Study set with typical representative questions SI system of unit, precision, conversion, density Q: Given is density d= 2.22 g/mL . Desired conversion is to kg/m^3. Consider SigFigs. Atom, ion, isotope, basic knowledge about neutrons, protons and electrons Q: Find the number of electrons, protons and neutrons in 60 Co 2+. Nomenclature, ionic compounds, polyatomic ions, cations, anions, binary compounds. Q: What are the names of NaCl, CuCl2, N3O5, Na2SO4 Q: What is the formula of potassium chloride, cooper(I) chloride, dinitrogentetroxide Q: which one is not name correctly: dinitrogen teroxide N2O4, iron(iii) sulfate Fe2(SO4)3, nitrogen trifluoride NF3, aluminum trinitrate Al(NO3)3 Concept of amu, mole, molar mass, and conversions : atoms(ions) ->molecules(compounds) ->moles>mass Q : How many chlorine atoms are in 5g of CuCl2? Q: How many moles of CuCl2 are in 5g of CuCl2? Q: How many g (mass) is 2.344 10^26 compound units of CuCl2? Empirical formula from mass % and vice versa: Q: find empirical formula if 55% K, 15% P and 30% O Q: find % by mass of K3PO4 Electrolytes, conductivity, strong weak acids/base, ionic compounds, Q: Which is ionic compound, NH4Cl, CO2 ,I2 Q: Which is strongest electrolyte or conductor, SO2, HF, AgNO3 ? Solubility (using table) Q: Is SrSO4 soluble? Is CuS soluble? Is Ca(OH) 2 soluble ? Is Mg(OH)2 soluble? Q; Will Potassium acetate and hydrochloric acid produce a precipitate ? Ionic and net ionic equations (including solubility) Q: What is the net ionic equation of the reaction between CaCl2 and Na2CO3 Chemical reactions, balancing and quantitative aspects (equivalents) : finding moles or masses of products or reactants, limiting reactants and excess reactants Q: Balance a chemical reaction: C5H7O + O2 Q; If 26 g of oxygen gas reacts with excess hydrogen gass , how many moles of water are produced? Q: If 26 g of oxygen gas reacts with 26g of hydrogen gass , how many grams of water are produced Q; If 26 g of oxygen gas reacts with 26g of hydrogen gass , how many grams of hydrogen and how many of oxygen was left Chemical equations and stoichiometry in solution: M molarity, neutralization-titration-end point, dilution, concentration Q: What is the NO3 - concentration in 3. M solution of Al(NO3)3 Q: 5g of NaCl are dissolved in 250mL of water , what is the concentration M? Q; What is the concentration of Cl- in a solution made by dilution 250mL of 2M of FeCl3? Q: 20mL of H2SO4 is titrated to the end point (neutralized ) with 0.5 M solution of KOH. What is the concentration of H2SO4? Q; What is the concentration M of aqueous methanol when 0.2L of 2M solution is diluted to 0.8 L Electronic structure of atoms and the characteristics of electromagnetic fields –photons Q: What is the energy of a 420nm photon Q: What is the frequency of 420nm photon Q: Write down the eelectronic configuration of N, P and As Q: 1s22s22p63s23p63d3 is electron configuration of ..? Q: What are the rules for n, l, m, s? Apply to configurations Q: What is the electron screening? Q: Which of these has the largest size: K, F, ge, Rb , Br Q: Which of these has largest first ionization energy: Na, Al, Se, Cl and K. (How about the second?) Lewis structure, ionic , covalent bonds, lone/nonbonding pairs, Q: Write down the Lewis structures for SO2, H2SO4, IBr2, I3, NO3, SO3, H3PO4, C6H6, NF3, BF3, CO2 CHCl3, F2, XeF4, (add some more) Q Which of those violets octet rule and how Q; Count the number of double and single bonds, nonbonding pairs in the previous molecules Q: Cont the number of resonances in previous compounds Q: identify formal charges in those molecules, what can they help you with? Q: Find the molecular geometries (name them) for those compounds Q: Find the angles in these compounds Q; Find the hybridization for central atoms in these molecules Q: based on the found hybridization identify angles between bonds in these atoms Q Which of these molecules are polar? Q: Identify order of polarity for bonds they form using electronegativity data : Be, F, N, Mg Gas equation and its derivatives Q : find pressure of 1 mole of molecules if volume is22.4L and temperature is 25C Q: A balloon has volume of 5L at 50C and pressure of 200torr, what is the temperature if the volume was reduced to 3L at constant pressure? Q: in a gas mixture total pressure is 9 atm and partial pressures of He an Ne are 1.5 and 2 atm. What is the mole fraction of Ar? Q: Temperature of a gas is 22C , pressure 600torr and density 2g/L . What is the molar mass of that gas? Q: CH4 effuses in 500s and CO2 under the same condition will effuse in ………s ? Solutions and liquids Q: Which of the following pairs will stronger intermolecular bond: Xe or Rn, H2O or CH4, CO or CO2 Q: Find examples of two different molecules /compounds that are attracted by a) dipole force, b) hydrogen bond, C) ionic-dipole force, d ) induced dispersion force only Phase diagrams: Q: Identify all major points in the phase diagram of H2O, CO2