZARDOUS CHEMICAL OF CONCERN DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . C . E . . H I NFPA HAZARD CODES (H,F,R,O) 4 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5 - LD50 27.0 mg/Kg NEUROTOXIC - RISK INDEX 3.0 INHALATION RISK INDEX <1 - LC50 10.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be fatal if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be fatal if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Heart. Brain. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, headache, and vomiting. Laboratory experiments in animals have shown sodium azide to produce a profound hypotensive effect, demyelination of myelinated nerve fibers in the central nervous system, testicular damage, blindness, attacks of rigidity, and hepatic and cerebral effects. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Halogenated solvents Avoid contact with metals. Avoid contact with acid., Acid chlorides FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Reacts with protic solvents (water alcohols amines etc) to release toxichydrazoic acid Hazardous Decomposition Products Formed Upon Contact with Water: solvents (water alcohols amines etc) to rele Reacts with protic REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Azide reacts with many heavy metals such as lead, copper, mercury, silver, gold to form explosive compounds. Copper and lead azides are more sensitive than nitroglycerine. Azide reacts with metal halides to give a range of metal azide halides, many of which are explosive\. Incompatible with chromyl chloride, hydrazine, bromine, carbon disulfide, dimethyl sulfate, dibromomalonitrile\. SPECIAL REQUIREMENTS Heat sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+-N Indication of Danger: Very toxic. Dangerous for the environment. R: 28-32-50/53 Risk Statements: Very toxic if swallowed. Contact with acids liberates very toxic gas. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28-45-60-61 Safety Statements: After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Ceiling Limit .1 ppm OSHA Ceiling Limit .3 ppm ACGIH RECOMMENDED LIMITS ACGIH Ceiling Limit .029 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .29 mg/m3 DOE Short Term Exposure Limit .29 mg/m3 DOE Ceiling Limit .29 mg/m3 Immediately Dangerous to Life and Health 12.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BENZENESULFONATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 873552 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1200.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BICARBONATE A B C D CAS # 144558 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4220.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. . . . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Heavy or prolonged skin exposure may result in the absorption of harmful amounts of material. Gastrointestinal disturbances. Exposure to large amounts can cause: CONDITIONS AGGRAVATED BY EXPOSURE Alkalosis, an abnormal condition of increased alkalinity of the blood and tissues. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BICARBONATE A B C D CAS # 781321 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4220.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . . skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Heavy or prolonged skin exposure may result in the absorption of harmful amounts of material. Gastrointestinal disturbances. Exposure to large amounts can cause: CONDITIONS AGGRAVATED BY EXPOSURE Alkalosis, an abnormal condition of increased alkalinity of the blood and tissues. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BIS(TRIMETHYLSILYL)AMIDE CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 1070899 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . 2 HAZARDOUS CHEMICAL OF I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Explosive Forms explosive unstable peroxides Test periodically or discard Reacts violently with water SEGREGATION: SHELF # 3 STORAGE GROUP(S): b - Pyrophoric/Water Reactive k - Explosive/Unstable WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Silicon oxide Store at 2-8°C Handle and store under inert gas. Keep tightly closed. Store in a cool dry place. Incompatible Materials: Do not allow contact with wa REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Store at 2-8░C SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 14 Risk Statements: Causes burns. Reacts violently with water. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BISMUTHATE A B C D CAS # 12232994 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 420.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of chronic bismuth toxicity in humans consists of decreased appetite, weakness, rheumatic pain, diarrhea, fever, metal line on the gums, foul breathe, gingivitis, and dermatitis. Jaundice and conjunctival hemorrhage are rare, but have been reported. Bismuth nephropathy with proteinuria may occur. The kidney is the site of highest concentration with the liver being considerably lower. Bismuth does pass into the amniotic fluid and into the fetus. To the best of our knowledge, chemical, physical, and toxicological properties have not been thoroughly investigated. the PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium oxides Bismuth oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 35 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BISULFATE MONOHYDRATE CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 10034885 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARDOUS CHEMICAL OF I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2490.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Sodium oxide Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 41 Risk Statements: Risk of serious damage to eyes. S: 24-26 Safety Statements: Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2.5 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BISULFITE A B C D CAS # 7631905 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. Persons with allergies and/or asthma may exhibit hypersensitiveity to sulfites. Respiratory: Can cause pulmonary sensitization resulting in hyperactive airway dysfunction and pulmonary allergy accompanied by fatigue, malaise and aching. Significant symptoms of exposure can persist for more than two years and can be activated by a variety of nonspecific environmental stimuli such as automobile exhaust, perfumes and passive smoking. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Warning: certain individuals with preexisting respiratory conditions such as asthma may experience hypersensitiveity to sulfites and sulfur dioxide. The symptoms include bronchoconstriction, bronchospasm, gastrointestinal disturbances, flushing, hypotension, tingling sensation, urticaria/angioedema, and shock PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Sulfur oxidesHazardous Decomposition Products Formed Upon Contact with Water: Sulfur dioxide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-31 Risk Statements: Harmful if swallowed. Contact with acids liberates toxic gas. S: 25-46 Safety Statements: Avoid contact with eyes. If swallowed, seek medical advice immediately and show this container or label. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 25 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BORODEUTERIDE A B C D CAS # 15681897 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D E . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Acids, Alcohols. FIRE EXTINGUISHER: Use approved class D extinguishers or smother with drysand, dry ground limestone, or dry clay. Do not use water. TOXIC EMISSIONS WHEN BURNED: Borane/boron oxides Liberates flammable/explosive hydrogen gas REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under nitrogen\. Incompatible Materials: Avoid contact with acid\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T Indication of Danger: Highly Flammable. Toxic. R: 11 15 23/24/25 34 Risk Statements: Highly flammable. Contact with water liberates extremely flammable gases. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. S: 7/8 16 36/37/39 43 45 Safety Statements: Keep container tightly closed and dry. Keep away from sources of ignition - no smoking. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BOROHYDRIDE A B C D CAS # 16940662 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 3 3 ACUTE TOXICTY RISK INDEX 5 - LD50 INHALATION RISK INDEX <1 - LC50 . I J K L G . . 1 W 162.0 mg/Kg 36.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Chemically active metals, Oxidizing agents, Acids Reacts violently with water. FIRE EXTINGUISHER: Dry chemical powder. Do not use water, foam, or carbon dioxide. Do notuse halocarbon extinguishers. TOXIC EMISSIONS WHEN BURNED: Borane/boron oxides Sodium oxide Hydrogen gasHazardous Decomposition Products Formed Upon Contact with Water: Material readily reacts with water generating flammable and/or explosive hydrogen gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Sodium borohydride in dimethylformamide (DMF) will undergo runaway thermal reactions resulting in violent decompositions. An induction period is involved and it is temperature dependent, e.g., 45 hours at 62░C and 45 minutes at 90░C. The temperature can reach the autoignition temperature (190░C) of trimethylamine, the reaction byproduct. The addition of supported noble metal catalysts to solutions of sodium borohydride can result in ignition of liberated hydrogen gas. The reduction of ruthenium salts solutions with borohydride solutions to give the metal or an alloy gave solid products which were dried and subsequently exploded when disturbed by a spatula or on contact with water Special REQUIREMENTS Reacts violently with water. Heat sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T Indication of Danger: Highly Flammable. Toxic. R: 15 24/25 34 Risk Statements: Contact with water liberates extremely flammable gases. Toxic in contact with skin and if swallowed. Causes burns. S: 22 26 36/37/39 43 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry sand. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .075 mg/m3 DOE Short Term Exposure Limit .2 mg/m3 DOE Ceiling Limit 1.5 mg/m3 Immediately Dangerous to Life and Health 7.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BROMATE A CAS # 7789380 Special Carcinogen E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . J K L . 1 . Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Ears. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong reducing agents, Finely powdered metals, Alcohols, Strong acids. FIRE EXTINGUISHER: Water spray. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas Oxygen REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 8 22 36/37/38 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 17 26 36 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 12.5 mg/m3 Immediately Dangerous to Life and Health 60 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM BROMIDE A B C D CAS # 7647156 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Circulatory collapse. Bromide rashes, especially of the face, and resembling acne and furunculosis, often occur when bromide inhalation or administration is prolonged. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0200 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 35 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CARBONATE ANHYDROUS A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 497198 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4090.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 22-26 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CARBONATE MONOHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 5968116 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4090.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Aluminum. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 35 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CHLORATE CAS # 7775099 DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX ACUTE TOXICTY RISK INDEX 2.6 - LD50 1200.0 mg/Kg INHALATION RISK INDEX <1 - LC50 28000.0 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Blood. Liver. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms may be delayed. Dizziness. Coughing, chest pains, difficulty in breathing. Exposure can cause: Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Alcohols, Organic materials, Strong reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O-Xn-N Indication of Danger: Oxidizing. Harmful. Dangerous for the environment. R: 9-22-51/53 Risk Statements: Explosive when mixed with combustible material. Harmful if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 13-17-46-61 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Keep away from combustible material. If swallowed, seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .15 mg/m3 DOE Short Term Exposure Limit .4 mg/m3 DOE Ceiling Limit 3 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CHLORIDE A B C D CAS # 7647145 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 42000.0 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Sodium chloride (NaCl) in contact with eyes can cause irritation or redness due to abrasion. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Ingestion of large amounts causes vomiting and diarrhea. Dehydration and congestion may occur in internal organs. Hypertonic salt solutions can produce inflammatory reactions in the gastrointestinal tract. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0200 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 40 mg/m3 DOE Ceiling Limit 300 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CHLORODIFLUOROACETATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1895392 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CHROMATE A B C D CAS # 7775113 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . . H . J NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 5 - LD50 136.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K L 100.0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Severe eye irritant. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Kidneys. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 45 46 60 61 21 25 26 34 42/43 48/23 50/53 Risk Statements: May cause cancer. May cause heritable genetic damage. May impair fertility. May cause harm to the unborn child. Also harmful in contact with skin. Also toxic if swallowed. Also very toxic by inhalation. Causes burns. May cause sensitization by inhalation and skin contact. Also toxic: danger of serious damage to health by prolonged exposure through inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Ceiling Limit .1 ppm Immediately Dangerous to Life and Health 15 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0156 mg/m3 DOE Short Term Exposure Limit .125 mg/m3 DOE Ceiling Limit .75 mg/m3 Immediately Dangerous to Life and Health 46.7 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CHROMATE TETRAHYDRATE CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 10034829 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D E . . H NFPA HAZARD CODES (H,F,R,O) 3 0 1 OX INHALATION HAZARD INHALATION RISK INDEX <1 HAZARDOUS CHEMICAL OF I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE L To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Organic materials, Finely powdered metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 45 46 60 61 21 25 26 34 42/43 48/23 50/53 Risk Statements: May cause cancer. May cause heritable genetic damage. May impair fertility. May cause harm to the unborn child. Also harmful in contact with skin. Also toxic if swallowed. Also very toxic by inhalation. Causes burns. May cause sensitization by inhalation and skin contact. Also toxic: danger of serious damage to health by prolonged exposure through inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53 45 60 61 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 15 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0291 mg/m3 DOE Short Term Exposure Limit .873 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 87.4 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CITRATE DIHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6132043 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM COBALT(III) HEXANITRATE CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 13600981 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . 1 HAZARDOUS CHEMICAL OF I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L OX ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Damage to the liver. Lungs. Heart. Nerves. Blood. Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Repeated exposure can cause: Asthma. Lung irritation. Benign pneumoconiosis. Coughing, chest pains, difficulty in breathing. Damage to the liver. Neurotoxic effects. Gastrointestinal disturbances. Stomach pains, vomiting, diarrhea. Nausea, dizziness, and headache. Causes a fall in blood pressure. Convulsions. Cyanosis. Exposure to and/or consumption of alcohol may increase toxic effects. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Organic materials, Reducing agents, Amines. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sodium/sodium oxides Cobalt/cobalt oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 8 36/37/38 42/43 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. S: 17 26 36/37 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .125 mg/m3 DOE Short Term Exposure Limit .4 mg/m3 DOE Ceiling Limit 3 mg/m3 Immediately Dangerous to Life and Health 15 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CYANATE A B C D CAS # 917613 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1500.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Eye Contact: Causes eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 52/53 Risk Statements: Harmful if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 24/25 61 Safety Statements: Avoid contact with skin and eyes. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CYANIDE A B C D CAS # 143339 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C D E . . . I J NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.9 - LD50 6.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50 K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be fatal if absorbed through skin. Eye Contact: Causes burns. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Blood. Lungs. Cardiovascular system. Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Lung irritation. Cyanosis. CNS depression. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0200 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Avoid contact with acid., Strong oxidizing agents Carbon dioxide. FIRE EXTINGUISHER: appropriate foam. Do not use carbon dioxide extinguisher on thismaterial. TOXIC EMISSIONS WHEN BURNED: Hydrogen cyanide Nitrogen oxidesHazardous Decomposition Products Formed Upon Contact with Water: Hydrogen cyanide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 26/27/28 32 50/53 Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 7 28 29 45 60 61 Safety Statements: Keep container tightly closed. After contact with skin, wash immediately with plenty of soap-suds. Do not empty into drains. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 25 mg/m3 47.1 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM CYANOBOROHYDRIDE A B C D CAS # 25895607 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D E . G . NFPA HAZARD CODES (H,F,R,O) 4 3 1 W INHALATION HAZARD INHALATION RISK INDEX <1 I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be fatal if absorbed through skin. Eye Contact: Causes burns. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. May be fatal. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Avoid contact with acid., Oxidizing agents FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides Hydrogen cyanide Borane/boron oxidesHazardous Decomposition Products Formed Upon Contact with Water: Liberates flammable/explosive hydrogen gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid all contact. Open carefully. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS May develop pressure. Open carefully. Hygroscopic. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T+ N Indication of Danger: Highly Flammable. Very toxic. Dangerous for the environment. R: 11 26/27/28 32 34 50/53 Risk Statements: Highly flammable. Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Causes burns. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 28 36/37/39 45 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM DECANOATE A B C D CAS # 1002626 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM DEUTEROXIDE A B C D CAS # 14014063 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . 3 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Explosive Reacts violently with water Shock sensitive Explosive SEGREGATION: SHELF # 3 STORAGE GROUP(S): b - Pyrophoric/Water Reactive k - Explosive/Unstable WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents, Organic materials. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. Incompatible Materials: Absorbs carbon dioxide from air\. SPECIAL REQUIREMENTS Handle and store under inert gas. Air sensitive. Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 35 Risk Statements: Causes severe burns. S: 26 37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .15 mg/m3 DOE Short Term Exposure Limit .5 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM DICHROMATE DIHYDRATE A B Special Carcinogen Human Terato\Repro Haz CAS # 7789120 E F Dermal Hazard Corrosive HAZARDOUS CHEMICAL OF CONCERN I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL HAZARD INDEX . . . D E . G H NFPA HAZARD CODES (H,F,R,O) 3 0 1 OX INHALATION HAZARD INHALATION RISK INDEX <1 K L Suspect Terato\Repro Haz Sensitizers . J K L - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation of dichromate dusts can cause ulceration and perforation of the nasal septum. Contact with breaks in the skin can cause ulceration (chrome sores). Other symptoms of exposure include erosion and discoloration of the teeth, nephritis, epigastric pain (inflammation and ulceration of the gastrointestinal tract). Damage to the liver. Damage to the kidneys. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Alcohols, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O-T+-N Indication of Danger: Oxidizing. Very toxic. Dangerous for the environment. R: 45-46-60-61-8-21-25-26-34-42/43-48/23-50/53 Risk Statements: May cause cancer. May cause heritable genetic damage. May impair fertility. May cause harm to the unborn child. Contact with combustible material may cause fire. Also harmful in contact with skin. Also toxic if swallowed. Also very toxic by inhalation. Causes burns. May cause sensitization by inhalation and skin contact. Also toxic: danger of serious damage to health by prolonged exposure through inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-45-60-61 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 15 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0143 mg/m3 DOE Short Term Exposure Limit .43 mg/m3 DOE Ceiling Limit .716 mg/m3 Immediately Dangerous to Life and Health 43 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM DIHYDROGEN PHOSPHATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7558807 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8290.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Phosphorous oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 35 mg/m3 DOE Short Term Exposure Limit 100 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM DIHYDROGEN PYROPHOSPHATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 7758169 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8548.4 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM DITHIONITE A B C D CAS # 7775146 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 . 1 . W I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Acids, Strong oxidizing agents. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Avoid contact with acid\. SPECIAL REQUIREMENTS Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 7-22-31 Risk Statements: May cause fire. Harmful if swallowed. Contact with acids liberates toxic gas. S: 7/8-26-28-43 Safety Statements: Keep container tightly closed and dry. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds. In case of fire, use dry powder. Never use water. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ETHOXIDE A B C D CAS # 141526 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 3 2 1 W ACUTE TOXICTY RISK INDEX 2.4 - LD50 2037.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. . . . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Bladder. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable VAPOR PRESSURE .1000 mm Hg @ 20 °C FLASH POINT 86 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Acids, Chlorinated solvents, Water. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid prolonged or repeated exposure. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 14 34 Risk Statements: Highly flammable. Reacts violently with water. Causes burns. S: 8 16 26 43 45 Safety Statements: Keep container dry. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 DOE Short Term Exposure Limit 5 DOE Ceiling Limit 35 Immediately Dangerous to Life and Health 150 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ETHYLHEXYL SULFATE CAS # 126921 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM FERROCYANIDE DECAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 13601199 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents Avoid contact with acid. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen cyanide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Heat and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 32 Risk Statements: Irritating to eyes, respiratory system and skin. Contact with acids liberates very toxic gas. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Immediately Dangerous to Life and Health 25 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5.44 mg/m3 DOE Short Term Exposure Limit 16.3 mg/m3 DOE Ceiling Limit 27.2 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM FLUORIDE A B C D CAS # 7681494 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 REPRODUCTIVE RISK INDEX 2.9 ACUTE TOXICTY RISK INDEX 4 - LD50 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.9 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I J K . 0 52.0 mg/Kg ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. Kidneys. Bones. Nerves. G.I. System. Teeth. Damage to the lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of fluoride overexposure may include salivation, nausea, vomiting, abdominal pain, fever, and labored breathing. Fluoride ion can reduce serum calcium levels possibly causing fatal hypocalcemia. Prolonged exposure to fluoride dusts, vapors, or mists results in perforation of the nasal septum. Chronic effects include excessive calcification of the bones, ligaments, and tendons. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Stomach pains, vomiting, diarrhea. Prolonged exposure can cause: Damage to the lungs. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 1.4 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 32 36/38 Risk Statements: Toxic if swallowed. Contact with acids liberates very toxic gas. Irritating to eyes and skin. S: 22 36 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 250 mg/m US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5.53 mg/m3 DOE Short Term Exposure Limit 5.53 mg/m3 DOE Ceiling Limit 5.53 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM FLUOROBORATE A B C D CAS # 13755298 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. destructive SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Boron oxides Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 250 mg/m US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.61 mg/m3 DOE Short Term Exposure Limit 10.8 mg/m3 DOE Ceiling Limit 18.1 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM FORMALDEHYDE SULFOXYLATE DIHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 149440 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 50 mg/m3 DOE Ceiling Limit 350 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM FORMATE A B C D CAS # 141537 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.1 - LD50 36129.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. Other symptoms may include rash and itching. Eye contact may result in irritation or eye burns. Prolonged or repeated exposure to skin may cause irritation. Coughing, chest pains, difficulty in breathing. Asthmatic symptoms: cough, hoarseness, diarrhea. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam\. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits t REACTIVE PROPERTIES HANDLINGAvoid prolonged or repeated exposure. STORAGE: Keep tightly closed. SPECIAL REQUIREMENTS Moisture sensitive. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 40 mg/m3 DOE Short Term Exposure Limit 125 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM GLUCONATE A B C D CAS # 527071 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 2 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM GLYCEROPHOSPHATE A B C D CAS # 1555562 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE CARBON DIOXIDE, DRY CHEMICAL POWDER OR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM GLYCHOLATE HYDRATE CAS # 863570 A E Special Carcinogen Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . J K L . . Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HEXAFLUOROANTIMONATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 16925250 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. IRRITATION DATA Eyes PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 20/22 51/53 Risk Statements: Harmful by inhalation and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 61 Safety Statements: Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HEXAFLUOROARSENATE(V) CONCERN A B Special Carcinogen Human Terato\Repro Haz CAS # 12005866 E F Dermal Hazard Corrosive HAZARDOUS CHEMICAL OF I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL K L Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . . . . J NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 880.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K . cancer hazard ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) skin. Lungs. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Arsenic oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid all contact. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 23/25 50/53 Risk Statements: Toxic by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 20/21 28 45 60 61 Safety Statements: When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 35 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HEXAFLUOROPHOSPHATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 21324390 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 20/21/22 34 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HEXAFLUOROSILICATE CAS # 16893859 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . . . I J NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 125.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Acute effects: nausea, burning sensation, sores in the mouth, throat and digestive tract, tremors, convulsions, and shock occur around a dose of one gram. Death may result from ingestion of two to five grams. Long term exposure: may cause an increase in bone density, calcium deposits in the ligaments or stimulation of new bone growth. Exposure can cause: Stomach pains, vomiting, diarrhea. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Silicon oxide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. S: 26 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 250 mg/m US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4.12 mg/m3 DOE Short Term Exposure Limit 4.12 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HIPPURATE A B C D CAS # 532945 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HYDRIDE A B C D CAS # 7646697 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 INHALATION RISK INDEX <1 - LC50 . G 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 365 °F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Alcohols Carbon dioxide. FIRE EXTINGUISHER: Use approved class D extinguishers or smother with dry sand, dry ground limestone, or dry clay. Do not use water. Do not use carbon dioxide extinguisher on this material. Do not use halocarbon extinguishers. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Hydrogen gas Hazardous Decomposition Products Formed Upon Contact with Water: Hydrogen gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid prolonged or repeated exposure. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Handle and store under nitrogen\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 15 Risk Statements: Contact with water liberates extremely flammable gases. S: 7/8 24/25 43 Safety Statements: Keep container tightly closed and dry. Avoid contact with skin and eyes. In case of fire, use special powder for metal fire. Never use water. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 10 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HYDROGEN PHOSPHATE CAS # 7558794 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 17000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Phosphorous oxides Sodium oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 60 mg/m3 DOE Short Term Exposure Limit 200 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HYDROGEN SELENITE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7782823 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C D E . . . . J NFPA HAZARD CODES (H,F,R,O) 0 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4 - LD50 50.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K . ROUTE OF EXPOSURE Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Selenium/selenium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid all contact. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 23/25 33 50/53 Risk Statements: Toxic by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 20/21 28 45 60 61 Safety Statements: When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HYDROGEN SULFATE A B C D CAS # 7681381 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL . . . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 41 Risk Statements: Risk of serious damage to eyes. S: 24 26 Safety Statements: Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.25 mg/m3 DOE Short Term Exposure Limit 3.5 mg/m3 DOE Ceiling Limit 25 mg/m3 Immediately Dangerous to Life and Health 125 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HYDROGEN SULFIDE MONOHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 16721805 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . G NFPA HAZARD CODES (H,F,R,O) 3 2 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 194 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents Avoid contact with acid., Zinc, Aluminum, Copper, and their alloys FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen sulfide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 31 34 Risk Statements: Contact with acids liberates toxic gas. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .06 mg/m3 DOE Short Term Exposure Limit .15 mg/m3 DOE Ceiling Limit 1.25 mg/m3 Immediately Dangerous to Life and Health 6 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HYDROXIDE A B C D CAS # 1310732 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . I J K L H Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA skin Rabbit 500 mg 24 HR Remarks: Severe irritation effect Eyes Rabbit 0.5 mg 24 HR Remarks: Severe irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 18.0 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Water, Acids, Organic materials, Chlorinated solvents, Aluminum, Phosphorus, Tin/tin oxides, Zinc. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 35 Risk Statements: Causes severe burns. S: 26 37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 10 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit .5 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HYPOCHLORITE A B CAS # 7681529 Special Carcinogen Human Terato\Repro Haz E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL K L Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 18709.7 mg/Kg INHALATION RISK INDEX 1.8 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 17.5 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Organic materials, Finely powdered metals, Forms explosive mixtures with:, Amines Reacts violently with ammonium salts, aziridine, methanol, and phenylacetonitrile, sometimes resulting in explosions. Reacts with primary aliph FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Chlorine Store at 2-8°C Avoid contact with acid. Keep tightly closed. Incompatible Materials: Acids REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Incompatible Materials: Acids Store at 2-8░C SPECIAL REQUIREMENTS Avoid contact with acid. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 31 34 Risk Statements: Contact with acids liberates toxic gas. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 2 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM HYPOSULFITE A B C D CAS # 10102177 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Sodium nitrate, Strong oxidizing agents Incompatable with lead, silver and mercury salts, and iodines. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM IODATE A B C D CAS # 7681552 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 OX ACUTE TOXICTY RISK INDEX 2.5 - LD50 1629.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Blood. Bone marrow. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause nausea, vomiting, diarrhea, and skin rash. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Finely powdered metals Incompatibility: mixtures of iodates with finely divided aluminum, arsenic, copper, carbon, phosphorous (red or white) sulfur; hydrides of alkali and alkaline earth metals; sulfides of antimony, a FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Air, light, and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 8 22 42/43 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. May cause sensitization by inhalation and skin contact. S: 17 22 36/37 45 Safety Statements: Keep away from combustible material. Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 mg/m3 DOE Short Term Exposure Limit 6 mg/m3 DOE Ceiling Limit 40 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM IODIDE A B C D CAS # 7681825 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . B . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 3.3 ACUTE TOXICTY RISK INDEX 2 - LD50 4340.0 mg/Kg INHALATION RISK INDEX 1.4 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Blood. Bone marrow. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused across the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE***** mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents, Strong acids, Bromine trifluoride. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air, light, and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2.5 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM IODOACETATE A B C D CAS # 305533 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 267.7 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes severe skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25-41-37/38 Risk Statements: Toxic if swallowed. Risk of serious damage to eyes. Irritating to respiratory system and skin. S: 26-39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ISOPROPOXIDE A B C D CAS # 683603 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Do not mix with:, Strong oxidizing agents, Acids Dimethyl sulfoxide. (DMSO) FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION R: 34 Risk Statements: Causes burns. S: 26 27 28 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM LACTATE (L-) A B C D CAS # 867561 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM LAURYL SULFATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 151213 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 INHALATION RISK INDEX <1 - LC50 . I J K L G . . 0 438.0 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen sulfide gas REACTIVE PROPERTIES User Exposure: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22-36/37/38 Risk Statements: Harmful in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26-36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .35 mg/m3 DOE Short Term Exposure Limit 1 mg/m3 DOE Ceiling Limit 6 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM METAARSENITE A B C D CAS # 7784465 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . B C D E . . . I J NFPA HAZARD CODES (H,F,R,O) 3 0 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 5.3 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 41.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 . L cancer hazard ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Readily absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: May be fatal if swallowed. SENSITIZATION Sensitization: Causes dermatitis. TARGET ORGAN(S) OR SYSTEM(S) skin. Lungs. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Arsenic oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air sensitive. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T-N Indication of Danger: Toxic. Dangerous for the environment. R: 45-23/25-50/53 Risk Statements: May cause cancer. Also toxic by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 53-20/21-28-45-60-61 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 35 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0173 mg/m3 DOE Short Term Exposure Limit .075 mg/m3 DOE Ceiling Limit .6 mg/m3 Immediately Dangerous to Life and Health 8.67 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM METABISULFITE A B C D CAS # 7681574 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Coughing, chest pains, difficulty in breathing. Stomach pains, vomiting, diarrhea. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Warning: certain individuals with preexisting respiratory conditions such as asthma may experience hypersensitiveity to sulfites and sulfur dioxide. The symptoms include bronchoconstriction, bronchospasm, gastrointestinal disturbances, flushing, hypotension, tingling sensation, urticaria/angioedema, and shock PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 31 41 Risk Statements: Harmful if swallowed. Contact with acids liberates toxic gas. Risk of serious damage to eyes. S: 26 39 46 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. If swallowed, seek medical advice immediately and show this container or label. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 25 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM METAPERIODATE A B C D CAS # 7790285 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX ACUTE TOXICTY RISK INDEX 3.3 - LD50 264.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Organic materials, Forms explosive mixtures with:, Reducing agents, Finely powdered metals, Magnesium. FIRE EXTINGUISHER: Water spray. appropriate foam. TOXIC EMISSIONS WHEN BURNED: Iodine iodine oxides sodium oxide Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Light sensitive. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O-Xn Indication of Danger: Oxidizing. Harmful. R: 8-22-36/37/38 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .25 mg/m3 DOE Short Term Exposure Limit .75 mg/m3 DOE Ceiling Limit 5 mg/m3 Immediately Dangerous to Life and Health 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM METASILICATE A B C D CAS # 6834920 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1153.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Lead, Tin/tin oxides, Zinc, Aluminum. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Silicon oxide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34-37 Risk Statements: Causes burns. Irritating to respiratory system. S: 13-36/37/39-45 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 mg/m3 DOE Short Term Exposure Limit 12.5 mg/m3 DOE Ceiling Limit 75 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM METASILICATE NONAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 13517243 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1153.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes burns. Eye Contact: Causes burns. Lachrymator. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Lead, Tin/tin oxides, Zinc, FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: Silicon oxide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C R: 34 37 Risk Statements: Causes burns. Irritating to respiratory system. S: 13 36/37/39 45 Safety Statements: Keep away from food, drink, and animal eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 102 mg/m3 DOE Short Term Exposure Limit 306 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM METHOXIDE A B C D CAS # 124414 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . D HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL . F G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . NFPA HAZARD CODES (H,F,R,O) 3 4 2 W ACUTE TOXICTY RISK INDEX 2.8 - LD50 800.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.2 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Ears. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable VAPOR PRESSURE 50.0 mm Hg @ 20 °C FLASH POINT 91.4 °F Reacts violently in air Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC CORROSIVE INCOMPATIBILITIES:Water, Chlorinated solvents, Acids. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Handle and store under nitrogen\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F-C Indication of Danger: Highly Flammable. Corrosive. R: 11-14-34 Risk Statements: Highly flammable. Reacts violently with water. Causes burns. S: 8-16-26-43-45 Safety Statements: Keep container dry. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of fire, use special powder for metal fire. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM MOLYBDATE A B C D CAS # 7631950 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 4000.0 mg/Kg NEUROTOXIC - RISK INDEX 4.0 INHALATION RISK INDEX <1 - LC50 2080.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Molybdenum oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10.7 mg/m3 DOE Short Term Exposure Limit 10.7 mg/m3 DOE Ceiling Limit 10.7 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM NAPHTHALENESULFONATE (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 532025 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX ACUTE TOXICTY RISK INDEX 1.6 - LD50 13900.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE SPECIAL REQUIREMENTS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. Risk Statements: Toxic if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM NITRATE CAS # 7631994 DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX ACUTE TOXICTY RISK INDEX 2.6 - LD50 1267.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong reducing agents, Finely powdered metals, Strong acids, Organic materials. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 8 22 36/37/38 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 17 26 27 36/37/39 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .4 mg/m3 DOE Short Term Exposure Limit 1 mg/m3 DOE Ceiling Limit 7.5 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM NITRITE A B C D CAS # 1055243 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN HAZARD INDEX . B . . NFPA HAZARD CODES (H,F,R,O) 2 Dermal Hazard Corrosive Eye Damage STEL . F 1 G 1 I J K L . OX Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J . . HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 3.5 ACUTE TOXICTY RISK INDEX 5 - LD50 180.0 mg/Kg INHALATION RISK INDEX <1 - LC50 5.5 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Cardiovascular system. Smooth muscle. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure can cause: Headache. Nausea. Incoordination. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Finely powdered metals Avoid contact with acid., Ammonia, Cyanides, Amines, Activated carbon FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O T N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 8 25 50 Risk Statements: Contact with combustible material may cause fire. Toxic if swallowed. Very toxic to aquatic organisms S: 45 61 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM NITRITE A B C D CAS # 7632000 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . B . . . . . . I NFPA HAZARD CODES (H,F,R,O) 2 1 1 OX HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 3.5 ACUTE TOXICTY RISK INDEX 5 - LD50 180.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 5.5 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Cardiovascular system. Smooth muscle. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure can cause: Headache. Nausea. Incoordination. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Finely powdered metals Avoid contact with acid., Ammonia, Cyanides, Amines, Activated carbon FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O T N Indication of Danger: Oxidizing. Toxic. Dangerous for the environment. R: 8 25 50 Risk Statements: Contact with combustible material may cause fire. Toxic if swallowed. Very toxic to aquatic organisms S: 45 61 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .04 mg/m3 DOE Short Term Exposure Limit .125 mg/m3 DOE Ceiling Limit 1 mg/m3 Immediately Dangerous to Life and Health 60 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM NITROFERRICYANIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 13755389 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARDOUS CHEMICAL OF CONCERN I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.4 - LD50 20.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sodium/sodium oxides Hydrogen cyanide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ORTHOVANADATE (META-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 13718268 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 ACUTE TOXICTY RISK INDEX 3.7 - LD50 INHALATION RISK INDEX <1 - LC50 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . 98.0 mg/Kg ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Vanadium compounds can cause metallic taste and a greenish discoloration of the tongue. Exposure can cause coughing, respiratory distress, and diarrhea. Gastrointestinal disturbances. Tremors. Headache. wheezing, PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 mg/m3 DOE Short Term Exposure Limit .35 mg/m3 DOE Ceiling Limit 2 mg/m3 Immediately Dangerous to Life and Health 30 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM ORTHOVANADATE (ORTHO-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 13721396 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 330.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Vanadium compounds can cause metallic taste and a greenish discoloration of the tongue. Exposure can cause coughing, wheezing, respiratory distress, and diarrhea. Gastrointestinal disturbances. Tremors. Headache. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .182 mg/m3 DOE Short Term Exposure Limit .25 mg/m3 DOE Ceiling Limit 1.82 mg/m3 Immediately Dangerous to Life and Health 35.4 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM OXALATE A B C D CAS # 62760 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11160.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . . skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Nerves. Blood. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22 Risk Statements: Harmful in contact with skin and if swallowed. S: 24/25 Safety Statements: Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM OXIDE A B C D CAS # 1313593 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . G 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Reacts violently with water., Acids, Oxidizing agents FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fire conditions. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sodium oxide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PANTOTHENATE A B C D CAS # 867812 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 ROUTE OF EXPOSURE skin Contact: Prolonged or repeated exposure to skin causes defatting and dermatitis. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Damage to the heart. Nerves. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Can cause CNS depression. Prolonged exposure can cause: Nausea, headache, and vomiting. Narcotic effect. Damage to the heart. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Oxidizing agents, Acids, Acid anhydrides, Halogens, Aluminum. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Store at 2-8°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PENTAHYDRATE A B C D CAS # 6106076 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. Central nervous system. Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Ingestion of as little as 10 mg can cause thyrotoxicity. Symptoms may include: cardiac effects, nervous system disturbance, headache, sweating, fever, vomiting and weight loss. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PERBORATE MONOHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 10332339 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSUR To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong reducing agents, Heavy metal salts. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Boron oxides Oxygen REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Indication of Danger: Oxidizing. R: Risk Statements: Contact with combustible material may cause fire. S: 17 Safety Statements: Keep away from combustible material. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PERBORATE TETRAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 10486007 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Heavy metal salts. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Boron oxides Oxygen REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 8 22 36 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. Irritating to eyes. S: 17 26 36 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PERCARBONATE A B C D CAS # 15630894 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX ACUTE TOXICTY RISK INDEX 3 - LD50 1034.0 mg/Kg INHALATION RISK INDEX <1 - LC50 4580.0 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Will not occur SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Finely powdered metals, Organic materials, Strong acids, Strong reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Oxygen REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material\. Incompatible Materials: Moisture. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O-Xn Indication of Danger: Oxidizing. Harmful. R: 8-22-41 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. Risk of serious damage to eyes. S: 17-26-39 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PERCHLORATE A B C D CAS # 7601890 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 OX ACUTE TOXICTY RISK INDEX 2.4 - LD50 2100.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Blood. SIGNS AND SYMPTOMS OF EXPOSURE . Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Organic materials, Strong acids, Forms explosive mixtures with:, Finely powdered metals, Magnesium. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 9 22 Risk Statements: Explosive when mixed with combustible material. Harmful if swallowed. S: 13 22 27 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Do not breathe dust. Take off immediately all contaminated clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PERCHLORATE MONOHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 7791073 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 OX ACUTE TOXICTY RISK INDEX 2.4 - LD50 2100.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if inhaled or swallowed. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Blood. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Organic materials, Strong acids, Forms with:, Finely powdered metals, Reducing agents, FIRE EXTINGUISHER: Water spray. appropriate foam. explosive mixtures REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a dry area. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material\. SPECIAL REQUIREMENTS Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 9 22 Risk Statements: Explosive when mixed with combustible material. Harmful if swallowed. S: 13 22 27 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Do not breathe dust. Take off immediately all contaminated clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 100 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PEROXIDE A B C D CAS # 1313606 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 F G 1 I J K L . W,OX Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: Causes severe burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong reducing agents, Organic materials, Alcohols, Finely powdered metals. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. Do not use carbon dioxide extinguisher on this material. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: O C Indication of Danger: Oxidizing. Corrosive. R: 8 35 Risk Statements: Contact with combustible material may cause fire. Causes severe burns. S: 8 27 39 45 Safety Statements: Keep container dry. Take off immediately all contaminated clothing. Wear eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 10 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PERSULFATE A B C D CAS # 7775271 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 3 0 ACUTE TOXICTY RISK INDEX 3 - LD50 INHALATION RISK INDEX <1 - LC50 I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 OX 920.0 mg/Kg 5100.0 J K L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Alcohols, Strong reducing agents, Finely powdered metals, Strong bases, Avoid contact with organics. FIRE EXTINGUISHER: Water spray. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xn Indication of Danger: Oxidizing. Harmful. R: 8 22 42/43 Risk Statements: Contact with combustible material may cause fire. Harmful if swallowed. May cause sensitization by inhalation and skin contact. S: 16 17 22 26 36/37 45 Safety Statements: Keep away from sources of ignition - no smoking. Keep away from combustible material. Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 mg/m3 DOE Short Term Exposure Limit .3 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PHOSPHATE A B C D CAS # 7601549 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . C . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ACUTE TOXICTY RISK INDEX 4 - LD50 INHALATION RISK INDEX <1 - LC50 46.7 mg/Kg ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PHOSPHATE A B C D CAS # 7782856 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 12930.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 50 mg/m3 DOE Short Term Exposure Limit 150 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PHOSPHATE BASIC HYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 10049215 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8290.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 100 mg/m3 DOE Short Term Exposure Limit 300 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PHOSPHATE DIBASIC DODECAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 10039324 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8290.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 35 mg/m3 Immediately Dangerous to Life and Health 150 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PHOSPHATE MONOBASIC A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 13472350 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8290.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM POLYPHOSPHATE CAS # 50813166 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE A mild irritant to rabbit skin following a 24-hour exposure, but reported to produce strong irritation of the mucous membranes. If ingested, it is capable of seriously reducing the ionic serum calcium producing tetany, as well as a shock-like state, fall of blood pressure, slow pulse, cyanosis, and coma. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM POTASSIUM TARTRATE TETRAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 638595 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PYROPHOSPHATE DECAHYDRATE A Special Carcinogen E CAS # 13472361 Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL J K L Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM PYRUVATE A B C D CAS # 113246 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM SELENITE A B C D CAS # 10102188 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C D E . . . . J NFPA HAZARD CODES (H,F,R,O) 3 0 1 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.8 - LD50 7.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: May be fatal if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Eyes. Kidneys. Blood. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Anemia. Salivation. Tremors. Alopecia. Vomiting. Dermatitis. Nausea, dizziness, and headache. Exposure can cause: PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Selenium/selenium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+-N Indication of Danger: Very toxic. Dangerous for the environment. R: 23-28-31-43-51/53 Risk Statements: Toxic by inhalation. Very toxic if swallowed. Contact with acids liberates toxic gas. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28-36/37-45-61 Safety Statements: After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .438 mg/m3 DOE Short Term Exposure Limit 1.31 mg/m3 DOE Ceiling Limit 2.3 mg/m3 Immediately Dangerous to Life and Health 3 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM SESQUICARBONATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6106203 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. IRRITATION DATA Eyes Rabbit 100 mg 30S Remarks: Rinsed PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids cause material to decompose, producing dioxide. FIRE EXTINGUISHER: Noncombustible. carbon REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM STYRENESULFONATE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 2695376 HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: appropriate foam. Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM SULFATE A B C D CAS # 7757826 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 19319.4 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Aluminum, Magnesium. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM SULFATE DECAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7727733 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10325.9 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Aluminum, Magnesium. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM SULFIDE A B C D CAS # 1313822 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 208.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE If ingested, contact with stomach acids can liberate toxi hydrogen sulfide gas. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents, Copper, Zinc. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Sodium/sodium oxides Hydrogen sulfide gas Store at 2-8°C Hygroscopic. Air and light sensitive. Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C SPECIAL REQUIREMENTS Hygroscopic. Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C N Indication of Danger: Corrosive. Dangerous for the environment. R: 31 34 50 Risk Statements: Contact with acids liberates toxic gas. Causes burns. Very toxic to aquatic organisms. S: 26 61 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Avoid release to the environment. Refer to special instructions/safety data sheets. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2.5 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM SULFIDE A B C D CAS # 1313844 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 208.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE If ingested, contact with stomach acids can liberate toxi hydrogen sulfide gas. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents, Copper, Zinc. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Sodium/sodium oxides Hydrogen sulfide gas Store at 2-8°C Keep tightly closed. Hygroscopic. Air and light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C SPECIAL REQUIREMENTS Hygroscopic. Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C N Indication of Danger: Corrosive. Dangerous for the environment. R: 31 34 50 Risk Statements: Contact with acids liberates toxic gas. Causes burns. Very toxic to aquatic organisms. S: 26 61 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Avoid release to the environment. Refer to special instructions/safety data sheets. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .2 mg/m3 DOE Short Term Exposure Limit .6 mg/m3 DOE Ceiling Limit 4 mg/m3 Immediately Dangerous to Life and Health 20 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM SULFITE A B C D CAS # 7757837 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 2645.2 mg/Kg INHALATION RISK INDEX <1 - LC50 5500.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Ingestion results in irritation of the gastrointestinal tract. Large doses may cause violent colic and diarrhea, circulatory disturbances, central nervous depression, and even death. Persons with allergies and/or asthma may exhibit hypersensitiveity to sulfites. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION R: 31 Risk Statements: Contact with acids liberates toxic gas. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TARTRATE A B C D CAS # 526943 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 14064.5 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAG Suitable: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 50 mg/m3 DOE Ceiling Limit 400 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TARTRATE DIHYDRATE CAS # 6106247 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 100 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TAURODEOXYCHOLATE HYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 207737971 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TERT-BUTOXIDE A B C D CAS # 865485 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 INHALATION RISK INDEX <1 - LC50 . . 1 . W,OX I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water Oxidizing Agent SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive e - Oxidizer/Organic Peroxide l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Reducing agents, Oxygen, Water, Alcohols, Chlorinated solvents, Halogens. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 14 34 37 Risk Statements: Highly flammable. Reacts violently with water. Causes burns. Irritating to respiratory system. S: 7/8 26 36/37/39 43 45 Safety Statements: Keep container tightly closed and dry. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TETRABORATE DECAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 1303964 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2660.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Animal feeding studies in rat, mouse and dog, at high doses, have demonstrated effects on fertility and testes. Studies with the chemically related boric acid in the rat, mouse and rabbit, at high doses, demonstrate developmental effects on the fetus, including fetal weight loss and minor skeletal variations. The doses administered were many times in excess of those to which humans would normally be exposed. Human epidemiological studies show no increase in pulmonary disease in occupational populations with cronic exposures to boric acid dust and sodium borate dust. A recent epidemiological study under the conditions of normal occupational eposure to borate dusts indicated no effect on fertility. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Boron oxides Sodium oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 mg/m3 DOE Short Term Exposure Limit 6 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TETRADECYL SULFATE CAS # 1191500 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. S: 26 27 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TETRAETHYLBORATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 15523247 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 4 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 2 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently in air SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Boron oxides REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Very hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM THIOCYANATE A B C D CAS # 540727 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 764.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Thyroid. Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Nausea, headache, and vomiting. Exposure can cause: mucous PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22-32-52/53 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 13-61 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 25 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .25 mg/m3 DOE Short Term Exposure Limit .75 mg/m3 DOE Ceiling Limit 6 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM THIOMETHOXIDE A B C D CAS # 5188078 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 INHALATION RISK INDEX <1 - LC50 . G 1 I J K L . W Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids. FIRE EXTINGUISHER: Use approved class D extinguishers or smother with dry sand, dry ground limestone, or dry clay. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Moisture sensitive. Avoid contact with acid. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 31 34 Risk Statements: Contact with acids liberates toxic gas. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM THIOPHENOXIDE A B C D CAS # 930698 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D . . G NFPA HAZARD CODES (H,F,R,O) 3 0 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. TOXIC EMISSIONS WHEN BURNED: Hydrogen sulfide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air sensitive. Moisture sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM THIOSULFATE A B C D CAS # 7772987 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: NONCOMBUSTIBLE. SURROUNDING FIRE CONDITIONS. USE EXTINGUISHING MEDIA APPROPRIATE TO REACTIVE PROPERTIES INCOMPATABLE WITH LEAD, SILVER AND MERCURY SALTS, AND IODINES. A SODIUMNITRITE AND SODIUM THIOSULFATE MIXTURE EXPLODED WHEN HEATED TO DRYNESS. EXPLOSIONS OCCUR WHEN POTASSIUM SULFATE AND SODIUM SULFATE ARE MELTED WITHALUMINUM AND ALSO WHEN BARIUM SULFATE AND CALCIUM SULFATE ARE REDUCED BYALUMINUM. EXPLOSIVE WHEN MIXED WITH MAGNESIUM. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TIN OXIDE A B C D CAS # 12209982 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3457.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: Tin/tin oxidesROUTE OF EXPOSURE REACTIVE PROPERTIES HANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TRIACETOXYBOROHYDRIDE CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 56553607 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . W HAZARDOUS CHEMICAL OF Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Water, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Boron oxides REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 15 Risk Statements: Contact with water liberates extremely flammable gases. S: 7/8-43 Safety Statements: Keep container tightly closed and dry. In case of fire, use dry chemical. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TRIFLUOROACETATE A Special Carcinogen CAS # 2923184 E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . J K L . . Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TRIFLUOROMETHANESULFONATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 2926309 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TRIMETHOXYBOROHYDRIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 16940173 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Borane/boron oxides Carbon monoxide REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-Xi Indication of Danger: Highly Flammable. Irritant. R: 11-15-36/37/38 Risk Statements: Highly flammable. Contact with water liberates extremely flammable gases. Irritating to eyes, respiratory system and skin. S: 16-26-33-36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SODIUM TUNGSTATE DIHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 10213102 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 1 ACUTE TOXICTY RISK INDEX 3 - LD50 1453.0 mg/Kg INHALATION RISK INDEX <1 - LC50 5010.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Will not occur SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Guinea pigs treated orally or intravenously with sodium tungstate dihydrate suffered from anorexia, colic, incoordination of movement, trembling and dyspnea. Animals suffered a weight loss before a delayed death. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Tungsten oxide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.79 mg/m3 DOE Short Term Exposure Limit 5.38 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SOLVENT GREEN 3 A B C D CAS # 128803 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3660.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SOMATOTROPIN A B C D CAS # 9002726 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Promotes skeletal, visceral, and general body growth, stimulates protein anabolism, and affects fat and mineral metabolism. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SORBITAN MOMOLAURATE A B C D CAS # 1338392 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 1.2 - LD50 33600.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 350 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SORBITAN OLEATE A B C D CAS # 1338438 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA skin Rabbit Remarks: Mild irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 253.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: appropriate foam. REACTIVE PROPERTIES HANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 250 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SORBITAN TRIOLEATE A B C D CAS # 26266580 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA skin Rabbit 1.25 mg Remarks: Moderate irritation effect Eyes Rabbit 2.5 mg Remarks: Mild irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 38 Risk Statements: Irritating to skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 50 mg/m3 DOE Ceiling Limit 350 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SORBITOL A B C D CAS # 50704 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 15900.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE through skin. Causes irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0800 mm Hg @ 20 °C . SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: us Polymerization: Will not occur REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid all contact. STORAGE: Keep tightly closed. Store in a cool dry place. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 40 mg/m3 DOE Short Term Exposure Limit 125 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SORBOSE (L-) A B C D CAS # 87796 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 15900.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0734 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SOY PROTEIN ACID HYDROLYSATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 35 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. CARBON DIOXIDE, DRY CHEMICAL POWDER OR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SOY PROTEIN HYDROLYSATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 000036 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPARTEINE SULFATE A B C D CAS # 6160129 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. TARGET ORGAN(S) OR SYSTEM(S) Uterus. Peripheral nervous system. Autonomic nervous system. Heart. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPEARMINT OIL A B C D CAS # 8008795 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Dermatitis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 201.2 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPECTINOMYCIN A B C D CAS # 22189328 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPECTINOMYCIN DIHYDROCHLORIDE PENTAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 21736834 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas.HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS Store under inert gas\. Store under inert gas. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPERMIDINE A B C D CAS # 124209 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 INHALATION RISK INDEX <1 - LC50 F G 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 233.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Store under inert gas. Air sensitive. Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPERMIDINE TRIHYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 334509 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPERMINE A B C D CAS # 71443 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARD INDEX . . . . NFPA HAZARD CODES (H,F,R,O) 3 Dermal Hazard Corrosive Eye Damage STEL . . 1 G 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 230 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Store at 2-8°C Keep tightly closed. Store under nitrogen. Oxidizing agents. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPERMINE TETRAHYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 306672 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SPHINGOSINE (D-) A B C D CAS # 123784 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SQUALENE (TRANS-) A B C D CAS # 111024 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 16129.0 mg/Kg INHALATION RISK INDEX 1.2 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 2.0 mm Hg @ 20 °C FLASH POINT 230 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 20 mg/m3 DOE Short Term Exposure Limit 60 mg/m3 DOE Ceiling Limit 400 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STACHYOSE A B C D CAS # 10094583 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STAINS-ALL A B CAS # 7423316 Special Carcinogen Human Terato\Repro Haz E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . K L . . Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen bromide gas Store at 2-8°C Light sensitive. Keep container closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Use protective clothing, gloves, and mask. Avoid breathing dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place\. Store at 2-8°C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 24/25 Safety Statements: Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STANNIC CHLORIDE PENTAHYDRATE A B C Special Carcinogen Human Terato\Repro Haz Highly Toxic CAS # 10026069 E F G Dermal Hazard Corrosive Eye Damage I J K Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz D Inhalation Hazard H STEL L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 ACUTE TOXICTY RISK INDEX 3.5 - LD50 166.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Sensitizers J K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inorganic tin salts are poorly absorbed into the body. When parenterally administered tin salts are highly toxic. Tin oxide inhaled as a dust or fume leads to a benign pneumoconiosis with no sign of interference with pulmonary function. Deposited dust appears nodular with the particles being mostly extracelluar. No necrosis, foreign-body giant-cell reaction, or collagen formation has been seen. Tin salts that have gained access to the blood stream are highly toxic and produce neurologic damage and paralysis. With most common tin salts, the toxicity profile is complicated by hydrolysis in body fluids producing unphysiologic pH values. The reported symptoms of hyperemia, vascular changes with bleeding in the central nervous system, liver, heart, and other organs may be due to tin itself or to the unphysiological pH changes. Ingestion produces vomiting due to the gastric irritation from the activity and astringency of tin compounds. Injection of inorganic tin salts produces diarrhea, muscle paralysis, and twitching. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Tin/tin oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 100 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STANNOUS CHLORIDE A B C D CAS # 7772998 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 700.0 mg/Kg NEUROTOXIC - RISK INDEX 3.0 INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Potassium, Hydrogen peroxide, Bromine trifluoride, Hydrazine, Halides, Strong reducing agents, calcium acetylide, Strong bases, Strong oxidizing agents, Sodium. FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Tin/tin oxides HAZARDOUS EXOTHERMIC REACTIONS Conditions of Hazardous Exothermic Reactions: Exothermic in contact with water REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen. Unsuitable: Mixing with water results in generation of heat Moisture\. SPECIAL REQUIREMENTS Moisture sensitive. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22-34 Risk Statements: Harmful if swallowed. Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.19 mg/m3 DOE Short Term Exposure Limit 9.58 mg/m3 DOE Ceiling Limit 16 mg/m3 Immediately Dangerous to Life and Health 160 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STANNOUS CHLORIDE DIHYDRATE A Special Carcinogen CAS # 10025691 E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL J K L Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 700.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Can cause blindness. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Bones. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. On contact with moist skin, muccous membranes or atmospheric moisture, this material reacts to form hydrochloric acid which may contribute to it's toxicity. Long-term inhalation of high concentrations of inorganic tin compounds can result in stannosis, a benign dust-induced lung condition, generally without symptoms of interference with lung function. If swallowed, this material may cause mild to severe burns to the mouth, throat and digestive tract, difficulty in swallowing, nausea and vomiting, followed by diarrhea and respiratory distress. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Sodium, Potassium, Hydrogen peroxide, Strong bases, Strong oxidizing agents Incompatability: vigorous reaction occurs on mixing with bromine trifluoride, calcium carbide, hydrazine hydrate, ethylene oxide, metal or organic nitrates. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Tin/tin oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Store under inert gas. Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Air and moisture sensitive. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 100 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 3.8 mg/m3 DOE Short Term Exposure Limit 11.4 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 190 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STARCH A B C D CAS # 9005258 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The nuisance dust may be an allergen and a mild irritant. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STARCH (ALPHA-) A B C D CAS # 9005849 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The nuisance dust may be an allergen and a mild irritant. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STAUROSPORINE A B C D CAS # 62996741 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 2 1 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Target organ: heart because methylene chloride is converted to carbon monoxide in the body. Target organ: central nervous system because of possible dizziness, headache, loss of consciousness and death at high concentrations. Liver. Pancreas. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Dichloromethane is metabolized in the body producing carbon monoxide which increases and sustains carboxyhemoglobin levels in the blood, reducing the oxygen-carrying capacity of the blood. A simple asphyxiant, exposure can cause anesthetic action, difficulty in breathing, headache, and dizziness. Prolonged or repeated contact with skin can cause defatting and dermatitis. Contact with eyes can cause redness, tearing, and blurred vision. Ingestion may cause gastrointestinal irritation. CNS depression. Paresthesia. Somnolence. Convulsions. Conjunctivitis. Pulmonary edema. Effects may be delayed. Irregular breathing. CONDITIONS AGGRAVATED BY EXPOSURE Existing data suggests that methylene chloride may be a weak mutagen in mammalian systems. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Aluminum, Alkali metals, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. TOXIC EMISSIONS WHEN BURNED: Phosgene gasHydrogen chloride gas Store at 2-8°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 40 Risk Statements: Limited evidence of a carcinogenic effect. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STEARIC ACID A B C CAS # 57114 Special Carcinogen Human Terato\Repro Haz Highly Toxic E F G Dermal Hazard Corrosive Eye Damage I J K Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .120 mm Hg @ 20 °C FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 38 Risk Statements: Irritating to skin. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 60 mg/m3 DOE Short Term Exposure Limit 150 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STEARIC ACID ANHYDRIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 638084 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STEARIC ACID BUTYL ESTER A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 123955 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 1.2 - LD50 32000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 320 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STILBENE (CIS-) A B C D CAS # 645498 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Store at 2-8°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STILBENE (TRANS-) A B C D CAS # 103300 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 ACUTE TOXICTY RISK INDEX 2.8 - LD50 802.7 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 22 36 43 51/53 Risk Statements: Harmful if swallowed. Irritating to eyes. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 36/37 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STODDARD SOLVENT A B C D CAS # 8052413 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . . H . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 . . PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT. Immediately Dangerous to Life and Health 20000 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 500 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STREPTAVIDIN A B C D CAS # 9013201 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.STORAGE: Keep tightly closed\. Store at -20°C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STREPTOLYSIN A B C D O CAS # 98072470 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 4 0 INHALATION RISK INDEX <1 - LC50 . . . . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE May be fatal if enters bloodstream. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Do not use if skin is cut or scratched. Wash thoroughly after handling. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: B Indication of Danger: Biohazard. Risk Statements: Possible biohazardous material. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STREPTOMYCIN SULFATE CAS # 3810740 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 640.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) SIGNS AND SYMPTOMS OF EXPOSURE Aminoglycosides are associated with significant nephrotoxicity and/or ototoxicity. To the best of our knowledge, the chemical, investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM CARBONATE A B C D CAS # 1633052 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin andclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 20 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 20 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM CHLORIDE A B C CAS # 10476854 Special Carcinogen Human Terato\Repro Haz Highly Toxic E F G Dermal Hazard Corrosive Eye Damage I J K Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2250.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Strontium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38-41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26-39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM CHLORIDE HEXAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 10025704 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2250.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Stomach pains, vomiting, diarrhea. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Strontium oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 41 Risk Statements: Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM HYDROXIDE A B C D CAS # 1311100 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Dry chemical powder. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAG Suitable: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM HYDROXIDE A B C D CAS # 18480074 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Dry chemical powder. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAG Suitable: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit .75 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM NITRATE A B C D CAS # 100042769 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Heart. Liver. Kidneys. Spleen. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 36/37/39 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM NITRATE A B C D CAS # 10042769 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX ACUTE TOXICTY RISK INDEX 2.2 - LD50 2750.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Heart. Liver. Kidneys. Spleen. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 36/37/39 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 250 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM OXALATE A B C D CAS # 814959 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Ingestion may cause severe gastroenteritis with vomiting, diarrhea, and melena. Renal damage can result. To the best of our knowledge, the chemical, physical, and toxicological PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Oxalic acid Strontium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22 Risk Statements: Harmful in contact with skin and if swallowed. S: 24/25 Safety Statements: Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 60 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STRONTIUM PERCHLORATE HYDRATE A Special Carcinogen CAS # 13450970 E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL HAZARD INDEX . . . D . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX INHALATION HAZARD INHALATION RISK INDEX <1 J K L Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Cyanosis. Seizures. Coma. Exposure can cause renal failure. Nausea, vomiting, diarrhea. IRRITATION DATA Eyes PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Finely powdered metals, Organic materials. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Carbon monoxide Strontium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O-T Indication of Danger: Oxidizing. Toxic. R: 8-23/25-36/38 Risk Statements: Contact with combustible material may cause fire. Toxic by inhalation and if swallowed. Irritating to eyes and skin. S: 26-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STYRENE A B C D CAS # 100425 HAZARDOUS CHEMICAL OF CONCERN Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A . . . . . G H I . NFPA HAZARD CODES (H,F,R,O) 2 3 2 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.3 - TD50 23.3 mg/Kg REPRODUCTIVE RISK INDEX 1.3 ACUTE TOXICTY RISK INDEX 3 - LD50 2650.0 mg/Kg NEUROTOXIC - RISK INDEX 4.0 INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 2945.0 K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Lachrymator. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Blood. Lymphatic system. Endocrine system. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Dermatitis. CNS depression. Nausea, dizziness, and headache. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable Explosive VAPOR PRESSURE 5.7 mm Hg @ 20 °C FLASH POINT 89.6 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback Forms explosive unstable peroxides Test periodically or discard SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Oxidizing agents Copper, Copper alloys. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. Store at 2-8°C Light sensitive. Keep tightly closed. Keep away from heat, sparks, and open flame. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store at 2-8░C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 10 20 36/38 Risk Statements: Flammable. Harmful by inhalation. Irritating to eyes and skin. S: 23 Safety Statements: Do not breathe vapor. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 50 ppm OSHA Short Term Exposure Limit 100 ppm OSHA Ceiling Limit 200 ppm Immediately Dangerous to Life and Health 700 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 20 ppm DOE Short Term Exposure Limit 20 ppm DOE Ceiling Limit 130 ppm Immediately Dangerous to Life and Health 1100 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STYRENE OXIDE A B C D CAS # 20780534 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Lachrymator. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. SIGNS AND SYMPTOMS OF EXPOSURE CNS depression. Exposure can cause: Nausea, headache, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 176 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45-21-36 Risk Statements: May cause cancer. Also harmful in contact with skin. Irritating to eyes. S: 53-45 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STYRENE OXIDE A B C D CAS # 96093 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . B . . . . G . I NFPA HAZARD CODES (H,F,R,O) 1 2 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 3.4 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 J . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Lachrymator. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. SIGNS AND SYMPTOMS OF EXPOSURE CNS depression. Exposure can cause: Nausea, headache, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 176 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45-21-36 Risk Statements: May cause cancer. Also harmful in contact with skin. Irritating to eyes. S: 53-45 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 ppm DOE Short Term Exposure Limit 12.5 ppm DOE Ceiling Limit 50 ppm Immediately Dangerous to Life and Health 50 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STYRENESULFONYL CHLORIDE (TRANS,BETA-) OF CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 52147974 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . HAZARDOUS CHEMICAL Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. STYRYLACETIC ACID (TRANS-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1914585 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUBERIC ACID A B C D CAS # 505486 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 410 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUBTILISIN A B C D CAS # 9014011 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Severe eye irritant. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. Store under nitrogen. Store under inert gas.Hygroscopic . REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen. Store at -20░C SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 37/38 41 42 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. May cause sensitization by inhalation. S: 22 24 26 36/37/39 Safety Statements: Do not breathe dust. Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCCINIC ACID A B C D CAS # 110156 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2260.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38 41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCCINIC ACID DISODIUM HEXAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 6106214 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 35 mg/m3 DOE Short Term Exposure Limit 100 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCCINIC ANHYDRIDE A B C D CAS # 108305 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 2.7 - LD50 888.2 mg/Kg INHALATION RISK INDEX 1.4 - LC50 J K L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .220 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Alcohols, Amines. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37 Risk Statements: Irritating to eyes and respiratory system. S: 25 Safety Statements: Avoid contact with eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCCINIC DIMETHYLHYDRAZIDE (2,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 1596845 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . I J K L . . I 0 432.9 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCCINIMIDE A B C D CAS # 123568 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 14000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .000300 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Acids, Bases, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCCINIMIDYLTETRAMETHYLURONIUM TETRAFLUOROBORATE ( A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . CAS # 105832380 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Borane/boron oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCCINONITRILE A B C D CAS # 110612 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 ACUTE TOXICTY RISK INDEX 3 - LD50 NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 2.3 - LC50 F I J K L G . I 0 450.0 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Eyes. Skin. Central nervous system. Cardiovascular system. Respiratory system. SIGNS AND SYMPTOMS OF EXPOSURE Exposure may cause: Convulsions. Blurred vision. Nausea, abdominal pain, diarrhea, itching, dizziness, and headache. Vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE 2.0 mm Hg @ 20 °C FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong acids, Strong bases, Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 45 26 36/37 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. Immediately Dangerous to Life and Health 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCCINYL DICHLORIDE A B C D CAS # 543204 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 INHALATION RISK INDEX <1 - LC50 . G 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .253 mm Hg @ 20 °C FLASH POINT 168.8 °F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Water, Alcohols, Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Phosgene gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14-34 Risk Statements: Reacts violently with water. Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCROSE (D-) A B C D CAS # 57501 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.2 - LD50 29700.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUCROSE OCTAACETATE (D(+)-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 126147 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUDAN BLACK B A B C D CAS # 4197255 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUDAN I A B C D CAS # 842079 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A . C . E . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.2 - TD50 29.4 mg/Kg EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION RISK INDEX <1 - LC50 K L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 40 43 53 68 Risk Statements: Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. May cause long-term adverse effects in the aquatic environment. Possible risk of irreversible effects. S: 22 36/37 46 61 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. If swallowed, seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUDAN III A B C D CAS # 85869 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUDAN IV A B C D CAS # 85836 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Stomach pains, vomiting, diarrhea. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUDAN RED B A B C D CAS # 3176792 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFADIAZINE A B C D CAS # 68359 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4838.7 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 42/43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFAMERAZINE A B C D CAS # 127797 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.3 - LD50 25000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic TARGET ORGAN(S) OR SYSTEM(S) Blood. Adverse effects may include nausea, vomiting, diarrhea, headache, dizziness, rashes and cyanosis. CONDITIONS AGGRAVATED BY EXPOSURE PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .010000 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFAMERAZINE SODIUM A B C D CAS # 127582 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4830.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . L ROUTE OF EXPOSURE skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Blood. CONDITIONS AGGRAVATED BY EXPOSURE toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFAMIC ACID A B C D CAS # 5329146 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3160.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): f - Inorganic Acid (Non-Oxidizing) WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 52/53 Risk Statements: Irritating to eyes and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 28 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap-suds. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 12.5 mg/m3 DOE Short Term Exposure Limit 40 mg/m3 DOE Ceiling Limit 250 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFAMIDE A B C D CAS # 7803589 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFANILAMIDE A B C D CAS # 63741 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3900.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 mg/m3 DOE Short Term Exposure Limit 3 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFANILIC ACID A B C D CAS # 121573 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E F G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 12300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 43 Risk Statements: Irritating to eyes and skin. May cause sensitization by skin contact. S: 24 37 Safety Statements: Avoid contact with skin. Wear suitable gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 50 mg/m3 DOE Short Term Exposure Limit 150 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFANILIC ACID SODIUM SALT HYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 123333700 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFAPYRIDINE A B C D CAS # 144832 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 15800.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE . Exposure to sulfonamides can cause nausea, vomiting, drug fever, and reactions involving the blood, bone marrow, kidney, liver, skin, and peripheral nerves. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFATASE A B C D CAS # 9016175 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fire conditions. Store at -20°C Keep container closed. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFISOXAZOLE A B C D CAS # 127695 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wea suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFONIC ACID SODIUM A B C D CAS # 2039965 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Silicon oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Handle and store under nitrogen. Store at 2-8░C SPECIAL REQUIREMENTS Handle and store under inert gas. Very hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFONYL CHLORIDE A B C D CAS # 7791255 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4 - LD50 mg/Kg INHALATION RISK INDEX <1 - LC50 875.9 . . . ROUTE OF EXPOSURE Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes burns. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 105.0 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Alcohols Avoid contact with metals., Amines FIRE EXTINGUISHER: Unsuitable: Do not use water. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. Incompatible Materials: Do not allow contact with water GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 34 37 Risk Statements: Reacts violently with water. Causes burns. Irritating to respiratory system. S: 26 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .4 ppm DOE Short Term Exposure Limit 1.25 ppm DOE Ceiling Limit 7.5 ppm Immediately Dangerous to Life and Health 15 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFONYLDIPHENOL (4,4'-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 80091 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4556.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and . toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFOPHTHALIC ACID TRISODIUM (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 3325084 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFOPROPYLPYRIDINIUM HYDROXIDE (1,3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 15471177 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 320 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFOSALICYLIC ACID DIHYDRATE (5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 5965833 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2450.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFOSALYCILIC ACID A B C D CAS # 59655833 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2450.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. TOXIC EMISSIONS WHEN BURNED: CTS CARBON DIOXIDE, DRY CHEMICAL POWDER OR TOXIC FUMES OF: CARB REACTIVE PROPERTIES MINOR AMOUNTS OF ACID CAUSE ACROLEIN TO POYLMERIZE WITH RELEASE OF HEAT.BENZYL ALCOHOL CONTAINING ACIDIC CONSTITUENTS AND DISSOLVED IRON WAS FOUND TOPOLYMERIZE WITH A RAPID TEMPERATURE INCREASE WHEN HEATED IN EXCESS OF100C.(AMINES, PYRIDINE, AND ALKALI HYDROXIDES ACT AS INHIBITORS AND PREVENTPOLYMERIZATION.) REACT VIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE. HIGHCONCENTRATIONS OF ACID REACT EXPLOSIVELY WITH NICKEL NITRIDE AND HEAT.INITIATE A FAST DECOMPOSITION OF SODIUM OZONATE. REACTS WITH THORIUMPHOSPHIDE TO RELEASE SPONTANEOUSLY FLAMMABLE PHSOPHINE. REACTS VIOLENTLY WITHTRI-ISO-BUTYL ALUMINUM. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFUR A B C D CAS # 7704349 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 4 - LD50 5000.0 mg/Kg INHALATION RISK INDEX 1.3 - LC50 1660.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Will not occur SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Dermatitis. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .810 mm Hg @ 20 °C FLASH POINT 334.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen sulfide gas REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 16 26 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .125 mg/m3 DOE Short Term Exposure Limit .4 mg/m3 DOE Ceiling Limit 2.5 mg/m3 Immediately Dangerous to Life and Health 12.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFUR DIOXIDE CAS # 7446095 DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C D . . G H . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 REPRODUCTIVE RISK INDEX 2.9 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 3 - LD50 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 . . 930.0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Can cause rapid suffocation. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Gas VAPOR PRESSURE 1694.3 mm Hg @ 20 °C SEGREGATION: SHELF # 3 STORAGE GROUP(S): i - CorrosiveorNon-Toxic Gas WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Zinc, Strong reducing agents, Strong oxidizing agents. FIRE EXTINGUISHER: Use water spray or fog nozzle to keep cylinder cool.Move cylinder away from fire if there is no risk. REACTIVE PROPERTIES HANDLING: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Cylinder temperature should not exceed 125░F (52░C)\. SPECIAL REQUIREMENTS Contents under pressure. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23-34 Risk Statements: Toxic by inhalation. Causes burns. S: 9-26-36/37/39-45 Safety Statements: Keep container in a well-ventilated place. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm OSHA Short Term Exposure Limit 5 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 2 ppm ACGIH Short Term Exposure Limit 5 ppm Immediately Dangerous to Life and Health US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .2 ppm 100 ppm DOE Short Term Exposure Limit .2 ppm DOE Ceiling Limit .75 ppm Immediately Dangerous to Life and Health 30 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFUR TRIOXIDE PYRIDINE COMPLEX A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 26412873 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: N MONOXIDENITROGEN OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFURIC ACID A B C D CAS # 7664939 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W ACUTE TOXICTY RISK INDEX 5 - LD50 2140.0 mg/Kg INHALATION RISK INDEX 1.7 - LC50 18.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. . Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Teeth. Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 1.6 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive f - Inorganic Acid (Non-Oxidizing) WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Do not allow contact with water, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 35 37 Risk Statements: Reacts violently with water. Causes severe burns. Irritating to respiratory system. S: 26 30 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Never add water to this product. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value .2 mg/m3 Immediately Dangerous to Life and Health 15 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .2 mg/m3 DOE Short Term Exposure Limit .2 mg/m3 DOE Ceiling Limit 8.7 mg/m3 Immediately Dangerous to Life and Health 160 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFURIC ACID A B C D CAS # 8014957 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . G 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Toxic if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Teeth. Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 1.6 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Do not allow contact with water, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Incompatible Materials: Do not allow contact with water SPECIAL REQUIREMENTS Very hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 35 37 Risk Statements: Reacts violently with water. Causes severe burns. Irritating to respiratory system. S: 26 30 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Never add water to this product. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .2 mg/m3 DOE Short Term Exposure Limit .2 mg/m3 DOE Ceiling Limit 8.7 mg/m3 Immediately Dangerous to Life and Health 160 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SULFUROUS ACID A B C D CAS # 7782992 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents, Zinc. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 20-34 Risk Statements: Harmful by inhalation. Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0125 mg/m3 DOE Short Term Exposure Limit .04 mg/m3 DOE Ceiling Limit .3 mg/m3 Immediately Dangerous to Life and Health 1.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUNSET YELLOW FCF A B C D CAS # 2783940 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Sodium oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUPELCLEAN ENVI-CHROM P A B C D CAS # 104219638 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.STORAGE: Keep tightly closed. Store in a cool dry place. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SUPEROXIDE DISMUTASE A B C CAS # 9054891 Special Carcinogen Human Terato\Repro Haz Highly Toxic E F G Dermal Hazard Corrosive Eye Damage I J K Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz D Inhalation Hazard H STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 4 0 INHALATION RISK INDEX <1 - LC50 L . . . Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Potentially biohazardous material. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fire conditions. Store at -20°C Keep container closed. Store under argon. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Store under argon. Store at -20░C SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SYRINGALDAZINE A B C D CAS # 14414325 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE CARBON DIOXIDE, DRY CHEMICAL POWDER OR NITROGEN OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. SYRINGALDEHYDE A B C D CAS # 134963 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible.